Ra 88

Radium (Ra)

alkaline-earth-metal
Period: 7 Group: 2 Block: s

Solid

Standard Atomic Weight

[226]

Electron configuration

[Rn] 7s2

Melting point

699.85 °C (973 K)

Boiling point

1139.85 °C (1413 K)

Density

5000 kg/m³

Oxidation states

+2

Electronegativity (Pauling)

0.9

Ionization energy (1st)

Discovery year

1898

Atomic radius

215 pm

Details

Name origin Latin: radius (ray).
Discovery country France
Discoverers Pierre and Marie Curie

Radium is a heavy alkaline earth metal and the element below barium in group 2. All of its isotopes are radioactive; ²²⁶Ra, with a half-life of about 1600 years, is the best known and occurs in uranium ores as part of the ²³⁸U decay series. Its chemistry is dominated by the Ra²⁺ ion, which resembles Ba²⁺ but is less commonly handled because intense radioactivity limits direct study.

Radium is obtained commercially as bromide and chloride; it is doubtful if any appreciable stock of the isolated element now exists. The pure metal is brilliant white when freshly prepared, but blackens on exposure to air, probably due to formation of the nitride. It exhibits luminescence, as do its slats; it decomposes in water and is somewhat more volatile than barium. It is a member of the alkaline-earth group of metals. Radium imparts a carmine red color to a flame. Radium emits alpha, beta, and gamma rays and when mixed with beryllium produce neutrons. One gram of 226Ra undergoes 3.7 x 1010 disintegrations per second. The curie is defined as that amount of radioactivity which has the same disintegration rate as 1 g of 226Ra. Twenty five isotopes are now known; radium 226, the common isotope, has a half-life of 1600 years.

Radium was discovered by Marie Sklodowska Curie, a Polish chemist, and Pierre Curie, a French chemist, in 1898. Marie Curie obtained radium from pitchblende, a material that contains uranium, after noticing that unrefined pitchblende was more radioactive than the uranium that was separated from it. She reasoned that pitchblende must contain at least one other radioactive element. Curie needed to refine several tons of pitchblende in order to obtain tiny amounts of radium and polonium, another radioactive element discovered by Curie. One ton of uranium ore contains only about 0.14 grams of radium. Today, radium can be obtained as a byproduct of refining uranium and is usually sold as radium chloride (RaCl2) or radium bromide (RaBr2) and not as a pure material. Radium's most stable isotope, radium-226, has a half-life of about 1600 years. It decays into radon-222 through alpha decay or into lead-212 by ejecting a carbon-14 nucleus.

Radium was discovered in 1898 by Madame Curie in the pitchblende or uraninite of North Bohemia, where it occurs. There is about 1 g of radium in 7 tons of pitchblende. The element was isolated in 1911 by Mme. Curie and Debierne by the electrolysis of a solution of pure radium chloride employing a mercury cathode; on distillation in an atmosphere of hydrogen, this amalgam yielded the pure metal.

Images

Properties

Physical

Atomic radius (empirical) 215 pm
Covalent radius 221 pm
Van der Waals radius 283 pm
Density
Molar volume 0.045 L/mol
Phase at STP solid
Melting point 699.85 °C
Boiling point 1139.85 °C

Chemical

Electronegativity (Pauling) 0.9
Electronegativity (Allen) 0.89
Electron affinity
Ionization energy (1st)
Ionization energy (2nd)
Ionization energy (3rd)
Ionization energy (4th)
Ionization energy (5th)
Oxidation states +2
Valence electrons 2
Electron configuration
Electron configuration (semantic)

Thermodynamic

Heat of fusion 0.08291444 eV
Heat of vaporization 1.171167 eV
Heat of sublimation 1.647925 eV
Heat of atomization 1.647925 eV
Atomization enthalpy

Nuclear

Stable isotopes 0
Mass number (most stable) 226
Discovery year 1898

Abundance

Abundance (Earth's crust) 9.000e-7 mg/kg
Abundance (ocean)

Reactivity

N/A

Crystal Structure

N/A

Electronic Structure

Electrons per shell 2, 8, 18, 32, 18, 8, 2

Identifiers

CAS number 7440-14-4
Term symbol
InChI InChI=1S/Ra
InChI Key HCWPIIXVSYCSAN-UHFFFAOYSA-N

Electron Configuration Measured

Ion charge
Protons 88
Electrons 88
Charge Neutral
Configuration Ra: 7s²
Electron configuration
Measured
[Rn] 7s²
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d¹⁰ 6s² 6p⁶ 7s²
Orbital diagram
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
2/2
4d
10/10
5p
6/6
6s
2/2
4f
14/14
5d
10/10
6p
6/6
7s
2/2
Total electrons: 88 Unpaired: 0

Atomic model

Protons 88
Neutrons 128
Electrons 88
Mass number 216
Stability Radioactive

Isotopes change neutron count, mass, and stability — not the electron configuration of a neutral atom.

Schematic atomic model, not to scale.

Atomic Fingerprint

Emission / Absorption Spectrum

25 / 50 (50 with intensity)
Measured
Emission Visible: 380–750 nm

Isotope Distribution

No stable isotopes.

Mass numberAtomic mass (u)Natural abundanceHalf-life
206 Radioactive206.003828 ± 0.000019N/A240 ms
205 Radioactive205.006268 ± 0.000076N/A220 ms
216 Radioactive216.0035334 ± 0.0000094N/A172 ns
231 Radioactive231.041027 ± 0.000012N/A104 seconds
230 Radioactive230.037055 ± 0.000011N/A93 minutes
Measured

Phase / State

1 atm / 101.325 kPa
Solid 25 °C (298.15 K)

Reason: 674.9 °C below melting point (699.85 °C)

Melting point 699.85 °C
Boiling point 1139.85 °C
Below melting by 674.9 °C
0 K Current temperature: 25 °C 6000 K
Phase timeline

Schematic, not to scale

Solid
Liquid
Gas
Melting
Boiling
25°C
Solid
Liquid
Gas
Current

Phase transition points

Melting point Literature
699.85 °C
Boiling point Literature
1139.85 °C
Current phase Calculated
Solid

Transition energies

Heat of fusion Literature
0.08291444 eV

Energy required to melt 1 mol at melting point

Heat of vaporization Literature
1.171167 eV

Energy required to vaporize 1 mol at boiling point

Heat of sublimation Literature
1.647925 eV

Energy required to sublime 1 mol at sublimation point

Density

Reference density Literature
5000 kg/m³

At standard conditions

Current density Calculated
5000 kg/m³

At standard conditions

Atomic Spectra

Showing 10 of 88 Atomic Spectra. Sorted by ion charge (ascending).

Lines Holdings ?

IonChargeTotal linesTransition probabilitiesLevel designations
Ra I 014319112
Ra II +163963
NIST Lines Holdings →

Levels Holdings ?

IonChargeLevels
Ra I 082
Ra II +137
Ra III +22
Ra IV +32
Ra V +42
Ra VI +52
Ra VII +62
Ra VIII +72
Ra IX +82
Ra X +92
NIST Levels Holdings →
88 Ra 226

Radium — Atomic Orbital Visualizer

[Rn]7s2
Energy levels 2 8 18 32 18 8 2
Oxidation states +2
HOMO 7s n=7 · l=0 · m=0
Radium — Atomic Orbital Visualizer Preview
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88 Ra 226

Radium — Crystal Structure Visualizer

Crystal structure data not available

Ionic Radii

ChargeCoordinationSpinRadius
+28N/A148 pm
+212N/A170 pm

Compounds

Ra
226.025 u
Ra
226.025 u
Ra
228.031 u
Ra
224.020 u
Ra
223.018 u
Ra
225.024 u
Ra
227.029 u
Ra
222.015 u
Ra
220.011 u
Ra
230.037 u
Ra
212.000 u
Ra
233.048 u

Isotopes (5)

Mass numberAtomic mass (u)Natural abundanceHalf-lifeDecay mode
206 Radioactive206.003828 ± 0.000019N/A240 ms
α ≈100%β+ ?
205 Radioactive205.006268 ± 0.000076N/A220 ms
α ≈100%β+ ?
216 Radioactive216.0035334 ± 0.0000094N/A172 ns
α =100%ε<1e-8%
231 Radioactive231.041027 ± 0.000012N/A104 seconds
β- =100%
230 Radioactive230.037055 ± 0.000011N/A93 minutes
β- =100%
206 Radioactive
Atomic mass (u) 206.003828 ± 0.000019
Natural abundance N/A
Half-life 240 ms
Decay mode
α ≈100%β+ ?
205 Radioactive
Atomic mass (u) 205.006268 ± 0.000076
Natural abundance N/A
Half-life 220 ms
Decay mode
α ≈100%β+ ?
216 Radioactive
Atomic mass (u) 216.0035334 ± 0.0000094
Natural abundance N/A
Half-life 172 ns
Decay mode
α =100%ε<1e-8%
231 Radioactive
Atomic mass (u) 231.041027 ± 0.000012
Natural abundance N/A
Half-life 104 seconds
Decay mode
β- =100%
230 Radioactive
Atomic mass (u) 230.037055 ± 0.000011
Natural abundance N/A
Half-life 93 minutes
Decay mode
β- =100%

Spectral Lines

Showing 50 of 90 Spectral Lines. Only spectral lines with measured intensity are shown by default.

Wavelength (nm)IntensityIon stageTypeTransitionAccuracySource
381.44219 nm200Ra IIemission7s 2S → 7p 2P*MeasuredNIST
468.22394 nm100Ra IIemission7s 2S → 7p 2P*MeasuredNIST
482.59281 nm100Ra Iemission7s2 1S → 7s.7p 1P*MeasuredNIST
566.0812 nm50Ra Iemission7s.6d 3D → 6d.7p 3F*MeasuredNIST
714.12167 nm50Ra Iemission7s2 1S → 7s.7p 3P*MeasuredNIST
453.3111 nm30Ra IIemission7p 2P* → 8s 2SMeasuredNIST
620.0304 nm30Ra Iemission7s.6d 3D → 6d.7p 3F*MeasuredNIST
443.6259 nm20Ra IIemission7p 2P* → 7d 2DMeasuredNIST
540.0231 nm20Ra Iemission7s.6d 3D → 6d.7p 3D*MeasuredNIST
540.6796 nm20Ra Iemission7s.6d 3D → 6d.7p 3D*MeasuredNIST
555.5852 nm20Ra Iemission7s.7p 3P* → 7s.7d 3DMeasuredNIST
581.3628 nm20Ra IIemission7p 2P* → 8s 2SMeasuredNIST
644.62 nm20Ra Iemission7s.7p 3P* → 7s.7d 3DMeasuredNIST
648.7319 nm20Ra Iemission7s.6d 3D → 6d.7p 3F*MeasuredNIST
698.0232 nm20Ra Iemission7s.6d 3D → 6d.7p 3F*MeasuredNIST
711.8486 nm20Ra Iemission7s.6d 3D → 6d.7p 3F*MeasuredNIST
722.5166 nm20Ra Iemission7s.6d 1D → 6d.7p 1D*MeasuredNIST
485.6071 nm10Ra Iemission7s.6d 3D → 7s.5f 3F*MeasuredNIST
485.942 nm10Ra IIemission5f 2F* → 6g 2GMeasuredNIST
492.752 nm10Ra IIemission5f 2F* → 6g 2GMeasuredNIST
520.5948 nm10Ra Iemission7s.6d 3D → 6d.7p 3D*MeasuredNIST
528.3277 nm10Ra Iemission7s.7p 3P* → 7s.7d 3DMeasuredNIST
532.029 nm10Ra Iemission7s.6d 3D → 6d.7p 3D*MeasuredNIST
539.9784 nm10Ra Iemission7s.6d 3D → 6d.7p 3D*MeasuredNIST
550.1985 nm10Ra Iemission7s.7p 3P* → 7p2? 3PMeasuredNIST
555.3574 nm10Ra Iemission7s.7p 3P* → 7s.7d 3DMeasuredNIST
561.6661 nm10Ra Iemission7s.6d 3D → 6d.7p 3D*MeasuredNIST
633.6899 nm10Ra Iemission7s.6d 1D → 7s.8p 1P*MeasuredNIST
659.3341 nm10Ra IIemission5f 2F* → 5g 2GMeasuredNIST
671.932 nm10Ra IIemission5f 2F* → 5g 2GMeasuredNIST
731.0269 nm10Ra Iemission7s.7p 3P* → 7s.8s 3SMeasuredNIST
419.4091 nm8Ra IIemission5f 2F* → 7g 2GMeasuredNIST
424.472 nm8Ra IIemission5f 2F* → 7g 2GMeasuredNIST
464.1284 nm8Ra Iemission7s.6d 3D → 7s.5f 3F*MeasuredNIST
469.9272 nm8Ra Iemission7s.6d 3D → 7s.5f 3F*MeasuredNIST
548.215 nm8Ra Iemission7s.6d 3D → 6d.7p 3D*MeasuredNIST
508.1036 nm6Ra Iemission7s.6d 3D → 6d.7p 3P*MeasuredNIST
566.165 nm6Ra IIemission8p 2P* → 9d 2DMeasuredNIST
389.455 nm5Ra IIemission5f 2F* → 8g 2GMeasuredNIST
497.179 nm5Ra Iemission7s.6d 3D → 6d.7p 3P*MeasuredNIST
504.154 nm5Ra Iemission7s.6d 3D → 6d.7p 3P*MeasuredNIST
560.143 nm5Ra Iemission7s.6d 3D → 7s.8p 3P*MeasuredNIST
577.824 nm5Ra Iemission7s.6d 1D → 6d.7p 3P*MeasuredNIST
579.5745 nm5Ra Iemission7s.7p 3P* → 7p2? 3PMeasuredNIST
581.1588 nm5Ra Iemission7s.6d 3D → 6d.7p 1D*MeasuredNIST
616.7051 nm5Ra Iemission7s.6d 3D → 6d.7p 1D*MeasuredNIST
707.79042 nm5Ra IIemission6d 2D → 7p 2P*MeasuredNIST
417.798 nm4Ra Iemission7s.6d 3D → 7s.6f 3F*MeasuredNIST
430.5 nm4Ra Iemission7s.6d 3D → 7s.6f 3F*MeasuredNIST
490.3263 nm4Ra Iemission7s.6d 3D → 6d.7p 3P*MeasuredNIST

Extended Properties

Covalent Radii (Extended)

Covalent radius (Pyykkö)  
Covalent radius (Pyykkö, double)  
Covalent radius (Pyykkö, triple)  

Van der Waals Radii

Truhlar  
UFF  
MM3  

Atomic & Metallic Radii

Atomic radius (Rahm)  

Numbering Scales

Mendeleev
Pettifor
Glawe

Electronegativity Scales

Ghosh

Polarizability & Dispersion

Dipole polarizability  
Dipole polarizability (unc.)  

Phase Transitions & Allotropes

Melting point969.15 K

Oxidation State Categories

+2 main

Advanced Reference Data

Crystal Radii Detail (2)
ChargeCNSpinrcrystal (pm)Origin
2VIII162from r^3 vs V plots,
2XII184from r^3 vs V plots,
Isotope Decay Modes (55)
IsotopeModeIntensity
201A100%
202A100%
203A100%
203B+
204A100%
204B+
205A100%
205B+
206A100%
206B+
X‑ray Scattering Factors (516)
Energy (eV)f₁f₂
100.04162
10.16170.04479
10.32610.0482
10.49310.05188
10.66280.05584
10.83530.0601
11.01060.06468
11.18860.06961
11.36960.07492
11.55350.08102

Additional Data

Sources

Sources of this element.

Originally, radium was obtained from the rich pitchblende ore found in Joachimsthal, Bohemia. The carnotite sands of Colorado furnish some radium, but richer ores are found in the Republic of Zaire and the Great Lake region of Canada. Radium is present in all uranium minerals, and could be extracted, if desired, from the extensive wastes of uranium processing. Large uranium deposits are located in Ontario, New Mexico, Utah, Australia, and elsewhere.

References (1)

References

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
Ra

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Radium

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

License note: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Radium

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

License note: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Radium

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Radium

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Radium

This section provides all form of data related to element Radium.

9 PubChem Elements
Radium

The element property data was retrieved from publications.

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