Sr 38

Strontium (Sr)

alkaline-earth-metal
周期: 5 族: 2 区: s

Solid

标准原子量

87.62 u

电子排布

[Kr] 5s2

熔点

776.85 °C

沸点

1381.85 °C

密度

2640 kg/m³

氧化态

+1, +2

电负性(鲍林)

0.95

第一电离能

5.694867 eV

发现年份

1792

原子半径

200 pm

详细信息

名称来源 From the Scottish town, Strontian.
发现国家 Scotland
发现者 A. Crawford

Strontium is an alkaline earth metal below calcium and above barium in group 2. Natural strontium is stable and occurs mainly as the minerals celestine and strontianite rather than as the free metal. Its chemistry is dominated by the Sr²⁺ ion, which closely resembles Ca²⁺ but is larger and more readily forms insoluble sulfate and carbonate salts. Strontium is best known technologically for red pyrotechnic colors, ferrite magnets, glass additives, and the radioactive isotope ⁹⁰Sr.

Strontium is softer than calcium and decomposes in water more vigorously. It does not absorb nitrogen below 380°C. It should be kept under kerosene to prevent oxidation. Freshly cut strontium has a silvery appearance, but rapidly turns a yellowish color with the formation of the oxide. The finely divided metal ignites spontaneously in air. Volatile strontium salts impart a beautiful crimson color to flames, and these salts are used in pyrotechnics and in the production of flares. Natural strontium is a mixture of four stable isotopes.

The name derives from Strontian, a town in Scotland. The mineral strontianite is found in mines in Strontian. The element was discovered in 1792 by the Scottish chemist and physician Thomas Charles Hope, who observed the brilliant red flame colour of strontium. It was first isolated by the English chemist Humphry Davy in 1808.

Strontium was discovered by Adair Crawford, an Irish chemist, in 1790 while studying the mineral witherite (BaCO3). When he mixed witherite with hydrochloric acid (HCl) he did not get the results he expected. He assumed that his sample of witherite was contaminated with an unknown mineral, a mineral he named strontianite (SrCO3). Strontium was first isolated by Sir Humphry Davy, an English chemist, in 1808 through the electrolysis of a mixture of strontium chloride (SrCl2) and mercuric oxide (HgO). Today, strontium is obtained from two of its most common ores, celestite (SrSO4) and strontianite (SrCO3), by treating them with hydrochloric acid, forming strontium chloride. The strontium chloride, usually mixed with potassium chloride (KCl), is then melted and electrolyzed, forming strontium and chlorine gas (Cl2).

Named after Strontian, a town in Scotland. Isolated by Davey by electrolysis in 1808, however, Adair Crawford recognized a new mineral (strontianite) as differing from other barium minerals in 1790.

图片

性质

物理性质

原子半径(经验值)
200 pm 比较所有元素的原子半径(经验值) →
共价半径
195 pm 比较所有元素的共价半径 →
范德华半径
249 pm 比较所有元素的范德华半径 →
金属半径
191 pm 比较所有元素的金属半径 →
密度
2640 kg/m³ 比较所有元素的密度 →
摩尔体积
0.0337 L/mol
标准温度和压力下的物相
固态 比较所有元素的标准温度和压力下的物相 →
熔点
776.85 °C 比较所有元素的熔点 →
沸点
1381.85 °C 比较所有元素的沸点 →
比热容
0.306 J/(g·K) 比较所有元素的比热容 →
摩尔热容
26.79 J/(mol·K) 比较所有元素的摩尔热容 →
晶体结构
面心立方 比较所有元素的晶体结构 →

化学性质

电负性(鲍林)
0.95 比较所有元素的电负性(鲍林) →
电负性(Allen)
0.963
电子亲和能
0.052 eV
第一电离能
5.694867 eV 比较所有元素的第一电离能 →
第二电离能
11.030314 eV 比较所有元素的第二电离能 →
第三电离能
42.883678 eV 比较所有元素的第三电离能 →
第四电离能
56.280194 eV 比较所有元素的第四电离能 →
第五电离能
70.700243 eV 比较所有元素的第五电离能 →
氧化态
+1, +2 比较所有元素的氧化态 →
价电子
2 比较所有元素的价电子 →
电子排布
[Kr] 5s2

热力学性质

熔化热
0.08602373 eV 比较所有元素的熔化热 →
汽化热
1.421983 eV 比较所有元素的汽化热 →
升华热
1.703892 eV
原子化热
1.703892 eV
原子化焓
1.699746 eV

核性质

质子
38 比较所有元素的质子 →
中子
50 比较所有元素的中子 →
已知同位素
35 比较所有元素的已知同位素 →
稳定同位素
4 比较所有元素的稳定同位素 →
最稳定同位素
Sr-88
发现年份
1792

丰度

丰度(地壳)
370 mg/kg 比较所有元素的丰度(地壳) →
丰度(海洋)
7.9 mg/L 比较所有元素的丰度(海洋) →

晶体结构

晶格常数a
608 pm

电子结构

各电子层电子数
2, 8, 18, 8, 2 比较所有元素的各电子层电子数 →

标识符

CAS登记号
7440-24-6 比较所有元素的CAS登记号 →
谱项符号
1S0
InChI
InChI=1S/Sr
InChI Key
CIOAGBVUUVVLOB-UHFFFAOYSA-N

电子排布 实测值

离子电荷
质子 38
电子 38
电荷 中性
电子排布 Sr: 5s²
电子排布
实测值
[Kr] 5s²
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 5s²
轨道图
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
2/2
电子总数: 38 未配对: 0

原子模型

质子 38
中子 50
电子 38
质量数 88
稳定性 稳定

不同同位素的中子数、质量和稳定性不同,但中性原子的电子排布不变。

原子模型示意图,未按比例绘制。

原子指纹

发射 / 吸收光谱

25 / 50 (50 50条具有强度数据)
实测值
发射 可见光:380–750 nm

同位素分布

8882.5800%869.8600%877.0000%840.5600%质量数天然丰度(%)
质量数原子质量(u)天然丰度半衰期
84 稳定83.9134191 ± 0.00000130.5600%稳定
86 稳定85.9092606 ± 0.00000129.8600%稳定
87 稳定86.9088775 ± 0.00000127.0000%稳定
88 稳定87.9056125 ± 0.000001282.5800%稳定
实测值

物相 / 状态

1 atm / 101.325 kPa
固态 25 °C (298.15 K)

原因: 低于熔点(776.85 °C)751.9 °C

熔点 776.85 °C
沸点 1381.85 °C
低于熔点的温差 751.9 °C
0 K 当前温度: 25 °C 6000 K
物相变化轴

示意图,未按比例绘制

固态
液态
气态
熔化
沸腾
25°C
固态
液态
气态
当前

相变点

熔点 文献值
776.85 °C
沸点 文献值
1381.85 °C
当前物相 计算值
固态

相变能

熔化热 文献值
0.08602373 eV

在熔点熔化1 mol物质所需的能量

汽化热 文献值
1.421983 eV

在沸点汽化1 mol物质所需的能量

升华热 文献值
1.703892 eV

在升华点升华1 mol物质所需的能量

密度

参考密度 文献值
2640 kg/m³

标准条件下

当前密度 计算值
2640 kg/m³

标准条件下

原子光谱

已显示10项,共38项。 按离子电荷升序排列。

收录谱线 ?

离子电荷谱线总数跃迁概率能级标记
Sr I 036186361
Sr II +113533135
Sr III +26130613
Sr IV +3118301183
Sr V +46250625
Sr VI +5571457
Sr VII +6303030
Sr VIII +7262426
Sr IX +8462846
Sr X +9545154
NIST收录谱线 →

收录能级 ?

离子电荷能级
Sr I 0380
Sr II +172
Sr III +2150
Sr IV +3255
Sr V +4144
Sr VI +522
Sr VII +620
Sr VIII +721
Sr IX +831
Sr X +947
NIST收录能级 →
38 Sr 87.62

Strontium — 原子轨道可视化工具

[Kr]5s2
能级 2 8 18 8 2
氧化态 +1, +2
HOMO 5s n=5 · l=0 · m=0
Strontium — 原子轨道可视化预览
Three.js仅在需要时加载
38 Sr 87.62

Strontium — 晶体结构可视化工具

Face-Centered Cubic · 皮尔逊符号 cF4
实验数据
皮尔逊符号 cF4
配位数 12
堆积系数 74.000%
Strontium — 晶体结构可视化预览
Three.js仅在需要时加载

离子半径

电荷配位自旋半径
+26暂无118 pm
+27暂无121 pm
+28暂无126 pm
+29暂无131 pm
+210暂无136 pm
+212暂无144 pm

化合物

Sr
87.620 u
Sr
89.908 u
Sr+2
87.620 u
Sr
88.907 u
Sr+2
88.907 u
Sr
84.913 u
Sr
86.909 u
Sr
85.909 u
Sr
81.918 u
Sr
87.906 u
Sr
83.913 u
Sr+2
84.913 u
Sr
90.910 u
Sr
91.911 u
Sr
80.923 u
Sr
82.918 u
Sr
79.925 u
Sr+2
89.908 u
Sr+2
86.909 u
Sr+2
87.906 u
Sr+2
81.918 u
Sr+2
82.918 u
Sr+2
91.911 u

同位素 (4)

Sixteen other unstable isotopes are known to exist. Of greatest importance is 90Sr with a half-life of 29 years. It is a product of nuclear fallout and presents a health problem. This isotope is one of the best long-lived high-energy beta emitters known, and is used in SNAP (Systems for Nuclear Auxilliary Power) devices. These devices hold promise for use in space vehicles, remote weather stations, navigational buoys, etc., and where a lightweight, long-lived, nuclear-electric power source is needed.

质量数原子质量(u)天然丰度半衰期衰变方式
84 稳定83.9134191 ± 0.00000130.5600% ± 0.0100%稳定
stable
86 稳定85.9092606 ± 0.00000129.8600% ± 0.0100%稳定
stable
87 稳定86.9088775 ± 0.00000127.0000% ± 0.0100%稳定
stable
88 稳定87.9056125 ± 0.000001282.5800% ± 0.0100%稳定
stable
84 稳定
原子质量(u) 83.9134191 ± 0.0000013
天然丰度 0.5600% ± 0.0100%
半衰期 稳定
衰变方式
stable
86 稳定
原子质量(u) 85.9092606 ± 0.0000012
天然丰度 9.8600% ± 0.0100%
半衰期 稳定
衰变方式
stable
87 稳定
原子质量(u) 86.9088775 ± 0.0000012
天然丰度 7.0000% ± 0.0100%
半衰期 稳定
衰变方式
stable
88 稳定
原子质量(u) 87.9056125 ± 0.0000012
天然丰度 82.5800% ± 0.0100%
半衰期 稳定
衰变方式
stable

谱线

已显示50项,共500项。 默认仅显示具有实测强度的谱线。

波长(nm)强度电离级类型跃迁准确度来源
707.0072 nm14000Sr Iemission5s.5p 3P* → 5s.6s 3S实测值NIST
687.83128 nm12000Sr Iemission5s.5p 3P* → 5s.6s 3S实测值NIST
679.10198 nm7000Sr Iemission5s.5p 3P* → 5s.6s 3S实测值NIST
525.68986 nm3400Sr Iemission5s.4d 3D → 4d.5p 3P*实测值NIST
640.8463 nm3100Sr Iemission5s.4d 3D → 4d.5p 3F*实测值NIST
483.20425 nm2900Sr Iemission5s.5p 3P* → 5s.5d 3D实测值NIST
548.08638 nm2700Sr Iemission5s.4d 3D → 4d.5p 3D*实测值NIST
496.2263 nm2500Sr Iemission5s.5p 3P* → 5s.5d 3D实测值NIST
481.18799 nm2300Sr Iemission5s.5p 3P* → 5p2 3P实测值NIST
689.25894 nm2300Sr Iemission5s2 1S → 5s.5p 3P*实测值NIST
650.3992 nm2100Sr Iemission5s.4d 3D → 4d.5p 3F*实测值NIST
523.85479 nm2000Sr Iemission5s.4d 3D → 4d.5p 3P*实测值NIST
550.4181 nm2000Sr Iemission5s.4d 3D → 4d.5p 3D*实测值NIST
496.5585 nm1900Sr Iemission5s.5p 1P* → 5s.7d 1D实测值NIST
516.5486 nm1800Sr Iemission5s.5p 1P* → 5s.8s 1S实测值NIST
478.43198 nm1700Sr Iemission5s.5p 3P* → 5p2 3P实测值NIST
552.1768 nm1700Sr Iemission5s.4d 3D → 4d.5p 3D*实测值NIST
730.94166 nm1700Sr Iemission5s.4d 1D → 4d.5p 1D*实测值NIST
472.22769 nm1600Sr Iemission5s.5p 3P* → 5p2 3P实测值NIST
474.19221 nm1600Sr Iemission5s.5p 3P* → 5p2 3P实测值NIST
478.3782 nm1500Sr Iemission5s.5p 1P* → 5s.9s 1S实测值NIST
487.249 nm1500Sr Iemission5s.5p 3P* → 5s.5d 3D实测值NIST
489.198 nm1500Sr Iemission5s.4d 3D → 5s.4f 3F*实测值NIST
581.67702 nm1500Sr Iemission5s.4d 1D → 4d.5p 3P*实测值NIST
468.8546 nm1400Sr Iemission5s.5p 1P* → 5s.8d 1D实测值NIST
522.21992 nm1400Sr Iemission5s.4d 3D → 4d.5p 3P*实测值NIST
522.51079 nm1400Sr Iemission5s.4d 3D → 4d.5p 3P*实测值NIST
522.92697 nm1400Sr Iemission5s.4d 3D → 4d.5p 3P*实测值NIST
555.6375 nm1400Sr Iemission5s.5p 1P* → 5s.6d 3D实测值NIST
634.57265 nm1400Sr Iemission5s.4d 3D → 5s.6p 3P*实测值NIST
655.0244 nm1400Sr Iemission5s.5p 1P* → 4d2 1D实测值NIST
495.6274 nm1300Sr Iemission5s.5p 1P* → 5s.7d 3D实测值NIST
638.64581 nm1300Sr Iemission5s.4d 3D → 5s.6p 3P*实测值NIST
485.50448 nm1200Sr Iemission5s.4d 3D → 5s.4f 3F*实测值NIST
486.87005 nm1200Sr Iemission5s.4d 3D → 5s.4f 3F*实测值NIST
487.60745 nm1200Sr Iemission5s.5p 3P* → 5s.5d 3D实测值NIST
496.7942 nm1200Sr Iemission5s.5p 3P* → 5s.5d 3D实测值NIST
559.8159 nm1200Sr Iemission5s.4d 1D → 4d.5p 1F*实测值NIST
458.29879 nm1100Sr Iemission5s.5p 1P* → 5s.10s 1S实测值NIST
486.91724 nm1100Sr Iemission5s.4d 3D → 5s.4f 3F*实测值NIST
489.2642 nm1100Sr Iemission5s.4d 3D → 5s.4f 3F*实测值NIST
661.72651 nm1100Sr Iemission5s.4d 3D → 4d.5p 3F*实测值NIST
403.03772 nm1000Sr Iemission5s.5p 3P* → 5s.6d 3D实测值NIST
443.8043 nm1000Sr Iemission5s.5p 3P* → 5s.7s 3S实测值NIST
446.32981 nm1000Sr Iemission5s.5p 1P* → 5s.11s 1S实测值NIST
453.2375 nm1000Sr Iemission5s.5p 1P* → 5s.9d 1D实测值NIST
471.2151 nm1000Sr Iemission5s.4d 1D → 5s.5f 3F*实测值NIST
545.08373 nm1000Sr Iemission5s.4d 3D → 4d.5p 3D*实测值NIST
548.6135 nm1000Sr Iemission5s.4d 3D → 4d.5p 3D*实测值NIST
553.4799 nm1000Sr Iemission5s.4d 3D → 4d.5p 3D*实测值NIST

扩展性质

共价半径(扩展)

共价半径(Pyykkö)
185 pm
共价半径(Pyykkö,双键)
157 pm
共价半径(Pyykkö,三键)
139 pm
共价半径(Bragg)
195 pm

范德华半径

Truhlar
249 pm
Batsanov
255 pm
Alvarez
284 pm
UFF
364.1 pm
MM3
300 pm

原子半径与金属半径

原子半径(Rahm)
279 pm
金属半径(C12)
215 pm

编号标度

Mendeleev
8
Pettifor
15
Glawe
15

电负性标度

Ghosh
0
Miedema
2
Gunnarsson–Lundqvist
3
Robles–Bartolotti
2

极化率与色散

偶极极化率
197.2 a.u.
偶极极化率(不确定度)
0.2 a.u.
C₆
3175 Ha·Bohr6
C₆ (Gould–Bučko)
3230 Ha·Bohr6

Miedema参数

Miedema摩尔体积
33.93 cm3/mol
Miedema电子密度
1

供应风险与经济性

生产集中度
83
相对供应风险
9
储量分布
100
政治稳定性(最大生产国)
24
政治稳定性(最大储量国)
24

相变与同素异形体

熔点1050.15 K
沸点1650.15 K

氧化态分类

+2 main
+1 extended

高级参考数据

屏蔽常数 (9)
n轨道σ
1s0.8089
2p3.9696
2s10.0982
3d15.2738
3p15.8324
3s15.3362
4p26.068
4s24.5556
5s31.9295
晶体半径详情 (6)
电荷CN自旋rcrystal (pm)来源
2VI132
2VII135
2VIII140
2IX145
2X150calculated,
2XII158calculated,
同位素衰变方式 (54)
同位素模式强度
73B+100%
73B+p63%
74B+100%
74B+p—
75B+100%
75B+p5.2%
76B+100%
76B+p3.4%
77B+100%
77B+p0.1%
X射线散射因子 (508)
能量 (eV)f₁f₂
10—0.17126
10.1617—0.1749
10.3261—0.17861
10.4931—0.1824
10.6628—0.18627
10.8353—0.19061
11.0106—0.19514
11.1886—0.19977
11.3696—0.2045
11.5535—0.20936

补充数据

Isotopes in Forensic Science and Anthropology

Information on the use of this element's isotopes in forensic science and anthropology.

The isotope-amount ratio n(87Sr)/n(86Sr) is highly variable in rocks, minerals, soils, and waters, and it can be transmitted to plants (Fig. IUPAC.38.1), animals, and manufactured materials. Measurements of n(87Sr)/n(86Sr) ratios are used for forensic applications in food authentication (determining where food came from), archaeology, crime-scene investigation, and human migration [298] B. L. Beard, C. M. Johnson. J. Forensic Sci.45, 1049 (2000)., [299] K. M. Frei, R. Frei. Appl. Geochem.26, 326 (2011)..

参考文献 (4)
  • [298] B. L. Beard, C. M. Johnson. J. Forensic Sci.45, 1049 (2000).
  • [299] K. M. Frei, R. Frei. Appl. Geochem.26, 326 (2011).
  • [300] K. Miller, T. B. Coplen, M. Wieser. “Identification of the geographical origin of exotic wood species using 87Sr/86Sr isotope amount ratios”, in Goldschmidt 22nd Conference, Montreal, Quebec, Canada.
  • [4] IUPAC Periodic Table of the Elements and Isotopes (IPTEI) https://doi.org/10.1515/pac-2015-0703

参考文献

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
Sr

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Strontium

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

许可证说明: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Strontium

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

许可证说明: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Strontium

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Strontium

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Strontium

This section provides all form of data related to element Strontium.

9 PubChem Elements
Strontium

The element property data was retrieved from publications.

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