Copper (Cu)
transition-metalSolid
標準原子量
63.546 u電子配置
[Ar] 4s1 3d10融点
1084.62 °C沸点
2561.85 °C密度
8933 kg/m³酸化数
−2, 0, +1, +2, +3, +4電気陰性度（Pauling）
1.9第1イオン化エネルギー
7.72638 eV発見年
データなし原子半径
135 pm詳細
Copper is a transition metal with high electrical and thermal conductivity, good ductility, and a chemistry dominated by the +1 and +2 oxidation states. It is one of the few metals found naturally in native form and has been worked since prehistory. Modern importance rests on electrical conductors, plumbing, heat exchangers, alloys, and catalytic or biological redox chemistry. Its surfaces oxidize slowly in air, often developing protective films rather than deep rusting.
Copper is reddish and takes on a bright metallic luster. It is malleable, ductile, and a good conductor of heat and electricity (second only to silver in electrical conductivity).
The name derives from the Latin cuprum for Cyprus, the island where the Romans first obtained copper. The symbol Cu also comes from the Latin cuprum. The element has been known since prehistoric times.
Archaeological evidence suggests that people have been using copper for at least 11,000 years. Relatively easy to mine and refine, people discovered methods for extracting copper from its ores at least 7,000 years ago. The Roman Empire obtained most of its copper from the island of Cyprus, which is where copper's name originated. Today, copper is primarily obtained from the ores cuprite (CuO2), tenorite (CuO), malachite (CuO3·Cu(OH)2), chalcocite (Cu2S), covellite (CuS) and bornite (Cu6FeS4). Large deposits of copper ore are located in the United States, Chile, Zambia, Zaire, Peru and Canada.
From the Latin word cuprum, from the island of Cyprus. It is believed that copper has been mined for 5,000 years.
Pure copper is a reddish-orange, lustrous metal when freshly polished. It is soft, malleable, and ductile, and it can be drawn into fine wire. In air it darkens as oxide and sulfide films form; long outdoor exposure may produce a green patina of basic copper salts.
The largest use of copper is in electrical wiring, power equipment, motors, generators, and electronics, where its conductivity and workability are central. Copper tubing and sheet are used in plumbing, roofing, heat exchangers, and refrigeration. Important alloys include brass, bronze, cupronickel, and beryllium copper, each chosen for combinations of strength, corrosion resistance, machinability, or spring properties. Copper surfaces and salts also have established antimicrobial and fungicidal applications, although soluble copper compounds require controlled use.
Used in large amounts by the electrical industry in the form of wire, copper is second only to silver in electrical conductance. Since it resists corrosion from the air, moisture and seawater, copper has been widely used in coins. Although once made nearly entirely from copper, American pennies are now made from zinc that has been coated with copper. Copper is also used to make water pipes and jewelry, as well as other items.
Pure copper is usually too soft for most uses. People first learned about 5,000 years ago that copper can be strengthened if it is mixed with other metals. The two most familiar alloys of copper are bronze and brass. Bronze, the first alloy created by people, is a mix of copper that contains as much as 25% tin. Early people used bronze to make tools, weaponry, containers and ornamental items. Brass, a mix of copper that contains between 5% and 45% zinc, was first used about 2,500 years ago. The Romans were the first to make extensive use of brass, using it to make such things as coins, kettles and ornamental objects. Today, brass is also used in some musical instruments, screws and other hardware that must resist corrosion.
Hydrated copper sulfate (CuSO4·H2O), also known as blue vitriol, is the best known copper compound. It is used as an agricultural poison, as an algicide in water purification and as a blue pigment for inks. Cuperic chloride (CuCl2), another copper compound, is used to fix dyes to fabrics. Cuprous chloride (CuCl) is a poisonous white powder that is chiefly used to absorb carbon dioxide (CO2). Copper cyanide (CuCN) is commonly used in electroplating.
The electrical industry is one of the greatest users of copper. Iron's alloys brass and bronze are very important: all American coins are copper alloys and gun metals also contain copper.
Copper has wide use as an agricultural poison and as an algaecide in water purification. Copper compounds, such as Fehling's solution, are widely used in analytical chemistry tests for sugar.
Isotopes in Earth/Planetary Science
Molecules, atoms, and ions of the stable isotopes of copper possess slightly different physical and chemical properties, and they commonly will be fractionated during physical, chemical, and biological processes, giving rise to variations in isotopic abundances and in atomic weights. There are measureable variations in the isotopic abundances of copper in natural terrestrial materials (Fig. IUPAC.29.1). 63Cu and 65Cu have been used to study copper isotope science of supergene (formed by descending solutions) copper minerals for potential use as an indicator of the paleohydraulic (ancient hydraulic) gradient, and for potential to provide a vector toward unrecognized copper source regions [236] D. Braxton, R. Mathur. Econ. Geol.106, 1447 (2011).. Copper isotope ratios of iron oxides and supergene copper sulfides in surface samples or fossil leached caps of ore deposits are being used in prospecting to rank prospects and focus on drilling areas that have the greatest potential for mature enrichment profiles [236] D. Braxton, R. Mathur. Econ. Geol.106, 1447 (2011)..
Isotopes in Forensic Science and Anthropology
The copper isotope-amount ratio n(65Cu)/n(63Cu) along with the silver isotope-amount ratio n(109Ag)/n(107Ag) and lead isotope-amount ratios n(206Pb)/n(204Pb), n(207Pb)/n(204Pb), and n(208Pb)/n(204Pb) have been used to determine the origin of European coins and the flow of goods in the historical world market. Metals from Peru and Mexico and those from European mining sites have distinct isotopic signatures that enable the origin of the metal to be determined based on the isotopic compositions of silver, copper, and lead in the coins. Silver from mines in Mexico and Peru in the 16 th century was used to mint coins but did not influence the European coin market until the 18 th century [237] A. M. Desaulty, P. Telouk, E. Albalat, F. Albarede. Proc. Natl. Acad. Sci.108, 9002 (2011)..
Isotopes in Medicine
The radiopharmaceutical 62Cu-PTSM, which contains radioactive 62Cu (with a half-life of 9.7 min), is used as a tracer in positron emission tomography (PET) to quantify myocardial perfusion (heart blood-flow measurements) [238] H. Jadvar, J. A. Parker. Clinical PET and PET/CT, Springer-Verlag London Limited, New York, NY (2005)., [239] M. Shokeen, C. J. Anderson. Acc. Chem. Res.42, 832 (2009).. The radioisotope 64Cu (with a half-life of 12.7 h) is used for PET imaging and radiotherapy to diagnose, understand, and monitor disease (Fig. IUPAC.29.2) [238] H. Jadvar, J. A. Parker. Clinical PET and PET/CT, Springer-Verlag London Limited, New York, NY (2005)., [240] C. J. Anderson, R. Ferdani. Cancer Biother Radiopharm.24 (4), 379 (2009).. The stable isotope 65Cu has been used as a tracer to study copper absorption, utilization, and excretion in humans [241] J. R. Turnlund. Sci. Total Environ.28, 385 (1983)., [242] L. J. Harvey, J. R. Dainty, W. J. Hollands, V. J. Bull, J. H. Beattie, T. I. Venelinov, J. A. Hoogewerff, I. M. Davies, S. J. Fairweather-Tait. Am. J. Clin. Nutr.81, 807 (2005)..
Copper forms two especially important ionic states: copper(I), Cu⁺, and copper(II), Cu²⁺. Copper(I) oxide, Cu₂O, is red and semiconducting, while copper(II) oxide, CuO, is black and more strongly oxidized. Copper(II) sulfate, CuSO₄, is a common laboratory and agricultural salt, usually encountered as the blue pentahydrate CuSO₄·5H₂O. Halides such as copper(I) chloride, CuCl, and copper(II) chloride, CuCl₂, show the contrast between Cu⁺ and Cu²⁺ chemistry. Complex formation with ammonia, cyanide, and organic ligands is a major part of copper chemistry.
See more information at the Copper compound page.
Copper is an essential trace element, but excessive intake or exposure can be harmful. Soluble copper salts may irritate the gastrointestinal tract and can be toxic at sufficient dose. Dusts and fumes from cutting, welding, or smelting copper-containing materials are occupational hazards, and some copper compounds are hazardous to aquatic life. Metallic copper is not highly reactive in bulk, but fine powders can present fire or dust risks under some conditions.
Copper occurs in sulfide, oxide, carbonate, and native-metal deposits, and it cycles through weathering, sediment transport, biological uptake, and mineral precipitation. In soils and waters it binds strongly to organic matter, sulfides, clays, and iron or manganese oxides, which limits mobility but can concentrate it in sediments. Copper is required by many organisms in enzymes, yet elevated dissolved copper is toxic to fish, invertebrates, algae, and microorganisms.
Copper is a major industrial metal produced chiefly from sulfide ores by mining, concentration, smelting, converting, and electrorefining, and from some oxide ores by leaching and electrowinning. Demand is tied closely to construction, electrical infrastructure, transport, industrial machinery, and electronics. Recycling is economically important because copper retains its properties after remelting and refining; scrap from wiring, plumbing, motors, and manufacturing waste is a major secondary source. Substitution by aluminium, optical fiber, plastics, or stainless steels is possible in some uses, but performance requirements often keep copper preferred.
Copper occasionally occurs natively, and is found in many minerals such as cuprite, malachite, azurite, chalcopyrite, and bornite.
Large copper ore deposits are found in the U.S., Chile, Zambia, Zaire, Peru, and Canada. The most important copper ores are the sulfides, the oxides, and carbonates. From these, copper is obtained by smelting, leaching, and by electrolysis.
Copper is less abundant in the cosmos than iron, nickel, or zinc. Its stable isotopes, ⁶³Cu and ⁶⁵Cu, are produced mainly by neutron-capture and charged-particle processes in evolved stars and supernova environments. In the Solar System it is a minor lithophile to chalcophile element, concentrating strongly into sulfide minerals during planetary differentiation and ore formation.
- Copper has only two stable isotopes, ⁶³Cu and ⁶⁵Cu.
- Its chemical symbol comes from Latin cuprum, linked to Cyprus.
- Copper is diamagnetic, despite being a transition metal.
- Very high-purity copper is used where residual elements would reduce electrical conductivity.
- The green patina on old copper roofs is not a single compound.
- Copper can catalyze oxidation reactions by cycling between Cu⁺ and Cu²⁺.
画像
性質
物理的性質
- 原子半径（経験値）
- 135 pm 全元素の原子半径（経験値）を比較 →
- 共有結合半径
- 132 pm 全元素の共有結合半径を比較 →
- ファンデルワールス半径
- 140 pm 全元素のファンデルワールス半径を比較 →
- 金属半径
- 118 pm 全元素の金属半径を比較 →
- 密度
- 8933 kg/m³ 全元素の密度を比較 →
- モル体積
- 0.0071 L/mol
- 標準温度・圧力（STP）での相
- 固体 全元素の標準温度・圧力（STP）での相を比較 →
- 融点
- 1084.62 °C 全元素の融点を比較 →
- 沸点
- 2561.85 °C 全元素の沸点を比較 →
- 熱伝導率
- 401 W/(m·K) 全元素の熱伝導率を比較 →
- 比熱容量
- 0.385 J/(g·K) 全元素の比熱容量を比較 →
- モル熱容量
- 24.44 J/(mol·K) 全元素のモル熱容量を比較 →
- 結晶構造
- 面心立方構造 全元素の結晶構造を比較 →
化学的性質
- 電気陰性度（Pauling）
- 1.9 全元素の電気陰性度（Pauling）を比較 →
- 電気陰性度（Allen）
- 1.85
- 電子親和力
- 1.235 eV
- 第1イオン化エネルギー
- 7.72638 eV 全元素の第1イオン化エネルギーを比較 →
- 第2イオン化エネルギー
- 20.29246 eV 全元素の第2イオン化エネルギーを比較 →
- 第3イオン化エネルギー
- 36.841127 eV 全元素の第3イオン化エネルギーを比較 →
- 第4イオン化エネルギー
- 57.380198 eV 全元素の第4イオン化エネルギーを比較 →
- 第5イオン化エネルギー
- 79.800275 eV 全元素の第5イオン化エネルギーを比較 →
- 酸化数
- −2, 0, +1, +2, +3, +4 全元素の酸化数を比較 →
- 価電子
- 11 全元素の価電子を比較 →
- 電子配置
- [Ar] 4s1 3d10
熱力学的性質
- 融解熱
- 0.13743069 eV 全元素の融解熱を比較 →
- 蒸発熱
- 3.113437 eV 全元素の蒸発熱を比較 →
- 昇華熱
- 3.496917 eV
- 原子化熱
- 3.496917 eV
- 原子化エンタルピー
- 3.496917 eV
原子核
- 陽子数
- 29 全元素の陽子数を比較 →
- 中性子数
- 34 全元素の中性子数を比較 →
- 既知の同位体
- 33 全元素の既知の同位体を比較 →
- 安定同位体
- 2 全元素の安定同位体を比較 →
- 最も安定な同位体
- Cu-63
存在度
- 存在度（地殻）
- 60 mg/kg 全元素の存在度（地殻）を比較 →
- 存在度（海洋）
- 2.5 × 10−4 mg/L 全元素の存在度（海洋）を比較 →
結晶構造
- 格子定数a
- 361 pm
電子構造
- 各電子殻の電子数
- 2, 8, 18, 1 全元素の各電子殻の電子数を比較 →
識別子
- CAS登録番号
- 7440-50-8 全元素のCAS登録番号を比較 →
- 項記号
- 2S1/2
- InChI
- InChI=1S/Cu
- InChI Key
- RYGMFSIKBFXOCR-UHFFFAOYSA-N
電子配置 測定値
Cu: 3d¹⁰ 4s¹[Ar] 3d¹⁰ 4s¹1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s¹原子モデル
同位体によって中性子数、質量、安定性は変わりますが、中性原子の電子配置は変わりません。
模式的な原子モデルです。実際の縮尺とは異なります。
原子の指紋
発光／吸収スペクトル
同位体分布
| 質量数 | 原子質量（u） | 天然存在比 | 半減期 |
|---|---|---|---|
| 63 安定 | 62.92959772 ± 0.00000056 | 69.1500% | 安定 |
| 65 安定 | 64.9277897 ± 0.00000071 | 30.8500% | 安定 |
相／状態
理由: 融点（1084.62 °C）より1059.6 °C低い
模式図、実際の縮尺とは異なります
相転移点
相転移エネルギー
融点で1 molを融解させるのに必要なエネルギー
沸点で1 molを蒸発させるのに必要なエネルギー
昇華点で1 molを昇華させるのに必要なエネルギー
密度
標準条件下
標準条件下
原子スペクトル
全29件中10件を表示しています。 イオンの電荷の昇順で並べています。
スペクトル線データの収録状況 ?
| イオン | 電荷 | スペクトル線の総数 | 遷移確率 | 準位の表記 |
|---|---|---|---|---|
| Cu I | 0 | 1003 | 37 | 1003 |
| Cu II | +1 | 2557 | 554 | 2557 |
| Cu III | +2 | 100 | 0 | 0 |
| Cu IV | +3 | 60 | 0 | 0 |
| Cu V | +4 | 50 | 0 | 0 |
| Cu X | +9 | 28 | 0 | 28 |
準位データの収録状況 ?
| イオン | 電荷 | 準位 |
|---|---|---|
| Cu I | 0 | 365 |
| Cu II | +1 | 468 |
| Cu III | +2 | 390 |
| Cu IV | +3 | 298 |
| Cu V | +4 | 249 |
| Cu VI | +5 | 255 |
| Cu VII | +6 | 5 |
| Cu VIII | +7 | 2 |
| Cu IX | +8 | 2 |
| Cu X | +9 | 31 |
イオン半径
| 電荷 | 配位 | スピン | 半径 |
|---|---|---|---|
| +1 | 2 | データなし | 46 pm |
| +1 | 4 | データなし | 60 pm |
| +1 | 6 | データなし | 77 pm |
| +2 | 4 | データなし | 56.99999999999999 pm |
| +2 | 4 | データなし | 56.99999999999999 pm |
| +2 | 5 | データなし | 65 pm |
| +2 | 6 | データなし | 73 pm |
| +3 | 6 | low | 54 pm |
化合物
同位体 (2)
| 質量数 | 原子質量（u） | 天然存在比 | 半減期 | 崩壊形式 | |
|---|---|---|---|---|---|
| 63 安定 | 62.92959772 ± 0.00000056 | 69.1500% ± 0.1500% | 安定 | stable | |
| 65 安定 | 64.9277897 ± 0.00000071 | 30.8500% ± 0.1500% | 安定 | stable |
スペクトル線
全1058件中50件を表示しています。 初期設定では、強度の測定値があるスペクトル線のみを表示します。
| 波長（nm） | 強度 | 電離段階 | 種類 | 遷移 | 精度 | 出典 | |
|---|---|---|---|---|---|---|---|
| 490.973351 nm | 160000 | Cu II | emission | 3d9.(2D<5/2>).4d 2[9/2] → 3d9.(2D<5/2>).4f 2[11/2]* | 測定値 | NIST | |
| 493.16981 nm | 140000 | Cu II | emission | 3d9.(2D<5/2>).4d 2[9/2] → 3d9.(2D<5/2>).4f 2[11/2]* | 測定値 | NIST | |
| 505.179209 nm | 120000 | Cu II | emission | 3d9.(2D<5/2>).4d 2[7/2] → 3d9.(2D<5/2>).4f 2[9/2]* | 測定値 | NIST | |
| 495.37246 nm | 82000 | Cu II | emission | 3d9.(2D<3/2>).4d 2[7/2] → 3d9.(2D<3/2>).4f 2[9/2]* | 測定値 | NIST | |
| 498.550498 nm | 70000 | Cu II | emission | 3d9.(2D<5/2>).4d 2[5/2] → 3d9.(2D<5/2>).4f 2[7/2]* | 測定値 | NIST | |
| 506.545861 nm | 70000 | Cu II | emission | 3d9.(2D<3/2>).4d 2[5/2] → 3d9.(2D<3/2>).4f 2[7/2]* | 測定値 | NIST | |
| 508.827603 nm | 57000 | Cu II | emission | 3d9.(2D<5/2>).4d 2[5/2] → 3d9.(2D<5/2>).4f 2[5/2]* | 測定値 | NIST | |
| 740.43532 nm | 55000 | Cu II | emission | 3d9.(2D<5/2>).5p 2[3/2]* → 3d9.(2D<5/2>).6s 2[5/2] | 測定値 | NIST | |
| 491.83778 nm | 54000 | Cu II | emission | 3d9.(2D<3/2>).4d 2[7/2] → 3d9.(2D<3/2>).4f 2[9/2]* | 測定値 | NIST | |
| 505.890923 nm | 48000 | Cu II | emission | 3d9.(2D<5/2>).4d 2[7/2] → 3d9.(2D<5/2>).4f 2[7/2]* | 測定値 | NIST | |
| 627.334763 nm | 47000 | Cu II | emission | 3d9.(2D<5/2>).5p 2[7/2]* → 3d9.(2D<5/2>).5d 2[9/2] | 測定値 | NIST | |
| 500.679978 nm | 46000 | Cu II | emission | 3d9.(2D<3/2>).4d 2[3/2] → 3d9.(2D<3/2>).4f 2[5/2]* | 測定値 | NIST | |
| 506.709423 nm | 46000 | Cu II | emission | 3d9.(2D<3/2>).4d 2[5/2] → 3d9.(2D<3/2>).4f 2[7/2]* | 測定値 | NIST | |
| 509.381536 nm | 41000 | Cu II | emission | 3d9.(2D<5/2>).4d 2[5/2] → 3d9.(2D<5/2>).4f 2[5/2]* | 測定値 | NIST | |
| 621.69385 nm | 39000 | Cu II | emission | 3d9.(2D<5/2>).5p 2[7/2]* → 3d9.(2D<5/2>).5d 2[9/2] | 測定値 | NIST | |
| 600.01168 nm | 38000 | Cu II | emission | 3d9.(2D<5/2>).5p 2[3/2]* → 3d9.(2D<5/2>).5d 2[3/2] | 測定値 | NIST | |
| 501.26199 nm | 37000 | Cu II | emission | 3d9.(2D<5/2>).4d 2[7/2] → 3d9.(2D<5/2>).4f 2[9/2]* | 測定値 | NIST | |
| 468.19935 nm | 36000 | Cu II | emission | 3d9.(2D<5/2>).4d 2[1/2] → 3d9.(2D<5/2>).4f 2[1/2]* | 測定値 | NIST | |
| 481.29474 nm | 36000 | Cu II | emission | 3d9.(2D<3/2>).4d 2[1/2] → 3d9.(2D<3/2>).4f 2[3/2]* | 測定値 | NIST | |
| 500.985058 nm | 35000 | Cu II | emission | 3d9.(2D<5/2>).4d 2[5/2] → 3d9.(2D<5/2>).4f 2[5/2]* | 測定値 | NIST | |
| 485.498743 nm | 34000 | Cu II | emission | 3d9.(2D<5/2>).4d 2[9/2] → 3d9.(2D<5/2>).4f 2[9/2]* | 測定値 | NIST | |
| 502.127849 nm | 32000 | Cu II | emission | 3d9.(2D<5/2>).4d 2[5/2] → 3d9.(2D<5/2>).4f 2[7/2]* | 測定値 | NIST | |
| 507.230253 nm | 32000 | Cu II | emission | 3d9.(2D<5/2>).4d 2[7/2] → 3d9.(2D<5/2>).4f 2[5/2]* | 測定値 | NIST | |
| 594.11951 nm | 31000 | Cu II | emission | 3d9.(2D<5/2>).5p 2[3/2]* → 3d9.(2D<5/2>).5d 2[5/2] | 測定値 | NIST | |
| 512.44753 nm | 30000 | Cu II | emission | 3d9.(2D<5/2>).4d 2[7/2] → 3d8.(3F).4s.4p.(1P*) 3G* | 測定値 | NIST | |
| 467.170176 nm | 29000 | Cu II | emission | 3d9.(2D<5/2>).4d 2[1/2] → 3d9.(2D<5/2>).4f 2[3/2]* | 測定値 | NIST | |
| 491.291987 nm | 29000 | Cu II | emission | 3d9.(2D<5/2>).4d 2[3/2] → 3d9.(2D<5/2>).4f 2[5/2]* | 測定値 | NIST | |
| 520.7134 nm | 29000 | Cu II | emission | 3d9.(2D<3/2>).4d 2[7/2] → 3d8.(1G).4s.4p.(3P*) 3H* | 測定値 | NIST | |
| 493.155505 nm | 28000 | Cu II | emission | 3d9.(2D<5/2>).4d 2[3/2] → 3d9.(2D<5/2>).4f 2[3/2]* | 測定値 | NIST | |
| 404.34858 nm | 27000 | Cu II | emission | 3d9.4p 1F* → 3d8.4s2 1G | 測定値 | NIST | |
| 504.73477 nm | 27000 | Cu II | emission | 3d9.(2D<5/2>).4d 2[7/2] → 3d9.(2D<5/2>).4f 2[7/2]* | 測定値 | NIST | |
| 630.10137 nm | 27000 | Cu II | emission | 3d9.(2D<3/2>).5p 2[5/2]* → 3d9.(2D<3/2>).5d 2[7/2] | 測定値 | NIST | |
| 490.142634 nm | 26000 | Cu II | emission | 3d9.(2D<5/2>).4d 2[3/2] → 3d9.(2D<5/2>).4f 2[5/2]* | 測定値 | NIST | |
| 492.64232 nm | 26000 | Cu II | emission | 3d9.(2D<5/2>).4d 2[3/2] → 3d9.(2D<5/2>).4f 2[3/2]* | 測定値 | NIST | |
| 493.722031 nm | 26000 | Cu II | emission | 3d9.(2D<3/2>).4d 2[3/2] → 3d9.(2D<3/2>).4f 2[5/2]* | 測定値 | NIST | |
| 508.84896 nm | 25000 | Cu II | emission | 3d9.(2D<3/2>).4d 2[5/2] → 3d9.(2D<3/2>).4f 2[5/2]* | 測定値 | NIST | |
| 615.42211 nm | 25000 | Cu II | emission | 3d9.(2D<5/2>).5p 2[3/2]* → 3d9.(2D<5/2>).5d 2[1/2] | 測定値 | NIST | |
| 621.98488 nm | 24000 | Cu II | emission | 3d9.(2D<3/2>).5p 2[5/2]* → 3d9.(2D<3/2>).5d 2[7/2] | 測定値 | NIST | |
| 526.99904 nm | 23000 | Cu II | emission | 3d9.4p 3P* → 3d8.4s2 1D | 測定値 | NIST | |
| 589.79758 nm | 23000 | Cu II | emission | 3d8.(3F).4s.4p.(3P*) 3G* → 3d9.(2D<5/2>).6s 2[5/2] | 測定値 | NIST | |
| 490.656612 nm | 21000 | Cu II | emission | 3d9.(2D<5/2>).4d 2[3/2] → 3d9.(2D<5/2>).4f 2[5/2]* | 測定値 | NIST | |
| 508.397879 nm | 21000 | Cu II | emission | 3d9.(2D<5/2>).4d 2[7/2] → 3d9.(2D<5/2>).4f 2[5/2]* | 測定値 | NIST | |
| 467.35774 nm | 20000 | Cu II | emission | 3d9.(2D<5/2>).4d 2[1/2] → 3d9.(2D<5/2>).4f 2[1/2]* | 測定値 | NIST | |
| 494.3025 nm | 20000 | Cu II | emission | 3d9.(2D<5/2>).4d 2[3/2] → 3d9.(2D<5/2>).4f 2[1/2]* | 測定値 | NIST | |
| 512.075319 nm | 20000 | Cu II | emission | 3d9.(2D<5/2>).4d 2[5/2] → 3d9.(2D<5/2>).4f 2[3/2]* | 測定値 | NIST | |
| 644.85593 nm | 20000 | Cu II | emission | 3d9.4p 3D* → 3d8.4s2 3P | 測定値 | NIST | |
| 508.89421 nm | 19000 | Cu II | emission | 3d9.(2D<3/2>).4d 2[5/2] → 3d9.(2D<3/2>).4f 2[5/2]* | 測定値 | NIST | |
| 518.33664 nm | 19000 | Cu II | emission | 3d9.(2D<5/2>).4d 2[1/2] → 3d9.(2D<5/2>).4f 2[1/2]* | 測定値 | NIST | |
| 524.53423 nm | 19000 | Cu II | emission | 3d8.(3F).4s.4p.(3P*) 3F* → 3d9.(2D<5/2>).5d 2[9/2] | 測定値 | NIST | |
| 626.18464 nm | 19000 | Cu II | emission | 3d9.(2D<5/2>).5p 2[5/2]* → 3d9.(2D<5/2>).5d 2[7/2] | 測定値 | NIST |
詳細な性質
共有結合半径（詳細）
- 共有結合半径（Pyykkö）
- 112 pm
- 共有結合半径（Pyykkö、二重結合）
- 115 pm
- 共有結合半径（Pyykkö、三重結合）
- 120 pm
- 共有結合半径（Bragg）
- 137 pm
ファンデルワールス半径
- Batsanov
- 200 pm
- Alvarez
- 238 pm
- UFF
- 349.5 pm
- MM3
- 226 pm
原子半径と金属半径
- 原子半径（Rahm）
- 217 pm
- 金属半径（C12）
- 128 pm
番号付けの尺度
- Mendeleev
- 71
- Pettifor
- 72
- Glawe
- 68
電気陰性度の尺度
- Ghosh
- 0
- Miedema
- 4
- Robles–Bartolotti
- 4
分極率と分散
- 双極子分極率
- 46.5 a.u.
- 双極子分極率（不確かさ）
- 0.5 a.u.
- C₆
- 253 Ha·Bohr6
- C₆ (Gould–Bučko)
- 264 Ha·Bohr6
化学親和力
- プロトン親和力
- 655.3 kJ/mol
- 気相塩基性
- 632.4 kJ/mol
ミーデマパラメータ
- ミーデマモル体積
- 7.12 cm3/mol
- ミーデマ電子密度
- 3
供給リスクと経済性
- 生産集中度
- 34
- 相対供給リスク
- 4
- 埋蔵量の分布
- 28
- 政治的安定性（最大生産国）
- 68
- 政治的安定性（最大埋蔵国）
- 68
相転移と同素体
| 融点 | 1357.77 K |
| 沸点 | 2833.15 K |
酸化数の分類
専門参考データ
遮蔽定数 (7)
| n | 軌道 | σ |
|---|---|---|
| 1 | s | 0.6614 |
| 2 | p | 3.903 |
| 2 | s | 7.9802 |
| 3 | d | 15.7994 |
| 3 | p | 14.2694 |
| 3 | s | 13.4057 |
| 4 | s | 23.1576 |
結晶半径の詳細 (8)
| 電荷 | CN | スピン | rcrystal (pm) | 由来 |
|---|---|---|---|---|
| 1 | II | 60 | ||
| 1 | IV | 74 | estimated, | |
| 1 | VI | 91 | estimated, | |
| 2 | IV | 71 | ||
| 2 | IVSQ | 71 | ||
| 2 | V | 79 | ||
| 2 | VI | 87 | ||
| 3 | VI | LS | 60 |
同位体の崩壊形式 (52)
| 同位体 | モード | 強度 |
|---|---|---|
| 52 | p | — |
| 53 | p | — |
| 54 | p | — |
| 55 | B+ | 100% |
| 55 | B+p | — |
| 56 | B+ | 100% |
| 56 | B+p | 0.4% |
| 57 | B+ | 100% |
| 58 | B+ | 100% |
| 59 | B+ | 100% |
X線散乱因子 (504)
| エネルギー (eV) | f₁ | f₂ |
|---|---|---|
| 10 | — | 1.30088 |
| 10.1617 | — | 1.33374 |
| 10.3261 | — | 1.36743 |
| 10.4931 | — | 1.40197 |
| 10.6628 | — | 1.43738 |
| 10.8353 | — | 1.47369 |
| 11.0106 | — | 1.51091 |
| 11.1886 | — | 1.54908 |
| 11.3696 | — | 1.58821 |
| 11.5535 | — | 1.62833 |
追加データ
Estimated Crustal Abundance
The estimated element abundance in the earth's crust.
6.0×101 milligrams per kilogram
参考文献 (1)
Estimated Oceanic Abundance
The estimated element abundance in the earth's oceans.
2.5×10-4 milligrams per liter
参考文献 (1)
Sources
Sources of this element.
Copper occasionally occurs natively, and is found in many minerals such as cuprite, malachite, azurite, chalcopyrite, and bornite.
Large copper ore deposits are found in the U.S., Chile, Zambia, Zaire, Peru, and Canada. The most important copper ores are the sulfides, the oxides, and carbonates. From these, copper is obtained by smelting, leaching, and by electrolysis.
参考文献 (1)
- [6] Copper https://periodic.lanl.gov/29.shtml
Isotopes in Forensic Science and Anthropology
Information on the use of this element's isotopes in forensic science and anthropology.
The copper isotope-amount ratio n(65Cu)/n(63Cu) along with the silver isotope-amount ratio n(109Ag)/n(107Ag) and lead isotope-amount ratios n(206Pb)/n(204Pb), n(207Pb)/n(204Pb), and n(208Pb)/n(204Pb) have been used to determine the origin of European coins and the flow of goods in the historical world market. Metals from Peru and Mexico and those from European mining sites have distinct isotopic signatures that enable the origin of the metal to be determined based on the isotopic compositions of silver, copper, and lead in the coins. Silver from mines in Mexico and Peru in the 16 th century was used to mint coins but did not influence the European coin market until the 18 th century [237] A. M. Desaulty, P. Telouk, E. Albalat, F. Albarede. Proc. Natl. Acad. Sci.108, 9002 (2011)..
参考文献 (2)
- [237] A. M. Desaulty, P. Telouk, E. Albalat, F. Albarede. Proc. Natl. Acad. Sci.108, 9002 (2011).
- [4] IUPAC Periodic Table of the Elements and Isotopes (IPTEI) https://doi.org/10.1515/pac-2015-0703
参考文献
(9)
Data deposited in or computed by PubChem
The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.
Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.
The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.
Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/
The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.
The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database
This section provides all form of data related to element Copper.
The element property data was retrieved from publications.