Mg 12

Magnesium (Mg)

alkaline-earth-metal
周期: 3 族: 2 区: s

Solid

标准原子量

24.305 u [24.304, 24.307]

电子排布

[Ne] 3s2

熔点

649.85 °C

沸点

1089.85 °C

密度

1740 kg/m³

氧化态

0, +1, +2

电负性(鲍林)

1.31

第一电离能

7.646236 eV

发现年份

1755

原子半径

150 pm

详细信息

名称来源 From Magnesia ancient city in district of Thessaly, Greece.
发现国家 England
发现者 Sir Humphrey Davy

Magnesium is a light alkaline earth metal and a major rock-forming element. It occurs in silicate minerals, carbonates, evaporites, seawater, and brines, almost entirely as Mg²⁺ rather than as native metal. Its low density, ready formation of stable salts, and high affinity for oxygen shape both its metallurgy and its geochemistry. Magnesium is also essential in biology, where it stabilizes phosphate chemistry and is central to chlorophyll.

Magnesium is a light, silvery-white, and fairly tough metal. It tarnishes slightly in air, and finely divided magnesium readily ignites upon heating in air and burns with a dazzling white flame.

The name derives from Magnesia, a district in the north-eastern region of Greece called Thessalia. The Scottish chemist Joseph Black recognized it as a separate element in 1755. In 1808, the English chemist Humphry Davy obtained the impure metal, and in 1831 the French pharmacist and chemist Antoine- Alexandre Brutus Bussy isolated the metal in the pure state.

Although it is the eighth most abundant element in the universe and the seventh most abundant element in the earth's crust, magnesium is never found free in nature. Magnesium was first isolated by Sir Humphry Davy, an English chemist, through the electrolysis of a mixture of magnesium oxide (MgO) and mercuric oxide (HgO) in 1808. Today, magnesium can be extracted from the minerals dolomite (CaCO3·MgCO3) and carnallite (KCl·MgCl2·6H2O), but is most often obtained from seawater. Every cubic kilometer of seawater contains about 1.3 billion kilograms of magnesium (12 billion pounds per cubic mile).

From Magnesia, district in Thessaly. Compounds of magnesium have long been known. Black recognized magnesium as an element in 1755. Davy isolated it in 1808 and Bussy prepared it in coherent form in 1831. Magnesium is the eighth most abundant element in the earth's crust. It does not occur uncombined, but is found in large deposits in the form of magnesite, dolomite, and other minerals.

图片

性质

物理性质

原子半径(经验值)
150 pm 比较所有元素的原子半径(经验值) →
共价半径
141 pm 比较所有元素的共价半径 →
范德华半径
173 pm 比较所有元素的范德华半径 →
金属半径
136 pm 比较所有元素的金属半径 →
密度
1740 kg/m³ 比较所有元素的密度 →
摩尔体积
0.014 L/mol
标准温度和压力下的物相
固态 比较所有元素的标准温度和压力下的物相 →
熔点
649.85 °C 比较所有元素的熔点 →
沸点
1089.85 °C 比较所有元素的沸点 →
热导率
156 W/(m·K) 比较所有元素的热导率 →
比热容
1.023 J/(g·K) 比较所有元素的比热容 →
摩尔热容
24.869 J/(mol·K) 比较所有元素的摩尔热容 →
晶体结构
六方密堆积 比较所有元素的晶体结构 →

化学性质

电负性(鲍林)
1.31 比较所有元素的电负性(鲍林) →
电负性(Allen)
1.293
电子亲和能
-0.4 eV (负值——预计该原子不结合额外电子)
第一电离能
7.646236 eV 比较所有元素的第一电离能 →
第二电离能
15.035323 eV 比较所有元素的第二电离能 →
第三电离能
80.143876 eV 比较所有元素的第三电离能 →
第四电离能
109.265776 eV 比较所有元素的第四电离能 →
第五电离能
141.330486 eV 比较所有元素的第五电离能 →
氧化态
0, +1, +2 比较所有元素的氧化态 →
价电子
2 比较所有元素的价电子 →
电子排布
[Ne] 3s2

热力学性质

熔化热
0.08788931 eV 比较所有元素的熔化热 →
汽化热
1.326631 eV 比较所有元素的汽化热 →
升华热
1.524589 eV
原子化热
1.524589 eV
原子化焓
1.524589 eV

核性质

质子
12 比较所有元素的质子 →
中子
12 比较所有元素的中子 →
已知同位素
23 比较所有元素的已知同位素 →
稳定同位素
3 比较所有元素的稳定同位素 →
最稳定同位素
Mg-24
发现年份
1755

丰度

丰度(地壳)
2.33e+4 mg/kg 比较所有元素的丰度(地壳) →
丰度(海洋)
1290 mg/L 比较所有元素的丰度(海洋) →

晶体结构

晶格常数a
321 pm

电子结构

各电子层电子数
2, 8, 2 比较所有元素的各电子层电子数 →

标识符

CAS登记号
7439-95-4 比较所有元素的CAS登记号 →
谱项符号
1S0
InChI
InChI=1S/Mg
InChI Key
FYYHWMGAXLPEAU-UHFFFAOYSA-N

电子排布 实测值

离子电荷
质子 12
电子 12
电荷 中性
电子排布 Mg: 3s²
电子排布
实测值
[Ne] 3s²
1s² 2s² 2p⁶ 3s²
轨道图
1s
2/2
2s
2/2
2p
6/6
3s
2/2
电子总数: 12 未配对: 0

原子模型

质子 12
中子 12
电子 12
质量数 24
稳定性 稳定

不同同位素的中子数、质量和稳定性不同,但中性原子的电子排布不变。

原子模型示意图,未按比例绘制。

原子指纹

发射 / 吸收光谱

25 / 50 (50 50条具有强度数据)
实测值
发射 可见光:380–750 nm

同位素分布

2478.9900%2611.0100%2510.0000%质量数天然丰度(%)
质量数原子质量(u)天然丰度半衰期
24 稳定23.985041697 ± 0.00000001478.9900%稳定
25 稳定24.985836976 ± 0.0000000510.0000%稳定
26 稳定25.982592968 ± 0.00000003111.0100%稳定
实测值

物相 / 状态

1 atm / 101.325 kPa
固态 25 °C (298.15 K)

原因: 低于熔点(649.85 °C)624.9 °C

熔点 649.85 °C
沸点 1089.85 °C
低于熔点的温差 624.9 °C
0 K 当前温度: 25 °C 6000 K
物相变化轴

示意图,未按比例绘制

固态
液态
气态
熔化
沸腾
25°C
固态
液态
气态
当前

相变点

熔点 文献值
649.85 °C
沸点 文献值
1089.85 °C
当前物相 计算值
固态

相变能

熔化热 文献值
0.08788931 eV

在熔点熔化1 mol物质所需的能量

汽化热 文献值
1.326631 eV

在沸点汽化1 mol物质所需的能量

升华热 文献值
1.524589 eV

在升华点升华1 mol物质所需的能量

密度

参考密度 文献值
1740 kg/m³

标准条件下

当前密度 计算值
1740 kg/m³

标准条件下

原子光谱

已显示10项,共12项。 按离子电荷升序排列。

收录谱线 ?

离子电荷谱线总数跃迁概率能级标记
Mg I 0134210901342
Mg II +1601482601
Mg III +2452149452
Mg IV +3821625821
Mg V +4518513515
Mg VI +5890883890
Mg VII +6379344379
Mg VIII +7944941944
Mg IX +8461444461
Mg X +9223184223
NIST收录谱线 →

收录能级 ?

离子电荷能级
Mg I 0323
Mg II +1149
Mg III +2114
Mg IV +3173
Mg V +4104
Mg VI +5120
Mg VII +6104
Mg VIII +7113
Mg IX +894
Mg X +960
NIST收录能级 →
12 Mg 24.3055

Magnesium — 原子轨道可视化工具

[Ne]3s2
能级 2 8 2
氧化态 0, +1, +2
HOMO 3s n=3 · l=0 · m=0
Magnesium — 原子轨道可视化预览
Three.js仅在需要时加载
12 Mg 24.3055

Magnesium — 晶体结构可视化工具

简单六方 · 皮尔逊符号 hP2
实验数据
皮尔逊符号 hP2
配位数 12
堆积系数 75.499%
Magnesium — 晶体结构可视化预览
Three.js仅在需要时加载

离子半径

电荷配位自旋半径
+24暂无56.99999999999999 pm
+25暂无66 pm
+26暂无72 pm
+28暂无89 pm

化合物

Mg
24.305 u
Mg+2
24.305 u
Mg
27.984 u
Mg
26.984 u
Mg
24.986 u
Mg+2
27.984 u
Mg+2
24.986 u
Mg
23.985 u
Mg
25.983 u

同位素 (3)

质量数原子质量(u)天然丰度半衰期衰变方式
24 稳定23.985041697 ± 0.00000001478.9900% ± 0.0400%稳定
stable
25 稳定24.985836976 ± 0.0000000510.0000% ± 0.0100%稳定
stable
26 稳定25.982592968 ± 0.00000003111.0100% ± 0.0300%稳定
stable
24 稳定
原子质量(u) 23.985041697 ± 0.000000014
天然丰度 78.9900% ± 0.0400%
半衰期 稳定
衰变方式
stable
25 稳定
原子质量(u) 24.985836976 ± 0.00000005
天然丰度 10.0000% ± 0.0100%
半衰期 稳定
衰变方式
stable
26 稳定
原子质量(u) 25.982592968 ± 0.000000031
天然丰度 11.0100% ± 0.0300%
半衰期 稳定
衰变方式
stable

谱线

已显示50项,共399项。 默认仅显示具有实测强度的谱线。

波长(nm)强度电离级类型跃迁准确度来源
518.36043 nm45Mg Iemission3s.3p 3P* → 3s.4s 3S实测值NIST
517.26844 nm44Mg Iemission3s.3p 3P* → 3s.4s 3S实测值NIST
516.73213 nm42Mg Iemission3s.3p 3P* → 3s.4s 3S实测值NIST
383.82919 nm40Mg Iemission3s.3p 3P* → 3s.3d 3D实测值NIST
552.84047 nm40Mg Iemission3s.3p 1P* → 3s.4d 1D实测值NIST
383.23039 nm38Mg Iemission3s.3p 3P* → 3s.3d 3D实测值NIST
382.93547 nm36Mg Iemission3s.3p 3P* → 3s.3d 3D实测值NIST
470.29908 nm30Mg Iemission3s.3p 1P* → 3s.5d 1D实测值NIST
571.1088 nm30Mg Iemission3s.3p 1P* → 3s.5s 1S实测值NIST
435.19057 nm20Mg Iemission3s.3p 1P* → 3s.6d 1D实测值NIST
416.72713 nm15Mg Iemission3s.3p 1P* → 3s.7d 1D实测值NIST
625.6757 nm15Mg IIIemission2s2.2p5.(2P*<3/2>).4s 2[3/2]* → 2s2.2p5.(2P*<3/2>).4p 2[5/2]实测值NIST
448.1126 nm14Mg IIemission2p6.3d 2D → 2p6.4f 2F*实测值NIST
448.1325 nm13Mg IIemission2p6.3d 2D → 2p6.4f 2F*实测值NIST
738.7689 nm12Mg Iemission3s.3d 1D → 3s.8f 1F*实测值NIST
405.75052 nm10Mg Iemission3s.3p 1P* → 3s.8d 1D实测值NIST
439.0572 nm10Mg IIemission2p6.4p 2P* → 2p6.5d 2D实测值NIST
473.00286 nm10Mg Iemission3s.3p 1P* → 3s.6s 1S实测值NIST
491.5991 nm10Mg IIIemission2s2.2p5.(2P*<3/2>).4p 2[5/2] → 2s2.2p5.(2P*<3/2>).4d 2[7/2]*实测值NIST
583.981 nm10Mg IIIemission2s2.2p5.(2P*<3/2>).4s 2[3/2]* → 2s2.2p5.(2P*<3/2>).4p 2[3/2]实测值NIST
631.8717 nm10Mg Iemission3s.4s 3S → 3s.6p 3P*实测值NIST
634.6742 nm10Mg IIemission2p6.4d 2D → 2p6.6f 2F*实测值NIST
719.3184 nm10Mg Iemission3s.3d 1D → 3s.9f 1F*实测值NIST
729.1055 nm10Mg Iemission3s.4s 1S → 3s.6p 1P*实测值NIST
438.4637 nm9Mg IIemission2p6.4p 2P* → 2p6.5d 2D实测值NIST
443.3988 nm9Mg IIemission2p6.4p 2P* → 2p6.6s 2S实测值NIST
452.6219 nm9Mg IIIemission2s2.2p5.(2P*<3/2>).4p 2[1/2] → 2s2.2p5.(2P*<3/2>).4d 2[3/2]*实测值NIST
459.6921 nm9Mg IIIemission2s2.2p5.(2P*<3/2>).4p 2[1/2] → 2s2.2p5.(2P*<3/2>).4d 2[1/2]*实测值NIST
496.041 nm9Mg IIIemission2s2.2p5.(2P*<3/2>).4p 2[5/2] → 2s2.2p5.(2P*<3/2>).4d 2[7/2]*实测值NIST
631.9237 nm9Mg Iemission3s.4s 3S → 3s.6p 3P*实测值NIST
634.6964 nm9Mg IIemission2p6.4d 2D → 2p6.6f 2F*实测值NIST
384.8211 nm8Mg IIemission2p6.3d 2D → 2p6.5p 2P*实测值NIST
398.67533 nm8Mg Iemission3s.3p 1P* → 3s.9d 1D实测值NIST
442.7994 nm8Mg IIemission2p6.4p 2P* → 2p6.6s 2S实测值NIST
467.3315 nm8Mg IIIemission2s2.2p5.(2P*<1/2>).4s 2[1/2]* → 2s2.2p5.(2P*<1/2>).4p 2[1/2]实测值NIST
498.1469 nm8Mg IIIemission2s2.2p5.(2P*<1/2>).4p 2[3/2] → 2s2.2p5.(2P*<1/2>).4d 2[5/2]*实测值NIST
526.422 nm8Mg IIemission2p6.4d 2D → 2p6.7f 2F*实测值NIST
640.6637 nm8Mg IIIemission2s2.2p5.(2P*<3/2>).4s 2[3/2]* → 2s2.2p5.(2P*<3/2>).4p 2[5/2]实测值NIST
678.7855 nm8Mg IIemission2p6.5p 2P* → 2p6.7d 2D实测值NIST
681.927 nm8Mg IIemission2p6.5p 2P* → 2p6.8s 2S实测值NIST
706.0414 nm8Mg Iemission3s.3d 1D → 3s.10f 1F*实测值NIST
385.0386 nm7Mg IIemission2p6.3d 2D → 2p6.5p 2P*实测值NIST
423.9473 nm7Mg IIIemission2s2.2p5.(2P*<3/2>).4s 2[3/2]* → 2s2.2p5.(2P*<1/2>).4p 2[1/2]实测值NIST
463.2537 nm7Mg IIIemission2s2.2p5.(2P*<3/2>).4p 2[1/2] → 2s2.2p5.(2P*<3/2>).4d 2[1/2]*实测值NIST
480.2585 nm7Mg IIIemission2s2.2p5.(2P*<3/2>).4p 2[3/2] → 2s2.2p5.(2P*<3/2>).4d 2[3/2]*实测值NIST
491.5363 nm7Mg IIIemission2s2.2p5.(2P*<1/2>).4p 2[3/2] → 2s2.2p5.(2P*<1/2>).4d 2[5/2]*实测值NIST
497.0497 nm7Mg IIIemission2s2.2p5.(2P*<3/2>).4p 2[3/2] → 2s2.2p5.(2P*<3/2>).4d 2[5/2]*实测值NIST
502.3674 nm7Mg IIIemission2s2.2p5.(2P*<3/2>).4p 2[3/2] → 2s2.2p5.(2P*<3/2>).4d 2[5/2]*实测值NIST
526.4364 nm7Mg IIemission2p6.4d 2D → 2p6.7f 2F*实测值NIST
591.6431 nm7Mg IIemission2p6.4d 2D → 2p6.7p 2P*实测值NIST

扩展性质

共价半径(扩展)

共价半径(Pyykkö)
139 pm
共价半径(Pyykkö,双键)
132 pm
共价半径(Pyykkö,三键)
127 pm
共价半径(Bragg)
142 pm

范德华半径

Bondi
173 pm
Batsanov
220 pm
Alvarez
251 pm
UFF
302.1 pm
MM3
243 pm

原子半径与金属半径

原子半径(Rahm)
240 pm
金属半径(C12)
160 pm

编号标度

Mendeleev
76
Pettifor
73
Glawe
73

电负性标度

Ghosh
0
Miedema
3
Gunnarsson–Lundqvist
3
Robles–Bartolotti
3

极化率与色散

偶极极化率
71.2 a.u.
偶极极化率(不确定度)
0.4 a.u.
C₆
626 Ha·Bohr6
C₆ (Gould–Bučko)
629 Ha·Bohr6

化学亲和力

质子亲和能
819.6 kJ/mol
气相碱性
797.3 kJ/mol

Miedema参数

Miedema摩尔体积
14 cm3/mol
Miedema电子密度
2

供应风险与经济性

生产集中度
64
相对供应风险
7
储量分布
26
政治稳定性(最大生产国)
24
政治稳定性(最大储量国)
18

相变与同素异形体

熔点923.15 K
沸点1363.15 K

氧化态分类

+2 main
+1 extended
0 extended

高级参考数据

屏蔽常数 (4)
n轨道σ
1s0.3911
2p4.1742
2s4.608
3s8.6925
晶体半径详情 (4)
电荷CN自旋rcrystal (pm)来源
2IV71
2V80
2VI86
2VIII103calculated,
同位素衰变方式 (43)
同位素模式强度
192p100%
20B+100%
20B+p30.3%
21B+100%
21B+p20.1%
21B+A0.1%
21B+pA0%
22B+100%
23B+100%
27B-100%
X射线散射因子 (755)
能量 (eV)f₁f₂
0.50.1170.14592
0.50790.11680.14896
0.5160.11650.15206
0.52420.11650.15522
0.53250.11620.15845
0.54090.11620.16175
0.54950.11620.16511
0.55820.11610.16855
0.56710.11630.17205
0.57610.11670.17558

补充数据

Sources

Sources of this element.

The metal is now principally obtained in the U.S. by electrolysis of fused magnesium chloride derived from brines, wells, and sea water.

参考文献 (1)

参考文献

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
Mg

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Magnesium

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

许可证说明: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Magnesium

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

许可证说明: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Magnesium

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Magnesium

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Magnesium

This section provides all form of data related to element Magnesium.

9 PubChem Elements
Magnesium

The element property data was retrieved from publications.

最后更新:

数据已核实:

内容已依据最新科学数据进行审核。