Y 39

Yttrium (Y)

transition-metal
周期: 5 族: 3 区: d

Solid

标准原子量

88.90584 u

电子排布

[Kr] 5s2 4d1

熔点

1521.85 °C

沸点

3344.85 °C

密度

4470 kg/m³

氧化态

0, +1, +2, +3

电负性(鲍林)

1.22

第一电离能

6.21726 eV

发现年份

1794

原子半径

180 pm

详细信息

名称来源 From the Swedish village, Ytterby, where one of its minerals was first found.
发现国家 Finland
发现者 Johann Gadolin

Yttrium is a silvery transition metal grouped with the rare-earth elements because it commonly occurs with lanthanides and forms predominantly trivalent cations. Its chemistry is close to the heavier lanthanides, especially holmium and erbium, rather than to scandium. Although not itself a lanthanide, yttrium is a key component of phosphors, ceramics, lasers, and high-temperature oxide materials.

Yttrium has a silver-metallic luster and is relatively stable in air. Turnings of the metal, however, ignite in air if their temperature exceeds 400°C. Finely divided yttrium is very unstable in air.

The name derives from the Swedish village of Ytterby where the mineral gadolinite was found. In 1794, the Finnish chemist Johan Gadolin discovered yttrium in the mineral ytterbite, which was later renamed gadolinite for Gadolin. Gadolin originally called the element ytterbium after ytterbite. The name was subsequently shortened to yttrium, and later another element was given the name ytterbium.

Yttrium was discovered by Johan Gadolin, a Finnish chemist, while analyzing the composition of the mineral gadolinite ((Ce, La, Nd, Y)2FeBe2Si2O10) in 1789. Gadolinite, which was named for Johan Gadolin, was discovered several years earlier in a quarry near the town of Ytterby, Sweden. Today, yttrium is primarily obtained through an ion exchange process from monazite sand ((Ce, La, Th, Nd, Y)PO4), a material rich in rare earth elements.

Namded after Ytterby, a village in Sweden near Vauxholm. Yttria earth containing yttrium was discovered by Gadolin in 1794. Ytterby is the site of a quarry which yielded many unusual minerals containing rare earths and other elements. This small town, near Stockholm, bears the honor of giving names to erbium, terbium, and ytterbium as well as yttrium.

In 1843 Mosander showed that yttira could be resolved into the oxides (or earths) of three elements. The name yttria was reserved for the most basic one; the others were named erbia and terbia.

图片

性质

物理性质

原子半径(经验值)
180 pm 比较所有元素的原子半径(经验值) →
共价半径
190 pm 比较所有元素的共价半径 →
范德华半径
219 pm 比较所有元素的范德华半径 →
金属半径
162 pm 比较所有元素的金属半径 →
密度
4470 kg/m³ 比较所有元素的密度 →
摩尔体积
0.0198 L/mol
标准温度和压力下的物相
固态 比较所有元素的标准温度和压力下的物相 →
熔点
1521.85 °C 比较所有元素的熔点 →
沸点
3344.85 °C 比较所有元素的沸点 →
比热容
0.298 J/(g·K) 比较所有元素的比热容 →
摩尔热容
26.53 J/(mol·K) 比较所有元素的摩尔热容 →
晶体结构
六方密堆积 比较所有元素的晶体结构 →

化学性质

电负性(鲍林)
1.22 比较所有元素的电负性(鲍林) →
电负性(Allen)
1.12
电子亲和能
0.307 eV
第一电离能
6.21726 eV 比较所有元素的第一电离能 →
第二电离能
12.223642 eV 比较所有元素的第二电离能 →
第三电离能
20.524481 eV 比较所有元素的第三电离能 →
第四电离能
60.607409 eV 比较所有元素的第四电离能 →
第五电离能
75.350259 eV 比较所有元素的第五电离能 →
氧化态
0, +1, +2, +3 比较所有元素的氧化态 →
价电子
3 比较所有元素的价电子 →
电子排布
[Kr] 5s2 4d1

热力学性质

熔化热
0.11836037 eV 比较所有元素的熔化热 →
汽化热
3.762243 eV 比较所有元素的汽化热 →
升华热
4.394465 eV
原子化热
4.394465 eV
原子化焓
4.40172 eV

核性质

质子
39 比较所有元素的质子 →
中子
50 比较所有元素的中子 →
已知同位素
35 比较所有元素的已知同位素 →
稳定同位素
1 比较所有元素的稳定同位素 →
最稳定同位素
Y-89
发现年份
1794

丰度

丰度(地壳)
33 mg/kg 比较所有元素的丰度(地壳) →
丰度(海洋)
1.3 × 10−5 mg/L 比较所有元素的丰度(海洋) →

晶体结构

晶格常数a
365 pm

电子结构

各电子层电子数
2, 8, 18, 9, 2 比较所有元素的各电子层电子数 →

标识符

CAS登记号
7440-65-5 比较所有元素的CAS登记号 →
谱项符号
2D3/2
InChI
InChI=1S/Y
InChI Key
VWQVUPCCIRVNHF-UHFFFAOYSA-N

电子排布 实测值

离子电荷
质子 39
电子 39
电荷 中性
电子排布 Y: 4d¹ 5s²
电子排布
实测值
[Kr] 4d¹ 5s²
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹ 5s²
轨道图
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
2/2
4d
1/10 1↑
电子总数: 39 未配对: 1 ?

原子模型

质子 39
中子 50
电子 39
质量数 89
稳定性 稳定

不同同位素的中子数、质量和稳定性不同,但中性原子的电子排布不变。

原子模型示意图,未按比例绘制。

原子指纹

发射 / 吸收光谱

25 / 50 (50 50条具有强度数据)
实测值
发射 可见光:380–750 nm

同位素分布

单同位素元素
唯一天然存在的同位素:89 — 100.0000%
89100.0000%质量数天然丰度(%)
质量数原子质量(u)天然丰度半衰期
89 稳定88.9058403 ± 0.0000024100.0000%稳定
实测值

物相 / 状态

1 atm / 101.325 kPa
固态 25 °C (298.15 K)

原因: 低于熔点(1521.85 °C)1496.8 °C

熔点 1521.85 °C
沸点 3344.85 °C
低于熔点的温差 1496.8 °C
0 K 当前温度: 25 °C 6000 K
物相变化轴

示意图,未按比例绘制

固态
液态
气态
熔化
沸腾
25°C
固态
液态
气态
当前

相变点

熔点 文献值
1521.85 °C
沸点 文献值
3344.85 °C
当前物相 计算值
固态

相变能

熔化热 文献值
0.11836037 eV

在熔点熔化1 mol物质所需的能量

汽化热 文献值
3.762243 eV

在沸点汽化1 mol物质所需的能量

升华热 文献值
4.394465 eV

在升华点升华1 mol物质所需的能量

密度

参考密度 文献值
4470 kg/m³

标准条件下

当前密度 计算值
4470 kg/m³

标准条件下

原子光谱

已显示10项,共39项。 按离子电荷升序排列。

收录谱线 ?

离子电荷谱线总数跃迁概率能级标记
Y I 0361189351
Y II +111666116
Y III +211300
Y IV +32500
Y V +4632632632
Y VII +6168168168
Y VIII +7707070
NIST收录谱线 →

收录能级 ?

离子电荷能级
Y I 0194
Y II +1249
Y III +251
Y IV +3130
Y V +4114
Y VI +52
Y VII +657
Y VIII +733
Y IX +82
Y X +92
NIST收录能级 →
39 Y 88.90584

Yttrium — 原子轨道可视化工具

[Kr]5s24d1
能级 2 8 18 9 2
氧化态 0, +1, +2, +3
HOMO 4d n=4 · l=2 · m=-2
Yttrium — 原子轨道可视化预览
Three.js仅在需要时加载
39 Y 88.90584

Yttrium — 晶体结构可视化工具

简单六方 · 皮尔逊符号 hP2
实验数据
皮尔逊符号 hP2
配位数 12
堆积系数 75.071%
Yttrium — 晶体结构可视化预览
Three.js仅在需要时加载

离子半径

电荷配位自旋半径
+36暂无90 pm
+37暂无96 pm
+38暂无101.89999999999999 pm
+39暂无107.5 pm

化合物

Y
88.906 u
Y
89.907 u
Y+3
88.906 u
Y
90.907 u
Y
87.909 u
Y
85.915 u
Y
86.911 u
Y
88.906 u
Y
92.910 u
Y
91.909 u
Y
94.913 u
Y
93.912 u
Y+3
89.907 u
Y+3
88.906 u
Y
98.924 u
Y+3
85.915 u

同位素 (1)

Natural yttrium contains one isotope, 89Y. Nineteen other unstable isotopes have been characterized.

质量数原子质量(u)天然丰度半衰期衰变方式
89 稳定88.9058403 ± 0.0000024100.0000%稳定
stable
89 稳定
原子质量(u) 88.9058403 ± 0.0000024
天然丰度 100.0000%
半衰期 稳定
衰变方式
stable

谱线

已显示50项,共266项。 默认仅显示具有实测强度的谱线。

波长(nm)强度电离级类型跃迁准确度来源
410.23691 nm9900Y Iemission4d.5s2 a 2D → 4d.5s.(1D).5p y 2F*实测值NIST
407.735998 nm9400Y Iemission4d.5s2 a 2D → 4d.5s.(1D).5p y 2F*实测值NIST
412.829876 nm8900Y Iemission4d.5s2 a 2D → 4d.5s.(1D).5p y 2D*实测值NIST
414.28358 nm7500Y Iemission4d.5s2 a 2D → 4d.5s.(1D).5p y 2D*实测值NIST
404.76281 nm2400Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p y 2P*实测值NIST
416.750671 nm2400Y Iemission4d.5s2 a 2D → 4d.5s.(1D).5p y 2F*实测值NIST
423.5934 nm2200Y Iemission4d.5s2 a 2D → 4d.5s.(1D).5p y 2D*实测值NIST
408.37033 nm2000Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p y 2P*实测值NIST
417.41339 nm2000Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p y 2P*实测值NIST
464.368813 nm2000Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p z 2F*实测值NIST
467.48486 nm2000Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p z 2F*实测值NIST
619.17183 nm1200Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p z 2D*实测值NIST
643.50036 nm1000Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p z 2D*实测值NIST
403.982219 nm940Y Iemission4d.5s2 a 2D → 4d.5s.(1D).5p y 2D*实测值NIST
452.72342 nm890Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4D*实测值NIST
483.9861 nm770Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4F*实测值NIST
552.75472 nm740Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p z 4G*实测值NIST
546.6464 nm710Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p z 4G*实测值NIST
558.18694 nm620Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p z 4G*实测值NIST
563.01301 nm560Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p z 4G*实测值NIST
484.56655 nm550Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4F*实测值NIST
450.59441 nm500Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4D*实测值NIST
452.77815 nm440Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4D*实测值NIST
476.09753 nm410Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p z 2F*实测值NIST
485.26766 nm410Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4F*实测值NIST
485.98428 nm330Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4F*实测值NIST
425.11994 nm300Y Iemission4d.5s.(3D).5p z 4F* → 4d.5s.(3D).5d e 4G实测值NIST
448.74634 nm300Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4D*实测值NIST
550.3466 nm300Y Iemission4d2.(3F).5s a 2F → 4d2.(3F).5p x 2F*实测值NIST
622.25784 nm300Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p z 2D*实测值NIST
543.82242 nm190Y Iemission4d2.(3F).5s a 2F → 4d2.(3F).5p x 2D*实测值NIST
546.62434 nm190Y Iemission4d.5s.(3D).5p z 4F* → 4d.5s.(3D).6s e 4D实测值NIST
679.37029 nm190Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p z 4F*实测值NIST
524.08001 nm181Y Iemission4d2.(1G).5s a 2G → 4d2.(1G).5p z 2H*实测值NIST
447.69471 nm180Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p x 2F*实测值NIST
469.67994 nm180Y Iemission4d2.(1D).5s b 2D → 4d2.(1D).5p w 2F*实测值NIST
479.92999 nm180Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4F*实测值NIST
513.51993 nm180Y Iemission4d2.(1G).5s a 2G → 4d2.(1G).5p z 2H*实测值NIST
557.74153 nm180Y Iemission4d2.(3F).5s a 2F → 4d2.(3F).5p z 2G*实测值NIST
447.57178 nm170Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4D*实测值NIST
472.8516 nm170Y Iemission5s2.5p z 2P* → 5s2.6s e 2S实测值NIST
478.68762 nm170Y Iemission4d2.(3P).5s a 4P → 4d2.(3P).5p x 4D*实测值NIST
421.77985 nm160Y Iemission5s2.5p z 2P* → 5s2.(2D).5d e 2D实测值NIST
447.74436 nm160Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4D*实测值NIST
475.2787 nm160Y Iemission4d2.(3F).5s a 2F → 4d2.(3P).5p x 4D*实测值NIST
570.67133 nm160Y Iemission4d.5s.(3D).5p z 4F* → 4d.5s.(3D).6s e 4D实测值NIST
492.18769 nm150Y Iemission5s2.5p z 2P* → 5s2.6s e 2S实测值NIST
613.84349 nm150Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p z 4D*实测值NIST
668.75669 nm150Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p z 4F*实测值NIST
465.37837 nm140Y Iemission4d2.(1D).5s b 2D → 4d2.(3P).5p y 4P*实测值NIST

扩展性质

共价半径(扩展)

共价半径(Pyykkö)
163 pm
共价半径(Pyykkö,双键)
130 pm
共价半径(Pyykkö,三键)
124 pm

范德华半径

Batsanov
240 pm
Alvarez
275 pm
UFF
334.5 pm
MM3
271 pm

原子半径与金属半径

原子半径(Rahm)
274 pm
金属半径(C12)
180 pm

编号标度

Mendeleev
12
Pettifor
19
Glawe
21

电负性标度

Ghosh
0
Miedema
3
Gunnarsson–Lundqvist
3
Robles–Bartolotti
3

极化率与色散

偶极极化率
162 a.u.
偶极极化率(不确定度)
12 a.u.
C₆ (Gould–Bučko)
2600 Ha·Bohr6

化学亲和力

质子亲和能
967 kJ/mol
气相碱性
945.9 kJ/mol

Miedema参数

Miedema摩尔体积
19.9 cm3/mol
Miedema电子密度
2

供应风险与经济性

生产集中度
97
相对供应风险
10
储量分布
50
政治稳定性(最大生产国)
24
政治稳定性(最大储量国)
24

相变与同素异形体

熔点1795.15 K
沸点3618.15 K

氧化态分类

+2 extended
+1 extended
+3 main
0 extended

高级参考数据

屏蔽常数 (10)
n轨道σ
1s0.8244
2p3.9968
2s10.3778
3d13.6029
3p15.9075
3s15.4485
4d23.0416
4p26.2544
4s24.7364
5s32.744
晶体半径详情 (4)
电荷CN自旋rcrystal (pm)来源
3VI104from r^3 vs V plots,
3VII110
3VIII115.9from r^3 vs V plots,
3IX121.5from r^3 vs V plots,
同位素衰变方式 (60)
同位素模式强度
75B+—
75B+p—
75p—
76B+—
76p—
76B+p—
77B+100%
77B+p—
77p—
78B+100%
X射线散射因子 (619)
能量 (eV)f₁f₂
10—2.26036
10.1617—2.25621
10.3261—2.25207
10.4931—2.24793
10.6628—2.2438
10.8353—2.23968
11.0105—2.23344
11.1886—2.21122
11.3696—2.18921
11.5535—2.16742

补充数据

Sources

Sources of this element.

Yttrium occurs in nearly all of the rare-earth minerals. Analysis of lunar rock samples obtained during the Apollo missions show a relatively high yttrium content.

It is recovered commercially from monazite sand, which contains about 3%, and from bastnasite, which contains about 0.2%. Wohler obtained the impure element in 1828 by reduction of the anhydrous chloride with potassium. The metal is now produced commercially by reduction of the fluoride with calcium metal. It can also be prepared by other techniques.

参考文献 (1)

参考文献

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
Y

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Yttrium

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

许可证说明: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Yttrium

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

许可证说明: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Yttrium

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Yttrium

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Yttrium

This section provides all form of data related to element Yttrium.

9 PubChem Elements
Yttrium

The element property data was retrieved from publications.

最后更新:

数据已核实:

内容已依据最新科学数据进行审核。