Te 52

Tellurium (Te)

metalloid
周期: 5 族: 16 区: p

Solid

标准原子量

127.6 u

电子排布

[Kr] 5s2 4d10 5p4

熔点

449.51 °C

沸点

987.85 °C

密度

6232 kg/m³

氧化态

−2, −1, 0, +1, +2, +3, +4, +5, +6

电负性(鲍林)

2.1

第一电离能

9.009808 eV

发现年份

1782

原子半径

140 pm

详细信息

名称来源 Latin: tellus (earth).
发现国家 Romania
发现者 Franz Müller von Reichenstein

Tellurium is a brittle metalloid in group 16, below selenium and above polonium. It is chemically related to sulfur and selenium but is more metallic, less abundant, and more easily reduced. In nature it occurs mainly as telluride minerals and as a minor constituent of copper ores. Its technological importance comes from semiconducting and thermoelectric compounds, cadmium telluride photovoltaics, and small alloying additions that modify machinability and corrosion behavior.

Crystalline tellurium has a silvery-white appearance, and when pure it exhibits a metallic luster. It is brittle and easily pulverized. Amorphous tellurium is found by precipitating tellurium from a solution of telluric or tellurous acid. Whether this form is truly amorphous, or made of minute crystals, is open to question. Tellurium is a p-type semiconductor, and shows greater conductivity in certain directions, depending on alignment of the atoms.

Its conductivity increases slightly with exposure to light. It can be doped with silver, copper, gold, tin, or other elements. In air, tellurium burns with a greenish-blue flames, forming the dioxide. Molten tellurium corrodes iron, copper, and stainless steel.

The name derives from the Latin Tellus, who was the Roman goddess of the Earth. Tellurium was discovered by Franz Joseph Müller von Reichenstein in 1782 and overlooked for 15 years until it was isolated by the German chemist Martin-Heinrich Klaproth in 1798. The Hungarian chemist Paul Kitaibel independently discovered tellurium in 1789, prior to Klaproth's work but after von Reichenstein.

Tellurium was discovered by Franz Joseph Müller von Reichenstein, a Romanian mining official, in 1782. Reichenstein was the chief inspector of all mines, smelters and saltworks in Transylvania. He also had an interest in chemistry and extracted a new metal from an ore of gold, known as aurum album, which he believed was antimony. He shortly realized that the metal he had produced wasn't antimony at all, but a previously unknown element. Reichenstein's work was forgotten until 1798 when Martin Heinrich Klaproth, a German chemist, mentioned the substance in a paper. Klaproth named the new element tellurium but gave full credit for its discovery to Reichenstein. Tellurium is found free in nature, but is most often found in the ores sylvanite (AgAuTe4), calaverite (AuTe2) and krennerite (AuTe2). Today, most tellurium is obtained as a byproduct of mining and refining copper.

From the Latin word tellus, earth. Discovered by Muller von Reichenstein in 1782; named by Klaproth, who isolated it in 1798.

图片

性质

物理性质

原子半径(经验值)
140 pm 比较所有元素的原子半径(经验值) →
共价半径
138 pm 比较所有元素的共价半径 →
范德华半径
206 pm 比较所有元素的范德华半径 →
金属半径
137 pm 比较所有元素的金属半径 →
密度
6232 kg/m³ 比较所有元素的密度 →
摩尔体积
0.0205 L/mol
标准温度和压力下的物相
固态 比较所有元素的标准温度和压力下的物相 →
熔点
449.51 °C 比较所有元素的熔点 →
沸点
987.85 °C 比较所有元素的沸点 →
热导率
14.3 W/(m·K) 比较所有元素的热导率 →
比热容
0.202 J/(g·K) 比较所有元素的比热容 →
摩尔热容
25.73 J/(mol·K) 比较所有元素的摩尔热容 →
晶体结构
六方密堆积 比较所有元素的晶体结构 →

化学性质

电负性(鲍林)
2.1 比较所有元素的电负性(鲍林) →
电负性(Allen)
2.158
电子亲和能
1.9708 eV
第一电离能
9.009808 eV 比较所有元素的第一电离能 →
第二电离能
18.600064 eV 比较所有元素的第二电离能 →
第三电离能
27.840096 eV 比较所有元素的第三电离能 →
第四电离能
37.415629 eV 比较所有元素的第四电离能 →
第五电离能
59.300204 eV 比较所有元素的第五电离能 →
氧化态
−2, −1, 0, +1, +2, +3, +4, +5, +6 比较所有元素的氧化态 →
价电子
6 比较所有元素的价电子 →
电子排布
[Kr] 5s2 4d10 5p4

热力学性质

临界点(温度)
2056 °C
熔化热
0.1812717 eV 比较所有元素的熔化热 →
汽化热
0.54412603 eV 比较所有元素的汽化热 →
升华热
2.041768 eV
原子化热
2.041768 eV
原子化焓
2.037622 eV

核性质

质子
52 比较所有元素的质子 →
中子
74 比较所有元素的中子 →
已知同位素
42 比较所有元素的已知同位素 →
稳定同位素
4 比较所有元素的稳定同位素 →
最稳定同位素
Te-126
发现年份
1782

丰度

丰度(地壳)
0.001 mg/kg 比较所有元素的丰度(地壳) →

晶体结构

晶格常数a
445 pm

电子结构

各电子层电子数
2, 8, 18, 18, 6 比较所有元素的各电子层电子数 →

标识符

CAS登记号
13494-80-9 比较所有元素的CAS登记号 →
谱项符号
3P2
InChI
InChI=1S/Te
InChI Key
PORWMNRCUJJQNO-UHFFFAOYSA-N

电子排布 实测值

离子电荷
质子 52
电子 52
电荷 中性
电子排布 Te: 4d¹⁰ 5s² 5p⁴
电子排布
实测值
[Kr] 4d¹⁰ 5s² 5p⁴
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁴
轨道图
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
2/2
4d
10/10
5p
4/6 2↑
电子总数: 52 未配对: 2 ?

原子模型

质子 52
中子 74
电子 52
质量数 126
稳定性 稳定

不同同位素的中子数、质量和稳定性不同,但中性原子的电子排布不变。

原子模型示意图,未按比例绘制。

原子指纹

发射 / 吸收光谱

25 / 50 (50 50条具有强度数据)
实测值
发射 可见光:380–750 nm

同位素分布

12618.8400%1257.0700%1244.7400%1222.5500%质量数天然丰度(%)
质量数原子质量(u)天然丰度半衰期
122 稳定121.9030435 ± 0.00000162.5500%稳定
124 稳定123.9028171 ± 0.00000164.7400%稳定
125 稳定124.9044299 ± 0.00000167.0700%稳定
126 稳定125.9033109 ± 0.000001618.8400%稳定
实测值

物相 / 状态

1 atm / 101.325 kPa
固态 25 °C (298.15 K)

原因: 低于熔点(449.51 °C)424.5 °C

熔点 449.51 °C
沸点 987.85 °C
低于熔点的温差 424.5 °C
0 K 当前温度: 25 °C 6000 K
物相变化轴

示意图,未按比例绘制

固态
液态
气态
熔化
沸腾
25°C
固态
液态
气态
当前

相变点

熔点 文献值
449.51 °C
沸点 文献值
987.85 °C
当前物相 计算值
固态

相变能

熔化热 文献值
0.1812717 eV

在熔点熔化1 mol物质所需的能量

汽化热 文献值
0.54412603 eV

在沸点汽化1 mol物质所需的能量

升华热 文献值
2.041768 eV

在升华点升华1 mol物质所需的能量

密度

参考密度 文献值
6232 kg/m³

标准条件下

当前密度 计算值
6232 kg/m³

标准条件下

高级

临界点 文献值
2056 °C

原子光谱

已显示10项,共52项。 按离子电荷升序排列。

收录谱线 ?

离子电荷谱线总数跃迁概率能级标记
Te I 01336112
Te II +13450310
NIST收录谱线 →

收录能级 ?

离子电荷能级
Te I 0120
Te II +1129
Te III +255
Te IV +316
Te V +445
Te VI +59
Te VII +660
Te VIII +72
Te IX +82
Te X +92
NIST收录能级 →
52 Te 127.6

Tellurium — 原子轨道可视化工具

[Kr]5s24d105p4
能级 2 8 18 18 6
氧化态 -2, -1, 0, +1, +2, +3, +4, +5, +6
HOMO 5p n=5 · l=1 · m=-1
Tellurium — 原子轨道可视化预览
Three.js仅在需要时加载
52 Te 127.6

Tellurium — 晶体结构可视化工具

简单六方 · 皮尔逊符号 hP2
实验数据
皮尔逊符号 hP2
配位数 12
堆积系数 74.048%
Tellurium — 晶体结构可视化预览
Three.js仅在需要时加载

离子半径

电荷配位自旋半径
-26暂无221 pm
+43暂无52 pm
+44暂无66 pm
+46暂无97 pm
+64暂无43 pm
+66暂无56.00000000000001 pm

化合物

Te
127.600 u
Te+4
127.600 u
Te
131.909 u
Te
124.904 u
Te
132.911 u
Te
125.903 u
Te
129.906 u
Te
128.907 u
Te
126.905 u
Te
122.904 u
Te
130.909 u
Te
120.905 u
Te
121.903 u
Te
127.904 u
Te
115.909 u
Te
133.911 u
Te+
127.600 u
Te+4
124.904 u
Te
123.903 u
Te
109.922 u
Te
119.904 u

同位素 (4)

Thirty isotopes of tellurium are known, with atomic masses ranging from 108 to 137. Natural tellurium consists of eight isotopes.

质量数原子质量(u)天然丰度半衰期衰变方式
122 稳定121.9030435 ± 0.00000162.5500% ± 0.1200%稳定
stable
124 稳定123.9028171 ± 0.00000164.7400% ± 0.1400%稳定
stable
125 稳定124.9044299 ± 0.00000167.0700% ± 0.1500%稳定
stable
126 稳定125.9033109 ± 0.000001618.8400% ± 0.2500%稳定
stable
122 稳定
原子质量(u) 121.9030435 ± 0.0000016
天然丰度 2.5500% ± 0.1200%
半衰期 稳定
衰变方式
stable
124 稳定
原子质量(u) 123.9028171 ± 0.0000016
天然丰度 4.7400% ± 0.1400%
半衰期 稳定
衰变方式
stable
125 稳定
原子质量(u) 124.9044299 ± 0.0000016
天然丰度 7.0700% ± 0.1500%
半衰期 稳定
衰变方式
stable
126 稳定
原子质量(u) 125.9033109 ± 0.0000016
天然丰度 18.8400% ± 0.2500%
半衰期 稳定
衰变方式
stable

谱线

已显示50项,共74项。 默认仅显示具有实测强度的谱线。

波长(nm)强度电离级类型跃迁准确度来源
486.623 nm2300Te IIemission5s2.5p2.(3P).6p 4D* → 5s2.5p2.(3P).6d 4F实测值NIST
557.636 nm2100Te IIemission5s2.5p2.(1D).6s 2D → 5s2.5p2.(1D).6p 2F*实测值NIST
570.812 nm1900Te IIemission5s2.5p2.(3P).6s 4P → 5s2.5p2.(3P).6p 4D*实测值NIST
483.13 nm1600Te IIemission5s2.5p2.(3P).6p 4D* → 5s2.5p2.(3P).6d 4P实测值NIST
564.926 nm1500Te IIemission5s2.5p2.(3P).6s 4P → 5s2.5p2.(3P).6p 4D*实测值NIST
575.586 nm1500Te IIemission5s2.5p2.(3P).6s 4P → 5s2.5p2.(3P).6p 4D*实测值NIST
544.984 nm1400Te IIemission5s2.5p2.(3P).6s 4P → 5s2.5p2.(3P).6p 4P*实测值NIST
468.691 nm1310Te IIemission5s2.5p2.(3P).6p 4P* → 5s2.5p2.(3P).6d 4D实测值NIST
476.605 nm1300Te IIemission5s2.5p2.(3P).6p 2D* → 5s2.5p2.(3P).6d 2F实测值NIST
490.442 nm1300Te IIemission5s2.5p2.(3P).6p 2D* → 5s2.5p2.(3P).6d 2F实测值NIST
566.622 nm1200Te IIemission5s2.5p2.(3P).6s 2P → 5s2.5p2.(3P).6p 2D*实测值NIST
597.468 nm1200Te IIemission5s2.5p2.(3P).6s 4P → 5s2.5p2.(3P).6p 4P*实测值NIST
548.795 nm1100Te IIemission5s2.5p2.(3P).5d 2P → 5s2.5p2.(3P).6p 4D*实测值NIST
484.29 nm1000Te IIemission5s2.5p2.(3P).5d 2D → 5s2.5p2.(3P).4f 4D*实测值NIST
486.513 nm1000Te IIemission5s2.5p2.(3P).6p 4D* → 5s2.5p2.(3P).6d 4D实测值NIST
482.712 nm900Te IIemission5s2.5p2.(3P).6p 4P* → 5s2.5p2.(3P).6d 4D实测值NIST
447.865 nm830Te IIemission5s2.5p2.(3P).6p 4P* → 5s2.5p2.(3P).6d 4D实测值NIST
500.081 nm810Te IIemission5s2.5p2.(3P).6s 4P → 5s2.5p2.(3P).6p 2D*实测值NIST
477.155 nm800Te IIemission5s2.5p2.(3P).6p 4D* → 5s2.5p2.(3P).6d 4F实测值NIST
593.615 nm730Te IIemission5s2.5p2.(3P).6s 4P → 5s2.5p2.(3P).6p 4S*实测值NIST
464.111 nm680Te IIemission5s2.5p2.(3P).6p 4D* → 5s2.5p2.(3P).6d 4D实测值NIST
470.654 nm670Te IIemission5s2.5p2.(1D).6s 2D → 5s2.5p2.(1D).6p 2P*实测值NIST
436.402 nm650Te IIemission5s2.5p2.(3P).5d 4P → 5s2.5p2.(3P).4f 4D*实测值NIST
636.713 nm570Te IIemission5s.(2S).5p4.(1D) 2D → 5s2.5p2.(3P).6p 4D*实测值NIST
469.638 nm560Te IIemission5s2.5p2.(3P).5d 4P → 5s2.5p2.(3P).4f 2D*实测值NIST
416.977 nm540Te IIemission5s2.5p2.(3P).5d 2D → 5s2.5p2.(3P).4f 2F*实测值NIST
463.062 nm540Te IIemission5s2.5p2.(3P).6p 4S* → 5s2.5p2.(3P).7s 2P实测值NIST
478.488 nm510Te IIemission5s2.5p2.(1D).6s 2D → 5s2.5p2.(1D).6p 2P*实测值NIST
455.778 nm480Te IIemission5s2.5p2.(3P).6p 4S* → 5s2.5p2.(3P).6d 4D实测值NIST
683.7663 nm430Te Iemission5p3.(4S*).6p 5P → 5p3.(4S*).8d 5D*实测值NIST
404.716 nm400Te IIemission5s2.5p2.(3P).5d 4P → 5s2.5p2.(3P).4f 2D*实测值NIST
428.583 nm370Te IIemission5s2.5p2.(3P).6p 2S* → 5s2.5p2.(3P).6d 4D实测值NIST
394.798 nm340Te IIemission5s2.5p2.(3P).5d 4P → 5s2.5p2.(3P).4f 4F*实测值NIST
422.572 nm340Te IIemission5s2.5p2.(3P).5d 4P → 5s2.5p2.(3P).4f 4D*实测值NIST
396.921 nm320Te IIemission5s.(2S).5p4.(1D) 2D → 5s2.5p2.(1D).6p 2D*实测值NIST
410.105 nm320Te IIemission5s2.5p2.(1D).5d 2S → 5s2.5p2.(3P).4f 2D*实测值NIST
412.732 nm320Te IIemission5s2.5p2.(1D).5d 2S → 5s2.5p2.(3P).4f 4D*实测值NIST
496.187 nm320Te IIemission5s2.5p2.(3P).6p 4P* → 5s2.5p2.(3P).6d 4D实测值NIST
400.653 nm310Te IIemission5s.(2S).5p4.(3P) 4P → 5s2.5p2.(3P).6p 4D*实测值NIST
438.51 nm310Te IIemission5s2.5p2.(3P).5d 4P → 5s2.5p2.(3P).4f 2D*实测值NIST
417.929 nm300Te IIemission5s2.5p2.(3P).5d 4P → 5s2.5p2.(1S).6p 2P*实测值NIST
427.343 nm300Te IIemission5s2.5p2.(3P).6p 2S* → 5s2.5p2.(3P).7s 2P实测值NIST
679.109 nm300Te Iemission5p3.(4S*).6p 5P → 5p3.(4S*).8d 3D*实测值NIST
669.0154 nm290Te Iemission5p3.(4S*).6p 5P → 5p3.(4S*).8d 5D*实测值NIST
453.708 nm260Te IIemission5s2.5p2.(3P).5d 4P → 5s2.5p2.(3P).4f 4F*实测值NIST
397.592 nm250Te IIemission5s.(2S).5p4.(1D) 2D → 5s2.5p2.(1D).6p 2F*实测值NIST
416.356 nm250Te IIemission5s2.5p2.(3P).5d 4P → 5s2.5p2.(3P).4f 4D*实测值NIST
398.176 nm240Te IIemission5s2.5p2.(3P).6s 2P → 5s2.5p2.(1D).6p 2P*实测值NIST
425.114 nm240Te IIemission5s2.5p2.(3P).5d 2D → 5s2.5p2.(3P).4f 2F*实测值NIST
404.888 nm230Te IIemission5s.(2S).5p4.(3P) 4P → 5s2.5p2.(3P).6p 4S*实测值NIST

扩展性质

共价半径(扩展)

共价半径(Pyykkö)
136 pm
共价半径(Pyykkö,双键)
128 pm
共价半径(Pyykkö,三键)
121 pm
共价半径(Bragg)
133 pm

范德华半径

Bondi
206 pm
Batsanov
210 pm
Alvarez
199 pm
UFF
447 pm
MM3
244 pm
Dreiding
423 pm

原子半径与金属半径

原子半径(Rahm)
242 pm
金属半径(C12)
160 pm

编号标度

Mendeleev
102
Pettifor
92
Glawe
94

电负性标度

Ghosh
0
Gunnarsson–Lundqvist
6
Robles–Bartolotti
4

极化率与色散

偶极极化率
38 a.u.
偶极极化率(不确定度)
4 a.u.
C₆
445 Ha·Bohr6
C₆ (Gould–Bučko)
471 Ha·Bohr6

相变与同素异形体

熔点722.66 K
沸点1261.15 K
临界点(温度)2329.15 K

氧化态分类

+2 main
−2 main
+1 extended
+6 main
+3 extended
0 extended
+5 extended
−1 extended
+4 main

高级参考数据

屏蔽常数 (11)
n轨道σ
1s1.0432
2p4.14
2s13.6688
3d14.1607
3p17.9911
3s18.0019
4d32.04
4p28.878
4s27.5916
5p41.1915
晶体半径详情 (6)
电荷CN自旋rcrystal (pm)来源
-2VI207Pauling's (1960) crystal radius,
4III66
4IV80
4VI111
6IV57calculated,
6VI70
同位素衰变方式 (67)
同位素模式强度
104A100%
105A100%
106A100%
107A70%
107B+—
107B+p—
108B+51%
108A49%
108B+p2.4%
108B+A0.1%
X射线散射因子 (508)
能量 (eV)f₁f₂
10—9.70237
10.1617—9.72653
10.3261—9.75076
10.4931—9.77506
10.6628—9.7994
10.8353—9.77638
11.0106—9.72308
11.1886—9.67008
11.3696—9.61736
11.5535—9.54395

补充数据

Sources

Sources of this element.

Tellurium is occasionally found native, but is more often found as the telluride of gold (calaverite), and combined with other metals. It is recovered commercially from anode muds produced during the electrolytic refining of blister copper. The U.S., Canada, Peru, and Japan are the largest Free World producers of the element.

参考文献 (1)

参考文献

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
Te

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Tellurium

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

许可证说明: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Tellurium

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

许可证说明: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Tellurium

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Tellurium

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Tellurium

This section provides all form of data related to element Tellurium.

9 PubChem Elements
Tellurium

The element property data was retrieved from publications.

最后更新:

数据已核实:

内容已依据最新科学数据进行审核。