Technetium (Tc)
transition-metalSolid
标准原子量
[98]电子排布
[Kr] 5s2 4d5熔点
2156.85 °C沸点
4264.85 °C密度
1.1e+4 kg/m³氧化态
−3, −1, +1, +2, +3, +4, +5, +6, +7电负性（鲍林）
1.9第一电离能
7.11938 eV发现年份
1937原子半径
135 pm详细信息
Technetium is a radioactive transition metal in group 7, between molybdenum and ruthenium. It was the first element discovered without a stable isotope. Only trace natural technetium occurs, mainly from spontaneous fission of uranium and from neutron capture processes; practical quantities are made artificially. Its chemistry resembles rhenium and manganese in several oxidation states, and the isotope ⁹⁹ᵐTc is central to diagnostic nuclear medicine.
Technetium is a silvery-gray metal that tarnishes slowly in moist air. The common oxidation states of technetium are +7, +5, and +4. Under oxidizing conditions technetium (VII) will exist as the pertechnetate ion, TcO4-. The chemistry of technetium is said to be similar to that of rhenium. Technetium dissolves in nitric acid, aqua regia, and concentrated sulfuric acid, but is not soluble in hydrochloric acid of any strength. The element is a remarkable corrosion inhibitor for steel. The metal is an excellent superconductor at 11K and below.
Technetium was the first artificially produced element. It was isolated by Carlo Perrier and Emilio Segrè in 1937. Technetium was created by bombarding molybdenum atoms with deuterons that had been accelerated by a device called a cyclotron. Today, technetium is produced by bombarding molybdenum-98 with neutrons. Molybdenum-98 becomes molybdenum-99 when it captures a neutron. Molybdenum-99, with a half-life of 65.94 hours, decays into technetium-99 through beta decay. While technetium has never been found to occur naturally on earth, its spectral lines have been observed in S-, M- and N-type stars.
Technetium's most stable isotope, technetium-98, has a half-life of about 4,200,000 years. It decays into ruthenium-98 through beta decay.
From the Greek word technetos, artificial. Element 43 was predicted on the basis of the periodic table, and was erroneously reported as having been discovered in 1925, at which time it was named masurium. The element was actually discovered by Perrier and Segre in Italy in 1937. It was also found in a sample of molybdenum sent by E. Lawrence that was bombarded by deuterons in the Berkeley cyclotron. Technetium was the first element to be produced artificially. Since its discovery, searches for the element in terrestrial material have been made. Finally in 1962, technetium-99 was isolated and identified in African pitchblende (a uranium rich ore) in extremely minute quantities as a spontaneous fission product of uranium-238 by B.T. Kenna and P.K. Kuroda. If it does exist, the concentration must be very small. Technetium has been found in the spectrum of S-, M-, and N-type stars, and its presence in stellar matter is leading to new theories of the production of heavy elements in the stars.
Macroscopic technetium metal is a silvery-gray, metallic solid when prepared in the laboratory. Because all isotopes are radioactive, specimens are handled as controlled radioactive materials rather than ordinary metal samples.
The most important use is isotope-specific: ⁹⁹ᵐTc is used as a short-lived gamma-emitting tracer in many diagnostic imaging procedures, usually bound in radiopharmaceutical complexes selected for particular organs or physiological processes. Longer-lived ⁹⁹Tc has been studied as a corrosion inhibitor for steel in closed systems, but its radioactivity and regulatory burden prevent ordinary industrial use. Other technetium isotopes and compounds are used mainly in chemical, nuclear, and tracer research.
Small amounts of technetium can retard the corrosion of steel, although this protection can only be applied to closed systems due to technetium's radioactivity. Technetium can also be used as a medical tracer and to calibrate particle detectors.
Isotopes in Medicine
99mTc is an isomer of 99Tc with a half-life of approximately 6 h that is used to label peptides for morphologic (the form and structure of an organism) and dynamic modeling of renal (kidney), hepatic (liver), bone, and cardiac imaging [320] U. Abram, R. Alberto. J. Braz. Chem. Soc.17, 1486 (2006)., [322] M. Pérez Díaz, J. Quevedo Garcia, O. Diaz Rizo, R. Dopico Hernandez, E. Estevez Aparicio, A. Viamonte Marin, O. Cabrera Gorrin. Alasbimn J.4 (16), (2002).. 99mTc radiopharmaceuticals absorb to a variety of tumors. These tumors can be imaged using single-photon emission computed tomography (SPECT) coupled with non-invasive computed tomography (CT scan), which provides a high level of functional and anatomical information in a three-dimensional image (Fig. IUPAC.43.1) [323] A. Ballard. Biomarkers Key to Drug Development: Imaging and Biomarkers Drive Drug Development Engineered for Personalized Medicine, Imaging Technology News (2014), Feb. 26; http://www.itnonline.com/article/biomarkers-key-drug-development., [324] P. Ghosh, M. Kelly. Expanding the Power of PET with 18F-Sodium Fluoride, Siemens Medical Solutions USA, Inc (2017), Feb. 26; https://usa.healthcare.siemens.com/siemens_hwem-hwem_ssxa_websites-context-root/wcm/idc/groups/public/@us/@imaging/@molecular/documents/mdaw/ndu0/∼edisp/white_paper10_sodium_fluoride-00309726.. Medronate is a radioactive pharmaceutical, which has been used to find, treat, or study certain diseases or body functions. 99mTc-labeled medronate (99mTc-MDP) is used in a diagnostic test to detect metastases from prostate, lung or thyroid cancer, making use of a gamma camera to record the distribution of 99mTc-MDP within the body. A two-dimensional image of the affected areas is produced.
Technetium shows rich redox chemistry, with common oxidation states including +7, +4, and lower states in coordination complexes. Pertechnetate, TcO₄⁻, contains technetium(VII) and is chemically analogous to perrhenate; sodium pertechnetate, NaTcO₄, is a key soluble form in radiochemistry. Technetium dioxide, TcO₂, contains technetium(IV) and is much less mobile in many reducing environments. Technetium forms halides, oxides, sulfides, and numerous complexes with phosphines, carbonyls, and biological ligands.
See more information at the Technetium compound page.
All technetium isotopes are radioactive, but hazards differ strongly by isotope, activity, chemical form, and route of exposure. ⁹⁹ᵐTc has a short half-life and is managed under medical radiation controls. ⁹⁹Tc is a long-lived beta emitter; ingestion or inhalation of soluble pertechnetate is a principal concern because it can distribute in body fluids. Metal dusts and contaminated laboratory surfaces require radiological containment and monitoring.
It is reported that mild carbon steels may be effectively protected by as little as 55 ppm of KTcO4 in aerated distilled water at temperatures up to 250°C. This corrosion protection is limited to closed systems, since technetium is radioative and must be confined. 98Tc has a specific activity of 6.2 x 108 Bq/g. Activity of this level must not be allowed to spread. 99Tc is a contamination hazard and should be handled in a glove box.
Natural technetium is extremely scarce and transient on geological scales. Environmental technetium of practical concern comes mainly from nuclear fission products in reactor fuel, reprocessing streams, waste, and fallout residues. Pertechnetate, TcO₄⁻, is soluble and relatively mobile under oxidizing conditions, while reduced technetium(IV) species such as TcO₂ are less soluble and can be retained by sediments or engineered waste forms.
Technetium has no normal commodity market as a bulk metal. Supply is tied to the nuclear industry and to isotope generation. Medical ⁹⁹ᵐTc is obtained from decay of ⁹⁹Mo in generator systems, with ⁹⁹Mo produced mainly by fission or neutron-activation routes. Long-lived ⁹⁹Tc is available as a fission product recovered in specialized facilities, but demand is limited by regulation and by its lack of ordinary commercial applications. Costs are dominated by reactor or accelerator production, radiochemical processing, transport timing, quality control, and waste management rather than by the elemental metal itself.
Made first by bombarding molybdenum with deuterons (heavy hydrogen) in a cyclotron.
Technetium has no stable nuclides, so any primordial technetium has decayed away. It is produced in stars by neutron-capture nucleosynthesis, and its spectroscopic detection in some red giant stars shows that freshly made heavy elements can be brought to stellar surfaces. In planetary materials it is expected only in trace radiogenic or cosmogenic amounts unless introduced by nuclear processes.
- Technetium was identified in molybdenum targets irradiated with deuterons.
- Its name comes from a Greek word meaning artificial.
- The diagnostic isotope ⁹⁹ᵐTc decays to ⁹⁹Tc.
- Pertechnetate, TcO₄⁻, is often the most mobile oxidized form in water.
- A visible technetium spectrum in a star proved that some stellar heavy elements are made recently.
图片
性质
物理性质
- 原子半径（经验值）
- 135 pm 比较所有元素的原子半径（经验值） →
- 共价半径
- 147 pm 比较所有元素的共价半径 →
- 范德华半径
- 209 pm 比较所有元素的范德华半径 →
- 金属半径
- 127 pm 比较所有元素的金属半径 →
- 密度
- 1.1 × 104 kg/m³ 比较所有元素的密度 →
- 摩尔体积
- 0.0085 L/mol
- 标准温度和压力下的物相
- 固态 比较所有元素的标准温度和压力下的物相 →
- 熔点
- 2156.85 °C 比较所有元素的熔点 →
- 沸点
- 4264.85 °C 比较所有元素的沸点 →
- 热导率
- 50.6 W/(m·K) 比较所有元素的热导率 →
- 晶体结构
- 六方密堆积 比较所有元素的晶体结构 →
化学性质
- 电负性（鲍林）
- 1.9 比较所有元素的电负性（鲍林） →
- 电负性（Allen）
- 1.51
- 电子亲和能
- 0.55 eV
- 第一电离能
- 7.11938 eV 比较所有元素的第一电离能 →
- 第二电离能
- 15.260053 eV 比较所有元素的第二电离能 →
- 第三电离能
- 29.550102 eV 比较所有元素的第三电离能 →
- 第四电离能
- 41.000141 eV 比较所有元素的第四电离能 →
- 第五电离能
- 57.000196 eV 比较所有元素的第五电离能 →
- 氧化态
- −3, −1, +1, +2, +3, +4, +5, +6, +7 比较所有元素的氧化态 →
- 价电子
- 7 比较所有元素的价电子 →
- 电子排布
- [Kr] 5s2 4d5
热力学性质
- 熔化热
- 0.24667047 eV 比较所有元素的熔化热 →
- 汽化热
- 5.182153 eV 比较所有元素的汽化热 →
- 升华热
- 6.063119 eV
- 原子化热
- 6.063119 eV
- 原子化焓
- 7.026999 eV
核性质
- 质子
- 43 比较所有元素的质子 →
- 中子
- 55 比较所有元素的中子 →
- 已知同位素
- 40 比较所有元素的已知同位素 →
- 稳定同位素
- 0 比较所有元素的稳定同位素 →
- 质量数（最稳定同位素）
- 98
- 最稳定同位素
- Tc-98
- 发现年份
- 1937
丰度
暂无
晶体结构
- 晶格常数a
- 274 pm
电子结构
- 各电子层电子数
- 2, 8, 18, 13, 2 比较所有元素的各电子层电子数 →
标识符
- CAS登记号
- 7440-26-8 比较所有元素的CAS登记号 →
- 谱项符号
- 6S5/2
- InChI
- InChI=1S/Tc
- InChI Key
- GKLVYJBZJHMRIY-UHFFFAOYSA-N
电子排布 实测值
Tc: 4d⁵ 5s²[Kr] 4d⁵ 5s²1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d⁵ 5s²原子模型
不同同位素的中子数、质量和稳定性不同，但中性原子的电子排布不变。
原子模型示意图，未按比例绘制。
原子指纹
发射 / 吸收光谱
同位素分布
无稳定同位素。
| 质量数 | 原子质量（u） | 天然丰度 | 半衰期 |
|---|---|---|---|
| 109 放射性 | 108.920256 ± 0.00001 | 暂无 | 905 ms |
| 110 放射性 | 109.923744 ± 0.00001 | 暂无 | 900 ms |
| 111 放射性 | 110.925901 ± 0.000011 | 暂无 | 350 ms |
| 112 放射性 | 111.9299458 ± 0.000006 | 暂无 | 323 ms |
| 94 放射性 | 93.9096536 ± 0.0000044 | 暂无 | 293 分钟 |
物相 / 状态
原因: 低于熔点（2156.85 °C）2131.8 °C
示意图，未按比例绘制
相变点
相变能
在熔点熔化1 mol物质所需的能量
在沸点汽化1 mol物质所需的能量
在升华点升华1 mol物质所需的能量
密度
标准条件下
标准条件下
原子光谱
已显示10项，共43项。 按离子电荷升序排列。
收录能级 ?
| 离子 | 电荷 | 能级 |
|---|---|---|
| Tc I | 0 | 290 |
| Tc II | +1 | 34 |
| Tc III | +2 | 2 |
| Tc IV | +3 | 2 |
| Tc V | +4 | 2 |
| Tc VI | +5 | 2 |
| Tc VII | +6 | 2 |
| Tc VIII | +7 | 2 |
| Tc IX | +8 | 2 |
| Tc X | +9 | 2 |
离子半径
| 电荷 | 配位 | 自旋 | 半径 |
|---|---|---|---|
| +4 | 6 | 暂无 | 64.5 pm |
| +5 | 6 | 暂无 | 60 pm |
| +7 | 4 | 暂无 | 37 pm |
| +7 | 6 | 暂无 | 56.00000000000001 pm |
化合物
同位素 (5)
Twenty-two isotopes of technetium with masses ranging from 90 to 111 are reported. All the isotopes of technetium are radioactive. It is one of two elements with Z < 83 that have no stable isotopes; the other element is promethium (Z = 61). Technetium has three long lived radioactive isotopes: 97Tc (T1/2 = 2.6 x 106 years), 98Tc (T1/2 = 4.2 x 106 years) and 99Tc (T1/2 = 2.1 x 105 years). 95Tcm ("m" stands for meta state) (T1/2 = 61 days) is used in tracer work. However, the most useful isotope of technetium is 99Tcm (T1/2 = 6.01 hours) is used in many medical radioactive isotope tests because of its half-life being short, the energy of the gamma ray it emits, and the ability of technetium to be chemically bound to many biologically active molecules. Because 99Tc is produced as a fission product from the fission of uranium in nuclear reactors, large quantities have been produced over the years. There are kilogram quantities of technetium currently existing.
| 质量数 | 原子质量（u） | 天然丰度 | 半衰期 | 衰变方式 | |
|---|---|---|---|---|---|
| 109 放射性 | 108.920256 ± 0.00001 | 暂无 | 905 ms | β- =100%β-n =0.08±0.2% | |
| 110 放射性 | 109.923744 ± 0.00001 | 暂无 | 900 ms | β- =100%β-n =0.04±0.2% | |
| 111 放射性 | 110.925901 ± 0.000011 | 暂无 | 350 ms | β- =100%β-n =0.85±2% | |
| 112 放射性 | 111.9299458 ± 0.000006 | 暂无 | 323 ms | β- =100%β-n =1.5±0.2% | |
| 94 放射性 | 93.9096536 ± 0.0000044 | 暂无 | 293 分钟 | β+ =100% |
谱线
已显示50项，共277项。 默认仅显示具有实测强度的谱线。
| 波长（nm） | 强度 | 电离级 | 类型 | 跃迁 | 准确度 | 来源 | |
|---|---|---|---|---|---|---|---|
| 485.359 nm | 20000 | Tc I | emission | 4d6.(5D).5s 4D → 4d6.(5D).5p 4F* | 实测值 | NIST | |
| 409.5662 nm | 15000 | Tc I | emission | 4d6.(5D).5s 6D → 4d6.(5D).5p 6D* | 实测值 | NIST | |
| 408.8702 nm | 10000 | Tc I | emission | 4d6.(5D).5s 6D → 4d6.(5D).5p 6D* | 实测值 | NIST | |
| 411.5065 nm | 10000 | Tc I | emission | 4d6.(5D).5s 6D → 4d6.(5D).5p 6D* | 实测值 | NIST | |
| 416.5605 nm | 10000 | Tc I | emission | 4d6.(5D).5s 4D → 4d5.(6S).5s.(5S).5p 4P* | 实测值 | NIST | |
| 426.2245 nm | 10000 | Tc I | emission | 4d5.5s2 6S → 4d5.(6S).5s.(7S).5p 6P* | 实测值 | NIST | |
| 429.7034 nm | 10000 | Tc I | emission | 4d5.5s2 6S → 4d5.(6S).5s.(7S).5p 6P* | 实测值 | NIST | |
| 452.283 nm | 10000 | Tc I | emission | 4d6.(5D).5s 4D → 4d6.(5D).5p 4D* | 实测值 | NIST | |
| 474.0602 nm | 10000 | Tc I | emission | 4d6.(5D).5s 4D → 4d6.(5D).5p 4F* | 实测值 | NIST | |
| 482.0744 nm | 10000 | Tc I | emission | 4d5.(6S).5s.(7S).5p 8P* → 4d5.(6S).5s.(7S).6s e 8S | 实测值 | NIST | |
| 486.6732 nm | 10000 | Tc I | emission | 4d6.(5D).5s 4D → 4d6.(5D).5p 4F* | 实测值 | NIST | |
| 412.4217 nm | 8000 | Tc I | emission | 4d6.(5D).5s 6D → 4d6.(5D).5p 6D* | 实测值 | NIST | |
| 489.1909 nm | 8000 | Tc I | emission | 4d6.(5D).5s 4D → 4d6.(5D).5p 4F* | 实测值 | NIST | |
| 414.4961 nm | 6000 | Tc I | emission | 4d6.(5D).5s 6D → 4d6.(5D).5p 6D* | 实测值 | NIST | |
| 417.2523 nm | 5000 | Tc I | emission | 4d6.(5D).5s 6D → 4d6.(5D).5p 6D* | 实测值 | NIST | |
| 497.6341 nm | 5000 | Tc I | emission | 4d5.(6S).5s.(7S).5p 8P* → 4d5.(6S).5s.(7S).6s e 8S | 实测值 | NIST | |
| 509.6269 nm | 5000 | Tc I | emission | 4d6.(5D).5s 4D → 4d6.(5D).5p 6F* | 实测值 | NIST | |
| 417.0266 nm | 4000 | Tc I | emission | 4d6.(5D).5s 6D → 4d6.(5D).5p 6D* | 实测值 | NIST | |
| 477.1539 nm | 4000 | Tc I | emission | 4d6.(5D).5s 4D → 4d6.(5D).5p 4F* | 实测值 | NIST | |
| 414.5126 nm | 3000 | Tc I | emission | 4d6.(5D).5s 6D → 4d6.(5D).5p 6D* | 实测值 | NIST | |
| 448.7049 nm | 3000 | Tc I | emission | 4d6.(5D).5s 4D → 4d6.(5D).5p 4D* | 实测值 | NIST | |
| 463.7499 nm | 3000 | Tc I | emission | 4d6.(5D).5s 4D → 4d6.(5D).5p 4D* | 实测值 | NIST | |
| 394.709 nm | 2000 | Tc I | emission | 4d6.(3H).5s 4H → 4d6.(3H).5p 2I* | 实测值 | NIST | |
| 399.4498 nm | 2000 | Tc I | emission | 4d6.(3H).5s 4H → 4d6.(3H).5p 4G* | 实测值 | NIST | |
| 402.0759 nm | 2000 | Tc I | emission | 4d6.(3H).5s 2H → 4d6.(3H).5p 2H* | 实测值 | NIST | |
| 453.9513 nm | 2000 | Tc I | emission | 4d6.(5D).5s 4D → 4d6.(5D).5p 4D* | 实测值 | NIST | |
| 456.4541 nm | 2000 | Tc I | emission | 4d6.(5D).5s 4D → 4d6.(5D).5p 4D* | 实测值 | NIST | |
| 464.8328 nm | 2000 | Tc I | emission | 4d6.(5D).5s 4D → 4d6.(5D).5p 4D* | 实测值 | NIST | |
| 466.9303 nm | 2000 | Tc I | emission | 4d6.(5D).5s 4D → 4d6.(5D).5p 4P* | 实测值 | NIST | |
| 471.7758 nm | 2000 | Tc I | emission | 4d6.(5D).5s 4D → 4d6.(5D).5p 4F* | 实测值 | NIST | |
| 490.9509 nm | 2000 | Tc I | emission | 4d6.(5D).5s 4D → 4d6.(5D).5p 4F* | 实测值 | NIST | |
| 517.4813 nm | 2000 | Tc I | emission | 4d6.(5D).5s 4D → 4d6.(5D).5p 6F* | 实测值 | NIST | |
| 383.7565 nm | 1500 | Tc I | emission | 4d6.(3H).5s 4H → 4d6.(3H).5p 4I* | 实测值 | NIST | |
| 564.2116 nm | 1500 | Tc I | emission | 4d6.(3F2).5s 4F → 4d6.(5D).5p 4D* | 实测值 | NIST | |
| 386.8248 nm | 1000 | Tc I | emission | 4d6.(3H).5s 4H → 4d6.(3H).5p 4I* | 实测值 | NIST | |
| 401.1998 nm | 1000 | Tc I | emission | 4d6.(3H).5s 4H → 4d5.(4D).5s.(5D).5p 6F* | 实测值 | NIST | |
| 403.9232 nm | 1000 | Tc I | emission | 4d6.(3H).5s 4H → 4d6.(3H).5p 4G* | 实测值 | NIST | |
| 411.0214 nm | 1000 | Tc I | emission | 4d6.(1I).5s 2I → 4d6.(1I).5p 2K* | 实测值 | NIST | |
| 412.8263 nm | 1000 | Tc I | emission | 4d5.5s2 4G → 4d5.(4G).5s.(5G).5p 4H* | 实测值 | NIST | |
| 416.966 nm | 1000 | Tc I | emission | 4d6.(3H).5s 4H → 4d5.(4G).5s.(5G).5p 4H* | 实测值 | NIST | |
| 417.6253 nm | 1000 | Tc I | emission | 4d6.(5D).5s 6D → 4d6.(5D).5p 6D* | 实测值 | NIST | |
| 426.2682 nm | 1000 | Tc I | emission | 4d6.(5D).5s 4D → 4d5.(6S).5s.(5S).5p 4P* | 实测值 | NIST | |
| 442.9581 nm | 1000 | Tc I | emission | 4d6.(5D).5s 4D → 4d6.(5D).5p 4D* | 实测值 | NIST | |
| 448.1534 nm | 1000 | Tc I | emission | 4d6.(3H).5s 2H → 4d6.(3H).5p 4H* | 实测值 | NIST | |
| 451.5974 nm | 1000 | Tc I | emission | 4d6.(3H).5s 2H → 4d6.(3H).5p 4H* | 实测值 | NIST | |
| 455.7038 nm | 1000 | Tc I | emission | 4d6.(3F2).5s 4F → 4d6.(3F2).5p 4G* | 实测值 | NIST | |
| 457.8438 nm | 1000 | Tc I | emission | 4d6.(3G).5s 4G → 4d6.(3H).5p 2I* | 实测值 | NIST | |
| 459.3334 nm | 1000 | Tc I | emission | 4d6.(5D).5s 4D → 4d6.(5D).5p 4D* | 实测值 | NIST | |
| 461.6842 nm | 1000 | Tc I | emission | 4d5.(6S).5s.(7S).5p 6P* → 4d5.(6S).5s.(7S).5d f 6D | 实测值 | NIST | |
| 463.0527 nm | 1000 | Tc I | emission | 4d6.(5D).5s 4D → 4d6.(5D).5p 4D* | 实测值 | NIST |
扩展性质
共价半径（扩展）
- 共价半径（Pyykkö）
- 128 pm
- 共价半径（Pyykkö，双键）
- 120 pm
- 共价半径（Pyykkö，三键）
- 110 pm
范德华半径
- Batsanov
- 205 pm
- Alvarez
- 244 pm
- UFF
- 299.8 pm
- MM3
- 236 pm
原子半径与金属半径
- 原子半径（Rahm）
- 252 pm
- 金属半径（C12）
- 136 pm
编号标度
- Mendeleev
- 56
- Pettifor
- 58
- Glawe
- 59
电负性标度
- Ghosh
- 0
- Miedema
- 5
- Gunnarsson–Lundqvist
- 5
- Robles–Bartolotti
- 4
极化率与色散
- 偶极极化率
- 79 a.u.
- 偶极极化率（不确定度）
- 10 a.u.
- C₆ (Gould–Bučko)
- 939 Ha·Bohr6
Miedema参数
- Miedema摩尔体积
- 8.64 cm3/mol
- Miedema电子密度
- 6
相变与同素异形体
| 熔点 | 2430.15 K |
| 沸点 | 4535.15 K |
氧化态分类
高级参考数据
屏蔽常数 (10)
| n | 轨道 | σ |
|---|---|---|
| 1 | s | 0.891 |
| 2 | p | 4.0592 |
| 2 | s | 11.3718 |
| 3 | d | 14.647 |
| 3 | p | 16.6159 |
| 3 | s | 16.2088 |
| 4 | d | 30.118 |
| 4 | p | 27.1888 |
| 4 | s | 25.8016 |
| 5 | s | 35.7735 |
晶体半径详情 (4)
| 电荷 | CN | 自旋 | rcrystal (pm) | 来源 |
|---|---|---|---|---|
| 4 | VI | 78.5 | from r^3 vs V plots, from metallic oxides, | |
| 5 | VI | 74 | estimated, from r^3 vs V plots, | |
| 7 | IV | 51 | ||
| 7 | VI | 70 | Ahrens (1952) ionic radius, |
同位素衰变方式 (70)
| 同位素 | 模式 | 强度 |
|---|---|---|
| 83 | p | — |
| 83 | B+ | — |
| 83 | B+p | — |
| 84 | p | — |
| 84 | B+ | — |
| 84 | B+p | — |
| 85 | p | — |
| 86 | B+ | 100% |
| 86 | B+p | — |
| 87 | B+ | 100% |
X射线散射因子 (508)
| 能量 (eV) | f₁ | f₂ |
|---|---|---|
| 10 | — | 1.1689 |
| 10.1617 | — | 1.2263 |
| 10.3261 | — | 1.28651 |
| 10.4931 | — | 1.34968 |
| 10.6628 | — | 1.41595 |
| 10.8353 | — | 1.48547 |
| 11.0106 | — | 1.55841 |
| 11.1886 | — | 1.63493 |
| 11.3696 | — | 1.7152 |
| 11.5535 | — | 1.7906 |
补充数据
Estimated Crustal Abundance
The estimated element abundance in the earth's crust.
Not Applicable
参考文献 (1)
- [5] Technetium https://education.jlab.org/itselemental/ele043.html
Estimated Oceanic Abundance
The estimated element abundance in the earth's oceans.
Not Applicable
参考文献 (1)
- [5] Technetium https://education.jlab.org/itselemental/ele043.html
参考文献
(9)
Data deposited in or computed by PubChem
The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.
Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.
The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.
Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/
The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.
The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database
This section provides all form of data related to element Technetium.
The element property data was retrieved from publications.