Rh 45

Rhodium (Rh)

transition-metal
周期: 5 族: 9 区: d

Solid

标准原子量

102.9055 u

电子排布

[Kr] 5s1 4d8

熔点

1963.85 °C

沸点

3694.85 °C

密度

1.24e+4 kg/m³

氧化态

−3, −1, +1, +2, +3, +4, +5, +6, +7

电负性(鲍林)

2.28

第一电离能

7.4589 eV

发现年份

1803

原子半径

135 pm

详细信息

名称来源 Greek: rhodon (rose). Its salts give a rosy solution.
发现国家 England
发现者 William Wollaston

Rhodium is a very rare platinum-group transition metal. It is chemically noble, hard, highly reflective, and most often encountered in nature alloyed with platinum, palladium, and other platinum-group elements. Its industrial importance is dominated by catalysis, especially control of nitrogen oxides in automotive exhaust. Rhodium also forms stable coordination compounds, commonly with Rh(I) and Rh(III), that are important in homogeneous catalysis and organometallic chemistry.

The metal is silvery white and at red heat slowly changes in air to the resquioxide. At higher temperatures it converts back to the element. Rhodium has a higher melting point and lower density than platinum. It is highly reflective, hard, and durable.

The name derives from the Greek rhodon for rose because of the rose color of dilute solutions of its salts. It was discovered by the English chemist and physicist William Hyde Wollaston in 1803 in a crude platinum ore.

Rhodium was discovered by William Hyde Wollaston, an English chemist, in 1803 shortly after his discovery of the element palladium. He obtained rhodium from a sample of platinum ore that was obtained from South America. After removing the platinum and palladium from the sample, he was left with a dark red powder. The powder turned out to be sodium rhodium chloride (Na3RhCl6·12H2O). Wollaston obtained rhodium from the powder by treating it with hydrogen gas (H2). Rhodium tends to occur along with deposits of platinum and is primarily obtained as a byproduct of mining and refining platinum. Rhodium is also obtained as a byproduct of the nickel mining operation in the Sudbury region of Ontario, Canada.

From the Greek word rhodon, rose. Wollaston discovered rhodium between 1803 and 1804 in crude platinum ore he presumably obtained from South America.

图片

性质

物理性质

原子半径(经验值)
135 pm 比较所有元素的原子半径(经验值) →
共价半径
142 pm 比较所有元素的共价半径 →
范德华半径
195 pm 比较所有元素的范德华半径 →
金属半径
125 pm 比较所有元素的金属半径 →
密度
1.24 × 104 kg/m³ 比较所有元素的密度 →
摩尔体积
0.0083 L/mol
标准温度和压力下的物相
固态 比较所有元素的标准温度和压力下的物相 →
熔点
1963.85 °C 比较所有元素的熔点 →
沸点
3694.85 °C 比较所有元素的沸点 →
热导率
150 W/(m·K) 比较所有元素的热导率 →
比热容
0.243 J/(g·K) 比较所有元素的比热容 →
摩尔热容
24.98 J/(mol·K) 比较所有元素的摩尔热容 →
晶体结构
面心立方 比较所有元素的晶体结构 →

化学性质

电负性(鲍林)
2.28 比较所有元素的电负性(鲍林) →
电负性(Allen)
1.56
电子亲和能
1.137 eV
第一电离能
7.4589 eV 比较所有元素的第一电离能 →
第二电离能
18.080062 eV 比较所有元素的第二电离能 →
第三电离能
31.060107 eV 比较所有元素的第三电离能 →
第四电离能
42.000145 eV 比较所有元素的第四电离能 →
第五电离能
63.000217 eV 比较所有元素的第五电离能 →
氧化态
−3, −1, +1, +2, +3, +4, +5, +6, +7 比较所有元素的氧化态 →
价电子
9 比较所有元素的价电子 →
电子排布
[Kr] 5s1 4d8

热力学性质

熔化热
0.22490543 eV 比较所有元素的熔化热 →
汽化热
5.119967 eV 比较所有元素的汽化热 →
升华热
5.762554 eV
原子化热
5.762554 eV
原子化焓
5.762554 eV

核性质

质子
45 比较所有元素的质子 →
中子
58 比较所有元素的中子 →
已知同位素
41 比较所有元素的已知同位素 →
稳定同位素
1 比较所有元素的稳定同位素 →
最稳定同位素
Rh-103
发现年份
1803

丰度

丰度(地壳)
0.001 mg/kg 比较所有元素的丰度(地壳) →

晶体结构

晶格常数a
380 pm

电子结构

各电子层电子数
2, 8, 18, 16, 1 比较所有元素的各电子层电子数 →

标识符

CAS登记号
7440-16-6 比较所有元素的CAS登记号 →
谱项符号
4F9/2
InChI
InChI=1S/Rh
InChI Key
MHOVAHRLVXNVSD-UHFFFAOYSA-N

电子排布 实测值

离子电荷
质子 45
电子 45
电荷 中性
电子排布 Rh: 4d⁸ 5s¹
电子排布
实测值
[Kr] 4d⁸ 5s¹
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d⁸ 5s¹
轨道图
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
1/2 1↑
4d
8/10 2↑
电子总数: 45 未配对: 3 ?

原子模型

质子 45
中子 58
电子 45
质量数 103
稳定性 稳定

不同同位素的中子数、质量和稳定性不同,但中性原子的电子排布不变。

原子模型示意图,未按比例绘制。

原子指纹

发射 / 吸收光谱

25 / 50 (50 50条具有强度数据)
实测值
发射 可见光:380–750 nm

同位素分布

单同位素元素
唯一天然存在的同位素:103 — 100.0000%
103100.0000%质量数天然丰度(%)
质量数原子质量(u)天然丰度半衰期
103 稳定102.905498 ± 0.0000026100.0000%稳定
实测值

物相 / 状态

1 atm / 101.325 kPa
固态 25 °C (298.15 K)

原因: 低于熔点(1963.85 °C)1938.8 °C

熔点 1963.85 °C
沸点 3694.85 °C
低于熔点的温差 1938.8 °C
0 K 当前温度: 25 °C 6000 K
物相变化轴

示意图,未按比例绘制

固态
液态
气态
熔化
沸腾
25°C
固态
液态
气态
当前

相变点

熔点 文献值
1963.85 °C
沸点 文献值
3694.85 °C
当前物相 计算值
固态

相变能

熔化热 文献值
0.22490543 eV

在熔点熔化1 mol物质所需的能量

汽化热 文献值
5.119967 eV

在沸点汽化1 mol物质所需的能量

升华热 文献值
5.762554 eV

在升华点升华1 mol物质所需的能量

密度

参考密度 文献值
1.24e+4 kg/m³

标准条件下

当前密度 计算值
1.24e+4 kg/m³

标准条件下

原子光谱

已显示10项,共45项。 按离子电荷升序排列。

收录谱线 ?

离子电荷谱线总数跃迁概率能级标记
Rh I 0468111443
Rh II +134031
Rh III +27300
NIST收录谱线 →

收录能级 ?

离子电荷能级
Rh I 0138
Rh II +1126
Rh III +2196
Rh IV +32
Rh V +42
Rh VI +52
Rh VII +62
Rh VIII +72
Rh IX +82
Rh X +92
NIST收录能级 →
45 Rh 102.9055

Rhodium — 原子轨道可视化工具

[Kr]5s14d8
能级 2 8 18 16 1
氧化态 -3, -1, +1, +2, +3, +4, +5, +6, +7
HOMO 5s n=5 · l=0 · m=0
Rhodium — 原子轨道可视化预览
Three.js仅在需要时加载
45 Rh 102.9055

Rhodium — 晶体结构可视化工具

Face-Centered Cubic · 皮尔逊符号 cF4
实验数据
皮尔逊符号 cF4
配位数 12
堆积系数 74.000%
Rhodium — 晶体结构可视化预览
Three.js仅在需要时加载

离子半径

电荷配位自旋半径
+36暂无66.5 pm
+46暂无60 pm
+56暂无55.00000000000001 pm

化合物

Rh
102.906 u
Rh+3
102.906 u
Rh+2
102.906 u
Rh
105.907 u
Rh
104.906 u
Rh
101.907 u
Rh
98.908 u
Rh
99.908 u
Rh
100.906 u
Rh
106.907 u
Rh
102.905 u
Rh
103.907 u

同位素 (1)

质量数原子质量(u)天然丰度半衰期衰变方式
103 稳定102.905498 ± 0.0000026100.0000%稳定
stable
103 稳定
原子质量(u) 102.905498 ± 0.0000026
天然丰度 100.0000%
半衰期 稳定
衰变方式
stable

谱线

已显示50项,共186项。 默认仅显示具有实测强度的谱线。

波长(nm)强度电离级类型跃迁准确度来源
385.6513 nm5900Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 2G*实测值NIST
437.4809 nm4200Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 4G*实测值NIST
382.226 nm3800Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 2F*实测值NIST
395.8856 nm3800Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 2G*实测值NIST
421.1133 nm3300Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 4F*实测值NIST
382.8478 nm2300Rh Iemission4d8.(3P).5s a 4P → 4d8.(3P).5p z 4P*实测值NIST
413.5275 nm2100Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 4F*实测值NIST
383.3884 nm2000Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 2D*实测值NIST
393.4224 nm2000Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 4G*实测值NIST
412.8886 nm1500Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 2F*实测值NIST
380.6759 nm1300Rh Iemission4d8.(3F).5s a 4F → 4d8.(3F).5p z 4D*实测值NIST
381.8186 nm1300Rh Iemission4d8.(3P).5s a 4P → 4d8.(3P).5p z 4P*实测值NIST
412.1683 nm1100Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 2D*实测值NIST
428.8702 nm820Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 4G*实测值NIST
380.592 nm760Rh Iemission4d8.(1D).5s b 2D → 8*实测值NIST
381.6474 nm760Rh Iemission4d8.(1D).5s b 2D → 4d8.(1D).5p y 2F*实测值NIST
394.271 nm590Rh Iemission4d8.(3P).5s a 4P → 4d8.(3P).5p z 4P*实测值NIST
408.278 nm560Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 4F*实测值NIST
387.0018 nm490Rh Iemission4d8.(1G).5s a 2G → 12*实测值NIST
381.5021 nm470Rh Iemission4d8.(1G).5s a 2G → 13*实测值NIST
387.7346 nm380Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 4F*实测值NIST
397.5313 nm380Rh Iemission4d8.(1D).5s b 2D → 4*实测值NIST
399.6149 nm380Rh Iemission4d8.(3P).5s a 2P → 4d8.(3P).5p y 4D*实测值NIST
419.6496 nm330Rh Iemission4d8.(3P).5s a 4P → 4d8.(3F).5p z 2G*实测值NIST
392.2195 nm240Rh Iemission4d9 a 2D → 4d8.(3F).5p z 4D*实测值NIST
398.4393 nm240Rh Iemission4d8.(3P).5s a 4P → 4d8.(3P).5p z 4P*实测值NIST
399.5602 nm240Rh Iemission4d8.(3P).5s a 4P → 4d8.(3P).5p z 4P*实测值NIST
415.4343 nm240Rh Iemission4d7.5s2 b 4F → 4d8.(3P).5p y 4D*实测值NIST
559.9419 nm160Rh Iemission4d8.(3P).5s a 4P → 4d8.(3F).5p z 4D*实测值NIST
467.5022 nm150Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 4D*实测值NIST
409.7508 nm140Rh Iemission4d8.(3P).5s a 4P → 4d8.(3P).5p z 4P*实测值NIST
456.8993 nm130Rh Iemission4d8.(3P).5s a 4P → 4d8.(3F).5p z 4G*实测值NIST
535.4428 nm130Rh Iemission4d8.(3F).5p z 2G* → 16实测值NIST
598.3575 nm130Rh Iemission4d7.5s2 b 4F → 4d8.(3F).5p z 4F*实测值NIST
391.3508 nm120Rh Iemission4d8.(3F).5s a 4F → 4d8.(3F).5p z 4D*实测值NIST
402.3139 nm120Rh Iemission4d8.(1D).5s b 2D → 4d8.(1D).5p y 2P*实测值NIST
411.9679 nm120Rh Iemission4d8.(1G).5s a 2G → 4d8.(1D).5p y 2F*实测值NIST
381.2462 nm95Rh Iemission4d8.(1D).5s b 2D → 4d8.(3P).5p z 2S*实测值NIST
395.8233 nm95Rh Iemission4d8.(3P).5s a 2P → 4d8.(1D).5p y 2P*实测值NIST
437.9911 nm95Rh Iemission4d8.(3P).5s a 4P → 4d8.(3F).5p z 2D*实测值NIST
519.313 nm95Rh Iemission4d8.(3F).5p z 4G* → 2实测值NIST
539.0433 nm95Rh Iemission4d8.(3P).5s a 4P → 4d8.(3F).5p z 4D*实测值NIST
387.239 nm70Rh Iemission4d9 a 2D → 4d8.(3F).5p z 4F*实测值NIST
388.8331 nm70Rh Iemission4d8.(1D).5s b 2D → 4d8.(1D).5p y 2P*实测值NIST
407.758 nm70Rh Iemission4d8.(1D).5s b 2D → 4d8.(3P).5p y 4D*实测值NIST
411.6329 nm70Rh Iemission4d8.(1D).5s b 2D → 4*实测值NIST
420.6613 nm70Rh Iemission4d9 a 2D → 4d8.(3F).5p z 4D*实测值NIST
429.6763 nm70Rh Iemission4d8.(1D).5s b 2D → 4d8.(3P).5p y 4D*实测值NIST
474.5116 nm70Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 4D*实测值NIST
509.064 nm70Rh Iemission4d8.(3P).5s a 4P → 4d8.(3F).5p z 4D*实测值NIST

扩展性质

共价半径(扩展)

共价半径(Pyykkö)
125 pm
共价半径(Pyykkö,双键)
110 pm
共价半径(Pyykkö,三键)
106 pm

范德华半径

Batsanov
200 pm
Alvarez
244 pm
UFF
292.9 pm
MM3
234 pm

原子半径与金属半径

原子半径(Rahm)
233 pm
金属半径(C12)
134 pm

编号标度

Mendeleev
64
Pettifor
66
Glawe
63

电负性标度

Ghosh
0
Miedema
5
Gunnarsson–Lundqvist
4
Robles–Bartolotti
3

极化率与色散

偶极极化率
66 a.u.
偶极极化率(不确定度)
10 a.u.
C₆ (Gould–Bučko)
708 Ha·Bohr6

化学亲和力

质子亲和能
768 kJ/mol
气相碱性
745.4 kJ/mol

Miedema参数

Miedema摩尔体积
8.3 cm3/mol
Miedema电子密度
5

供应风险与经济性

生产集中度
60
相对供应风险
8
储量分布
95
政治稳定性(最大生产国)
44
政治稳定性(最大储量国)
44

相变与同素异形体

熔点2236.15 K
沸点3968.15 K

氧化态分类

−1 extended
+2 extended
+6 extended
−3 extended
+4 extended
+3 main
+1 extended
+5 extended
+7 extended

高级参考数据

屏蔽常数 (10)
n轨道σ
1s0.9244
2p4.0596
2s11.8454
3d14.595
3p16.8456
3s16.5615
4d31.5576
4p27.8604
4s26.4184
5s38.3605
晶体半径详情 (3)
电荷CN自旋rcrystal (pm)来源
3VI80.5from r^3 vs V plots,
4VI74from r^3 vs V plots, from metallic oxides,
5VI69
同位素衰变方式 (72)
同位素模式强度
88B+—
89B+—
89B+p—
89p—
90B+100%
90B+p0.7%
91B+100%
91B+p1.3%
92B+100%
92B+p2%
X射线散射因子 (508)
能量 (eV)f₁f₂
10—1.17537
10.1617—1.24044
10.3261—1.30912
10.4931—1.3816
10.6628—1.4581
10.8353—1.53883
11.0106—1.62403
11.1886—1.71394
11.3696—1.80884
11.5535—1.90899

补充数据

Sources

Sources of this element.

Rhodium occurs natively with other platinum metals in river sands of the Urals and in North and South America. It is also found with other platinum metals in the copper-nickel sulfide area of the Sudbury, Ontario region. Although the quantity occurring there is very small, the large tonnages of nickel processed make the recovery commercially feasible. The annual world production of rhodium is only 7 or 8 tons.

参考文献 (1)

参考文献

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
Rh

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Rhodium

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

许可证说明: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Rhodium

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

许可证说明: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Rhodium

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Rhodium

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Rhodium

This section provides all form of data related to element Rhodium.

9 PubChem Elements
Rhodium

The element property data was retrieved from publications.

最后更新:

数据已核实:

内容已依据最新科学数据进行审核。