Y 39

Yttrium (Y)

transition-metal
Period: 5 Group: 3 Block: s

Solid

Standard Atomic Weight

88.90584 u

Electron configuration

[Kr] 5s2 4d1

Melting point

1521.85 °C (1795 K)

Boiling point

3344.85 °C (3618 K)

Density

4470 kg/m³

Oxidation states

0, +1, +2, +3

Electronegativity (Pauling)

1.22

Ionization energy (1st)

Discovery year

1794

Atomic radius

180 pm

Details

Name origin From the Swedish village, Ytterby, where one of its minerals was first found.
Discovery country Finland
Discoverers Johann Gadolin

Yttrium is a silvery transition metal grouped with the rare-earth elements because it commonly occurs with lanthanides and forms predominantly trivalent cations. Its chemistry is close to the heavier lanthanides, especially holmium and erbium, rather than to scandium. Although not itself a lanthanide, yttrium is a key component of phosphors, ceramics, lasers, and high-temperature oxide materials.

Yttrium has a silver-metallic luster and is relatively stable in air. Turnings of the metal, however, ignite in air if their temperature exceeds 400°C. Finely divided yttrium is very unstable in air.

The name derives from the Swedish village of Ytterby where the mineral gadolinite was found. In 1794, the Finnish chemist Johan Gadolin discovered yttrium in the mineral ytterbite, which was later renamed gadolinite for Gadolin. Gadolin originally called the element ytterbium after ytterbite. The name was subsequently shortened to yttrium, and later another element was given the name ytterbium.

Yttrium was discovered by Johan Gadolin, a Finnish chemist, while analyzing the composition of the mineral gadolinite ((Ce, La, Nd, Y)2FeBe2Si2O10) in 1789. Gadolinite, which was named for Johan Gadolin, was discovered several years earlier in a quarry near the town of Ytterby, Sweden. Today, yttrium is primarily obtained through an ion exchange process from monazite sand ((Ce, La, Th, Nd, Y)PO4), a material rich in rare earth elements.

Namded after Ytterby, a village in Sweden near Vauxholm. Yttria earth containing yttrium was discovered by Gadolin in 1794. Ytterby is the site of a quarry which yielded many unusual minerals containing rare earths and other elements. This small town, near Stockholm, bears the honor of giving names to erbium, terbium, and ytterbium as well as yttrium.

In 1843 Mosander showed that yttira could be resolved into the oxides (or earths) of three elements. The name yttria was reserved for the most basic one; the others were named erbia and terbia.

Images

Properties

Physical

Atomic radius (empirical) 180 pm
Covalent radius 190 pm
Van der Waals radius 219 pm
Metallic radius 162 pm
Density
Molar volume 0.0198 L/mol
Phase at STP solid
Melting point 1521.85 °C
Boiling point 3344.85 °C
Specific heat capacity 0.298 J/(g·K)
Molar heat capacity 26.53 J/(mol·K)
Crystal structure hcp

Chemical

Electronegativity (Pauling) 1.22
Electronegativity (Allen) 1.12
Electron affinity
Ionization energy (1st)
Ionization energy (2nd)
Ionization energy (3rd)
Ionization energy (4th)
Ionization energy (5th)
Oxidation states 0, +1, +2, +3
Valence electrons 3
Electron configuration
Electron configuration (semantic)

Thermodynamic

Heat of fusion 0.11836037 eV
Heat of vaporization 3.762243 eV
Heat of sublimation 4.394465 eV
Heat of atomization 4.394465 eV
Atomization enthalpy

Nuclear

Stable isotopes 1
Discovery year 1794

Abundance

Abundance (Earth's crust) 33 mg/kg
Abundance (ocean)

Reactivity

N/A

Crystal Structure

Lattice constant a 365 pm

Electronic Structure

Electrons per shell 2, 8, 18, 9, 2

Identifiers

CAS number 7440-65-5
Term symbol
InChI InChI=1S/Y
InChI Key VWQVUPCCIRVNHF-UHFFFAOYSA-N

Electron Configuration Measured

Ion charge
Protons 39
Electrons 39
Charge Neutral
Configuration Y: 4d¹ 5s²
Electron configuration
Measured
[Kr] 4d¹ 5s²
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹ 5s²
Orbital diagram
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
2/2
4d
1/10 1↑
Total electrons: 39 Unpaired: 1 ?

Atomic model

Protons 39
Neutrons 50
Electrons 39
Mass number 89
Stability Stable

Isotopes change neutron count, mass, and stability — not the electron configuration of a neutral atom.

Schematic atomic model, not to scale.

Atomic Fingerprint

Emission / Absorption Spectrum

25 / 50 (50 with intensity)
Measured
Emission Visible: 380–750 nm

Isotope Distribution

Monoisotopic element
Only naturally occurring isotope: 89 — 100.0000%
89100.0000%Mass numberNatural abundance (%)
Mass numberAtomic mass (u)Natural abundanceHalf-life
89 Stable88.9058403 ± 0.0000024100.0000%Stable
Measured

Phase / State

1 atm / 101.325 kPa
Solid 25 °C (298.15 K)

Reason: 1496.8 °C below melting point (1521.85 °C)

Melting point 1521.85 °C
Boiling point 3344.85 °C
Below melting by 1496.8 °C
0 K Current temperature: 25 °C 6000 K
Phase timeline

Schematic, not to scale

Solid
Liquid
Gas
Melting
Boiling
25°C
Solid
Liquid
Gas
Current

Phase transition points

Melting point Literature
1521.85 °C
Boiling point Literature
3344.85 °C
Current phase Calculated
Solid

Transition energies

Heat of fusion Literature
0.11836037 eV

Energy required to melt 1 mol at melting point

Heat of vaporization Literature
3.762243 eV

Energy required to vaporize 1 mol at boiling point

Heat of sublimation Literature
4.394465 eV

Energy required to sublime 1 mol at sublimation point

Density

Reference density Literature
4470 kg/m³

At standard conditions

Current density Calculated
4470 kg/m³

At standard conditions

Atomic Spectra

Showing 10 of 39 Atomic Spectra. Sorted by ion charge (ascending).

Lines Holdings ?

IonChargeTotal linesTransition probabilitiesLevel designations
Y I 0361189351
Y II +111666116
Y III +211300
Y IV +32500
Y V +4632632632
Y VII +6168168168
Y VIII +7707070
NIST Lines Holdings →

Levels Holdings ?

IonChargeLevels
Y I 0194
Y II +1249
Y III +251
Y IV +3130
Y V +4114
Y VI +52
Y VII +657
Y VIII +733
Y IX +82
Y X +92
NIST Levels Holdings →
39 Y 88.90584

Yttrium — Atomic Orbital Visualizer

[Kr]5s24d1
Energy levels 2 8 18 9 2
Oxidation states 0, +1, +2, +3
HOMO 4d n=4 · l=2 · m=-2
Yttrium — Atomic Orbital Visualizer Preview
Three.js loads only on request
39 Y 88.90584

Yttrium — Crystal Structure Visualizer

Primitive Hexagonal · Pearson hP2
Experimental
Pearson hP2
Coord. № 12
Packing 75.071%
Yttrium — Crystal Structure Visualizer Preview
Three.js loads only on request

Ionic Radii

ChargeCoordinationSpinRadius
+36N/A90 pm
+37N/A96 pm
+38N/A101.89999999999999 pm
+39N/A107.5 pm

Compounds

Y
88.906 u
Y
89.907 u
Y+3
88.906 u
Y
90.907 u
Y
87.909 u
Y
85.915 u
Y
86.911 u
Y
88.906 u
Y
92.910 u
Y
91.909 u
Y
94.913 u
Y
93.912 u
Y+3
89.907 u
Y+3
88.906 u
Y
98.924 u
Y+3
85.915 u

Isotopes (1)

Natural yttrium contains one isotope, 89Y. Nineteen other unstable isotopes have been characterized.

Mass numberAtomic mass (u)Natural abundanceHalf-lifeDecay mode
89 Stable88.9058403 ± 0.0000024100.0000%Stable
stable
89 Stable
Atomic mass (u) 88.9058403 ± 0.0000024
Natural abundance 100.0000%
Half-life Stable
Decay mode
stable

Spectral Lines

Showing 50 of 266 Spectral Lines. Only spectral lines with measured intensity are shown by default.

Wavelength (nm)IntensityIon stageTypeTransitionAccuracySource
410.23691 nm9900Y Iemission4d.5s2 a 2D → 4d.5s.(1D).5p y 2F*MeasuredNIST
407.735998 nm9400Y Iemission4d.5s2 a 2D → 4d.5s.(1D).5p y 2F*MeasuredNIST
412.829876 nm8900Y Iemission4d.5s2 a 2D → 4d.5s.(1D).5p y 2D*MeasuredNIST
414.28358 nm7500Y Iemission4d.5s2 a 2D → 4d.5s.(1D).5p y 2D*MeasuredNIST
404.76281 nm2400Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p y 2P*MeasuredNIST
416.750671 nm2400Y Iemission4d.5s2 a 2D → 4d.5s.(1D).5p y 2F*MeasuredNIST
423.5934 nm2200Y Iemission4d.5s2 a 2D → 4d.5s.(1D).5p y 2D*MeasuredNIST
408.37033 nm2000Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p y 2P*MeasuredNIST
417.41339 nm2000Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p y 2P*MeasuredNIST
464.368813 nm2000Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p z 2F*MeasuredNIST
467.48486 nm2000Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p z 2F*MeasuredNIST
619.17183 nm1200Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p z 2D*MeasuredNIST
643.50036 nm1000Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p z 2D*MeasuredNIST
403.982219 nm940Y Iemission4d.5s2 a 2D → 4d.5s.(1D).5p y 2D*MeasuredNIST
452.72342 nm890Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4D*MeasuredNIST
483.9861 nm770Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4F*MeasuredNIST
552.75472 nm740Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p z 4G*MeasuredNIST
546.6464 nm710Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p z 4G*MeasuredNIST
558.18694 nm620Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p z 4G*MeasuredNIST
563.01301 nm560Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p z 4G*MeasuredNIST
484.56655 nm550Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4F*MeasuredNIST
450.59441 nm500Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4D*MeasuredNIST
452.77815 nm440Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4D*MeasuredNIST
476.09753 nm410Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p z 2F*MeasuredNIST
485.26766 nm410Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4F*MeasuredNIST
485.98428 nm330Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4F*MeasuredNIST
425.11994 nm300Y Iemission4d.5s.(3D).5p z 4F* → 4d.5s.(3D).5d e 4GMeasuredNIST
448.74634 nm300Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4D*MeasuredNIST
550.3466 nm300Y Iemission4d2.(3F).5s a 2F → 4d2.(3F).5p x 2F*MeasuredNIST
622.25784 nm300Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p z 2D*MeasuredNIST
543.82242 nm190Y Iemission4d2.(3F).5s a 2F → 4d2.(3F).5p x 2D*MeasuredNIST
546.62434 nm190Y Iemission4d.5s.(3D).5p z 4F* → 4d.5s.(3D).6s e 4DMeasuredNIST
679.37029 nm190Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p z 4F*MeasuredNIST
524.08001 nm181Y Iemission4d2.(1G).5s a 2G → 4d2.(1G).5p z 2H*MeasuredNIST
447.69471 nm180Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p x 2F*MeasuredNIST
469.67994 nm180Y Iemission4d2.(1D).5s b 2D → 4d2.(1D).5p w 2F*MeasuredNIST
479.92999 nm180Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4F*MeasuredNIST
513.51993 nm180Y Iemission4d2.(1G).5s a 2G → 4d2.(1G).5p z 2H*MeasuredNIST
557.74153 nm180Y Iemission4d2.(3F).5s a 2F → 4d2.(3F).5p z 2G*MeasuredNIST
447.57178 nm170Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4D*MeasuredNIST
472.8516 nm170Y Iemission5s2.5p z 2P* → 5s2.6s e 2SMeasuredNIST
478.68762 nm170Y Iemission4d2.(3P).5s a 4P → 4d2.(3P).5p x 4D*MeasuredNIST
421.77985 nm160Y Iemission5s2.5p z 2P* → 5s2.(2D).5d e 2DMeasuredNIST
447.74436 nm160Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4D*MeasuredNIST
475.2787 nm160Y Iemission4d2.(3F).5s a 2F → 4d2.(3P).5p x 4D*MeasuredNIST
570.67133 nm160Y Iemission4d.5s.(3D).5p z 4F* → 4d.5s.(3D).6s e 4DMeasuredNIST
492.18769 nm150Y Iemission5s2.5p z 2P* → 5s2.6s e 2SMeasuredNIST
613.84349 nm150Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p z 4D*MeasuredNIST
668.75669 nm150Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p z 4F*MeasuredNIST
465.37837 nm140Y Iemission4d2.(1D).5s b 2D → 4d2.(3P).5p y 4P*MeasuredNIST

Extended Properties

Covalent Radii (Extended)

Covalent radius (Pyykkö)  
Covalent radius (Pyykkö, double)  
Covalent radius (Pyykkö, triple)  

Van der Waals Radii

Batsanov  
Alvarez  
UFF  
MM3  

Atomic & Metallic Radii

Atomic radius (Rahm)  
Metallic radius (C12)  

Numbering Scales

Mendeleev
Pettifor
Glawe

Electronegativity Scales

Ghosh
Miedema
Gunnarsson–Lundqvist
Robles–Bartolotti

Polarizability & Dispersion

Dipole polarizability  
Dipole polarizability (unc.)  
C₆ (Gould–Bučko)  

Chemical Affinity

Proton affinity  
Gas basicity  

Miedema Parameters

Miedema molar volume  
Miedema electron density

Supply Risk & Economics

Production concentration
Relative supply risk
Reserve distribution
Political stability (top producer)
Political stability (top reserve)

Phase Transitions & Allotropes

Melting point1795.15 K
Boiling point3618.15 K

Oxidation State Categories

+2 extended
+1 extended
+3 main
0 extended

Advanced Reference Data

Screening Constants (10)
nOrbitalσ
1s0.8244
2p3.9968
2s10.3778
3d13.6029
3p15.9075
3s15.4485
4d23.0416
4p26.2544
4s24.7364
5s32.744
Crystal Radii Detail (4)
ChargeCNSpinrcrystal (pm)Origin
3VI104from r^3 vs V plots,
3VII110
3VIII115.9from r^3 vs V plots,
3IX121.5from r^3 vs V plots,
Isotope Decay Modes (60)
IsotopeModeIntensity
75B+
75B+p
75p
76B+
76p
76B+p
77B+100%
77B+p
77p
78B+100%
X‑ray Scattering Factors (619)
Energy (eV)f₁f₂
102.26036
10.16172.25621
10.32612.25207
10.49312.24793
10.66282.2438
10.83532.23968
11.01052.23344
11.18862.21122
11.36962.18921
11.55352.16742

Additional Data

Sources

Sources of this element.

Yttrium occurs in nearly all of the rare-earth minerals. Analysis of lunar rock samples obtained during the Apollo missions show a relatively high yttrium content.

It is recovered commercially from monazite sand, which contains about 3%, and from bastnasite, which contains about 0.2%. Wohler obtained the impure element in 1828 by reduction of the anhydrous chloride with potassium. The metal is now produced commercially by reduction of the fluoride with calcium metal. It can also be prepared by other techniques.

References (1)

References

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
Y

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Yttrium

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

License note: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Yttrium

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

License note: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Yttrium

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Yttrium

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Yttrium

This section provides all form of data related to element Yttrium.

9 PubChem Elements
Yttrium

The element property data was retrieved from publications.

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Data verified:

Content is reviewed against latest scientific data.