Bi 83

Bismuth (Bi)

post-transition-metal
Period: 6 Group: 15 Block: p

Solid

Standard Atomic Weight

208.9804 u

Electron configuration

[Xe] 6s2 4f14 5d10 6p3

Melting point

271.4 °C

Boiling point

1563.85 °C

Density

9807 kg/m³

Oxidation states

−3, −2, −1, 0, +1, +2, +3, +4, +5

Electronegativity (Pauling)

2.02

Ionization energy (1st)

7.285516 eV

Discovery year

1753

Atomic radius

160 pm

Details

Name origin German: bisemutum, (white mass), Now spelled wismut.
Discoverers Known to the ancients.

Bismuth is a heavy post-transition metal and the heaviest element with a primordial isotope that is effectively stable on human timescales. Natural bismuth is almost entirely ²⁰⁹Bi, now known to be very weakly radioactive by alpha decay. It has unusually low toxicity for a heavy metal, low thermal conductivity, a low melting point, and a strong tendency to form +3 compounds. These traits make it useful where lead, cadmium, or mercury are undesirable.

It is a white, crystalline, brittle metal with a pinkish tinge. It occurs in a native state. Bismuth is the most diamagnetic of all metals, and the thermal conductivity is lower than any metal, except mercury. It has a high electrical resistance, and has the highest Hall effect of any metal (i.e., greatest increase in electrical resistance when placed in a magnetic field).

The name derives from the German weisse masse for "white mass" from the colour of its oxides. The ancients did not distinguish bismuth from lead. The French chemist Claude-Francois Geoffroy showed that bismuth was distinct from lead in 1753.

Bismuth, which has been known since ancient times, was often confused with lead and tin. Bismuth was first shown to be a distinct element in 1753 by Claude Geoffroy the Younger. Bismuth does occur free in nature and in such minerals as bismuthinite (Bi2S3) and bismite (Bi2O3). The largest deposits of bismuth are found in Bolivia, although bismuth is usually obtained as a by-product of mining and refining lead, copper, tin, silver and gold.

From the German Weisse Masse, meaning white mass; later Wisuth and Bisemutum. In early times bismuth was confused with tin and lead. Claude Geoffroy the Younger showed it to be distinct from lead in 1753.

Images

Properties

Physical

Atomic radius (empirical)
160 pm Compare Atomic radius (empirical) of all elements →
Covalent radius
148 pm Compare Covalent radius of all elements →
Van der Waals radius
207 pm Compare Van der Waals radius of all elements →
Metallic radius
151 pm Compare Metallic radius of all elements →
Density
9807 kg/m³ Compare Density of all elements →
Molar volume
0.0213 L/mol
Phase at STP
Solid Compare Phase at STP of all elements →
Melting point
271.4 °C Compare Melting point of all elements →
Boiling point
1563.85 °C Compare Boiling point of all elements →
Thermal conductivity
7.9 W/(m·K) Compare Thermal conductivity of all elements →
Specific heat capacity
0.122 J/(g·K) Compare Specific heat capacity of all elements →
Molar heat capacity
25.52 J/(mol·K) Compare Molar heat capacity of all elements →
Crystal structure
Rhombohedral Compare Crystal structure of all elements →

Chemical

Electronegativity (Pauling)
2.02 Compare Electronegativity (Pauling) of all elements →
Electronegativity (Allen)
2.01
Electron affinity
0.942 eV
Ionization energy (1st)
7.285516 eV Compare Ionization energy (1st) of all elements →
Ionization energy (2nd)
16.703057 eV Compare Ionization energy (2nd) of all elements →
Ionization energy (3rd)
25.570838 eV Compare Ionization energy (3rd) of all elements →
Ionization energy (4th)
45.370156 eV Compare Ionization energy (4th) of all elements →
Ionization energy (5th)
54.856189 eV Compare Ionization energy (5th) of all elements →
Oxidation states
−3, −2, −1, 0, +1, +2, +3, +4, +5 Compare Oxidation states of all elements →
Valence electrons
5 Compare Valence electrons of all elements →
Electron configuration
[Xe] 6s2 4f14 5d10 6p3

Thermodynamic

Critical point (temperature)
4347 °C
Heat of fusion
0.11297093 eV Compare Heat of fusion of all elements →
Heat of vaporization
1.56501 eV Compare Heat of vaporization of all elements →
Heat of sublimation
2.176504 eV
Heat of atomization
2.176504 eV
Atomization enthalpy
2.172358 eV

Nuclear

Protons
83 Compare Protons of all elements →
Neutrons
126 Compare Neutrons of all elements →
Known isotopes
41 Compare Known isotopes of all elements →
Stable isotopes
0 Compare Stable isotopes of all elements →
Most stable isotope
Bi-209
Discovery year
1753

Abundance

Abundance (Earth's crust)
0.009 mg/kg Compare Abundance (Earth's crust) of all elements →
Abundance (ocean)
2 × 10−5 mg/L Compare Abundance (ocean) of all elements →

Crystal Structure

Lattice constant a
475 pm

Electronic Structure

Electrons per shell
2, 8, 18, 32, 18, 5 Compare Electrons per shell of all elements →

Identifiers

CAS number
7440-69-9 Compare CAS number of all elements →
Term symbol
4S°3/2
InChI
InChI=1S/Bi
InChI Key
JCXGWMGPZLAOME-UHFFFAOYSA-N

Electron Configuration Measured

Ion charge
Protons 83
Electrons 83
Charge Neutral
Configuration Bi: 4f¹⁴ 5d¹⁰ 6s² 6p³
Electron configuration
Measured
[Xe] 4f¹⁴ 5d¹⁰ 6s² 6p³
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d¹⁰ 6s² 6p³
Orbital diagram
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
2/2
4d
10/10
5p
6/6
6s
2/2
4f
14/14
5d
10/10
6p
3/6 3↑
Total electrons: 83 Unpaired: 3 ?

Atomic model

Protons 83
Neutrons 118
Electrons 83
Mass number 201
Stability Radioactive

Isotopes change neutron count, mass, and stability — not the electron configuration of a neutral atom.

Schematic atomic model, not to scale.

Atomic Fingerprint

Emission / Absorption Spectrum

25 / 27 (9 9 with intensity)
Measured
Emission Visible: 380–750 nm

Isotope Distribution

No stable isotopes.

Mass numberAtomic mass (u)Natural abundanceHalf-life
189 Radioactive188.989195 ± 0.000022N/A688 ms
208 Radioactive207.9797425 ± 0.0000025N/A368 ky
195 Radioactive194.9806488 ± 0.0000057N/A183 seconds
201 Radioactive200.97701 ± 0.000016N/A103 minutes
217 Radioactive217.009372 ± 0.000019N/A98.5 seconds
Measured

Phase / State

1 atm / 101.325 kPa
Solid 25 °C (298.15 K)

Reason: 246.4 °C below melting point (271.4 °C)

Melting point 271.4 °C
Boiling point 1563.85 °C
Below melting by 246.4 °C
0 K Current temperature: 25 °C 6000 K
Phase timeline

Schematic, not to scale

Solid
Liquid
Gas
Melting
Boiling
25°C
Solid
Liquid
Gas
Current

Phase transition points

Melting point Literature
271.4 °C
Boiling point Literature
1563.85 °C
Current phase Calculated
Solid

Transition energies

Heat of fusion Literature
0.11297093 eV

Energy required to melt 1 mol at melting point

Heat of vaporization Literature
1.56501 eV

Energy required to vaporize 1 mol at boiling point

Heat of sublimation Literature
2.176504 eV

Energy required to sublime 1 mol at sublimation point

Density

Reference density Literature
9807 kg/m³

At standard conditions

Current density Calculated
9807 kg/m³

At standard conditions

Advanced

Critical point Literature
4347 °C

Atomic Spectra

Showing 10 of 83. Sorted by ion charge (ascending).

Lines Holdings ?

IonChargeTotal linesTransition probabilitiesLevel designations
Bi I 0693963
Bi II +1111416
Bi III +2204204204
Bi IV +34500
Bi V +41800
NIST Lines Holdings →

Levels Holdings ?

IonChargeLevels
Bi I 075
Bi II +178
Bi III +268
Bi IV +338
Bi V +415
Bi VI +5115
Bi VII +62
Bi VIII +72
Bi IX +82
Bi X +92
NIST Levels Holdings →
83 Bi 208.9804

Bismuth — Atomic Orbital Visualizer

[Xe]6s24f145d106p3
Energy levels 2 8 18 32 18 5
Oxidation states -3, -2, -1, 0, +1, +2, +3, +4, +5
HOMO 6p n=6 · l=1 · m=-1
Bismuth — Atomic Orbital Visualizer Preview
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83 Bi 208.9804

Bismuth — Crystal Structure Visualizer

Trigonal · Pearson N/A
Experimental
Pearson N/A
Bismuth — Crystal Structure Visualizer Preview
Three.js loads only on request

Ionic Radii

ChargeCoordinationSpinRadius
+35N/A96 pm
+36N/A103 pm
+38N/A117 pm
+56N/A76 pm

Compounds

Bi
208.980 u
Bi+3
208.980 u
Bi
209.984 u
Bi
213.999 u
Bi
211.991 u
Bi
206.978 u
Bi
205.978 u
Bi
212.994 u
Bi
204.977 u
Bi
199.978 u
Bi
201.978 u
Bi
210.987 u
Bi
202.977 u
Bi
200.977 u
Bi
208.980 u
Bi+2
208.980 u
Bi+3
212.994 u
Bi
216.006 u
Bi
207.980 u
Bi
197.979 u
Bi
191.986 u
Bi
193.983 u
Bi
195.981 u
Bi
217.009 u

Isotopes (5)

Mass numberAtomic mass (u)Natural abundanceHalf-lifeDecay mode
189 Radioactive188.989195 ± 0.000022N/A688 ms
α ≈100%β+ ?
208 Radioactive207.9797425 ± 0.0000025N/A368 ky
β+ =100%
195 Radioactive194.9806488 ± 0.0000057N/A183 seconds
β+ ≈100%α =0.030±1.2%
201 Radioactive200.97701 ± 0.000016N/A103 minutes
β+ =100%
217 Radioactive217.009372 ± 0.000019N/A98.5 seconds
β- =100%
189 Radioactive
Atomic mass (u) 188.989195 ± 0.000022
Natural abundance N/A
Half-life 688 ms
Decay mode
α ≈100%β+ ?
208 Radioactive
Atomic mass (u) 207.9797425 ± 0.0000025
Natural abundance N/A
Half-life 368 ky
Decay mode
β+ =100%
195 Radioactive
Atomic mass (u) 194.9806488 ± 0.0000057
Natural abundance N/A
Half-life 183 seconds
Decay mode
β+ ≈100%α =0.030±1.2%
201 Radioactive
Atomic mass (u) 200.97701 ± 0.000016
Natural abundance N/A
Half-life 103 minutes
Decay mode
β+ =100%
217 Radioactive
Atomic mass (u) 217.009372 ± 0.000019
Natural abundance N/A
Half-life 98.5 seconds
Decay mode
β- =100%

Spectral Lines

Wavelength (nm)IntensityIon stageTypeTransitionAccuracySource
384.893 nm21Bi IIIemission6s2.6d 2D → 6s2.7p 2P*MeasuredNIST
392.72 nmN/ABi IIIemission6s.6p2.(3P) 2P → 6s2.8p 2P*MeasuredNIST
393.036 nmN/ABi IIIemission6s.6p2.(1S) 2S → 6s2.8p 2P*MeasuredNIST
422.469 nm350Bi IIIemission6s2.6f 2F* → 6s2.7g 2GMeasuredNIST
423.421 nm280Bi IIIemission6s2.6f 2F* → 6s2.7g 2GMeasuredNIST
425.9413 nmN/ABi IIemission6s2.6p.6d (1/2,5/2)* → 6s2.6p.5f (1/2,7/2)MeasuredNIST
430.1697 nmN/ABi IIemission6s2.6p.6d (1/2,5/2)* → 6s2.6p.5f (1/2,7/2)MeasuredNIST
430.653 nmN/ABi IIIemission6s.6p2.(1S) 2S → 6s2.8p 2P*MeasuredNIST
432.792 nm360Bi IIIemission6s2.7p 2P* → 6s2.8s 2SMeasuredNIST
456.143 nmN/ABi IIIemission6s2.7s 2S → 6s2.7p 2P*MeasuredNIST
470.5285 nmN/ABi IIemission6s2.6p.7p (1/2,1/2) → 6s2.6p.7d (1/2,3/2)*MeasuredNIST
472.883 nmN/ABi IIIemission6s.6p2.(1D) 2D → 6s2.5f 2F*MeasuredNIST
475.128 nmN/ABi IIIemission6s.6p2.(1D) 2D → 6s2.5f 2F*MeasuredNIST
479.742 nmN/ABi IIIemission6s2.6d 2D → 6s2.7p 2P*MeasuredNIST
480.9082 nmN/ABi IIIemission6s2.6p 2P* → 6s2.6p 2P*MeasuredNIST
505.178 nmN/ABi IIIemission6s2.5g 2G → 6s2.7h 2H*MeasuredNIST
505.178 nmN/ABi IIIemission6s2.5g 2G → 6s2.7h 2H*MeasuredNIST
505.244 nm120Bi IIIemission6s2.5g 2G → 6s2.7h 2H*MeasuredNIST
507.928 nmN/ABi IIIemission6s2.6d 2D → 6s2.7p 2P*MeasuredNIST
512.4356 nmN/ABi IIemission6s2.6p.7s (3/2,1/2)* → 6s2.6p.7p (3/2,3/2)MeasuredNIST
514.4507 nmN/ABi IIemission6s2.6p.7s (1/2,1/2)* → 6s2.6p.7p (1/2,3/2)MeasuredNIST
520.9325 nmN/ABi IIemission6s2.6p.7s (1/2,1/2)* → 6s2.6p.7p (1/2,3/2)MeasuredNIST
613.907 nm22Bi IIIemission6s2.6f 2F* → 6s2.6g 2GMeasuredNIST
614.039 nm150Bi IIIemission6s2.6f 2F* → 6s2.6g 2GMeasuredNIST
616.071 nm120Bi IIIemission6s2.6f 2F* → 6s2.6g 2GMeasuredNIST
662.323 nm180Bi IIIemission6s2.8p 2P* → 6s2.8d 2DMeasuredNIST
738.23 nmN/ABi IIIemission6s.6p2.(1D) 2D → 6s2.7p 2P*MeasuredNIST

Extended Properties

Covalent Radii (Extended)

Covalent radius (Pyykkö)
151 pm
Covalent radius (Pyykkö, double)
141 pm
Covalent radius (Pyykkö, triple)
135 pm
Covalent radius (Bragg)
148 pm

Van der Waals Radii

Truhlar
207 pm
Batsanov
230 pm
Alvarez
254 pm
UFF
437 pm
MM3
266 pm

Atomic & Metallic Radii

Atomic radius (Rahm)
250 pm
Metallic radius (C12)
178 pm

Numbering Scales

Mendeleev
97
Pettifor
87
Glawe
92

Electronegativity Scales

Ghosh
0
Miedema
4
Gunnarsson–Lundqvist
5
Robles–Bartolotti
4

Polarizability & Dispersion

Dipole polarizability
48 a.u.
Dipole polarizability (unc.)
4 a.u.
C₆ (Gould–Bučko)
513 Ha·Bohr6

Miedema Parameters

Miedema molar volume
19.32 cm3/mol
Miedema electron density
2

Supply Risk & Economics

Production concentration
42
Relative supply risk
9
Reserve distribution
75
Political stability (top producer)
24
Political stability (top reserve)
24

Phase Transitions & Allotropes

Melting point544.55 K
Boiling point1837.15 K
Critical point (temperature)4620.15 K

Oxidation State Categories

+5 extended
+2 extended
−1 extended
−2 extended
−3 extended
0 extended
+1 extended
+3 main
+4 extended

Advanced Reference Data

Screening Constants (15)
nOrbitalσ
1s1.6018
2p4.533
2s21.824
3d13.4585
3p23.0678
3s24.1145
4d37.7608
4f37.9308
4p36.1496
4s35.2928
Crystal Radii Detail (4)
ChargeCNSpinrcrystal (pm)Origin
3V110calculated,
3VI117from r^3 vs V plots,
3VIII131from r^3 vs V plots,
5VI90estimated,
Isotope Decay Modes (70)
IsotopeModeIntensity
184A100%
185p—
185A—
186A100%
186B+—
186B+SF0%
187A100%
188A100%
188B+—
188B+SF0%
X‑ray Scattering Factors (516)
Energy (eV)f₁f₂
10—5.59475
10.1617—5.63587
10.3261—5.67729
10.4931—5.71901
10.6628—5.74574
10.8353—5.7564
11.0106—5.76707
11.1886—5.77776
11.3696—5.78847
11.5535—5.7834

Additional Data

Sources

Sources of this element.

The most important ores are bismuthinite or bismuth glance and bismite. Peru, Japan, Mexico, Bolivia, and Canada are major bismuth producers. Much of the bismuth produced in the U.S. is obtained as a by-product in refining lead, copper, tin, silver, and gold ores.

References (1)

References

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
Bi

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Bismuth

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

License note: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Bismuth

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

License note: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Bismuth

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Bismuth

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Bismuth

This section provides all form of data related to element Bismuth.

9 PubChem Elements
Bismuth

The element property data was retrieved from publications.

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Data verified:

Content is reviewed against latest scientific data.