Zinc (Zn)
transition-metalSolid
標準原子量
65.38 u電子配置
[Ar] 4s2 3d10融点
419.53 °C沸点
906.85 °C密度
7134 kg/m³酸化数
−2, 0, +1, +2電気陰性度（Pauling）
1.65第1イオン化エネルギー
9.394197 eV発見年
1746原子半径
135 pm詳細
Zinc is a moderately reactive, bluish-white transition metal with a filled 3d shell and chemistry dominated by the +2 oxidation state. It is an essential trace element for living organisms and an important industrial metal, especially for corrosion protection of steel. In minerals it occurs chiefly as sulfide and carbonate ores, and in technology it is valued for sacrificial galvanic behavior, alloy formation, and stable, often colorless Zn²⁺ compounds.
Zinc is a bluish-white, lustrous metal. It is brittle at ordinary temperatures but malleable at 100 to 150°C. It is a fair conductor of electricity, and burns in air at high red heat with evolution of white clouds of the oxide.
It exhibits superplasticity. Neither zinc nor zirconium is ferromagnetic; but ZrZn2 exhibits ferromagnetism at temperatures below 35°K. It has unusual electrical, thermal, optical, and solid-state properties that have not been fully investigated.
The name derives from the German zink of unknown origin. It was first used in prehistoric times, where its compounds were used for healing wounds and sore eyes and for making brass. Zinc was recognized as a metal as early as 1374.
Although zinc compounds have been used for at least 2,500 years in the production of brass, zinc wasn't recognized as a distinct element until much later. Metallic zinc was first produced in India sometime in the 1400s by heating the mineral calamine (ZnCO3) with wool. Zinc was rediscovered by Andreas Sigismund Marggraf in 1746 by heating calamine with charcoal. Today, most zinc is produced through the electrolysis of aqueous zinc sulfate (ZnSO4).
From the German word Zink, of obscure origin. Centuries before zinc was recognized as a distinct element, zinc ores were used for making brass. An alloy containing 87 percent zinc has been found in prehistoric ruins in Transylvania.
Metallic zinc was produced in the 13th century A.D. India by reducing calamine with organic substances such as wool. The metal was rediscovered in Europe by Marggraf in 1746. He demonstrated that zinc could be obtained by reducing calamine with charcoal.
Pure zinc is a lustrous bluish-white metal when freshly cut, but it dulls in air as a thin protective surface film forms. It is brittle near room temperature in coarse cast form, becomes more workable when warmed, and melts at a comparatively low temperature for a structural metal.
The largest use of zinc is galvanizing, where a zinc coating protects iron and steel by forming a barrier and by acting as a sacrificial anode. Zinc is also used in brass and other alloys, die-cast components, roofing sheet, and anodes for batteries. Zinc oxide is used in rubber, ceramics, pigments, sunscreens, and topical preparations. Zinc is essential in nutrition, but supplemental or medicinal uses depend on specific compounds and doses rather than the metal itself.
Roughly one third of all metallic zinc produced today is used in a process known as galvanization. During galvanization, an object that is subject to corrosion, such as an iron nail, is given a protective coating of zinc. The zinc can be applied to an object by dipping it in a pool of molten zinc, but it is most often applied through an electroplating process. Sacrificial zinc anodes are used in cathodic protection systems to protect exposed iron from corrosion. Metallic zinc is also used to make dry cell batteries, roof cladding and die castings.
Zinc is used to make many useful alloys. Brass, an alloy of zinc that contains between 55% and 95% copper, is probably the best known zinc alloy. Brass was first used about 2,500 years ago and was widely used by the ancient Romans, who used it to make such things as coins, kettles and decorative items. Brass is still used today, particularly in musical instruments, screws and other hardware that must resist corrosion. Zinc is alloyed with lead and tin to make solder, a metal with a relatively low melting point used to join electrical components, pipes and other metallic items. Prestal®, an alloy containing 78% zinc and 22% aluminum, is a strange material that is nearly as strong as steel but is molded as easily as plastic. Nickel silver, typewriter metal, spring brass and German silver are other common zinc alloys.
Zinc oxide (ZnO), a common zinc compound, forms when metallic zinc is exposed to the air and forms a protective coating that protects the rest of the metal. Zinc oxide is used in paints, some rubber products, cosmetics, pharmaceuticals, plastics, printing inks, soap and batteries, among other things. Zinc sulfide (ZnS), another zinc compound, glows when it is exposed to ultraviolet light, X-rays or electrons and is used to make luminous watch dials, television screens and fluorescent light bulbs. Zinc chloride (ZnCl2) is another zinc compound that is used to protect wood from decay and insects.
The metal is employed to form numerous alloys with other metals. Brass, nickel silver, typewriter metal, commercial bronze, spring bronze, German silver, soft solder, and aluminum solder are some of the more important alloys.
Large quantities of zinc are used to produce die castings, which are used extensively by the automotive, electrical, and hardware industries. An alloy called Prestal(R), consisting of 78 percent zinc and 22 percent aluminum, is reported to be almost as strong as steel and as easy to mold as plastic. The alloy said to be so moldable that it can be molded into form using inexpensive ceramics or cement die casts.
Zinc is also used extensively to galvanize other metals such as iron to prevent corrosion. Zinc oxide is a unique and very useful material for modern civilization. It is widely used in the manufacture of paints, rubber products, cosmetics, pharmaceuticals, floor coverings, plastics, printing inks, soap, storage batteries, textiles, electrical equipment, and other products. Lithopone, a mixture of zinc sulfide and barium sulfate, is an important pigment.
Zinc sulfide is used in making luminous dials, X-ray and TV screens, and fluorescent lights.
The chloride and chromate are also important compounds. Zinc is an essential element in the growth of human beings and animals. Tests show that zinc-deficient animals require 50 percent more food to gain the same weight as an animal supplied with sufficient zinc.
Isotopes in Earth/Planetary Science
Molecules, atoms, and ions of the stable isotopes of zinc possess slightly different physical and chemical properties, and they commonly will be fractionated during physical, chemical, and biological processes, giving rise to variations in isotopic abundances and in atomic weights. There are measureable variations in the isotopic abundances of zinc in natural terrestrial materials (Fig. IUPAC.30.1). Stable zinc isotopes have been used as tracers to investigate biogeochemical and chemical processes in environmental contamination sites [243] M. Bigalke, S. Weyer, J. Kobza, W. Wilcke. Geochim. Cosmochim. Acta74, 6801 (2010).. The isotope-amount ratio n(66Zn)/n(64Zn) can be used as an environmental tracer for detecting the pathways of anthropogenic zinc [244] Y. Sivry, J. Riotte, J. E. Sonke, S. Audry, J. Schafer, J. Viers, G. Blanc, R. Freydier, B. Dupre. Chem. Geol.255, 295 (2008)., [245] C. Cloquet, J. Carignan, G. Libourel. Environ. Sci. Technol.40, 6594 (2006)., [246] J. Chen, J. Gaillardet, P. Louvat. Environ. Sci. Technol.42, 6494 (2008)..
Isotopes in Medicine
Oral tracers of enriched 67Zn and intravenously injected stable isotopic tracers with enriched 70Zn are used simultaneously to determine the fraction of dietary zinc absorbed in humans, maintaining the amount or concentration of a nutrient or biomolecule in organs and body fluids. For example, zinc-isotope tracers can be administered to humans to determine if zinc absorption in their bodies may be impaired by ingestion of certain foods, food components, or dietary supplements. One such study conducted with Peruvian women showed that prenatal iron supplements affected the absorption of zinc during pregnancy. Another isotope tracer study investigated zinc deficiency in children with Crohn’s disease (an inflammatory disease of the intestines, especially the colon and ileum) [249] K. O’Brien, N. Zavaleta, L. Caulfield, J. Wen, S. Abrams. J. Nutr.130, 2251 (2000)., [250] I. J. Griffin, S. C. Kim, P. D. Hicks, L. K. Liang, S. A. Abrams. Pediatr. Res.56, 235 (2004).. Zinc radioisotopes (e.g. 65Zn, with a half-life of 244 days) can also be used for determining zinc absorption in humans, but they are now used rarely because of radiation hazards [251] K. B. Payton, P. R. Flanagan, E. A. Stinson, D. P. Chodirker, M. J. Chamberlain, L. S. Valberg. Gastroenterology83, 1264 (1982)., [252] N. M. Lowe, L. R. Woodhouse, J. S. Matel, J. C. King. Am. J. Clin. Nutr.71, 523 (2000).. ZnO nanoparticles enriched with 67Zn have been used as biological/environmental nanotoxicity tracers [253] A. D. Dybowska, M. N. Croteau, S. K. Misra, D. Berhanu, S. N. Luoma, P. Christian, P. O’Brien, E. Valsami-Jones. Environ. Pollut.159, 266 (2011)..
Isotopes Used as a Source of Radioactive Isotope(s)
The 68Zn (p, 2p) 67Cu (with a half-life of 62 h) reaction in which targets with zinc enriched in 68Zn are irradiated and the neutron induced reaction 67Zn (n, p) 67Cu are both processes for producing 67Cu for radiotherapy [254] T. Katabuchi, S. Watanabe, N. S. Ishioka, Y. Iida, H. Hanaoka, K. Endo, S. Matsuhashi. J. Radioanal. Nucl. Chem.277, 467 (2008).. Irradiation of 64Zn with a deuteron (the nucleus of 2H, consisting of a proton and a neutron) in a cyclotron will produce the radioisotope 64Cu (with a half-life of 12.7 h), which can be used for therapeutic applications and diagnosis with positron emission tomography (PET) via the 64Zn (d, 2p) 64Cu reaction [255] K. Abbas, J. Kozempel, M. Bonardi, F. Groppi, A. Alfarano, U. Holzwarth, F. Simonelli, H. Hofman, W. Horstmann, E. Menapace, L. Leseticky, N. Gibson. Appl. Radiat. Isot.64, 1001 (2006)..
Zinc chemistry is mainly Zn²⁺, with little stable redox chemistry in water because the d¹⁰ ion is not easily oxidized or reduced under ordinary conditions. Important compounds include zinc oxide, ZnO, a white amphoteric oxide; zinc sulfide, ZnS, a major ore mineral and phosphor host; zinc sulfate, ZnSO₄, used in industry and agriculture; and zinc chloride, ZnCl₂, a hygroscopic Lewis-acidic salt. Zinc also forms many coordination complexes, and organozinc reagents are useful in synthetic chemistry.
See more information at the Zinc compound page.
Zinc is nutritionally essential, but excessive intake of soluble zinc salts can cause toxicity and can interfere with copper metabolism. Fumes from freshly formed zinc oxide, ZnO, produced during welding or cutting galvanized metal, can cause metal fume fever. Zinc dust is combustible under suitable conditions, and some soluble or strongly acidic zinc compounds are irritants or environmentally hazardous at elevated concentrations. The stable isotopes are not radioactive hazards.
Zinc is not considered to be toxic, but when freshly formed ZnO is inhaled a disorder known as oxide shakes or zinc chills sometimes occurs. Where zinc oxide is encountered, recommendations include providing good ventilation to avoid concentration exceeding 5 mg/m3, (time-weighted over an 8-hour exposure, 40-hour work week).
Zinc is naturally released by rock weathering, volcanic emissions, and biological cycling, and it is also mobilized by mining, smelting, tire wear, galvanized materials, and waste streams. In soils and waters it partitions among dissolved Zn²⁺, mineral surfaces, organic matter, sulfides, and carbonates, so pH and redox conditions strongly affect mobility. It is an essential micronutrient, but elevated bioavailable zinc can harm aquatic organisms and soil microbiota.
Zinc is a major base metal produced primarily from sphalerite-rich ores, commonly after concentration by flotation. Roasted concentrates are processed by electrolytic or pyrometallurgical routes, with sulfur captured largely as sulfuric acid, H₂SO₄, in modern plants. Demand is closely tied to steel galvanizing, construction, transport, die casting, brass, and batteries. Recycling is significant from brass scrap, galvanized steel dusts, and die-cast alloys, although dispersed coatings are harder to recover efficiently than bulk metal scrap.
The principal ores of zinc are sphalerite (sulfide), smithsonite (carbonate), calamine (silicate), and franklinite (zinc, manganese, iron oxide). One method of zinc extraction involves roasting its ores to form the oxide and reducing the oxide with coal or carbon, with subsequent distillation of the metal.
Zinc is less cosmically abundant than iron-group elements such as iron and nickel, but it is a normal constituent of the solar system and of many stellar spectra. Its stable isotopes are produced by several nucleosynthetic pathways in massive stars and supernova environments. In planetary materials zinc is moderately volatile, so its abundance can record thermal processing during planet formation and impact history.
- Zinc coatings can protect exposed scratches because zinc corrodes preferentially to iron.
- Brass, a copper-zinc alloy, was made long before zinc was isolated as a pure metal in Europe.
- Zinc oxide is white, but it turns yellow when hot and becomes white again on cooling.
- Many enzymes use Zn²⁺ as a structural or catalytic center without changing its oxidation state.
- Sphalerite, the main zinc ore, can contain economically important cadmium, indium, or germanium impurities.
画像
性質
物理的性質
- 原子半径（経験値）
- 135 pm 全元素の原子半径（経験値）を比較 →
- 共有結合半径
- 122 pm 全元素の共有結合半径を比較 →
- ファンデルワールス半径
- 139 pm 全元素のファンデルワールス半径を比較 →
- 金属半径
- 121 pm 全元素の金属半径を比較 →
- 密度
- 7134 kg/m³ 全元素の密度を比較 →
- モル体積
- 0.0092 L/mol
- 標準温度・圧力（STP）での相
- 固体 全元素の標準温度・圧力（STP）での相を比較 →
- 融点
- 419.53 °C 全元素の融点を比較 →
- 沸点
- 906.85 °C 全元素の沸点を比較 →
- 熱伝導率
- 116 W/(m·K) 全元素の熱伝導率を比較 →
- 比熱容量
- 0.388 J/(g·K) 全元素の比熱容量を比較 →
- モル熱容量
- 25.39 J/(mol·K) 全元素のモル熱容量を比較 →
- 結晶構造
- 六方最密充填構造 全元素の結晶構造を比較 →
化学的性質
- 電気陰性度（Pauling）
- 1.65 全元素の電気陰性度（Pauling）を比較 →
- 電気陰性度（Allen）
- 1.59
- 電子親和力
- -0.6 eV (負の値—この原子は電子を取り込まないと予測される)
- 第1イオン化エネルギー
- 9.394197 eV 全元素の第1イオン化エネルギーを比較 →
- 第2イオン化エネルギー
- 17.964452 eV 全元素の第2イオン化エネルギーを比較 →
- 第3イオン化エネルギー
- 39.723437 eV 全元素の第3イオン化エネルギーを比較 →
- 第4イオン化エネルギー
- 59.573205 eV 全元素の第4イオン化エネルギーを比較 →
- 第5イオン化エネルギー
- 82.600284 eV 全元素の第5イオン化エネルギーを比較 →
- 酸化数
- −2, 0, +1, +2 全元素の酸化数を比較 →
- 価電子
- 12 全元素の価電子を比較 →
- 電子配置
- [Ar] 4s2 3d10
熱力学的性質
- 融解熱
- 0.07617764 eV 全元素の融解熱を比較 →
- 蒸発熱
- 1.195004 eV 全元素の蒸発熱を比較 →
- 昇華熱
- 1.351505 eV
- 原子化熱
- 1.351505 eV
- 原子化エンタルピー
- 1.351505 eV
原子核
- 陽子数
- 30 全元素の陽子数を比較 →
- 中性子数
- 36 全元素の中性子数を比較 →
- 既知の同位体
- 33 全元素の既知の同位体を比較 →
- 安定同位体
- 3 全元素の安定同位体を比較 →
- 最も安定な同位体
- Zn-66
- 発見年
- 1746
存在度
- 存在度（地殻）
- 70 mg/kg 全元素の存在度（地殻）を比較 →
- 存在度（海洋）
- 0.005 mg/L 全元素の存在度（海洋）を比較 →
結晶構造
- 格子定数a
- 266 pm
電子構造
- 各電子殻の電子数
- 2, 8, 18, 2 全元素の各電子殻の電子数を比較 →
識別子
- CAS登録番号
- 7440-66-6 全元素のCAS登録番号を比較 →
- 項記号
- 1S0
- InChI
- InChI=1S/Zn
- InChI Key
- HCHKCACWOHOZIP-UHFFFAOYSA-N
電子配置 測定値
Zn: 3d¹⁰ 4s²[Ar] 3d¹⁰ 4s²1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s²原子モデル
同位体によって中性子数、質量、安定性は変わりますが、中性原子の電子配置は変わりません。
模式的な原子モデルです。実際の縮尺とは異なります。
原子の指紋
発光／吸収スペクトル
同位体分布
| 質量数 | 原子質量（u） | 天然存在比 | 半減期 |
|---|---|---|---|
| 66 安定 | 65.92603381 ± 0.00000094 | 27.7300% | 安定 |
| 67 安定 | 66.92712775 ± 0.00000096 | 4.0400% | 安定 |
| 68 安定 | 67.92484455 ± 0.00000098 | 18.4500% | 安定 |
相／状態
理由: 融点（419.53 °C）より394.5 °C低い
模式図、実際の縮尺とは異なります
相転移点
相転移エネルギー
融点で1 molを融解させるのに必要なエネルギー
沸点で1 molを蒸発させるのに必要なエネルギー
昇華点で1 molを昇華させるのに必要なエネルギー
密度
標準条件下
標準条件下
原子スペクトル
全30件中10件を表示しています。 イオンの電荷の昇順で並べています。
スペクトル線データの収録状況 ?
| イオン | 電荷 | スペクトル線の総数 | 遷移確率 | 準位の表記 |
|---|---|---|---|---|
| Zn I | 0 | 570 | 16 | 564 |
| Zn II | +1 | 96 | 22 | 90 |
| Zn III | +2 | 39 | 0 | 0 |
| Zn IV | +3 | 119 | 0 | 0 |
準位データの収録状況 ?
| イオン | 電荷 | 準位 |
|---|---|---|
| Zn I | 0 | 380 |
| Zn II | +1 | 94 |
| Zn III | +2 | 316 |
| Zn IV | +3 | 245 |
| Zn V | +4 | 158 |
| Zn VI | +5 | 193 |
| Zn VII | +6 | 134 |
| Zn VIII | +7 | 5 |
| Zn IX | +8 | 2 |
| Zn X | +9 | 2 |
イオン半径
| 電荷 | 配位 | スピン | 半径 |
|---|---|---|---|
| +2 | 4 | データなし | 60 pm |
| +2 | 5 | データなし | 68 pm |
| +2 | 6 | データなし | 74 pm |
| +2 | 8 | データなし | 90 pm |
化合物
同位体 (3)
Naturally occurring zinc contains five stable isotopes. Sixteen other unstable isotopes are recognized.
| 質量数 | 原子質量（u） | 天然存在比 | 半減期 | 崩壊形式 | |
|---|---|---|---|---|---|
| 66 安定 | 65.92603381 ± 0.00000094 | 27.7300% ± 0.9800% | 安定 | stable | |
| 67 安定 | 66.92712775 ± 0.00000096 | 4.0400% ± 0.1600% | 安定 | stable | |
| 68 安定 | 67.92484455 ± 0.00000098 | 18.4500% ± 0.6300% | 安定 | stable |
スペクトル線
| 波長（nm） | 強度 | 電離段階 | 種類 | 遷移 | 精度 | 出典 | |
|---|---|---|---|---|---|---|---|
| 387.9141 nm | データなし | Zn I | emission | 3d10.4s.4p 1P* → 3d10.4s.7d 1D | 測定値 | NIST | |
| 396.543 nm | 78000 | Zn I | emission | 3d10.4s.4p 1P* → 3d10.4s.8s 1S | 測定値 | NIST | |
| 411.31114 nm | 81000 | Zn I | emission | 3d10.4s.4p 1P* → 3d10.4s.6d 1D | 測定値 | NIST | |
| 429.2883 nm | 32000 | Zn I | emission | 3d10.4s.4p 3P* → 3d10.4s.5s 1S | 測定値 | NIST | |
| 429.8325 nm | 49000 | Zn I | emission | 3d10.4s.4p 1P* → 3d10.4s.7s 1S | 測定値 | NIST | |
| 455.326 nm | データなし | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.30p 1P* | 測定値 | NIST | |
| 455.548 nm | データなし | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.29p 1P* | 測定値 | NIST | |
| 455.795 nm | データなし | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.28p 1P* | 測定値 | NIST | |
| 456.073 nm | データなし | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.27p 1P* | 測定値 | NIST | |
| 456.388 nm | データなし | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.26p 1P* | 測定値 | NIST | |
| 456.745 nm | データなし | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.25p 1P* | 測定値 | NIST | |
| 457.155 nm | データなし | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.24p 1P* | 測定値 | NIST | |
| 457.623 nm | データなし | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.23p 1P* | 測定値 | NIST | |
| 458.167 nm | データなし | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.22p 1P* | 測定値 | NIST | |
| 458.796 nm | データなし | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.21p 1P* | 測定値 | NIST | |
| 459.541 nm | データなし | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.20p 1P* | 測定値 | NIST | |
| 460.423 nm | データなし | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.19p 1P* | 測定値 | NIST | |
| 461.482 nm | データなし | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.18p 1P* | 測定値 | NIST | |
| 462.768 nm | データなし | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.17p 1P* | 測定値 | NIST | |
| 462.980809 nm | 390000 | Zn I | emission | 3d10.4s.4p 1P* → 3d10.4s.5d 1D | 測定値 | NIST | |
| 464.351 nm | データなし | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.16p 1P* | 測定値 | NIST | |
| 466.559 nm | データなし | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.15p 3P* | 測定値 | NIST | |
| 468.013589 nm | 540000 | Zn I | emission | 3d10.4s.4p 3P* → 3d10.4s.5s 3S | 測定値 | NIST | |
| 469.143 nm | データなし | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.14p 3P* | 測定値 | NIST | |
| 472.215691 nm | 1000000 | Zn I | emission | 3d10.4s.4p 3P* → 3d10.4s.5s 3S | 測定値 | NIST | |
| 472.527 nm | データなし | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.13p 3P* | 測定値 | NIST | |
| 477.071 nm | データなし | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.12p 3P* | 測定値 | NIST | |
| 481.053206 nm | 1100000 | Zn I | emission | 3d10.4s.4p 3P* → 3d10.4s.5s 3S | 測定値 | NIST | |
| 506.866 nm | 77000 | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.9p 3P* | 測定値 | NIST | |
| 506.943 nm | 21000 | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.9p 3P* | 測定値 | NIST | |
| 506.998 nm | 3300 | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.9p 3P* | 測定値 | NIST | |
| 518.19819 nm | 120000 | Zn I | emission | 3d10.4s.4p 1P* → 3d10.4s.6s 1S | 測定値 | NIST | |
| 530.866 nm | 380000 | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.8p 3P* | 測定値 | NIST | |
| 531.017 nm | 160000 | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.8p 3P* | 測定値 | NIST | |
| 531.101 nm | 56000 | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.8p 3P* | 測定値 | NIST | |
| 577.205 nm | 490000 | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.7p 3P* | 測定値 | NIST | |
| 577.5452 nm | 210000 | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.7p 3P* | 測定値 | NIST | |
| 577.7033 nm | 85000 | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.7p 3P* | 測定値 | NIST | |
| 623.78967 nm | 93000 | Zn I | emission | 3d10.4s.4p 1P* → 3d10.4s.4d 3D | 測定値 | NIST | |
| 623.9169 nm | 38000 | Zn I | emission | 3d10.4s.4p 1P* → 3d10.4s.4d 3D | 測定値 | NIST | |
| 636.23458 nm | 240000 | Zn I | emission | 3d10.4s.4p 1P* → 3d10.4s.4d 1D | 測定値 | NIST | |
| 647.9184 nm | 55000 | Zn I | emission | 3d10.4s.5s 1S → 3d10.4s.7p 1P* | 測定値 | NIST | |
| 692.8295 nm | 40000 | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.6p 3P* | 測定値 | NIST | |
| 693.8449 nm | 20000 | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.6p 3P* | 測定値 | NIST | |
| 694.3184 nm | 7000 | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.6p 3P* | 測定値 | NIST |
詳細な性質
共有結合半径（詳細）
- 共有結合半径（Pyykkö）
- 118 pm
- 共有結合半径（Pyykkö、二重結合）
- 120 pm
- 共有結合半径（Bragg）
- 132 pm
ファンデルワールス半径
- Batsanov
- 210 pm
- Alvarez
- 239 pm
- UFF
- 276.3 pm
- MM3
- 229 pm
原子半径と金属半径
- 原子半径（Rahm）
- 222 pm
- 金属半径（C12）
- 134 pm
番号付けの尺度
- Mendeleev
- 77
- Pettifor
- 76
- Glawe
- 74
電気陰性度の尺度
- Ghosh
- 0
- Miedema
- 4
- Gunnarsson–Lundqvist
- 4
- Robles–Bartolotti
- 3
分極率と分散
- 双極子分極率
- 38.67 a.u.
- 双極子分極率（不確かさ）
- 0.3 a.u.
- C₆
- 284 Ha·Bohr6
- C₆ (Gould–Bučko)
- 276 Ha·Bohr6
化学親和力
- プロトン親和力
- 608.6 kJ/mol
- 気相塩基性
- 586 kJ/mol
ミーデマパラメータ
- ミーデマモル体積
- 9.17 cm3/mol
- ミーデマ電子密度
- 2
供給リスクと経済性
- 生産集中度
- 30
- 相対供給リスク
- 5
- 埋蔵量の分布
- 22
- 政治的安定性（最大生産国）
- 24
- 政治的安定性（最大埋蔵国）
- 75
相転移と同素体
| 融点 | 692.68 K |
| 沸点 | 1180.15 K |
酸化数の分類
専門参考データ
遮蔽定数 (7)
| n | 軌道 | σ |
|---|---|---|
| 1 | s | 0.6755 |
| 2 | p | 3.902 |
| 2 | s | 8.172 |
| 3 | d | 16.1217 |
| 3 | p | 14.6307 |
| 3 | s | 13.7808 |
| 4 | s | 24.0348 |
結晶半径の詳細 (4)
| 電荷 | CN | スピン | rcrystal (pm) | 由来 |
|---|---|---|---|---|
| 2 | IV | 74 | ||
| 2 | V | 82 | ||
| 2 | VI | 88 | from r^3 vs V plots, | |
| 2 | VIII | 104 | calculated, |
同位体の崩壊形式 (49)
| 同位体 | モード | 強度 |
|---|---|---|
| 54 | 2p | 87% |
| 55 | B+ | 100% |
| 55 | B+p | 91% |
| 56 | B+ | 100% |
| 56 | B+p | 88% |
| 57 | B+ | 100% |
| 57 | B+p | 87% |
| 58 | B+ | 100% |
| 58 | B+p | 0.7% |
| 59 | B+ | 100% |
X線散乱因子 (504)
| エネルギー (eV) | f₁ | f₂ |
|---|---|---|
| 10 | — | 2.21675 |
| 10.1617 | — | 2.11915 |
| 10.3261 | — | 2.02585 |
| 10.4931 | — | 1.93665 |
| 10.6628 | — | 1.85138 |
| 10.8353 | — | 1.76986 |
| 11.0106 | — | 1.69194 |
| 11.1886 | — | 1.63293 |
| 11.3696 | — | 1.57784 |
| 11.5535 | — | 1.5246 |
追加データ
Estimated Crustal Abundance
The estimated element abundance in the earth's crust.
7.0×101 milligrams per kilogram
参考文献 (1)
Estimated Oceanic Abundance
The estimated element abundance in the earth's oceans.
4.9×10-3 milligrams per liter
参考文献 (1)
Sources
Sources of this element.
The principal ores of zinc are sphalerite (sulfide), smithsonite (carbonate), calamine (silicate), and franklinite (zinc, manganese, iron oxide). One method of zinc extraction involves roasting its ores to form the oxide and reducing the oxide with coal or carbon, with subsequent distillation of the metal.
参考文献 (1)
- [6] Zinc https://periodic.lanl.gov/30.shtml
参考文献
(9)
Data deposited in or computed by PubChem
The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.
Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.
The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.
Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/
The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.
The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database
This section provides all form of data related to element Zinc.
The element property data was retrieved from publications.