S 16

Sulfur (S)

nonmetal
Period: 3 Group: 16 Block: p

Solid

Standard Atomic Weight

32.06 u [32.059, 32.076]

Electron configuration

[Ne] 3s2 3p4

Melting point

115.21 °C (388.36 K)

Boiling point

444.6 °C (717.75 K)

Density

2067 kg/m³

Oxidation states

−2, −1, 0, +1, +2, +3, +4, +5, +6

Electronegativity (Pauling)

2.58

Ionization energy (1st)

Discovery year

1777

Atomic radius

100 pm

Details

Name origin Latin: sulphur (brimstone).
Discoverers Known to the ancients.

Sulfur is a reactive nonmetal in group 16, occurring naturally as elemental sulfur and in sulfide and sulfate minerals. It forms many allotropes and a large range of compounds, especially with oxygen, hydrogen, metals, and organic groups. Its chemistry is central to fertilizers, petroleum refining, vulcanized rubber, and biological molecules such as amino acids and cofactors.

Sulfur is pale yellow, odorless, brittle solid, which is insoluble in water but soluble in carbon disulfide. In every state, whether gas, liquid or solid, elemental sulfur occurs in more than one allotropic form or modification; these present a confusing multitude of forms whose relations are not yet fully understood.

In 1975, University of Pennsylvania scientists reported synthesis of polymeric sulfur nitride, which has the properties of a metal, although it contains no metal atoms. The material has unusual optical and electrical properties.

High-purity sulfur is commercially available in purities of 99.999+%.

Amorphous or "plastic" sulfur is obtained by fast cooling of the crystalline form. X-ray studies indicate that amorphous sulfur may have a helical structure with eight atoms per spiral. Crystalline sulfur seems to be made of rings, each containing eight sulfur atoms, which fit together to give a normal X-ray pattern.

The name derives from the Latin sulphurium and the Sanskrit sulveri. Sulfur was known as brenne stone for "combustible stone" from which brim-stone is derived. It was known from prehistoric times and thought to contain hydrogen and oxygen. In 1809, the French chemists Louis-Joseph Gay-Lussac and Louis-Jacques Thenard proved the elemental nature of sulfur.

Sulfur, the tenth most abundant element in the universe, has been known since ancient times. Sometime around 1777, Antoine Lavoisier convinced the rest of the scientific community that sulfur was an element. Sulfur is a component of many common minerals, such as galena (PbS), gypsum (CaSO4·2(H2O), pyrite (FeS2), sphalerite (ZnS or FeS), cinnabar (HgS), stibnite (Sb2S3), epsomite (MgSO4·7(H2O)), celestite (SrSO4) and barite (BaSO4). Nearly 25% of the sulfur produced today is recovered from petroleum refining operations and as a byproduct of extracting other materials from sulfur containing ores. The majority of the sulfur produced today is obtained from underground deposits, usually found in conjunction with salt deposits, with a process known as the Frasch process. Sulfur is a pale yellow, odorless and brittle material. It displays three allotropic forms: orthorhombic, monoclinic and amorphous. The orthorhombic form is the most stable form of sulfur. Monoclinic sulfur exists between the temperatures of 96°C and 119°C and reverts back to the orthorhombic form when cooled. Amorphous sulfur is formed when molten sulfur is quickly cooled. Amorphous sulfur is soft and elastic and eventually reverts back to the orthorhombic form.

Known to the ancients; referred to in Genesis as brimstone.

Images

Properties

Physical

Atomic radius (empirical) 100 pm
Covalent radius 105 pm
Van der Waals radius 180 pm
Metallic radius 104 pm
Density
Molar volume 0.0155 L/mol
Phase at STP solid
Melting point 115.21 °C
Boiling point 444.6 °C
Thermal conductivity 0.27 W/(m·K)
Specific heat capacity 0.708 J/(g·K)
Molar heat capacity 22.7 J/(mol·K)
Crystal structure orthorhombic

Chemical

Electronegativity (Pauling) 2.58
Electronegativity (Allen) 2.589
Electron affinity
Ionization energy (1st)
Ionization energy (2nd)
Ionization energy (3rd)
Ionization energy (4th)
Ionization energy (5th)
Oxidation states −2, −1, 0, +1, +2, +3, +4, +5, +6
Valence electrons 6
Allotropes ["monoclinic", "rhombic"]
Electron configuration
Electron configuration (semantic)

Thermodynamic

Critical point (temperature) 1041 °C
Critical point (pressure) 2.070000e+7 Pa
Heat of fusion 0.01793025 eV
Heat of vaporization 0.46639374 eV
Heat of sublimation 2.870913 eV
Heat of atomization 2.870913 eV
Atomization enthalpy

Nuclear

Stable isotopes 4
Discovery year 1777

Abundance

Abundance (Earth's crust) 350 mg/kg
Abundance (ocean)

Reactivity

N/A

Crystal Structure

Lattice constant a 1047 pm

Electronic Structure

Electrons per shell 2, 8, 6

Identifiers

CAS number 7704-34-9
Term symbol
InChI InChI=1S/S
InChI Key NINIDFKCEFEMDL-UHFFFAOYSA-N

Electron Configuration Measured

Ion charge
Protons 16
Electrons 16
Charge Neutral
Configuration S: 3s² 3p⁴
Electron configuration
Measured
[Ne] 3s² 3p⁴
1s² 2s² 2p⁶ 3s² 3p⁴
Orbital diagram
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
4/6 2↑
Total electrons: 16 Unpaired: 2 ?

Atomic model

Protons 16
Neutrons 16
Electrons 16
Mass number 32
Stability Stable

Isotopes change neutron count, mass, and stability — not the electron configuration of a neutral atom.

Schematic atomic model, not to scale.

Atomic Fingerprint

Emission / Absorption Spectrum

25 / 50 (50 with intensity)
Measured
Emission Visible: 380–750 nm

Isotope Distribution

3294.9900%344.2500%330.7500%360.0100%Mass numberNatural abundance (%)
Mass numberAtomic mass (u)Natural abundanceHalf-life
32 Stable31.9720711744 ± 0.000000001494.9900%Stable
33 Stable32.9714589098 ± 0.00000000150.7500%Stable
34 Stable33.967867004 ± 0.0000000474.2500%Stable
36 Stable35.96708071 ± 0.00000020.0100%Stable
Measured

Phase / State

1 atm / 101.325 kPa
Solid 25 °C (298.15 K)

Reason: 90.2 °C below melting point (115.21 °C)

Melting point 115.21 °C
Boiling point 444.6 °C
Below melting by 90.2 °C
0 K Current temperature: 25 °C 6000 K
Phase timeline

Schematic, not to scale

Solid
Liquid
Gas
Melting
Boiling
25°C
Solid
Liquid
Gas
Current

Phase transition points

Melting point Literature
115.21 °C
Boiling point Literature
444.6 °C
Current phase Calculated
Solid

Transition energies

Heat of fusion Literature
0.01793025 eV

Energy required to melt 1 mol at melting point

Heat of vaporization Literature
0.46639374 eV

Energy required to vaporize 1 mol at boiling point

Heat of sublimation Literature
2.870913 eV

Energy required to sublime 1 mol at sublimation point

Density

Reference density Literature
2067 kg/m³

At standard conditions

Current density Calculated
2067 kg/m³

At standard conditions

Advanced

Critical point Literature
1041 °C

Atomic Spectra

Showing 10 of 16 Atomic Spectra. Sorted by ion charge (ascending).

Lines Holdings ?

IonChargeTotal linesTransition probabilitiesLevel designations
S I 0143710521429
S II +113497531349
S III +2329273329
S IV +311999991199
S V +4866699866
S VI +5457393457
S VII +6259253255
S VIII +7254253254
S IX +8175175175
S X +9270268270
NIST Lines Holdings →

Levels Holdings ?

IonChargeLevels
S I 0382
S II +1247
S III +259
S IV +3142
S V +4150
S VI +588
S VII +657
S VIII +754
S IX +845
S X +944
NIST Levels Holdings →
16 S 32.067499999999995

Sulfur — Atomic Orbital Visualizer

[Ne]3s23p4
Energy levels 2 8 6
Oxidation states -2, -1, 0, +1, +2, +3, +4, +5, +6
HOMO 3p n=3 · l=1 · m=-1
Sulfur — Atomic Orbital Visualizer Preview
Three.js loads only on request
16 S 32.067499999999995

Sulfur — Crystal Structure Visualizer

Orthorhombic · Pearson N/A
Experimental
Pearson N/A
Sulfur — Crystal Structure Visualizer Preview
Three.js loads only on request

Ionic Radii

ChargeCoordinationSpinRadius
-26N/A184 pm
+46N/A37 pm
+64N/A12 pm
+66N/A28.999999999999996 pm

Compounds

S
32.070 u
S-2
32.070 u
S-
32.070 u
S-2
33.968 u
S
33.968 u
S
32.971 u
S
31.972 u
S-2
34.969 u

Isotopes (4)

Eleven isotopes of sulfur exist. None of the four isotopes that are found in nature are radioactive. A finely divided form of sulfur, known as flowers of sulfur, is obtained by sublimation.

Mass numberAtomic mass (u)Natural abundanceHalf-lifeDecay mode
32 Stable31.9720711744 ± 0.000000001494.9900% ± 0.2600%Stable
stable
33 Stable32.9714589098 ± 0.00000000150.7500% ± 0.0200%Stable
stable
34 Stable33.967867004 ± 0.0000000474.2500% ± 0.2400%Stable
stable
36 Stable35.96708071 ± 0.00000020.0100% ± 0.0100%Stable
stable
32 Stable
Atomic mass (u) 31.9720711744 ± 0.0000000014
Natural abundance 94.9900% ± 0.2600%
Half-life Stable
Decay mode
stable
33 Stable
Atomic mass (u) 32.9714589098 ± 0.0000000015
Natural abundance 0.7500% ± 0.0200%
Half-life Stable
Decay mode
stable
34 Stable
Atomic mass (u) 33.967867004 ± 0.000000047
Natural abundance 4.2500% ± 0.2400%
Half-life Stable
Decay mode
stable
36 Stable
Atomic mass (u) 35.96708071 ± 0.0000002
Natural abundance 0.0100% ± 0.0100%
Half-life Stable
Decay mode
stable

Spectral Lines

Showing 50 of 556 Spectral Lines. Only spectral lines with measured intensity are shown by default.

Wavelength (nm)IntensityIon stageTypeTransitionAccuracySource
545.3853 nm42000S IIemission3s2.3p2.(3P).4s 4P → 3s2.3p2.(3P).4p 4D*MeasuredNIST
543.2797 nm30000S IIemission3s2.3p2.(3P).4s 4P → 3s2.3p2.(3P).4p 4D*MeasuredNIST
416.2665 nm25000S IIemission3s2.3p2.(3P).4p 4D* → 3s2.3p2.(3P).4d 4FMeasuredNIST
532.0715 nm24000S IIemission3s2.3p2.(1D).4s 2D → 3s2.3p2.(1D).4p 2F*MeasuredNIST
415.3066 nm20000S IIemission3s2.3p2.(3P).4p 4D* → 3s2.3p2.(3P).4d 4FMeasuredNIST
503.2435 nm20000S IIemission3s2.3p2.(3P).4s 4P → 3s2.3p2.(3P).4p 4P*MeasuredNIST
542.8658 nm20000S IIemission3s2.3p2.(3P).4s 4P → 3s2.3p2.(3P).4p 4D*MeasuredNIST
547.3617 nm20000S IIemission3s2.3p2.(3P).4s 4P → 3s2.3p2.(3P).4p 4D*MeasuredNIST
550.9702 nm20000S IIemission3s2.3p2.(3P).4s 4P → 3s2.3p2.(3P).4p 4D*MeasuredNIST
560.6158 nm20000S IIemission3s2.3p2.(3P).3d 4F → 3s2.3p2.(3P).4p 4D*MeasuredNIST
563.998 nm20000S IIemission3s2.3p2.(3P).4s 2P → 3s2.3p2.(3P).4p 2D*MeasuredNIST
414.5059 nm16000S IIemission3s2.3p2.(3P).4p 4D* → 3s2.3p2.(3P).4d 4FMeasuredNIST
429.44 nm16000S IIemission3s2.3p2.(3P).4p 4P* → 3s2.3p2.(3P).4d 4DMeasuredNIST
481.5553 nm16000S IIemission3s2.3p2.(3P).4s 4P → 3s2.3p2.(3P).4p 4S*MeasuredNIST
534.5715 nm16000S IIemission3s2.3p2.(1D).4s 2D → 3s2.3p2.(1D).4p 2F*MeasuredNIST
393.326 nm13000S IIemission3s2.3p2.(3P).4p 2D* → 3s2.3p2.(3P).4d 2FMeasuredNIST
402.875 nm13000S IIemission3s2.3p2.(3P).4p 4D* → 3s2.3p2.(3P).4d 4DMeasuredNIST
414.2259 nm13000S IIemission3s2.3p2.(3P).4p 4D* → 3s2.3p2.(3P).4d 4FMeasuredNIST
417.4266 nm13000S IIemission3s2.3p2.(1D).4p 2F* → 3s2.3p2.(1D).4d 2GMeasuredNIST
426.7762 nm13000S IIemission3s2.3p2.(3P).4p 4P* → 3s2.3p2.(3P).4d 4DMeasuredNIST
452.4942 nm13000S IIemission3s2.3p2.(1D).4s 2D → 3s2.3p2.(1D).4p 2P*MeasuredNIST
500.9564 nm13000S IIemission3s2.3p2.(3P).4s 4P → 3s2.3p2.(3P).4p 4P*MeasuredNIST
501.4044 nm13000S IIemission3s2.3p2.(3P).4s 2P → 3s2.3p2.(3P).4p 2P*MeasuredNIST
521.2614 nm13000S IIemission3s2.3p2.(1D).4s 2D → 3s2.3p2.(1D).4p 2D*MeasuredNIST
630.5479 nm13000S IIemission3s2.3p2.(3P).3d 4D → 3s2.3p2.(3P).4p 4P*MeasuredNIST
556.4958 nm12000S IIemission3s2.3p2.(3P).4s 4P → 3s2.3p2.(3P).4p 4D*MeasuredNIST
564.0336 nm12000S IIemission3s2.3p2.(3P).3d 4F → 3s2.3p2.(3P).4p 4D*MeasuredNIST
564.6998 nm12000S IIemission3s2.3p2.(3P).4s 2P → 3s2.3p2.(3P).4p 2D*MeasuredNIST
565.9998 nm12000S IIemission3s2.3p2.(3P).3d 4F → 3s2.3p2.(3P).4p 4D*MeasuredNIST
628.6951 nm12000S IIemission3s2.3p2.(3P).3d 2F → 3s2.3p2.(3P).4p 2D*MeasuredNIST
392.3449 nm10000S IIemission3s2.3p2.(3P).4p 2D* → 3s2.3p2.(3P).4d 2FMeasuredNIST
446.358 nm10000S IIemission3s2.3p2.(3P).4p 4D* → 3s2.3p2.(3P).5s 4PMeasuredNIST
639.7363 nm10000S IIemission3s2.3p2.(3P).3d 4D → 3s2.3p2.(3P).4p 4P*MeasuredNIST
471.6272 nm9900S IIemission3s2.3p2.(3P).4s 4P → 3s2.3p2.(3P).4p 4S*MeasuredNIST
499.1968 nm9800S IIemission3s2.3p2.(3P).4s 4P → 3s2.3p2.(3P).4p 4P*MeasuredNIST
502.72 nm9800S IIemission3s2.3p2.(3P).3d 2P → 3s2.3p2.(3P).4p 2S*MeasuredNIST
520.1025 nm9800S IIemission3s2.3p2.(1D).4s 2D → 3s2.3p2.(1D).4p 2D*MeasuredNIST
566.4773 nm9700S IIemission3s2.3p2.(3P).3d 4F → 3s2.3p2.(3P).4p 4D*MeasuredNIST
631.2666 nm7900S IIemission3s2.3p2.(3P).3d 2F → 3s2.3p2.(3P).4p 2D*MeasuredNIST
399.3499 nm7800S IIemission3s2.3p2.(3P).3d 2F → 3s2.3p2.(1D).4p 2F*MeasuredNIST
403.2767 nm7800S IIemission3s2.3p2.(3P).4p 4S* → 3s2.3p2.(3P).4d 4PMeasuredNIST
417.4001 nm7700S IIemission3s2.3p2.(1D).4p 2F* → 3s2.3p2.(1D).4d 2GMeasuredNIST
446.443 nm7700S IIemission3s2.3p2.(1D).3d 2F → 3s2.3p2.(3P<2>).4f 2[5]*MeasuredNIST
448.3428 nm7700S IIemission3s2.3p2.(3P).4p 4D* → 3s2.3p2.(3P).5s 4PMeasuredNIST
465.6762 nm7700S IIemission3s2.3p2.(3P).4s 4P → 3s2.3p2.(3P).4p 4S*MeasuredNIST
491.7197 nm7600S IIemission3s2.3p2.(3P).4s 2P → 3s2.3p2.(3P).4p 2P*MeasuredNIST
492.5347 nm7600S IIemission3s2.3p2.(3P).4s 4P → 3s2.3p2.(3P).4p 4P*MeasuredNIST
510.3332 nm7600S IIemission3s2.3p2.(3P).4s 4P → 3s2.3p2.(3P).4p 4P*MeasuredNIST
581.9238 nm7500S IIemission3s2.3p2.(3P).4s 2P → 3s2.3p2.(3P).4p 2D*MeasuredNIST
639.8015 nm7500S IIemission3s2.3p2.(3P).3d 4D → 3s2.3p2.(3P).4p 4P*MeasuredNIST

Extended Properties

Covalent Radii (Extended)

Covalent radius (Pyykkö)  
Covalent radius (Pyykkö, double)  
Covalent radius (Pyykkö, triple)  
Covalent radius (Bragg)  

Van der Waals Radii

Bondi  
Batsanov  
Alvarez  
UFF  
MM3  
Dreiding  
Rowland–Taylor  

Atomic & Metallic Radii

Atomic radius (Rahm)  
Metallic radius (C12)  

Numbering Scales

Mendeleev
Pettifor
Glawe

Electronegativity Scales

Ghosh
Gunnarsson–Lundqvist
Robles–Bartolotti

Polarizability & Dispersion

Dipole polarizability  
Dipole polarizability (unc.)  
C₆  
C₆ (Gould–Bučko)  

Chemical Affinity

Proton affinity  
Gas basicity  

Supply Risk & Economics

Production concentration
Relative supply risk
Political stability (top producer)

Phase Transitions & Allotropes

rhombic
Transition temperature368.35 K
Boiling point717.76 K
Critical point (temperature)1314.15 K
Critical point (pressure)20.7 MPa
monoclinic
Melting point388.36 K
Boiling point717.76 K
Critical point (temperature)1314.15 K

Oxidation State Categories

+2 main
0 extended
+1 extended
+3 extended
+5 extended
+4 main
+6 main
−1 extended
−2 main

Advanced Reference Data

Screening Constants (5)
nOrbitalσ
1s0.4591
2p4.023
2s5.3712
3p10.5181
3s9.6331
Crystal Radii Detail (4)
ChargeCNSpinrcrystal (pm)Origin
-2VI170Pauling's (1960) crystal radius,
4VI51Ahrens (1952) ionic radius,
6IV26
6VI43calculated,
Isotope Decay Modes (38)
IsotopeModeIntensity
262p
27B+100%
27B+p61%
272p3%
28B+100%
28B+p20.7%
29B+100%
29B+p46.4%
30B+100%
31B+100%
X‑ray Scattering Factors (504)
Energy (eV)f₁f₂
104.05213
10.16174.23511
10.32614.42637
10.49314.62625
10.66284.83517
10.83535.05351
11.01065.28172
11.18865.52024
11.36965.79892
11.55356.15554

Additional Data

Sources

Sources of this element.

Sulfur is found in meteorites. R.W. Wood suggests that the dark area near the crater Aristarchus is a sulfur deposit.

Sulfur occurs native in the vicinity of volcanos and hot springs. It is widely distributed in nature as iron pyrites, galena, sphalerite, cinnabar, stibnite, gypsum, epsom salts, celestite, barite, etc.

References (1)

Production

Production of this element (from raw materials or other compounds containing the element).

Sulfur is commercially recovered from wells sunk into the salt domes along the Gulf Coast of the U.S. Using the Frasch process heated water is forced into the wells to melt the sulfur, which is then brought to the surface.

Sulfur also occurs in natural gas and petroleum crudes and must be removed from these products. Formerly this was done chemically, which wasted the sulfur; new processes now permit recovery. Large amounts of sulfur are being recovered from Alberta gas fields.

References (1)

Isotopes in Forensic Science and Anthropology

Information on the use of this element's isotopes in forensic science and anthropology.

The isotope-amount ratio n(34S)/n(32S) can be used to authenticate the dietary source of cattle. First, stable isotopes are measured to infer the dietary source of the cattle. Once the source of the diet is found, the isotopic compositions can be traced in certain muscle groups of the cattle and can be used to determine if the diet of the animal has been changed or if the feed is consistent with what the animal has been claimed to have been fed [145] [145] B. Bahar, A. P. Moloney, F. J. Monahan, S. M. Harrison, A. Zazzo, C. M. Scrimgeour, I. S. Begley, O. Schmidt. J. Anim. Sci.87, 905 (2009).[145] B. Bahar, A. P. Moloney, F. J. Monahan, S. M. Harrison, A. Zazzo, C. M. Scrimgeour, I. S. Begley, O. Schmidt. J. Anim. Sci.87, 905 (2009)..

References (2)
  • [145] B. Bahar, A. P. Moloney, F. J. Monahan, S. M. Harrison, A. Zazzo, C. M. Scrimgeour, I. S. Begley, O. Schmidt. J. Anim. Sci.87, 905 (2009).
  • [4] IUPAC Periodic Table of the Elements and Isotopes (IPTEI) https://doi.org/10.1515/pac-2015-0703

References

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
S

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Sulfur

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

License note: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Sulfur

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

License note: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Sulfur

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Sulfur

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Sulfur

This section provides all form of data related to element Sulfur.

9 PubChem Elements
Sulfur

The element property data was retrieved from publications.

Last updated:

Data verified:

Content is reviewed against latest scientific data.