Sulfur (S)
nonmetalSolid
Standard Atomic Weight
32.06 u [32.059, 32.076]Electron configuration
[Ne] 3s2 3p4Melting point
115.21 °C (388.36 K)Boiling point
444.6 °C (717.75 K)Density
2067 kg/m³Oxidation states
−2, −1, 0, +1, +2, +3, +4, +5, +6Electronegativity (Pauling)
2.58Ionization energy (1st)
Discovery year
1777Atomic radius
100 pmDetails
Sulfur is a reactive nonmetal in group 16, occurring naturally as elemental sulfur and in sulfide and sulfate minerals. It forms many allotropes and a large range of compounds, especially with oxygen, hydrogen, metals, and organic groups. Its chemistry is central to fertilizers, petroleum refining, vulcanized rubber, and biological molecules such as amino acids and cofactors.
Sulfur is pale yellow, odorless, brittle solid, which is insoluble in water but soluble in carbon disulfide. In every state, whether gas, liquid or solid, elemental sulfur occurs in more than one allotropic form or modification; these present a confusing multitude of forms whose relations are not yet fully understood.
In 1975, University of Pennsylvania scientists reported synthesis of polymeric sulfur nitride, which has the properties of a metal, although it contains no metal atoms. The material has unusual optical and electrical properties.
High-purity sulfur is commercially available in purities of 99.999+%.
Amorphous or "plastic" sulfur is obtained by fast cooling of the crystalline form. X-ray studies indicate that amorphous sulfur may have a helical structure with eight atoms per spiral. Crystalline sulfur seems to be made of rings, each containing eight sulfur atoms, which fit together to give a normal X-ray pattern.
The name derives from the Latin sulphurium and the Sanskrit sulveri. Sulfur was known as brenne stone for "combustible stone" from which brim-stone is derived. It was known from prehistoric times and thought to contain hydrogen and oxygen. In 1809, the French chemists Louis-Joseph Gay-Lussac and Louis-Jacques Thenard proved the elemental nature of sulfur.
Sulfur, the tenth most abundant element in the universe, has been known since ancient times. Sometime around 1777, Antoine Lavoisier convinced the rest of the scientific community that sulfur was an element. Sulfur is a component of many common minerals, such as galena (PbS), gypsum (CaSO4·2(H2O), pyrite (FeS2), sphalerite (ZnS or FeS), cinnabar (HgS), stibnite (Sb2S3), epsomite (MgSO4·7(H2O)), celestite (SrSO4) and barite (BaSO4). Nearly 25% of the sulfur produced today is recovered from petroleum refining operations and as a byproduct of extracting other materials from sulfur containing ores. The majority of the sulfur produced today is obtained from underground deposits, usually found in conjunction with salt deposits, with a process known as the Frasch process. Sulfur is a pale yellow, odorless and brittle material. It displays three allotropic forms: orthorhombic, monoclinic and amorphous. The orthorhombic form is the most stable form of sulfur. Monoclinic sulfur exists between the temperatures of 96°C and 119°C and reverts back to the orthorhombic form when cooled. Amorphous sulfur is formed when molten sulfur is quickly cooled. Amorphous sulfur is soft and elastic and eventually reverts back to the orthorhombic form.
Known to the ancients; referred to in Genesis as brimstone.
Images
Properties
Physical
Chemical
Thermodynamic
Nuclear
Abundance
Reactivity
N/A
Crystal Structure
Electronic Structure
Identifiers
Electron Configuration Measured
S: 3s² 3p⁴[Ne] 3s² 3p⁴1s² 2s² 2p⁶ 3s² 3p⁴Atomic model
Isotopes change neutron count, mass, and stability — not the electron configuration of a neutral atom.
Schematic atomic model, not to scale.
Atomic Fingerprint
Emission / Absorption Spectrum
Isotope Distribution
| Mass number | Atomic mass (u) | Natural abundance | Half-life |
|---|---|---|---|
| 32 Stable | 31.9720711744 ± 0.0000000014 | 94.9900% | Stable |
| 33 Stable | 32.9714589098 ± 0.0000000015 | 0.7500% | Stable |
| 34 Stable | 33.967867004 ± 0.000000047 | 4.2500% | Stable |
| 36 Stable | 35.96708071 ± 0.0000002 | 0.0100% | Stable |
Phase / State
Reason: 90.2 °C below melting point (115.21 °C)
Schematic, not to scale
Phase transition points
Transition energies
Energy required to melt 1 mol at melting point
Energy required to vaporize 1 mol at boiling point
Energy required to sublime 1 mol at sublimation point
Density
At standard conditions
At standard conditions
Advanced
Atomic Spectra
Showing 10 of 16 Atomic Spectra. Sorted by ion charge (ascending).
Lines Holdings ?
| Ion | Charge | Total lines | Transition probabilities | Level designations |
|---|---|---|---|---|
| S I | 0 | 1437 | 1052 | 1429 |
| S II | +1 | 1349 | 753 | 1349 |
| S III | +2 | 329 | 273 | 329 |
| S IV | +3 | 1199 | 999 | 1199 |
| S V | +4 | 866 | 699 | 866 |
| S VI | +5 | 457 | 393 | 457 |
| S VII | +6 | 259 | 253 | 255 |
| S VIII | +7 | 254 | 253 | 254 |
| S IX | +8 | 175 | 175 | 175 |
| S X | +9 | 270 | 268 | 270 |
Levels Holdings ?
| Ion | Charge | Levels |
|---|---|---|
| S I | 0 | 382 |
| S II | +1 | 247 |
| S III | +2 | 59 |
| S IV | +3 | 142 |
| S V | +4 | 150 |
| S VI | +5 | 88 |
| S VII | +6 | 57 |
| S VIII | +7 | 54 |
| S IX | +8 | 45 |
| S X | +9 | 44 |
Ionic Radii
| Charge | Coordination | Spin | Radius |
|---|---|---|---|
| -2 | 6 | N/A | 184 pm |
| +4 | 6 | N/A | 37 pm |
| +6 | 4 | N/A | 12 pm |
| +6 | 6 | N/A | 28.999999999999996 pm |
Compounds
Isotopes (4)
Eleven isotopes of sulfur exist. None of the four isotopes that are found in nature are radioactive. A finely divided form of sulfur, known as flowers of sulfur, is obtained by sublimation.
| Mass number | Atomic mass (u) | Natural abundance | Half-life | Decay mode | |
|---|---|---|---|---|---|
| 32 Stable | 31.9720711744 ± 0.0000000014 | 94.9900% ± 0.2600% | Stable | stable | |
| 33 Stable | 32.9714589098 ± 0.0000000015 | 0.7500% ± 0.0200% | Stable | stable | |
| 34 Stable | 33.967867004 ± 0.000000047 | 4.2500% ± 0.2400% | Stable | stable | |
| 36 Stable | 35.96708071 ± 0.0000002 | 0.0100% ± 0.0100% | Stable | stable |
Spectral Lines
Showing 50 of 556 Spectral Lines. Only spectral lines with measured intensity are shown by default.
| Wavelength (nm) | Intensity | Ion stage | Type | Transition | Accuracy | Source | |
|---|---|---|---|---|---|---|---|
| 545.3853 nm | 42000 | S II | emission | 3s2.3p2.(3P).4s 4P → 3s2.3p2.(3P).4p 4D* | Measured | NIST | |
| 543.2797 nm | 30000 | S II | emission | 3s2.3p2.(3P).4s 4P → 3s2.3p2.(3P).4p 4D* | Measured | NIST | |
| 416.2665 nm | 25000 | S II | emission | 3s2.3p2.(3P).4p 4D* → 3s2.3p2.(3P).4d 4F | Measured | NIST | |
| 532.0715 nm | 24000 | S II | emission | 3s2.3p2.(1D).4s 2D → 3s2.3p2.(1D).4p 2F* | Measured | NIST | |
| 415.3066 nm | 20000 | S II | emission | 3s2.3p2.(3P).4p 4D* → 3s2.3p2.(3P).4d 4F | Measured | NIST | |
| 503.2435 nm | 20000 | S II | emission | 3s2.3p2.(3P).4s 4P → 3s2.3p2.(3P).4p 4P* | Measured | NIST | |
| 542.8658 nm | 20000 | S II | emission | 3s2.3p2.(3P).4s 4P → 3s2.3p2.(3P).4p 4D* | Measured | NIST | |
| 547.3617 nm | 20000 | S II | emission | 3s2.3p2.(3P).4s 4P → 3s2.3p2.(3P).4p 4D* | Measured | NIST | |
| 550.9702 nm | 20000 | S II | emission | 3s2.3p2.(3P).4s 4P → 3s2.3p2.(3P).4p 4D* | Measured | NIST | |
| 560.6158 nm | 20000 | S II | emission | 3s2.3p2.(3P).3d 4F → 3s2.3p2.(3P).4p 4D* | Measured | NIST | |
| 563.998 nm | 20000 | S II | emission | 3s2.3p2.(3P).4s 2P → 3s2.3p2.(3P).4p 2D* | Measured | NIST | |
| 414.5059 nm | 16000 | S II | emission | 3s2.3p2.(3P).4p 4D* → 3s2.3p2.(3P).4d 4F | Measured | NIST | |
| 429.44 nm | 16000 | S II | emission | 3s2.3p2.(3P).4p 4P* → 3s2.3p2.(3P).4d 4D | Measured | NIST | |
| 481.5553 nm | 16000 | S II | emission | 3s2.3p2.(3P).4s 4P → 3s2.3p2.(3P).4p 4S* | Measured | NIST | |
| 534.5715 nm | 16000 | S II | emission | 3s2.3p2.(1D).4s 2D → 3s2.3p2.(1D).4p 2F* | Measured | NIST | |
| 393.326 nm | 13000 | S II | emission | 3s2.3p2.(3P).4p 2D* → 3s2.3p2.(3P).4d 2F | Measured | NIST | |
| 402.875 nm | 13000 | S II | emission | 3s2.3p2.(3P).4p 4D* → 3s2.3p2.(3P).4d 4D | Measured | NIST | |
| 414.2259 nm | 13000 | S II | emission | 3s2.3p2.(3P).4p 4D* → 3s2.3p2.(3P).4d 4F | Measured | NIST | |
| 417.4266 nm | 13000 | S II | emission | 3s2.3p2.(1D).4p 2F* → 3s2.3p2.(1D).4d 2G | Measured | NIST | |
| 426.7762 nm | 13000 | S II | emission | 3s2.3p2.(3P).4p 4P* → 3s2.3p2.(3P).4d 4D | Measured | NIST | |
| 452.4942 nm | 13000 | S II | emission | 3s2.3p2.(1D).4s 2D → 3s2.3p2.(1D).4p 2P* | Measured | NIST | |
| 500.9564 nm | 13000 | S II | emission | 3s2.3p2.(3P).4s 4P → 3s2.3p2.(3P).4p 4P* | Measured | NIST | |
| 501.4044 nm | 13000 | S II | emission | 3s2.3p2.(3P).4s 2P → 3s2.3p2.(3P).4p 2P* | Measured | NIST | |
| 521.2614 nm | 13000 | S II | emission | 3s2.3p2.(1D).4s 2D → 3s2.3p2.(1D).4p 2D* | Measured | NIST | |
| 630.5479 nm | 13000 | S II | emission | 3s2.3p2.(3P).3d 4D → 3s2.3p2.(3P).4p 4P* | Measured | NIST | |
| 556.4958 nm | 12000 | S II | emission | 3s2.3p2.(3P).4s 4P → 3s2.3p2.(3P).4p 4D* | Measured | NIST | |
| 564.0336 nm | 12000 | S II | emission | 3s2.3p2.(3P).3d 4F → 3s2.3p2.(3P).4p 4D* | Measured | NIST | |
| 564.6998 nm | 12000 | S II | emission | 3s2.3p2.(3P).4s 2P → 3s2.3p2.(3P).4p 2D* | Measured | NIST | |
| 565.9998 nm | 12000 | S II | emission | 3s2.3p2.(3P).3d 4F → 3s2.3p2.(3P).4p 4D* | Measured | NIST | |
| 628.6951 nm | 12000 | S II | emission | 3s2.3p2.(3P).3d 2F → 3s2.3p2.(3P).4p 2D* | Measured | NIST | |
| 392.3449 nm | 10000 | S II | emission | 3s2.3p2.(3P).4p 2D* → 3s2.3p2.(3P).4d 2F | Measured | NIST | |
| 446.358 nm | 10000 | S II | emission | 3s2.3p2.(3P).4p 4D* → 3s2.3p2.(3P).5s 4P | Measured | NIST | |
| 639.7363 nm | 10000 | S II | emission | 3s2.3p2.(3P).3d 4D → 3s2.3p2.(3P).4p 4P* | Measured | NIST | |
| 471.6272 nm | 9900 | S II | emission | 3s2.3p2.(3P).4s 4P → 3s2.3p2.(3P).4p 4S* | Measured | NIST | |
| 499.1968 nm | 9800 | S II | emission | 3s2.3p2.(3P).4s 4P → 3s2.3p2.(3P).4p 4P* | Measured | NIST | |
| 502.72 nm | 9800 | S II | emission | 3s2.3p2.(3P).3d 2P → 3s2.3p2.(3P).4p 2S* | Measured | NIST | |
| 520.1025 nm | 9800 | S II | emission | 3s2.3p2.(1D).4s 2D → 3s2.3p2.(1D).4p 2D* | Measured | NIST | |
| 566.4773 nm | 9700 | S II | emission | 3s2.3p2.(3P).3d 4F → 3s2.3p2.(3P).4p 4D* | Measured | NIST | |
| 631.2666 nm | 7900 | S II | emission | 3s2.3p2.(3P).3d 2F → 3s2.3p2.(3P).4p 2D* | Measured | NIST | |
| 399.3499 nm | 7800 | S II | emission | 3s2.3p2.(3P).3d 2F → 3s2.3p2.(1D).4p 2F* | Measured | NIST | |
| 403.2767 nm | 7800 | S II | emission | 3s2.3p2.(3P).4p 4S* → 3s2.3p2.(3P).4d 4P | Measured | NIST | |
| 417.4001 nm | 7700 | S II | emission | 3s2.3p2.(1D).4p 2F* → 3s2.3p2.(1D).4d 2G | Measured | NIST | |
| 446.443 nm | 7700 | S II | emission | 3s2.3p2.(1D).3d 2F → 3s2.3p2.(3P<2>).4f 2[5]* | Measured | NIST | |
| 448.3428 nm | 7700 | S II | emission | 3s2.3p2.(3P).4p 4D* → 3s2.3p2.(3P).5s 4P | Measured | NIST | |
| 465.6762 nm | 7700 | S II | emission | 3s2.3p2.(3P).4s 4P → 3s2.3p2.(3P).4p 4S* | Measured | NIST | |
| 491.7197 nm | 7600 | S II | emission | 3s2.3p2.(3P).4s 2P → 3s2.3p2.(3P).4p 2P* | Measured | NIST | |
| 492.5347 nm | 7600 | S II | emission | 3s2.3p2.(3P).4s 4P → 3s2.3p2.(3P).4p 4P* | Measured | NIST | |
| 510.3332 nm | 7600 | S II | emission | 3s2.3p2.(3P).4s 4P → 3s2.3p2.(3P).4p 4P* | Measured | NIST | |
| 581.9238 nm | 7500 | S II | emission | 3s2.3p2.(3P).4s 2P → 3s2.3p2.(3P).4p 2D* | Measured | NIST | |
| 639.8015 nm | 7500 | S II | emission | 3s2.3p2.(3P).3d 4D → 3s2.3p2.(3P).4p 4P* | Measured | NIST |
Extended Properties
Covalent Radii (Extended)
Van der Waals Radii
Atomic & Metallic Radii
Numbering Scales
Electronegativity Scales
Polarizability & Dispersion
Chemical Affinity
Supply Risk & Economics
Phase Transitions & Allotropes
| Transition temperature | 368.35 K |
| Boiling point | 717.76 K |
| Critical point (temperature) | 1314.15 K |
| Critical point (pressure) | 20.7 MPa |
| Melting point | 388.36 K |
| Boiling point | 717.76 K |
| Critical point (temperature) | 1314.15 K |
Oxidation State Categories
Advanced Reference Data
Screening Constants (5)
| n | Orbital | σ |
|---|---|---|
| 1 | s | 0.4591 |
| 2 | p | 4.023 |
| 2 | s | 5.3712 |
| 3 | p | 10.5181 |
| 3 | s | 9.6331 |
Crystal Radii Detail (4)
| Charge | CN | Spin | rcrystal (pm) | Origin |
|---|---|---|---|---|
| -2 | VI | 170 | Pauling's (1960) crystal radius, | |
| 4 | VI | 51 | Ahrens (1952) ionic radius, | |
| 6 | IV | 26 | ||
| 6 | VI | 43 | calculated, |
Isotope Decay Modes (38)
| Isotope | Mode | Intensity |
|---|---|---|
| 26 | 2p | — |
| 27 | B+ | 100% |
| 27 | B+p | 61% |
| 27 | 2p | 3% |
| 28 | B+ | 100% |
| 28 | B+p | 20.7% |
| 29 | B+ | 100% |
| 29 | B+p | 46.4% |
| 30 | B+ | 100% |
| 31 | B+ | 100% |
X‑ray Scattering Factors (504)
| Energy (eV) | f₁ | f₂ |
|---|---|---|
| 10 | — | 4.05213 |
| 10.1617 | — | 4.23511 |
| 10.3261 | — | 4.42637 |
| 10.4931 | — | 4.62625 |
| 10.6628 | — | 4.83517 |
| 10.8353 | — | 5.05351 |
| 11.0106 | — | 5.28172 |
| 11.1886 | — | 5.52024 |
| 11.3696 | — | 5.79892 |
| 11.5535 | — | 6.15554 |
Additional Data
Estimated Crustal Abundance
The estimated element abundance in the earth's crust.
3.50×102 milligrams per kilogram
References (1)
Estimated Oceanic Abundance
The estimated element abundance in the earth's oceans.
9.05×102 milligrams per liter
References (1)
Sources
Sources of this element.
Sulfur is found in meteorites. R.W. Wood suggests that the dark area near the crater Aristarchus is a sulfur deposit.
Sulfur occurs native in the vicinity of volcanos and hot springs. It is widely distributed in nature as iron pyrites, galena, sphalerite, cinnabar, stibnite, gypsum, epsom salts, celestite, barite, etc.
References (1)
- [6] Sulfur https://periodic.lanl.gov/16.shtml
Production
Production of this element (from raw materials or other compounds containing the element).
Sulfur is commercially recovered from wells sunk into the salt domes along the Gulf Coast of the U.S. Using the Frasch process heated water is forced into the wells to melt the sulfur, which is then brought to the surface.
Sulfur also occurs in natural gas and petroleum crudes and must be removed from these products. Formerly this was done chemically, which wasted the sulfur; new processes now permit recovery. Large amounts of sulfur are being recovered from Alberta gas fields.
References (1)
- [6] Sulfur https://periodic.lanl.gov/16.shtml
Isotopes in Forensic Science and Anthropology
Information on the use of this element's isotopes in forensic science and anthropology.
The isotope-amount ratio n(34S)/n(32S) can be used to authenticate the dietary source of cattle. First, stable isotopes are measured to infer the dietary source of the cattle. Once the source of the diet is found, the isotopic compositions can be traced in certain muscle groups of the cattle and can be used to determine if the diet of the animal has been changed or if the feed is consistent with what the animal has been claimed to have been fed [145] [145] B. Bahar, A. P. Moloney, F. J. Monahan, S. M. Harrison, A. Zazzo, C. M. Scrimgeour, I. S. Begley, O. Schmidt. J. Anim. Sci.87, 905 (2009).[145] B. Bahar, A. P. Moloney, F. J. Monahan, S. M. Harrison, A. Zazzo, C. M. Scrimgeour, I. S. Begley, O. Schmidt. J. Anim. Sci.87, 905 (2009)..
References (2)
- [145] B. Bahar, A. P. Moloney, F. J. Monahan, S. M. Harrison, A. Zazzo, C. M. Scrimgeour, I. S. Begley, O. Schmidt. J. Anim. Sci.87, 905 (2009).
- [4] IUPAC Periodic Table of the Elements and Isotopes (IPTEI) https://doi.org/10.1515/pac-2015-0703
References
(9)
Data deposited in or computed by PubChem
The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.
Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.
The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.
Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/
The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.
The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database
This section provides all form of data related to element Sulfur.
The element property data was retrieved from publications.

