Al 13

Aluminum (Al)

post-transition-metal
周期: 3 族: 13 区: p

Solid

标准原子量

26.981538 u

电子排布

[Ne] 3s2 3p1

熔点

660.287 °C

沸点

2518.85 °C

密度

2700 kg/m³

氧化态

−2, −1, 0, +1, +2, +3

电负性(鲍林)

1.61

第一电离能

5.985769 eV

发现年份

1825

原子半径

125 pm

详细信息

名称来源 Latin: alumen, aluminis, (alum).
发现国家 Denmark
发现者 Hans Christian Oersted

Aluminum is a light, silvery post-transition metal and the most abundant metal in Earth’s crust. It is highly reactive thermodynamically, but a thin, adherent oxide film protects the metal from rapid corrosion in air and water. Its low density, electrical conductivity, formability, and alloying behavior make it one of the major structural and engineering metals.

Pure aluminum, a silvery-white metal, possesses many desirable characteristics. It is light, it is nonmagnetic and nonsparking, stands second among metals in the scale of malleability, and sixth in ductility.

The name derives from the Latin, alum and alumen for "stringent" because the early Romans called any substance with a stringent taste alum. The element was known in prehistoric times. In 1825, the Danish physicist, Hans Christian Oersted, isolated impure aluminium. The pure metal was first isolated by the German chemist Friedrich Wöhler in 1827.

Although aluminum is the most abundant metal in the earth's crust, it is never found free in nature. All of the earth's aluminum has combined with other elements to form compounds. Two of the most common compounds are alum, such as potassium aluminum sulfate (KAl(SO4)2·12H2O), and aluminum oxide (Al2O3). About 8.2% of the earth's crust is composed of aluminum. Scientists suspected than an unknown metal existed in alum as early as 1787, but they did not have a way to extract it until 1825. Hans Christian Oersted, a Danish chemist, was the first to produce tiny amounts of aluminum. Two years later, Friedrich Wöhler, a German chemist, developed a different way to obtain aluminum. By 1845, he was able to produce samples large enough to determine some of aluminum's basic properties. Wöhler's method was improved in 1854 by Henri Étienne Sainte-Claire Deville, a French chemist. Deville's process allowed for the commercial production of aluminum. As a result, the price of aluminum dropped from around $1200 per kilogram in 1852 to around $40 per kilogram in 1859. Unfortunately, aluminum remained too expensive to be widely used.

From the Latin word alumen, alum. The ancient Greeks and Romans used alum as an astringent and as a mordant in dyeing. In 1761 de Morveau proposed the name alumine for the base in alum, and Lavoisier, in 1787, thought this to be the oxide of a still undiscovered metal.

Friedrich Wohler is generally credited with having isolated the metal in 1827, although an impure form was prepared by Oersted two years earlier. In 1807, Davy proposed the name aluminium for the metal, undiscovered at that time, and later agreed to change it to aluminum. Shortly thereafter, the name aluminum was adopted to conform with the "ium" ending of most elements.

Aluminium was also the accepted spelling in the U.S. until 1925, at which time the American Chemical Society decided to use the name aluminum thereafter in their publications. See the Wikipedia entry on Aluminium for additional discussion on the spelling of this element.

图片

性质

物理性质

原子半径(经验值)
125 pm 比较所有元素的原子半径(经验值) →
共价半径
121 pm 比较所有元素的共价半径 →
范德华半径
184 pm 比较所有元素的范德华半径 →
金属半径
125 pm 比较所有元素的金属半径 →
密度
2700 kg/m³ 比较所有元素的密度 →
摩尔体积
0.01 L/mol
标准温度和压力下的物相
固态 比较所有元素的标准温度和压力下的物相 →
熔点
660.287 °C 比较所有元素的熔点 →
沸点
2518.85 °C 比较所有元素的沸点 →
热导率
237 W/(m·K) 比较所有元素的热导率 →
比热容
0.897 J/(g·K) 比较所有元素的比热容 →
摩尔热容
24.2 J/(mol·K) 比较所有元素的摩尔热容 →
晶体结构
面心立方 比较所有元素的晶体结构 →

化学性质

电负性(鲍林)
1.61 比较所有元素的电负性(鲍林) →
电负性(Allen)
1.613
电子亲和能
0.4328 eV
第一电离能
5.985769 eV 比较所有元素的第一电离能 →
第二电离能
18.828615 eV 比较所有元素的第二电离能 →
第三电离能
28.44774 eV 比较所有元素的第三电离能 →
第四电离能
119.992813 eV 比较所有元素的第四电离能 →
第五电离能
153.825729 eV 比较所有元素的第五电离能 →
氧化态
−2, −1, 0, +1, +2, +3 比较所有元素的氧化态 →
价电子
3 比较所有元素的价电子 →
电子排布
[Ne] 3s2 3p1

热力学性质

临界点(温度)
6427 °C
熔化热
0.11100171 eV 比较所有元素的熔化热 →
汽化热
3.047106 eV 比较所有元素的汽化热 →
升华热
3.382909 eV
原子化热
3.382909 eV
原子化焓
3.429549 eV

核性质

质子
13 比较所有元素的质子 →
中子
14 比较所有元素的中子 →
已知同位素
23 比较所有元素的已知同位素 →
稳定同位素
1 比较所有元素的稳定同位素 →
最稳定同位素
Al-27
发现年份
1825

丰度

丰度(地壳)
8.23e+4 mg/kg 比较所有元素的丰度(地壳) →
丰度(海洋)
0.002 mg/L 比较所有元素的丰度(海洋) →

晶体结构

晶格常数a
405 pm

电子结构

各电子层电子数
2, 8, 3 比较所有元素的各电子层电子数 →

标识符

CAS登记号
7429-90-5 比较所有元素的CAS登记号 →
谱项符号
2P°1/2
InChI
InChI=1S/Al
InChI Key
XAGFODPZIPBFFR-UHFFFAOYSA-N

电子排布 实测值

离子电荷
质子 13
电子 13
电荷 中性
电子排布 Al: 3s² 3p¹
电子排布
实测值
[Ne] 3s² 3p¹
1s² 2s² 2p⁶ 3s² 3p¹
轨道图
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
1/6 1↑
电子总数: 13 未配对: 1 ?

原子模型

质子 13
中子 14
电子 13
质量数 27
稳定性 稳定

不同同位素的中子数、质量和稳定性不同,但中性原子的电子排布不变。

原子模型示意图,未按比例绘制。

原子指纹

发射 / 吸收光谱

25 / 50 (50 50条具有强度数据)
实测值
发射 可见光:380–750 nm

同位素分布

单同位素元素
唯一天然存在的同位素:27 — 100.0000%
27100.0000%质量数天然丰度(%)
质量数原子质量(u)天然丰度半衰期
27 稳定26.98153853 ± 0.00000011100.0000%稳定
实测值

物相 / 状态

1 atm / 101.325 kPa
固态 25 °C (298.15 K)

原因: 低于熔点(660.287 °C)635.3 °C

熔点 660.287 °C
沸点 2518.85 °C
低于熔点的温差 635.3 °C
0 K 当前温度: 25 °C 6000 K
物相变化轴

示意图,未按比例绘制

固态
液态
气态
熔化
沸腾
25°C
固态
液态
气态
当前

相变点

熔点 文献值
660.287 °C
沸点 文献值
2518.85 °C
当前物相 计算值
固态

相变能

熔化热 文献值
0.11100171 eV

在熔点熔化1 mol物质所需的能量

汽化热 文献值
3.047106 eV

在沸点汽化1 mol物质所需的能量

升华热 文献值
3.382909 eV

在升华点升华1 mol物质所需的能量

密度

参考密度 文献值
2700 kg/m³

标准条件下

当前密度 计算值
2700 kg/m³

标准条件下

高级

临界点 文献值
6427 °C

原子光谱

已显示10项,共13项。 按离子电荷升序排列。

收录谱线 ?

离子电荷谱线总数跃迁概率能级标记
Al I 0589322560
Al II +114299861429
Al III +2344259344
Al IV +3409123409
Al V +4600444600
Al VI +5515491515
Al VII +6350339350
Al VIII +7440418438
Al IX +8372339372
Al X +9189169189
NIST收录谱线 →

收录能级 ?

离子电荷能级
Al I 0192
Al II +1219
Al III +284
Al IV +3121
Al V +4158
Al VI +587
Al VII +673
Al VIII +795
Al IX +869
Al X +961
NIST收录能级 →
13 Al 26.9815385

Aluminum — 原子轨道可视化工具

[Ne]3s23p1
能级 2 8 3
氧化态 -2, -1, 0, +1, +2, +3
HOMO 3p n=3 · l=1 · m=-1
Aluminum — 原子轨道可视化预览
Three.js仅在需要时加载
13 Al 26.9815385

Aluminum — 晶体结构可视化工具

Face-Centered Cubic · 皮尔逊符号 cF4
实验数据
皮尔逊符号 cF4
配位数 12
堆积系数 74.000%
Aluminum — 晶体结构可视化预览
Three.js仅在需要时加载

离子半径

电荷配位自旋半径
+34暂无39 pm
+35暂无48 pm
+36暂无53.5 pm

化合物

Al
26.982 u
Al+3
26.982 u
Al
25.987 u
Al
28.980 u
Al
26.982 u
Al
27.982 u
Al+3
26.982 u

同位素 (1)

质量数原子质量(u)天然丰度半衰期衰变方式
27 稳定26.98153853 ± 0.00000011100.0000%稳定
stable
27 稳定
原子质量(u) 26.98153853 ± 0.00000011
天然丰度 100.0000%
半衰期 稳定
衰变方式
stable

谱线

已显示50项,共341项。 默认仅显示具有实测强度的谱线。

波长(nm)强度电离级类型跃迁准确度来源
466.3046 nm1000Al IIemission3p2 1D → 3s.4p 1P*实测值NIST
559.33 nm800Al IIemission3s.4p 1P* → 3s.4d 1D实测值NIST
458.5818 nm500Al IIemission3s.4d 3D → 3s.7f 3F*实测值NIST
458.8199 nm400Al IIemission3s.4d 3D → 3s.7f 3F*实测值NIST
464.8609 nm400Al IIemission3s.4d 1D → 3s.10p 1P*实测值NIST
466.6799 nm400Al IIemission3s.5p 1P* → 3s.11s 1S实测值NIST
458.975 nm300Al IIemission3s.4d 3D → 3s.7f 3F*实测值NIST
444.7805 nm200Al IIemission3s.4d 1D → 3s.11p 1P*实测值NIST
458.968 nm200Al IIemission3s.4d 3D → 3s.7f 3F*实测值NIST
600.641 nm200Al IIemission3s.5p 3P* → 3s.7d 3D实测值NIST
390.0675 nm100Al IIemission3s.3p 1P* → 3p2 1D实测值NIST
528.3733 nm100Al IIemission3s.5p 3P* → 3s.8d 3D实测值NIST
561.329 nm100Al IIemission3s.4d 1D → 3s.7f 1F*实测值NIST
585.376 nm100Al IIemission3s.4d 3D → 3s.6f 3F*实测值NIST
624.337 nm100Al IIemission3s.4p 3P* → 3s.4d 3D实测值NIST
704.208 nm100Al IIemission3s.4s 3S → 3s.4p 3P*实测值NIST
747.141 nm90Al IIemission3s.3d 1D → 3s.4f 1F*实测值NIST
586.177 nm80Al IIemission3s.4d 3D → 3s.6f 3F*实测值NIST
597.197 nm80Al IIemission3s.5p 1P* → 3s.7d 1D实测值NIST
683.713 nm80Al IIemission3s.4p 3P* → 3s.5s 3S实测值NIST
623.175 nm75Al IIemission3s.4p 3P* → 3s.4d 3D实测值NIST
600.187 nm60Al IIemission3s.5p 3P* → 3s.7d 3D实测值NIST
422.6816 nm50Al IIemission3s.4d 3D → 3s.8f 3F*实测值NIST
422.7495 nm50Al IIemission3s.4d 3D → 3s.8f 3F*实测值NIST
422.7987 nm50Al IIemission3s.4d 3D → 3s.8f 3F*实测值NIST
586.79 nm50Al IIemission3s.4d 3D → 3s.6f 3F*实测值NIST
607.32 nm50Al IIemission3s.5p 3P* → 3s.8s 3S实测值NIST
622.619 nm50Al IIemission3s.4p 3P* → 3s.4d 3D实测值NIST
682.339 nm50Al IIemission3s.4p 3P* → 3s.5s 3S实测值NIST
705.671 nm50Al IIemission3s.4s 3S → 3s.4p 3P*实测值NIST
744.944 nm50Al IIemission3s.5p 1P* → 3s.6d 1D实测值NIST
399.5837 nm40Al IIemission3s.4d 3D → 3s.9f 3F*实测值NIST
450.371 nm40Al IVemission2s2.2p5.(2P*<3/2>).4s 2[3/2]* → 2s2.2p5.(2P*<3/2>).4p 2[5/2]实测值NIST
600.192 nm40Al IIemission3s.5p 3P* → 3s.7d 3D实测值NIST
399.6141 nm30Al IIemission3s.4d 3D → 3s.9f 3F*实测值NIST
450.237 nm30Al IVemission2s2.2p5.(2P*<1/2>).4s 2[1/2]* → 2s2.2p5.(2P*<1/2>).4p 2[3/2]实测值NIST
463.576 nm30Al IIemission3s.5p 3P* → 3s.10d 3D实测值NIST
528.5838 nm30Al IIemission3s.5p 1P* → 3s.8d 1D实测值NIST
606.112 nm30Al IIemission3s.5p 1P* → 3s.8s 1S实测值NIST
633.571 nm30Al IIemission3s.3d 1D → 3s.5p 1P*实测值NIST
399.6368 nm20Al IIemission3s.4d 3D → 3s.9f 3F*实测值NIST
402.6318 nm20Al IIemission3s.3d 1D → 3s.6p 1P*实测值NIST
446.894 nm20Al IVemission2s2.2p5.(2P*<3/2>).4s 2[3/2]* → 2s2.2p5.(2P*<3/2>).4p 2[3/2]实测值NIST
569.66 nm17Al IIIemission2p6.4s 2S → 2p6.4p 2P*实测值NIST
572.273 nm16Al IIIemission2p6.4s 2S → 2p6.4p 2P*实测值NIST
462.038 nm15Al IVemission2s2.2p5.(2P*<3/2>).4s 2[3/2]* → 2s2.2p5.(2P*<3/2>).4p 2[5/2]实测值NIST
531.6073 nm15Al IIemission3s.5p 3P* → 3s.9s 3S实测值NIST
452.919 nm14Al IIIemission2p6.4p 2P* → 2p6.4d 2D实测值NIST
451.257 nm13Al IIIemission2p6.4p 2P* → 2p6.4d 2D实测值NIST
669.6018 nm13Al Iemission3s2.4s 2S → 3s2.5p 2P*实测值NIST

扩展性质

共价半径(扩展)

共价半径(Pyykkö)
126 pm
共价半径(Pyykkö,双键)
113 pm
共价半径(Pyykkö,三键)
111 pm
共价半径(Bragg)
135 pm

范德华半径

Truhlar
184 pm
Batsanov
210 pm
Alvarez
225 pm
UFF
449.9 pm
MM3
236 pm
Dreiding
439 pm

原子半径与金属半径

原子半径(Rahm)
239 pm
金属半径(C12)
143 pm

编号标度

Mendeleev
82
Pettifor
80
Glawe
78

电负性标度

Ghosh
0
Miedema
4
Gunnarsson–Lundqvist
3
Robles–Bartolotti
3

极化率与色散

偶极极化率
57.8 a.u.
偶极极化率(不确定度)
1 a.u.
C₆
528 Ha·Bohr6
C₆ (Gould–Bučko)
520 Ha·Bohr6

Miedema参数

Miedema摩尔体积
10 cm3/mol
Miedema电子密度
3

供应风险与经济性

生产集中度
31
相对供应风险
5
储量分布
26
政治稳定性(最大生产国)
75
政治稳定性(最大储量国)
5

相变与同素异形体

熔点933.47 K
沸点2792.15 K
临界点(温度)6700.15 K

氧化态分类

+1 extended
−1 extended
0 extended
+2 extended
+3 main
−2 extended

高级参考数据

屏蔽常数 (5)
n轨道σ
1s0.409
2p4.0366
2s4.7864
3p8.9344
3s8.8828
晶体半径详情 (3)
电荷CN自旋rcrystal (pm)来源
3IV53
3V62
3VI67.5from r^3 vs V plots,
同位素衰变方式 (51)
同位素模式强度
21p—
22B+100%
22B+p55%
222p1.1%
22B+A0%
23B+100%
23B+p1.2%
24B+100%
24B+A0%
24B+p0%
X射线散射因子 (504)
能量 (eV)f₁f₂
10—3.1199
10.1617—3.05822
10.3261—2.99776
10.4931—2.9385
10.6628—2.88041
10.8353—2.82347
11.0106—2.76766
11.1886—2.722
11.3696—2.69148
11.5535—2.66129

补充数据

Sources

Sources of this element.

The method of obtaining aluminum metal by the electrolysis of alumina dissolved in cryolite was discovered in 1886 by Hall in the U.S. and at about the same time by Heroult in France. Cryolite, a natural ore found in Greenland, is no longer widely used in commercial production, but has been replaced by an artificial mixture of sodium, aluminum, and calcium fluorides.

Aluminum can now be produced from clay, but the process is not economically feasible at present. Aluminum is the most abundant metal to be found in the earth's crust (8.1%), but is never found free in nature. In addition to the minerals mentioned above, it is also found in granite and in many other common minerals.

参考文献 (1)

参考文献

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
Al

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Aluminium

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

许可证说明: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Aluminum

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

许可证说明: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Aluminum

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Aluminum

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Aluminum

This section provides all form of data related to element Aluminum.

9 PubChem Elements
Aluminum

The element property data was retrieved from publications.

最后更新:

数据已核实:

内容已依据最新科学数据进行审核。