Nb 41

Niobium (Nb)

transition-metal
周期: 5 族: 5 区: d

Solid

标准原子量

92.90637 u

电子排布

[Kr] 5s1 4d4

熔点

2476.85 °C

沸点

4743.85 °C

密度

8570 kg/m³

氧化态

−3, −1, 0, +1, +2, +3, +4, +5

电负性(鲍林)

1.6

第一电离能

6.75885 eV

发现年份

1801

原子半径

145 pm

详细信息

名称来源 From Niobe; daughter of the mythical Greek king Tantalus.
发现国家 England
发现者 Charles Hatchet

Niobium is a refractory transition metal of group 5, chemically similar to tantalum and commonly occurring with it in oxide minerals. It is valued for its ability to strengthen steel at very small additions and for forming superconducting intermetallic compounds. In most compounds niobium is pentavalent, but lower oxidation states are well established, especially in halides and cluster chemistry.

Niobium is a shiny, white, soft, and ductile metal, and takes on a bluish cast when exposed to air at room temperatures for a long time. The metal starts to oxidize in air at 200°C, and when processed at even moderate temperatures must be placed in a protective atmosphere.

The name derives from the Greek mythological character Niobe, who was the daughter of Tantalus, because the elements niobium and tantalum were originally thought to be identical. Niobium was discovered in a black mineral from America called columbite by the British chemist and manufacturer Charles Hatchett in 1801 and he called the element columbium. In 1809, the English chemist William Hyde Wollaston claimed that columbium and tantalum were identical.

Forty years later, the German chemist and pharmacist, Heinrich Rose, determined that they were two different elements in 1846 and gave the name niobium because it was so difficult to distinguish it from tantalum. The name columbium continued to be used in America and niobium in Europe until IUPAC adopted the name niobium in 1949. Niobium was first isolated by the chemist C. W. Blomstrand in 1846.

The story of niobium's discovery is a bit confusing. The first governor of Connecticut, John Winthrop the Younger, discovered a new mineral around 1734. He named the mineral columbite ((Fe, Mn, Mg)(Nb, Ta)2O6) and sent a sample of it to the British Museum in London, England. The columbite sat in the museum's mineral collection for years until it was analyzed by Charles Hatchett in 1801. Hatchett could tell that there was an unknown element in the columbite, but he was not able to isolate it. He named the new element columbium. The fate of columbium took a drastic turn in 1809 when William Hyde Wollaston, an English chemist and physicist, compared the minerals columbite and tantalite ((Fe, Mn)(Ta, Nb)2O6) and declared that columbium was actually the element tantalum. This confusion arose because tantalum and niobium are similar metals, are always found together and are very difficult to isolate.

Niobium was rediscovered and renamed by Heinrich Rose in 1844 when he produced two new acids, niobic acid and pelopic acid, from samples of columbite and tantalite. These acids are very similar to each other and it took another twenty-two years and a Swiss chemist named Jean Charles Galissard de Marignac to prove that these were two distinct chemicals produced from two different elements. Metallic niobium was finally isolated by the Swedish chemist Christian Wilhelm Blomstrand in 1864. Today, niobium is primarily obtained from the minerals columbite and pyrochlore ((Ca, Na)2Nb2O6(O, OH, F)).

Named after Niobe, the daughter of Tantalu. Discovered in 1801 by Hatchett in an ore sent to England. The metal was first prepared in 1864 by Blomstrand, who reduced the chloride by heating it in a hydrogen atmosphere. The name niobium was adopted by the International Union of Pure and Applied Chemicstry (IUPAC) in 1950 after 100 years of controversy. Many leading chemical societies and government organizations refer to it by this name. Most metallurgists, leading metal societies, and all but one of the leading U.S. commercial producers, however, still refer to the metal as "columbium."

图片

性质

物理性质

原子半径(经验值)
145 pm 比较所有元素的原子半径(经验值) →
共价半径
164 pm 比较所有元素的共价半径 →
范德华半径
207 pm 比较所有元素的范德华半径 →
金属半径
134 pm 比较所有元素的金属半径 →
密度
8570 kg/m³ 比较所有元素的密度 →
摩尔体积
0.0108 L/mol
标准温度和压力下的物相
固态 比较所有元素的标准温度和压力下的物相 →
熔点
2476.85 °C 比较所有元素的熔点 →
沸点
4743.85 °C 比较所有元素的沸点 →
热导率
53.7 W/(m·K) 比较所有元素的热导率 →
比热容
0.265 J/(g·K) 比较所有元素的比热容 →
摩尔热容
24.6 J/(mol·K) 比较所有元素的摩尔热容 →
晶体结构
体心立方 比较所有元素的晶体结构 →

化学性质

电负性(鲍林)
1.6 比较所有元素的电负性(鲍林) →
电负性(Allen)
1.41
电子亲和能
0.893 eV
第一电离能
6.75885 eV 比较所有元素的第一电离能 →
第二电离能
14.320049 eV 比较所有元素的第二电离能 →
第三电离能
25.040086 eV 比较所有元素的第三电离能 →
第四电离能
37.611129 eV 比较所有元素的第四电离能 →
第五电离能
50.572974 eV 比较所有元素的第五电离能 →
氧化态
−3, −1, 0, +1, +2, +3, +4, +5 比较所有元素的氧化态 →
价电子
5 比较所有元素的价电子 →
电子排布
[Kr] 5s1 4d4

热力学性质

熔化热
0.27776338 eV 比较所有元素的熔化热 →
汽化热
7.151371 eV 比较所有元素的汽化热 →
升华热
7.617764 eV
原子化热
7.617764 eV
原子化焓
7.597036 eV

核性质

质子
41 比较所有元素的质子 →
中子
52 比较所有元素的中子 →
已知同位素
38 比较所有元素的已知同位素 →
稳定同位素
1 比较所有元素的稳定同位素 →
最稳定同位素
Nb-93
发现年份
1801

丰度

丰度(地壳)
20 mg/kg 比较所有元素的丰度(地壳) →
丰度(海洋)
1 × 10−5 mg/L 比较所有元素的丰度(海洋) →

晶体结构

晶格常数a
330 pm

电子结构

各电子层电子数
2, 8, 18, 12, 1 比较所有元素的各电子层电子数 →

标识符

CAS登记号
7440-03-1 比较所有元素的CAS登记号 →
谱项符号
6D1/2
InChI
InChI=1S/Nb
InChI Key
GUCVJGMIXFAOAE-UHFFFAOYSA-N

电子排布 实测值

离子电荷
质子 41
电子 41
电荷 中性
电子排布 Nb: 4d⁴ 5s¹
电子排布
实测值
[Kr] 4d⁴ 5s¹
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d⁴ 5s¹
轨道图
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
1/2 1↑
4d
4/10 4↑
电子总数: 41 未配对: 5 ?

原子模型

质子 41
中子 52
电子 41
质量数 93
稳定性 稳定

不同同位素的中子数、质量和稳定性不同,但中性原子的电子排布不变。

原子模型示意图,未按比例绘制。

原子指纹

发射 / 吸收光谱

24 / 24 (22 22条具有强度数据)
实测值
发射 可见光:380–750 nm

同位素分布

单同位素元素
唯一天然存在的同位素:93 — 100.0000%
93100.0000%质量数天然丰度(%)
质量数原子质量(u)天然丰度半衰期
93 稳定92.906373 ± 0.000002100.0000%稳定
实测值

物相 / 状态

1 atm / 101.325 kPa
固态 25 °C (298.15 K)

原因: 低于熔点(2476.85 °C)2451.8 °C

熔点 2476.85 °C
沸点 4743.85 °C
低于熔点的温差 2451.8 °C
0 K 当前温度: 25 °C 6000 K
物相变化轴

示意图,未按比例绘制

固态
液态
气态
熔化
沸腾
25°C
固态
液态
气态
当前

相变点

熔点 文献值
2476.85 °C
沸点 文献值
4743.85 °C
当前物相 计算值
固态

相变能

熔化热 文献值
0.27776338 eV

在熔点熔化1 mol物质所需的能量

汽化热 文献值
7.151371 eV

在沸点汽化1 mol物质所需的能量

升华热 文献值
7.617764 eV

在升华点升华1 mol物质所需的能量

密度

参考密度 文献值
8570 kg/m³

标准条件下

当前密度 计算值
8570 kg/m³

标准条件下

原子光谱

已显示10项,共41项。 按离子电荷升序排列。

收录谱线 ?

离子电荷谱线总数跃迁概率能级标记
Nb I 050900
Nb II +115000
Nb III +210800
Nb IV +3819819819
Nb V +41200
NIST收录谱线 →

收录能级 ?

离子电荷能级
Nb I 0395
Nb II +1354
Nb III +2189
Nb IV +3183
Nb V +431
Nb VI +5105
Nb VII +632
Nb VIII +72
Nb IX +82
Nb X +92
NIST收录能级 →
41 Nb 92.90637

Niobium — 原子轨道可视化工具

[Kr]5s14d4
能级 2 8 18 12 1
氧化态 -3, -1, 0, +1, +2, +3, +4, +5
HOMO 5s n=5 · l=0 · m=0
Niobium — 原子轨道可视化预览
Three.js仅在需要时加载
41 Nb 92.90637

Niobium — 晶体结构可视化工具

体心立方 · 皮尔逊符号 cI2
实验数据
皮尔逊符号 cI2
配位数 8
堆积系数 68.000%
Niobium — 晶体结构可视化预览
Three.js仅在需要时加载

离子半径

电荷配位自旋半径
+36暂无72 pm
+46暂无68 pm
+48暂无79 pm
+54暂无48 pm
+56暂无64 pm
+57暂无69 pm
+58暂无74 pm

化合物

Nb
92.906 u
Nb
94.907 u
Nb
89.911 u
Nb
93.907 u
Nb
96.908 u
Nb
87.918 u
Nb
88.913 u
Nb
97.910 u
Nb
95.908 u
Nb
92.906 u
Nb
91.907 u
Nb+5
92.906 u
Nb+3
92.906 u
Nb+2
92.906 u

同位素 (1)

Eighteen isotopes of niobium are known. The metal can be isolated from tantalum, and prepared in several ways.

质量数原子质量(u)天然丰度半衰期衰变方式
93 稳定92.906373 ± 0.000002100.0000%稳定
stable
93 稳定
原子质量(u) 92.906373 ± 0.000002
天然丰度 100.0000%
半衰期 稳定
衰变方式
stable

谱线

波长(nm)强度电离级类型跃迁准确度来源
382.5416 nm5000Nb IVemission4d.5d 3P → 4d.6p 1P*实测值NIST
382.5694 nm200000Nb IVemission4d.6p 1F* → 4d.6d 3D实测值NIST
382.5875 nm250000Nb IVemission4d.6p 3P* → 4d.6d 3D实测值NIST
383.106 nm15000Nb IVemission4d.5d 3D → 4d.6p 1D*实测值NIST
385.2874 nm60000Nb IVemission4d.6p 3P* → 4d.6d 3D实测值NIST
385.5325 nm10000Nb IVemission4d.6p 1P* → 4d.6d 3P实测值NIST
386.9546 nm8000Nb IVemission4d.6p 3P* → 4d.6d 1P实测值NIST
387.5455 nm100000Nb IVemission4d.5d 3G → 4d.6p 1D*实测值NIST
388.2203 nm60000Nb IVemission4d.6p 1P* → 4d.6d 1S实测值NIST
389.8028 nm100000Nb IVemission4d.5d 3S → 4d.6p 3P*实测值NIST
390.0115 nm25000Nb IVemission4d.6p 3P* → 4d.6d 3D实测值NIST
391.6922 nm8000Nb IVemission4d.5d 3F → 4d.6p 1F*实测值NIST
392.1878 nm5000Nb IVemission4d.5d 1P → 4d.6p 3D*实测值NIST
394.057 nm25000Nb IVemission4d.6p 3P* → 4d.6d 3D实测值NIST
394.3315 nm20000Nb IVemission4d.5d 3F → 4d.6p 3F*实测值NIST
398.5759 nm5000Nb IVemission4d.(2D<3/2>).6s 2[3/2] → 4d.6p 1P*实测值NIST
400.1839 nm4000Nb IVemission4d.6p 3P* → 4d.6d 3D实测值NIST
403.2233 nm40000Nb IVemission4d.5d 3F → 4d.6p 3D*实测值NIST
404.998 nm10000Nb IVemission4d.5d 3F → 4d.6p 3F*实测值NIST
405.2616 nm15000Nb IVemission4d.5d 1P → 4d.6p 1D*实测值NIST
406.3412 nm200000Nb IVemission4d.5d 3F → 4d.6p 3F*实测值NIST
406.4694 nm暂无Nb IVemission4d.6p 1P* → 4d.6d 1D实测值NIST
409.6529 nm7000Nb IVemission4d.6p 3P* → 4d.6d 3D实测值NIST
459.6 nm暂无ID 841emission2p 2P* → 2s 2S实测值NIST

扩展性质

共价半径(扩展)

共价半径(Pyykkö)
147 pm
共价半径(Pyykkö,双键)
125 pm
共价半径(Pyykkö,三键)
116 pm

范德华半径

Batsanov
215 pm
Alvarez
256 pm
UFF
316.5 pm
MM3
243 pm

原子半径与金属半径

原子半径(Rahm)
251 pm
金属半径(C12)
146 pm

编号标度

Mendeleev
48
Pettifor
52
Glawe
53

电负性标度

Ghosh
0
Miedema
4
Gunnarsson–Lundqvist
4
Robles–Bartolotti
2

极化率与色散

偶极极化率
98 a.u.
偶极极化率(不确定度)
8 a.u.
C₆ (Gould–Bučko)
1140 Ha·Bohr6

Miedema参数

Miedema摩尔体积
10.87 cm3/mol
Miedema电子密度
4

供应风险与经济性

生产集中度
98
相对供应风险
8
储量分布
97
政治稳定性(最大生产国)
48
政治稳定性(最大储量国)
48

相变与同素异形体

熔点2750.15 K
沸点5014.15 K

氧化态分类

−1 extended
+4 extended
+2 extended
+3 extended
+1 extended
0 extended
+5 main
−3 extended

高级参考数据

屏蔽常数 (10)
n轨道σ
1s0.8577
2p4.0178
2s10.8748
3d14.753
3p16.3844
3s15.8285
4d29.7624
4p26.9156
4s25.7172
5s35.079
晶体半径详情 (7)
电荷CN自旋rcrystal (pm)来源
3VI86
4VI82from r^3 vs V plots, estimated,
4VIII93
5IV62calculated,
5VI78
5VII83calculated,
5VIII88
同位素衰变方式 (67)
同位素模式强度
79p—
79B+—
79B+p—
80p—
80B+—
80B+p—
81p—
81B+—
81B+p—
82B+100%
X射线散射因子 (757)
能量 (eV)f₁f₂
0.5—0.09113
0.5079—0.09258
0.516—0.09406
0.5242—0.09557
0.5325—0.0971
0.5409—0.09865
0.5495—0.10023
0.5582—0.10161
0.5671—0.103
0.5761—0.10441

补充数据

Sources

Sources of this element.

The element is found in niobite (or columbite), niobite-tantalite, parochlore, and euxenite. Large deposits of niobium have been found associated with carbonatites (carbon-silicate rocks), as a constituent of parochlore. Extensive ore reserves are found in Canada, Brazil, Nigeria, Zaire, and in Russia.

参考文献 (1)

参考文献

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
Nb

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Niobium

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

许可证说明: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Niobium

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

许可证说明: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Niobium

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Niobium

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Niobium

This section provides all form of data related to element Niobium.

9 PubChem Elements
Niobium

The element property data was retrieved from publications.

最后更新:

数据已核实:

内容已依据最新科学数据进行审核。