Radium (Ra)
alkaline-earth-metalSolid
Standard Atomic Weight
[226]Electron configuration
[Rn] 7s2Melting point
699.85 °C (973 K)Boiling point
1139.85 °C (1413 K)Density
5000 kg/m³Oxidation states
+2Electronegativity (Pauling)
0.9Ionization energy (1st)
Discovery year
1898Atomic radius
215 pmDetails
Radium is a heavy alkaline earth metal and the element below barium in group 2. All of its isotopes are radioactive; ²²⁶Ra, with a half-life of about 1600 years, is the best known and occurs in uranium ores as part of the ²³⁸U decay series. Its chemistry is dominated by the Ra²⁺ ion, which resembles Ba²⁺ but is less commonly handled because intense radioactivity limits direct study.
Radium is obtained commercially as bromide and chloride; it is doubtful if any appreciable stock of the isolated element now exists. The pure metal is brilliant white when freshly prepared, but blackens on exposure to air, probably due to formation of the nitride. It exhibits luminescence, as do its slats; it decomposes in water and is somewhat more volatile than barium. It is a member of the alkaline-earth group of metals. Radium imparts a carmine red color to a flame. Radium emits alpha, beta, and gamma rays and when mixed with beryllium produce neutrons. One gram of 226Ra undergoes 3.7 x 1010 disintegrations per second. The curie is defined as that amount of radioactivity which has the same disintegration rate as 1 g of 226Ra. Twenty five isotopes are now known; radium 226, the common isotope, has a half-life of 1600 years.
Radium was discovered by Marie Sklodowska Curie, a Polish chemist, and Pierre Curie, a French chemist, in 1898. Marie Curie obtained radium from pitchblende, a material that contains uranium, after noticing that unrefined pitchblende was more radioactive than the uranium that was separated from it. She reasoned that pitchblende must contain at least one other radioactive element. Curie needed to refine several tons of pitchblende in order to obtain tiny amounts of radium and polonium, another radioactive element discovered by Curie. One ton of uranium ore contains only about 0.14 grams of radium. Today, radium can be obtained as a byproduct of refining uranium and is usually sold as radium chloride (RaCl2) or radium bromide (RaBr2) and not as a pure material. Radium's most stable isotope, radium-226, has a half-life of about 1600 years. It decays into radon-222 through alpha decay or into lead-212 by ejecting a carbon-14 nucleus.
Radium was discovered in 1898 by Madame Curie in the pitchblende or uraninite of North Bohemia, where it occurs. There is about 1 g of radium in 7 tons of pitchblende. The element was isolated in 1911 by Mme. Curie and Debierne by the electrolysis of a solution of pure radium chloride employing a mercury cathode; on distillation in an atmosphere of hydrogen, this amalgam yielded the pure metal.
Images
Properties
Physical
Chemical
Thermodynamic
Nuclear
Abundance
Reactivity
N/A
Crystal Structure
N/A
Electronic Structure
Identifiers
Electron Configuration Measured
Ra: 7s²[Rn] 7s²1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d¹⁰ 6s² 6p⁶ 7s²Atomic model
Isotopes change neutron count, mass, and stability — not the electron configuration of a neutral atom.
Schematic atomic model, not to scale.
Atomic Fingerprint
Emission / Absorption Spectrum
Isotope Distribution
No stable isotopes.
| Mass number | Atomic mass (u) | Natural abundance | Half-life |
|---|---|---|---|
| 206 Radioactive | 206.003828 ± 0.000019 | N/A | 240 ms |
| 205 Radioactive | 205.006268 ± 0.000076 | N/A | 220 ms |
| 216 Radioactive | 216.0035334 ± 0.0000094 | N/A | 172 ns |
| 231 Radioactive | 231.041027 ± 0.000012 | N/A | 104 seconds |
| 230 Radioactive | 230.037055 ± 0.000011 | N/A | 93 minutes |
Phase / State
Reason: 674.9 °C below melting point (699.85 °C)
Schematic, not to scale
Phase transition points
Transition energies
Energy required to melt 1 mol at melting point
Energy required to vaporize 1 mol at boiling point
Energy required to sublime 1 mol at sublimation point
Density
At standard conditions
At standard conditions
Atomic Spectra
Showing 10 of 88 Atomic Spectra. Sorted by ion charge (ascending).
Lines Holdings ?
| Ion | Charge | Total lines | Transition probabilities | Level designations |
|---|---|---|---|---|
| Ra I | 0 | 143 | 19 | 112 |
| Ra II | +1 | 63 | 9 | 63 |
Levels Holdings ?
| Ion | Charge | Levels |
|---|---|---|
| Ra I | 0 | 82 |
| Ra II | +1 | 37 |
| Ra III | +2 | 2 |
| Ra IV | +3 | 2 |
| Ra V | +4 | 2 |
| Ra VI | +5 | 2 |
| Ra VII | +6 | 2 |
| Ra VIII | +7 | 2 |
| Ra IX | +8 | 2 |
| Ra X | +9 | 2 |
Crystal structure data not available
Ionic Radii
| Charge | Coordination | Spin | Radius |
|---|---|---|---|
| +2 | 8 | N/A | 148 pm |
| +2 | 12 | N/A | 170 pm |
Compounds
Isotopes (5)
| Mass number | Atomic mass (u) | Natural abundance | Half-life | Decay mode | |
|---|---|---|---|---|---|
| 206 Radioactive | 206.003828 ± 0.000019 | N/A | 240 ms | α ≈100%β+ ? | |
| 205 Radioactive | 205.006268 ± 0.000076 | N/A | 220 ms | α ≈100%β+ ? | |
| 216 Radioactive | 216.0035334 ± 0.0000094 | N/A | 172 ns | α =100%ε<1e-8% | |
| 231 Radioactive | 231.041027 ± 0.000012 | N/A | 104 seconds | β- =100% | |
| 230 Radioactive | 230.037055 ± 0.000011 | N/A | 93 minutes | β- =100% |
Spectral Lines
Showing 50 of 90 Spectral Lines. Only spectral lines with measured intensity are shown by default.
| Wavelength (nm) | Intensity | Ion stage | Type | Transition | Accuracy | Source | |
|---|---|---|---|---|---|---|---|
| 381.44219 nm | 200 | Ra II | emission | 7s 2S → 7p 2P* | Measured | NIST | |
| 468.22394 nm | 100 | Ra II | emission | 7s 2S → 7p 2P* | Measured | NIST | |
| 482.59281 nm | 100 | Ra I | emission | 7s2 1S → 7s.7p 1P* | Measured | NIST | |
| 566.0812 nm | 50 | Ra I | emission | 7s.6d 3D → 6d.7p 3F* | Measured | NIST | |
| 714.12167 nm | 50 | Ra I | emission | 7s2 1S → 7s.7p 3P* | Measured | NIST | |
| 453.3111 nm | 30 | Ra II | emission | 7p 2P* → 8s 2S | Measured | NIST | |
| 620.0304 nm | 30 | Ra I | emission | 7s.6d 3D → 6d.7p 3F* | Measured | NIST | |
| 443.6259 nm | 20 | Ra II | emission | 7p 2P* → 7d 2D | Measured | NIST | |
| 540.0231 nm | 20 | Ra I | emission | 7s.6d 3D → 6d.7p 3D* | Measured | NIST | |
| 540.6796 nm | 20 | Ra I | emission | 7s.6d 3D → 6d.7p 3D* | Measured | NIST | |
| 555.5852 nm | 20 | Ra I | emission | 7s.7p 3P* → 7s.7d 3D | Measured | NIST | |
| 581.3628 nm | 20 | Ra II | emission | 7p 2P* → 8s 2S | Measured | NIST | |
| 644.62 nm | 20 | Ra I | emission | 7s.7p 3P* → 7s.7d 3D | Measured | NIST | |
| 648.7319 nm | 20 | Ra I | emission | 7s.6d 3D → 6d.7p 3F* | Measured | NIST | |
| 698.0232 nm | 20 | Ra I | emission | 7s.6d 3D → 6d.7p 3F* | Measured | NIST | |
| 711.8486 nm | 20 | Ra I | emission | 7s.6d 3D → 6d.7p 3F* | Measured | NIST | |
| 722.5166 nm | 20 | Ra I | emission | 7s.6d 1D → 6d.7p 1D* | Measured | NIST | |
| 485.6071 nm | 10 | Ra I | emission | 7s.6d 3D → 7s.5f 3F* | Measured | NIST | |
| 485.942 nm | 10 | Ra II | emission | 5f 2F* → 6g 2G | Measured | NIST | |
| 492.752 nm | 10 | Ra II | emission | 5f 2F* → 6g 2G | Measured | NIST | |
| 520.5948 nm | 10 | Ra I | emission | 7s.6d 3D → 6d.7p 3D* | Measured | NIST | |
| 528.3277 nm | 10 | Ra I | emission | 7s.7p 3P* → 7s.7d 3D | Measured | NIST | |
| 532.029 nm | 10 | Ra I | emission | 7s.6d 3D → 6d.7p 3D* | Measured | NIST | |
| 539.9784 nm | 10 | Ra I | emission | 7s.6d 3D → 6d.7p 3D* | Measured | NIST | |
| 550.1985 nm | 10 | Ra I | emission | 7s.7p 3P* → 7p2? 3P | Measured | NIST | |
| 555.3574 nm | 10 | Ra I | emission | 7s.7p 3P* → 7s.7d 3D | Measured | NIST | |
| 561.6661 nm | 10 | Ra I | emission | 7s.6d 3D → 6d.7p 3D* | Measured | NIST | |
| 633.6899 nm | 10 | Ra I | emission | 7s.6d 1D → 7s.8p 1P* | Measured | NIST | |
| 659.3341 nm | 10 | Ra II | emission | 5f 2F* → 5g 2G | Measured | NIST | |
| 671.932 nm | 10 | Ra II | emission | 5f 2F* → 5g 2G | Measured | NIST | |
| 731.0269 nm | 10 | Ra I | emission | 7s.7p 3P* → 7s.8s 3S | Measured | NIST | |
| 419.4091 nm | 8 | Ra II | emission | 5f 2F* → 7g 2G | Measured | NIST | |
| 424.472 nm | 8 | Ra II | emission | 5f 2F* → 7g 2G | Measured | NIST | |
| 464.1284 nm | 8 | Ra I | emission | 7s.6d 3D → 7s.5f 3F* | Measured | NIST | |
| 469.9272 nm | 8 | Ra I | emission | 7s.6d 3D → 7s.5f 3F* | Measured | NIST | |
| 548.215 nm | 8 | Ra I | emission | 7s.6d 3D → 6d.7p 3D* | Measured | NIST | |
| 508.1036 nm | 6 | Ra I | emission | 7s.6d 3D → 6d.7p 3P* | Measured | NIST | |
| 566.165 nm | 6 | Ra II | emission | 8p 2P* → 9d 2D | Measured | NIST | |
| 389.455 nm | 5 | Ra II | emission | 5f 2F* → 8g 2G | Measured | NIST | |
| 497.179 nm | 5 | Ra I | emission | 7s.6d 3D → 6d.7p 3P* | Measured | NIST | |
| 504.154 nm | 5 | Ra I | emission | 7s.6d 3D → 6d.7p 3P* | Measured | NIST | |
| 560.143 nm | 5 | Ra I | emission | 7s.6d 3D → 7s.8p 3P* | Measured | NIST | |
| 577.824 nm | 5 | Ra I | emission | 7s.6d 1D → 6d.7p 3P* | Measured | NIST | |
| 579.5745 nm | 5 | Ra I | emission | 7s.7p 3P* → 7p2? 3P | Measured | NIST | |
| 581.1588 nm | 5 | Ra I | emission | 7s.6d 3D → 6d.7p 1D* | Measured | NIST | |
| 616.7051 nm | 5 | Ra I | emission | 7s.6d 3D → 6d.7p 1D* | Measured | NIST | |
| 707.79042 nm | 5 | Ra II | emission | 6d 2D → 7p 2P* | Measured | NIST | |
| 417.798 nm | 4 | Ra I | emission | 7s.6d 3D → 7s.6f 3F* | Measured | NIST | |
| 430.5 nm | 4 | Ra I | emission | 7s.6d 3D → 7s.6f 3F* | Measured | NIST | |
| 490.3263 nm | 4 | Ra I | emission | 7s.6d 3D → 6d.7p 3P* | Measured | NIST |
Extended Properties
Covalent Radii (Extended)
Van der Waals Radii
Atomic & Metallic Radii
Numbering Scales
Electronegativity Scales
Polarizability & Dispersion
Phase Transitions & Allotropes
| Melting point | 969.15 K |
Oxidation State Categories
Advanced Reference Data
Crystal Radii Detail (2)
| Charge | CN | Spin | rcrystal (pm) | Origin |
|---|---|---|---|---|
| 2 | VIII | 162 | from r^3 vs V plots, | |
| 2 | XII | 184 | from r^3 vs V plots, |
Isotope Decay Modes (55)
| Isotope | Mode | Intensity |
|---|---|---|
| 201 | A | 100% |
| 202 | A | 100% |
| 203 | A | 100% |
| 203 | B+ | — |
| 204 | A | 100% |
| 204 | B+ | — |
| 205 | A | 100% |
| 205 | B+ | — |
| 206 | A | 100% |
| 206 | B+ | — |
X‑ray Scattering Factors (516)
| Energy (eV) | f₁ | f₂ |
|---|---|---|
| 10 | — | 0.04162 |
| 10.1617 | — | 0.04479 |
| 10.3261 | — | 0.0482 |
| 10.4931 | — | 0.05188 |
| 10.6628 | — | 0.05584 |
| 10.8353 | — | 0.0601 |
| 11.0106 | — | 0.06468 |
| 11.1886 | — | 0.06961 |
| 11.3696 | — | 0.07492 |
| 11.5535 | — | 0.08102 |
Additional Data
Estimated Crustal Abundance
The estimated element abundance in the earth's crust.
9×10-7 milligrams per kilogram
References (1)
Estimated Oceanic Abundance
The estimated element abundance in the earth's oceans.
8.9×10-11 milligrams per liter
References (1)
Sources
Sources of this element.
Originally, radium was obtained from the rich pitchblende ore found in Joachimsthal, Bohemia. The carnotite sands of Colorado furnish some radium, but richer ores are found in the Republic of Zaire and the Great Lake region of Canada. Radium is present in all uranium minerals, and could be extracted, if desired, from the extensive wastes of uranium processing. Large uranium deposits are located in Ontario, New Mexico, Utah, Australia, and elsewhere.
References (1)
- [6] Radium https://periodic.lanl.gov/88.shtml
References
(9)
Data deposited in or computed by PubChem
The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.
Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.
The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.
Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/
The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.
The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database
This section provides all form of data related to element Radium.
The element property data was retrieved from publications.
