Te 52

Tellurium (Te)

metalloid
Period: 5 Group: 16 Block: p

Solid

Standard Atomic Weight

127.6 u

Electron configuration

[Kr] 5s2 4d10 5p4

Melting point

449.51 °C (722.66 K)

Boiling point

987.85 °C (1261 K)

Density

6232 kg/m³

Oxidation states

−2, −1, 0, +1, +2, +3, +4, +5, +6

Electronegativity (Pauling)

2.1

Ionization energy (1st)

Discovery year

1782

Atomic radius

140 pm

Details

Name origin Latin: tellus (earth).
Discovery country Romania
Discoverers Franz Müller von Reichenstein

Tellurium is a brittle metalloid in group 16, below selenium and above polonium. It is chemically related to sulfur and selenium but is more metallic, less abundant, and more easily reduced. In nature it occurs mainly as telluride minerals and as a minor constituent of copper ores. Its technological importance comes from semiconducting and thermoelectric compounds, cadmium telluride photovoltaics, and small alloying additions that modify machinability and corrosion behavior.

Crystalline tellurium has a silvery-white appearance, and when pure it exhibits a metallic luster. It is brittle and easily pulverized. Amorphous tellurium is found by precipitating tellurium from a solution of telluric or tellurous acid. Whether this form is truly amorphous, or made of minute crystals, is open to question. Tellurium is a p-type semiconductor, and shows greater conductivity in certain directions, depending on alignment of the atoms.

Its conductivity increases slightly with exposure to light. It can be doped with silver, copper, gold, tin, or other elements. In air, tellurium burns with a greenish-blue flames, forming the dioxide. Molten tellurium corrodes iron, copper, and stainless steel.

The name derives from the Latin Tellus, who was the Roman goddess of the Earth. Tellurium was discovered by Franz Joseph Müller von Reichenstein in 1782 and overlooked for 15 years until it was isolated by the German chemist Martin-Heinrich Klaproth in 1798. The Hungarian chemist Paul Kitaibel independently discovered tellurium in 1789, prior to Klaproth's work but after von Reichenstein.

Tellurium was discovered by Franz Joseph Müller von Reichenstein, a Romanian mining official, in 1782. Reichenstein was the chief inspector of all mines, smelters and saltworks in Transylvania. He also had an interest in chemistry and extracted a new metal from an ore of gold, known as aurum album, which he believed was antimony. He shortly realized that the metal he had produced wasn't antimony at all, but a previously unknown element. Reichenstein's work was forgotten until 1798 when Martin Heinrich Klaproth, a German chemist, mentioned the substance in a paper. Klaproth named the new element tellurium but gave full credit for its discovery to Reichenstein. Tellurium is found free in nature, but is most often found in the ores sylvanite (AgAuTe4), calaverite (AuTe2) and krennerite (AuTe2). Today, most tellurium is obtained as a byproduct of mining and refining copper.

From the Latin word tellus, earth. Discovered by Muller von Reichenstein in 1782; named by Klaproth, who isolated it in 1798.

Images

Properties

Physical

Atomic radius (empirical) 140 pm
Covalent radius 138 pm
Van der Waals radius 206 pm
Metallic radius 137 pm
Density
Molar volume 0.0205 L/mol
Phase at STP solid
Melting point 449.51 °C
Boiling point 987.85 °C
Thermal conductivity 14.3 W/(m·K)
Specific heat capacity 0.202 J/(g·K)
Molar heat capacity 25.73 J/(mol·K)
Crystal structure hcp

Chemical

Electronegativity (Pauling) 2.1
Electronegativity (Allen) 2.158
Electron affinity
Ionization energy (1st)
Ionization energy (2nd)
Ionization energy (3rd)
Ionization energy (4th)
Ionization energy (5th)
Oxidation states −2, −1, 0, +1, +2, +3, +4, +5, +6
Valence electrons 6
Electron configuration
Electron configuration (semantic)

Thermodynamic

Critical point (temperature) 2056 °C
Heat of fusion 0.1812717 eV
Heat of vaporization 0.54412603 eV
Heat of sublimation 2.041768 eV
Heat of atomization 2.041768 eV
Atomization enthalpy

Nuclear

Stable isotopes 5
Discovery year 1782

Abundance

Abundance (Earth's crust) 0.001 mg/kg

Reactivity

N/A

Crystal Structure

Lattice constant a 445 pm

Electronic Structure

Electrons per shell 2, 8, 18, 18, 6

Identifiers

CAS number 13494-80-9
Term symbol
InChI InChI=1S/Te
InChI Key PORWMNRCUJJQNO-UHFFFAOYSA-N

Electron Configuration Measured

Ion charge
Protons 52
Electrons 52
Charge Neutral
Configuration Te: 4d¹⁰ 5s² 5p⁴
Electron configuration
Measured
[Kr] 4d¹⁰ 5s² 5p⁴
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁴
Orbital diagram
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
2/2
4d
10/10
5p
4/6 2↑
Total electrons: 52 Unpaired: 2 ?

Atomic model

Protons 52
Neutrons 74
Electrons 52
Mass number 126
Stability Stable

Isotopes change neutron count, mass, and stability — not the electron configuration of a neutral atom.

Schematic atomic model, not to scale.

Atomic Fingerprint

Emission / Absorption Spectrum

25 / 50 (50 with intensity)
Measured
Emission Visible: 380–750 nm

Isotope Distribution

12618.8400%1257.0700%1244.7400%1222.5500%Mass numberNatural abundance (%)
Mass numberAtomic mass (u)Natural abundanceHalf-life
122 Stable121.9030435 ± 0.00000162.5500%Stable
124 Stable123.9028171 ± 0.00000164.7400%Stable
125 Stable124.9044299 ± 0.00000167.0700%Stable
126 Stable125.9033109 ± 0.000001618.8400%Stable
Measured

Phase / State

1 atm / 101.325 kPa
Solid 25 °C (298.15 K)

Reason: 424.5 °C below melting point (449.51 °C)

Melting point 449.51 °C
Boiling point 987.85 °C
Below melting by 424.5 °C
0 K Current temperature: 25 °C 6000 K
Phase timeline

Schematic, not to scale

Solid
Liquid
Gas
Melting
Boiling
25°C
Solid
Liquid
Gas
Current

Phase transition points

Melting point Literature
449.51 °C
Boiling point Literature
987.85 °C
Current phase Calculated
Solid

Transition energies

Heat of fusion Literature
0.1812717 eV

Energy required to melt 1 mol at melting point

Heat of vaporization Literature
0.54412603 eV

Energy required to vaporize 1 mol at boiling point

Heat of sublimation Literature
2.041768 eV

Energy required to sublime 1 mol at sublimation point

Density

Reference density Literature
6232 kg/m³

At standard conditions

Current density Calculated
6232 kg/m³

At standard conditions

Advanced

Critical point Literature
2056 °C

Atomic Spectra

Showing 10 of 52 Atomic Spectra. Sorted by ion charge (ascending).

Lines Holdings ?

IonChargeTotal linesTransition probabilitiesLevel designations
Te I 01336112
Te II +13450310
NIST Lines Holdings →

Levels Holdings ?

IonChargeLevels
Te I 0120
Te II +1129
Te III +255
Te IV +316
Te V +445
Te VI +59
Te VII +660
Te VIII +72
Te IX +82
Te X +92
NIST Levels Holdings →
52 Te 127.6

Tellurium — Atomic Orbital Visualizer

[Kr]5s24d105p4
Energy levels 2 8 18 18 6
Oxidation states -2, -1, 0, +1, +2, +3, +4, +5, +6
HOMO 5p n=5 · l=1 · m=-1
Tellurium — Atomic Orbital Visualizer Preview
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52 Te 127.6

Tellurium — Crystal Structure Visualizer

Primitive Hexagonal · Pearson hP2
Experimental
Pearson hP2
Coord. № 12
Packing 74.048%
Tellurium — Crystal Structure Visualizer Preview
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Ionic Radii

ChargeCoordinationSpinRadius
-26N/A221 pm
+43N/A52 pm
+44N/A66 pm
+46N/A97 pm
+64N/A43 pm
+66N/A56.00000000000001 pm

Compounds

Te
127.600 u
Te+4
127.600 u
Te
131.909 u
Te
124.904 u
Te
132.911 u
Te
125.903 u
Te
129.906 u
Te
128.907 u
Te
126.905 u
Te
122.904 u
Te
130.909 u
Te
120.905 u
Te
121.903 u
Te
127.904 u
Te
115.909 u
Te
133.911 u
Te+
127.600 u
Te+4
124.904 u
Te
123.903 u
Te
109.922 u
Te
119.904 u

Isotopes (4)

Thirty isotopes of tellurium are known, with atomic masses ranging from 108 to 137. Natural tellurium consists of eight isotopes.

Mass numberAtomic mass (u)Natural abundanceHalf-lifeDecay mode
122 Stable121.9030435 ± 0.00000162.5500% ± 0.1200%Stable
stable
124 Stable123.9028171 ± 0.00000164.7400% ± 0.1400%Stable
stable
125 Stable124.9044299 ± 0.00000167.0700% ± 0.1500%Stable
stable
126 Stable125.9033109 ± 0.000001618.8400% ± 0.2500%Stable
stable
122 Stable
Atomic mass (u) 121.9030435 ± 0.0000016
Natural abundance 2.5500% ± 0.1200%
Half-life Stable
Decay mode
stable
124 Stable
Atomic mass (u) 123.9028171 ± 0.0000016
Natural abundance 4.7400% ± 0.1400%
Half-life Stable
Decay mode
stable
125 Stable
Atomic mass (u) 124.9044299 ± 0.0000016
Natural abundance 7.0700% ± 0.1500%
Half-life Stable
Decay mode
stable
126 Stable
Atomic mass (u) 125.9033109 ± 0.0000016
Natural abundance 18.8400% ± 0.2500%
Half-life Stable
Decay mode
stable

Spectral Lines

Showing 50 of 74 Spectral Lines. Only spectral lines with measured intensity are shown by default.

Wavelength (nm)IntensityIon stageTypeTransitionAccuracySource
486.623 nm2300Te IIemission5s2.5p2.(3P).6p 4D* → 5s2.5p2.(3P).6d 4FMeasuredNIST
557.636 nm2100Te IIemission5s2.5p2.(1D).6s 2D → 5s2.5p2.(1D).6p 2F*MeasuredNIST
570.812 nm1900Te IIemission5s2.5p2.(3P).6s 4P → 5s2.5p2.(3P).6p 4D*MeasuredNIST
483.13 nm1600Te IIemission5s2.5p2.(3P).6p 4D* → 5s2.5p2.(3P).6d 4PMeasuredNIST
564.926 nm1500Te IIemission5s2.5p2.(3P).6s 4P → 5s2.5p2.(3P).6p 4D*MeasuredNIST
575.586 nm1500Te IIemission5s2.5p2.(3P).6s 4P → 5s2.5p2.(3P).6p 4D*MeasuredNIST
544.984 nm1400Te IIemission5s2.5p2.(3P).6s 4P → 5s2.5p2.(3P).6p 4P*MeasuredNIST
468.691 nm1310Te IIemission5s2.5p2.(3P).6p 4P* → 5s2.5p2.(3P).6d 4DMeasuredNIST
476.605 nm1300Te IIemission5s2.5p2.(3P).6p 2D* → 5s2.5p2.(3P).6d 2FMeasuredNIST
490.442 nm1300Te IIemission5s2.5p2.(3P).6p 2D* → 5s2.5p2.(3P).6d 2FMeasuredNIST
566.622 nm1200Te IIemission5s2.5p2.(3P).6s 2P → 5s2.5p2.(3P).6p 2D*MeasuredNIST
597.468 nm1200Te IIemission5s2.5p2.(3P).6s 4P → 5s2.5p2.(3P).6p 4P*MeasuredNIST
548.795 nm1100Te IIemission5s2.5p2.(3P).5d 2P → 5s2.5p2.(3P).6p 4D*MeasuredNIST
484.29 nm1000Te IIemission5s2.5p2.(3P).5d 2D → 5s2.5p2.(3P).4f 4D*MeasuredNIST
486.513 nm1000Te IIemission5s2.5p2.(3P).6p 4D* → 5s2.5p2.(3P).6d 4DMeasuredNIST
482.712 nm900Te IIemission5s2.5p2.(3P).6p 4P* → 5s2.5p2.(3P).6d 4DMeasuredNIST
447.865 nm830Te IIemission5s2.5p2.(3P).6p 4P* → 5s2.5p2.(3P).6d 4DMeasuredNIST
500.081 nm810Te IIemission5s2.5p2.(3P).6s 4P → 5s2.5p2.(3P).6p 2D*MeasuredNIST
477.155 nm800Te IIemission5s2.5p2.(3P).6p 4D* → 5s2.5p2.(3P).6d 4FMeasuredNIST
593.615 nm730Te IIemission5s2.5p2.(3P).6s 4P → 5s2.5p2.(3P).6p 4S*MeasuredNIST
464.111 nm680Te IIemission5s2.5p2.(3P).6p 4D* → 5s2.5p2.(3P).6d 4DMeasuredNIST
470.654 nm670Te IIemission5s2.5p2.(1D).6s 2D → 5s2.5p2.(1D).6p 2P*MeasuredNIST
436.402 nm650Te IIemission5s2.5p2.(3P).5d 4P → 5s2.5p2.(3P).4f 4D*MeasuredNIST
636.713 nm570Te IIemission5s.(2S).5p4.(1D) 2D → 5s2.5p2.(3P).6p 4D*MeasuredNIST
469.638 nm560Te IIemission5s2.5p2.(3P).5d 4P → 5s2.5p2.(3P).4f 2D*MeasuredNIST
416.977 nm540Te IIemission5s2.5p2.(3P).5d 2D → 5s2.5p2.(3P).4f 2F*MeasuredNIST
463.062 nm540Te IIemission5s2.5p2.(3P).6p 4S* → 5s2.5p2.(3P).7s 2PMeasuredNIST
478.488 nm510Te IIemission5s2.5p2.(1D).6s 2D → 5s2.5p2.(1D).6p 2P*MeasuredNIST
455.778 nm480Te IIemission5s2.5p2.(3P).6p 4S* → 5s2.5p2.(3P).6d 4DMeasuredNIST
683.7663 nm430Te Iemission5p3.(4S*).6p 5P → 5p3.(4S*).8d 5D*MeasuredNIST
404.716 nm400Te IIemission5s2.5p2.(3P).5d 4P → 5s2.5p2.(3P).4f 2D*MeasuredNIST
428.583 nm370Te IIemission5s2.5p2.(3P).6p 2S* → 5s2.5p2.(3P).6d 4DMeasuredNIST
394.798 nm340Te IIemission5s2.5p2.(3P).5d 4P → 5s2.5p2.(3P).4f 4F*MeasuredNIST
422.572 nm340Te IIemission5s2.5p2.(3P).5d 4P → 5s2.5p2.(3P).4f 4D*MeasuredNIST
396.921 nm320Te IIemission5s.(2S).5p4.(1D) 2D → 5s2.5p2.(1D).6p 2D*MeasuredNIST
410.105 nm320Te IIemission5s2.5p2.(1D).5d 2S → 5s2.5p2.(3P).4f 2D*MeasuredNIST
412.732 nm320Te IIemission5s2.5p2.(1D).5d 2S → 5s2.5p2.(3P).4f 4D*MeasuredNIST
496.187 nm320Te IIemission5s2.5p2.(3P).6p 4P* → 5s2.5p2.(3P).6d 4DMeasuredNIST
400.653 nm310Te IIemission5s.(2S).5p4.(3P) 4P → 5s2.5p2.(3P).6p 4D*MeasuredNIST
438.51 nm310Te IIemission5s2.5p2.(3P).5d 4P → 5s2.5p2.(3P).4f 2D*MeasuredNIST
417.929 nm300Te IIemission5s2.5p2.(3P).5d 4P → 5s2.5p2.(1S).6p 2P*MeasuredNIST
427.343 nm300Te IIemission5s2.5p2.(3P).6p 2S* → 5s2.5p2.(3P).7s 2PMeasuredNIST
679.109 nm300Te Iemission5p3.(4S*).6p 5P → 5p3.(4S*).8d 3D*MeasuredNIST
669.0154 nm290Te Iemission5p3.(4S*).6p 5P → 5p3.(4S*).8d 5D*MeasuredNIST
453.708 nm260Te IIemission5s2.5p2.(3P).5d 4P → 5s2.5p2.(3P).4f 4F*MeasuredNIST
397.592 nm250Te IIemission5s.(2S).5p4.(1D) 2D → 5s2.5p2.(1D).6p 2F*MeasuredNIST
416.356 nm250Te IIemission5s2.5p2.(3P).5d 4P → 5s2.5p2.(3P).4f 4D*MeasuredNIST
398.176 nm240Te IIemission5s2.5p2.(3P).6s 2P → 5s2.5p2.(1D).6p 2P*MeasuredNIST
425.114 nm240Te IIemission5s2.5p2.(3P).5d 2D → 5s2.5p2.(3P).4f 2F*MeasuredNIST
404.888 nm230Te IIemission5s.(2S).5p4.(3P) 4P → 5s2.5p2.(3P).6p 4S*MeasuredNIST

Extended Properties

Covalent Radii (Extended)

Covalent radius (Pyykkö)  
Covalent radius (Pyykkö, double)  
Covalent radius (Pyykkö, triple)  
Covalent radius (Bragg)  

Van der Waals Radii

Bondi  
Batsanov  
Alvarez  
UFF  
MM3  
Dreiding  

Atomic & Metallic Radii

Atomic radius (Rahm)  
Metallic radius (C12)  

Numbering Scales

Mendeleev
Pettifor
Glawe

Electronegativity Scales

Ghosh
Gunnarsson–Lundqvist
Robles–Bartolotti

Polarizability & Dispersion

Dipole polarizability  
Dipole polarizability (unc.)  
C₆  
C₆ (Gould–Bučko)  

Phase Transitions & Allotropes

Melting point722.66 K
Boiling point1261.15 K
Critical point (temperature)2329.15 K

Oxidation State Categories

+2 main
−2 main
+1 extended
+6 main
+3 extended
0 extended
+5 extended
−1 extended
+4 main

Advanced Reference Data

Screening Constants (11)
nOrbitalσ
1s1.0432
2p4.14
2s13.6688
3d14.1607
3p17.9911
3s18.0019
4d32.04
4p28.878
4s27.5916
5p41.1915
Crystal Radii Detail (6)
ChargeCNSpinrcrystal (pm)Origin
-2VI207Pauling's (1960) crystal radius,
4III66
4IV80
4VI111
6IV57calculated,
6VI70
Isotope Decay Modes (67)
IsotopeModeIntensity
104A100%
105A100%
106A100%
107A70%
107B+
107B+p
108B+51%
108A49%
108B+p2.4%
108B+A0.1%
X‑ray Scattering Factors (508)
Energy (eV)f₁f₂
109.70237
10.16179.72653
10.32619.75076
10.49319.77506
10.66289.7994
10.83539.77638
11.01069.72308
11.18869.67008
11.36969.61736
11.55359.54395

Additional Data

Sources

Sources of this element.

Tellurium is occasionally found native, but is more often found as the telluride of gold (calaverite), and combined with other metals. It is recovered commercially from anode muds produced during the electrolytic refining of blister copper. The U.S., Canada, Peru, and Japan are the largest Free World producers of the element.

References (1)

References

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
Te

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Tellurium

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

License note: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Tellurium

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

License note: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Tellurium

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Tellurium

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Tellurium

This section provides all form of data related to element Tellurium.

9 PubChem Elements
Tellurium

The element property data was retrieved from publications.

Last updated:

Data verified:

Content is reviewed against latest scientific data.