Hg 80

Mercury (Hg)

transition-metal
周期: 6 族: 12 区: d

Liquid

标准原子量

200.592 u

电子排布

[Xe] 6s2 4f14 5d10

熔点

-38.83 °C

沸点

356.73 °C

密度

1.35336e+4 kg/m³

氧化态

−2, +1, +2

电负性(鲍林)

2

第一电离能

10.437504 eV

发现年份

暂无

原子半径

150 pm

详细信息

名称来源 From the Roman god Mercury; symbol from Latin: hydrargyrus (liquid silver).
发现者 Known to the ancients.

Mercury is a heavy, silvery transition metal with the distinctive feature of being liquid near ordinary room temperature. It has a filled 5d shell and commonly forms +1 and +2 compounds, with covalent character more prominent than in many lighter metals. Mercury has been used in instruments, electrical devices, and gold extraction, but many uses have declined because its vapor and several compounds are highly toxic.

It is a heavy, silvery-white metal; a rather poor conductor of heat, as compared with other metals, and a fair conductor of electricity. It easily forms alloys with many metals, such as gold, silver, and tin, which are called amalgams. Its ease in amalgamating with gold is made use of in the recovery of gold from its ores. The most important salts are mercury chloride (corrosive sublimate - a violent poison), mercurous chloride (calomel, occasionally still used in medicine), mercury fulminate, a detonator widely used in explosives, and mercuric sulfide (vermilion, a high-grade paint pigment). Organic mercury compounds are important. It has been found that an electrical discharge causes mercury vapor to combine with neon, argon, krypton, and xenon. These products, held together with van der Waals' forces, correspond to HgNe, HgAr, HgKr, and HgXe. Mercury is a virulent poison and is readily absorbed through the respiratory tract, the gastrointestinal tract, or through unbroken skin. It acts as a cumulative poison and dangerous levels are readily attained in air. Air saturated with mercury vapor at 20°C contains a concentration that exceeds the toxicity limits. The danger increases at higher temperatures. It is important therefore that mercury be handled with care. Containers of mercury should be securely covered and spillage should be avoided. If it is necessary to heat mercury or mercury compounds, it should be done in a well-ventilated hood. Methyl mercury is a dangerous pollutant and is now widely found in water and streams. The triple point of mercury, -38.8344C, is a fixed point on the International Temperature Scale (ITS-90).

The name derives from the Roman god Mercury, the nimble messenger of the gods, because the ancients used that name for the element known from prehistoric times. The symbol Hg derives from the Greek hydrargyrum for "liquid silver" or "quick silver".

Mercury was known to the ancient Chinese and Hindus and has been found in 3500 year old Egyptian tombs. Mercury is not usually found free in nature and is primarily obtained from the mineral cinnabar (HgS). Spain and Italy produce about half of the world's supply of Mercury.

From Greek hydoor. Known to ancient Chinese and Hindus; found in Egyptian tombs of 1500 B.C. Mercury is the only common metal liquid at ordinary temperatures. It only rarely occurs free in nature. The chief ore is cinnabar; Spain and Italy produce about 50% of the world's supply of the metal. The commercial unit for handling mercury is the "flask," which weighs 76 lb. The metal is obtained by heating cinnabar in a current of air and by condensing the vapor.

图片

性质

物理性质

原子半径(经验值)
150 pm 比较所有元素的原子半径(经验值) →
共价半径
132 pm 比较所有元素的共价半径 →
范德华半径
209 pm 比较所有元素的范德华半径 →
金属半径
139 pm 比较所有元素的金属半径 →
密度
1.35336 × 104 kg/m³ 比较所有元素的密度 →
摩尔体积
0.0148 L/mol
标准温度和压力下的物相
液态 比较所有元素的标准温度和压力下的物相 →
熔点
-38.83 °C 比较所有元素的熔点 →
沸点
356.73 °C 比较所有元素的沸点 →
热导率
8.3 W/(m·K) 比较所有元素的热导率 →
比热容
0.14 J/(g·K) 比较所有元素的比热容 →
摩尔热容
27.983 J/(mol·K) 比较所有元素的摩尔热容 →
晶体结构
菱方 比较所有元素的晶体结构 →

化学性质

电负性(鲍林)
2 比较所有元素的电负性(鲍林) →
电负性(Allen)
1.76
电子亲和能
-0.5 eV (负值——预计该原子不结合额外电子)
第一电离能
10.437504 eV 比较所有元素的第一电离能 →
第二电离能
18.756945 eV 比较所有元素的第二电离能 →
第三电离能
34.490119 eV 比较所有元素的第三电离能 →
第四电离能
48.550167 eV 比较所有元素的第四电离能 →
第五电离能
61.200211 eV 比较所有元素的第五电离能 →
氧化态
−2, +1, +2 比较所有元素的氧化态 →
价电子
12 比较所有元素的价电子 →
电子排布
[Xe] 6s2 4f14 5d10

热力学性质

三相点(温度)
-38.8344 °C
临界点(温度)
1491 °C
临界点(压力)
1.67e+8 Pa
熔化热
0.02373426 eV 比较所有元素的熔化热 →
汽化热
0.61263409 eV 比较所有元素的汽化热 →
升华热
0.63636835 eV
原子化热
0.63636835 eV
原子化焓
0.63616106 eV

丰度

丰度(地壳)
0.085 mg/kg 比较所有元素的丰度(地壳) →
丰度(海洋)
3 × 10−5 mg/L 比较所有元素的丰度(海洋) →

晶体结构

晶格常数a
299 pm

电子结构

各电子层电子数
2, 8, 18, 32, 18, 2 比较所有元素的各电子层电子数 →

标识符

CAS登记号
7439-97-6 比较所有元素的CAS登记号 →
谱项符号
1S0
InChI
InChI=1S/Hg
InChI Key
QSHDDOUJBYECFT-UHFFFAOYSA-N

电子排布 实测值

离子电荷
质子 80
电子 80
电荷 中性
电子排布 Hg: 4f¹⁴ 5d¹⁰ 6s²
电子排布
实测值
[Xe] 4f¹⁴ 5d¹⁰ 6s²
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d¹⁰ 6s²
轨道图
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
2/2
4d
10/10
5p
6/6
6s
2/2
4f
14/14
5d
10/10
电子总数: 80 未配对: 0

原子模型

质子 80
中子 122
电子 80
质量数 202
稳定性 稳定

不同同位素的中子数、质量和稳定性不同,但中性原子的电子排布不变。

原子模型示意图,未按比例绘制。

原子指纹

发射 / 吸收光谱

25 / 50 (50 50条具有强度数据)
实测值
发射 可见光:380–750 nm

同位素分布

20229.8600%20023.1000%19916.8700%20113.1800%1989.9700%2046.8700%质量数天然丰度(%)
质量数原子质量(u)天然丰度半衰期
198 稳定197.9667686 ± 0.000000529.9700%稳定
199 稳定198.96828064 ± 0.0000004616.8700%稳定
200 稳定199.96832659 ± 0.0000004723.1000%稳定
201 稳定200.97030284 ± 0.0000006913.1800%稳定
202 稳定201.9706434 ± 0.0000006929.8600%稳定
204 稳定203.97349398 ± 0.000000536.8700%稳定
实测值

物相 / 状态

1 atm / 101.325 kPa
液态 25 °C (298.15 K)

原因: 位于熔点(-38.83 °C)与沸点(356.73 °C)之间

熔点 -38.83 °C
沸点 356.73 °C
相对于相变点 位于相变点之间
0 K 当前温度: 25 °C 6000 K
物相变化轴

示意图,未按比例绘制

固态
液态
气态
熔化
沸腾
25°C
固态
液态
气态
当前

相变点

熔点 文献值
-38.83 °C
沸点 文献值
356.73 °C
当前物相 计算值
液态

相变能

熔化热 文献值
0.02373426 eV

在熔点熔化1 mol物质所需的能量

汽化热 文献值
0.61263409 eV

在沸点汽化1 mol物质所需的能量

升华热 文献值
0.63636835 eV

在升华点升华1 mol物质所需的能量

密度

参考密度 文献值
1.35336e+4 kg/m³

标准条件下

当前密度 计算值
暂无

暂无液相数据

高级

三相点 文献值
-38.8344 °C
临界点 文献值
1491 °C

原子光谱

已显示10项,共81项。 按离子电荷升序排列。

收录谱线 ?

离子电荷谱线总数跃迁概率能级标记
Hg I 075453708
198Hg I 同位素02100210
Hg II +1554446463
Hg III +25200
NIST收录谱线 →

收录能级 ?

离子电荷能级
Hg I 0299
198Hg I 同位素061
Hg II +1115
Hg III +294
Hg IV +361
Hg V +42
Hg VI +52
Hg VII +62
Hg VIII +72
Hg IX +82
NIST收录能级 →
80 Hg 200.592

Mercury — 原子轨道可视化工具

[Xe]6s24f145d10
能级 2 8 18 32 18 2
氧化态 -2, +1, +2
HOMO 6s n=6 · l=0 · m=0
Mercury — 原子轨道可视化预览
Three.js仅在需要时加载
80 Hg 200.592

Mercury — 晶体结构可视化工具

标准条件下无晶体结构——在298 K、1 atm下为液态

暂无固相晶体结构数据

晶体结构: rhombohedral

离子半径

电荷配位自旋半径
+13暂无97 pm
+16暂无119 pm
+22暂无69 pm
+24暂无96 pm
+26暂无102 pm
+28暂无113.99999999999999 pm

化合物

Hg
200.590 u
Hg+2
200.590 u
Hg+
200.590 u
Hg
202.973 u
Hg
196.967 u
Hg
198.968 u
Hg
194.967 u
Hg
201.971 u
Hg
200.970 u
Hg
193.965 u
Hg
192.967 u
Hg
203.973 u
Hg
199.968 u
Hg
197.967 u
Hg+2
196.967 u

同位素 (6)

质量数原子质量(u)天然丰度半衰期衰变方式
198 稳定197.9667686 ± 0.000000529.9700% ± 0.2000%稳定
stable
199 稳定198.96828064 ± 0.0000004616.8700% ± 0.2200%稳定
stable
200 稳定199.96832659 ± 0.0000004723.1000% ± 0.1900%稳定
stable
201 稳定200.97030284 ± 0.0000006913.1800% ± 0.0900%稳定
stable
202 稳定201.9706434 ± 0.0000006929.8600% ± 0.2600%稳定
stable
204 稳定203.97349398 ± 0.000000536.8700% ± 0.1500%稳定
stable
198 稳定
原子质量(u) 197.9667686 ± 0.00000052
天然丰度 9.9700% ± 0.2000%
半衰期 稳定
衰变方式
stable
199 稳定
原子质量(u) 198.96828064 ± 0.00000046
天然丰度 16.8700% ± 0.2200%
半衰期 稳定
衰变方式
stable
200 稳定
原子质量(u) 199.96832659 ± 0.00000047
天然丰度 23.1000% ± 0.1900%
半衰期 稳定
衰变方式
stable
201 稳定
原子质量(u) 200.97030284 ± 0.00000069
天然丰度 13.1800% ± 0.0900%
半衰期 稳定
衰变方式
stable
202 稳定
原子质量(u) 201.9706434 ± 0.00000069
天然丰度 29.8600% ± 0.2600%
半衰期 稳定
衰变方式
stable
204 稳定
原子质量(u) 203.97349398 ± 0.00000053
天然丰度 6.8700% ± 0.1500%
半衰期 稳定
衰变方式
stable

谱线

已显示50项,共218项。 默认仅显示具有实测强度的谱线。

波长(nm)强度电离级类型跃迁准确度来源
542.5249 nm8000000Hg IIemission5d10.6d 2D → 5d10.5f 2F*实测值NIST
587.12779 nm1200000Hg IIemission5d10.7p 2P* → 5d10.7d 2D实测值NIST
559.526 nm200000Hg IIemission5d10.6d 2D → 5d10.5f 2F*实测值NIST
520.4768 nm150000Hg IIemission5d9.6s.6d [(2D<5/2>,1/2)<3>,5/2] → 5d9.6s.5f [(2D<5/2>,1/2)<3>,7/2]*实测值NIST
629.123 nm65000Hg IIemission5d10.5f 2F* → 5d10.6g 2G实测值NIST
639.4888 nm55000Hg IIemission5d10.5f 2F* → 5d10.6g 2G实测值NIST
380.63154 nm50000Hg IIemission5d10.7p 2P* → 5d10.8d 2D实测值NIST
439.8623 nm40000Hg IIemission5d10.7p 2P* → 5d10.8d 2D实测值NIST
521.6379 nm40000Hg IIemission5d9.6s.6d [(2D<5/2>,1/2)<3>,5/2] → 5d9.6s.5f [(2D<5/2>,1/2)<3>,5/2]*实测值NIST
466.0216 nm30000Hg IIemission5d9.6s.6p (2D<3/2>,3P<1>)* → 5d10.7d 2D实测值NIST
527.7593 nm18000Hg IIemission5d9.6s.6d [(2D<5/2>,1/2)<3>,5/2] → 5d9.6s.5f [(2D<5/2>,1/2)<3>,5/2]*实测值NIST
482.5564 nm17000Hg IIemission5d9.6s.6d [(2D<5/2>,1/2)<3>,3/2] → 5d9.6s.5f [(2D<5/2>,1/2)<3>,5/2]*实测值NIST
514.6293 nm15000Hg IIemission5d9.6s.6d [(2D<5/2>,1/2)<3>,5/2] → 5d9.6s.5f [(2D<5/2>,1/2)<3>,5/2]*实测值NIST
404.65643 nm12000Hg Iemission5d10.6s.6p 3P* → 5d10.6s.7s 3S实测值NIST
435.83363 nm12000Hg Iemission5d10.6s.6p 3P* → 5d10.6s.7s 3S实测值NIST
383.9255 nm10000Hg IIemission5d10.7s 2S → 5d9.6s.6p (2D<3/2>,1P<1>)*实测值NIST
546.07498 nm6000Hg Iemission5d10.6s.6p 3P* → 5d10.6s.7s 3S实测值NIST
391.43142 nm5000Hg IIemission5d9.6s.6p (2D<3/2>,3P<2>)* → 5d9.6s.7s [(2D<5/2>,1/2)<3>,1/2]实测值NIST
412.0447 nm4000Hg IIemission5d10.7p 2P* → 5d10.9s 2S实测值NIST
449.28309 nm2800Hg IIemission5d10.6d 2D → 5d10.8p 2P*实测值NIST
664.66839 nm1300Hg IIemission5d9.6s2 2D → 5d9.6s2 2D实测值NIST
506.6497 nm1200Hg IIemission5d9.6s.6d [(2D<5/2>,1/2)<3>,3/2] → 5d9.6s.5f [(2D<5/2>,1/2)<3>,7/2]*实测值NIST
382.89121 nm1000Hg IIemission5d9.6s.6p (2D<3/2>,3P<2>)* → 5d9.6s.7s [(2D<5/2>,1/2)<3>,1/2]实测值NIST
407.7837 nm1000Hg Iemission5d10.6s.6p 3P* → 5d10.6s.7s 1S实测值NIST
576.96095 nm1000Hg Iemission5d10.6s.6p 1P* → 5d10.6s.6d 3D实测值NIST
690.746 nm1000Hg Iemission5d10.6s.7s 3S → 5d10.6s.8p 3P*实测值NIST
708.1901 nm1000Hg Iemission5d10.6s.7s 3S → 5d10.6s.8p 3P*实测值NIST
579.06705 nm900Hg Iemission5d10.6s.6p 1P* → 5d10.6s.6d 1D实测值NIST
709.186 nm800Hg Iemission5d10.6s.7s 3S → 5d10.6s.8p 3P*实测值NIST
567.588 nm600Hg Iemission5d10.6s.7s 3S → 5d10.6s.9p 1P*实测值NIST
671.636 nm600Hg Iemission5d10.6s.7s 1S → 5d9.6s2.(2D<5/2>).6p 2[3/2]*实测值NIST
580.3783 nm400Hg Iemission5d10.6s.7s 1S → 5d10.6s.10p 1P*实测值NIST
474.2296 nm300Hg IIemission5d9.6s.6d [(2D<5/2>,1/2)<3>,3/2] → 5d9.6s.5f [(2D<5/2>,1/2)<3>,7/2]*实测值NIST
434.74951 nm150Hg Iemission5d10.6s.6p 1P* → 5d10.6s.7d 1D实测值NIST
594.7682 nm150Hg IIemission5d10.7d 2D → 5d10.8f 2F*实测值NIST
535.4036 nm130Hg Iemission5d10.6s.7s 3S → 5d10.6s.10p 3P*实测值NIST
585.9254 nm130Hg Iemission5d10.6s.7s 3S → 5d10.6s.9p 3P*实测值NIST
496.017 nm100Hg Iemission5d9.6s2.(2D<5/2>).6p 2[7/2]* → 5d9.6s2.(2D<5/2>).7s 2[5/2]实测值NIST
510.0945 nm100Hg IIemission5d9.6s.6d [(2D<5/2>,1/2)<3>,5/2] → 5d9.6s.5f [(2D<5/2>,1/2)<3>,7/2]*实测值NIST
410.8054 nm70Hg Iemission5d10.6s.6p 1P* → 5d10.6s.9s 1S实测值NIST
512.0637 nm70Hg Iemission5d10.6s.7s 3S → 5d10.6s.11p 3P*实测值NIST
509.8561 nm60Hg IIemission5d9.6s.6d [(2D<5/2>,1/2)<3>,5/2] → 5d9.6s.5f [(2D<5/2>,1/2)<3>,5/2]*实测值NIST
380.16582 nm50Hg Iemission5d10.6s.6p 1P* → 5d10.6s.10s 1S实测值NIST
382.037 nm50Hg Iemission5d9.6s2.(2D<5/2>).6p 2[7/2]* → 5d9.6s2.(2D<5/2>).7s 2[5/2]实测值NIST
404.7742 nm50Hg IIemission5d9.6s.6p (2D<3/2>,3P<2>)* → 5d9.6s.7s [(2D<5/2>,1/2)<3>,1/2]实测值NIST
433.92228 nm50Hg Iemission5d10.6s.6p 1P* → 5d10.6s.7d 3D实测值NIST
538.4627 nm50Hg Iemission5d10.6s.7s 3S → 5d10.6s.10p 3P*实测值NIST
554.9636 nm50Hg Iemission5d10.6s.7s 1S → 5d10.6s.11p 1P*实测值NIST
623.435 nm50Hg Iemission5d10.6s.7s 1S → 5d10.6s.9p 1P*实测值NIST
390.6383 nm40Hg Iemission5d10.6s.6p 1P* → 5d10.6s.8d 1D实测值NIST

扩展性质

共价半径(扩展)

共价半径(Pyykkö)
133 pm
共价半径(Pyykkö,双键)
142 pm

范德华半径

Batsanov
205 pm
Alvarez
245 pm
UFF
270.5 pm
MM3
253 pm

原子半径与金属半径

原子半径(Rahm)
229 pm
金属半径(C12)
151 pm

编号标度

Mendeleev
79
Pettifor
74
Glawe
76

电负性标度

Ghosh
0
Miedema
4
Gunnarsson–Lundqvist
4
Robles–Bartolotti
3

极化率与色散

偶极极化率
33.91 a.u.
偶极极化率(不确定度)
0.34 a.u.
C₆ (Gould–Bučko)
268 Ha·Bohr6

Miedema参数

Miedema摩尔体积
14.08 cm3/mol
Miedema电子密度
2

供应风险与经济性

生产集中度
74
相对供应风险
9
储量分布
29
政治稳定性(最大生产国)
24
政治稳定性(最大储量国)
23

相变与同素异形体

熔点234.32 K
沸点629.77 K
临界点(温度)1764.15 K
临界点(压力)167 MPa
三相点(温度)234.32 K

氧化态分类

+1 main
+2 main
−2 extended

高级参考数据

屏蔽常数 (14)
n轨道σ
1s1.5419
2p4.499
2s20.8906
3d13.4804
3p22.4798
3s23.4587
4d37.532
4f38.2392
4p35.594
4s34.7552
晶体半径详情 (6)
电荷CN自旋rcrystal (pm)来源
1III111
1VI133
2II83
2IV110
2VI116
2VIII128from r^3 vs V plots,
同位素衰变方式 (76)
同位素模式强度
170A100%
171A100%
171B+—
172A100%
172B+—
173A100%
174A100%
174B+—
175A100%
175B+—
X射线散射因子 (516)
能量 (eV)f₁f₂
10—3.07253
10.1617—3.05926
10.3261—3.04605
10.4931—3.0329
10.6628—3.0198
10.8353—3.00676
11.0106—3.02448
11.1886—3.04517
11.3696—3.066
11.5535—3.08698

补充数据

参考文献

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
Hg

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Mercury

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

许可证说明: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Mercury

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

许可证说明: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Mercury

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Mercury

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Mercury

This section provides all form of data related to element Mercury.

9 PubChem Elements
Mercury

The element property data was retrieved from publications.

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