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Zr 40

Zirconium (Zr)

transition-metal
Periode: 5 Golongan: 4 Blok: d

Solid

Bobot Atom Standar

91,224 u

Konfigurasi elektron

[Kr] 5s2 4d2

Titik lebur

1854,85 °C

Titik didih

4408,85 °C

Massa jenis

6520 kg/m³

Bilangan oksidasi

+1, +2, +3, +4

Keelektronegatifan (Pauling)

1,33

Energi ionisasi (ke-1)

6,634126 eV

Tahun penemuan

1789

Jari-jari atom

155 pm

Detail

Asal nama From the mineral, zircon.
Negara penemuan Germany
Penemu Martin Klaproth

Zirconium is a lustrous transition metal in group 4, chemically close to hafnium and titanium. It occurs mainly in zircon and related heavy minerals, almost always with hafnium as a companion. The metal is valued for its very low thermal-neutron absorption and its stable, adherent oxide film, which give it a central role in nuclear reactor materials and in corrosion-resistant alloys.

Reactor-grade zirconium is essentially free of hafnium. Zircaloy(R) is an important alloy developed specifically for nuclear applications. Zirconium is exceptionally resistant to corrosion by many common acids and alkalis, by sea water, and by other agents. Alloyed with zinc, zirconium becomes magnetic at temperatures below 35°K.

The name derives from the Arabic zargun for "gold-like". It was discovered in zirconia by the German chemist Martin-Heinrich Klaproth in 1789. Zirconium was first isolated by Swedish chemist Jöns Jacob Berzelius in 1824 in an impure state, and finally by the chemists D. Lely, Jr. and L. Hamburger in a pure state in 1914.

Zirconium was discovered by Martin Heinrich Klaproth, a German chemist, while analyzing the composition of the mineral jargon (ZrSiO4) in 1789. Zirconium was isolated by Jöns Jacob Berzelius, a Swedish chemist, in 1824 and finally prepared in a pure form in 1914. Obtaining pure zirconium is very difficult because it is chemically similar to hafnium, an element which is always found mixed with deposits of zirconium. Today, most zirconium is obtained from the minerals zircon (ZrSiO4) and baddeleyite (ZrO2) through a process known as the Kroll Process.

From the Persian zargun, gold like. Zircon, the primary gemstone of zirconium, is also known as jargon, hyacinth, jacinth, or ligure. This mineral, or its variations, is mentioned in biblical writings. The mineral was not known to contain a new element until Klaproth, in 1789, analyzed a jargon from Ceylon and identified the new element, which Werner named zircon (silex circonius), and which Klaproth called Zirkonertz (zirconia). The impure metal was first isolated by Berzelius in 1824 by heating a mixture of potassium and potassium zirconium fluoride in a small decomposition process they developed.

Gambar

Sifat

Fisika

Jari-jari atom (empiris)
155 pm Bandingkan Jari-jari atom (empiris) semua unsur →
Jari-jari kovalen
175 pm Bandingkan Jari-jari kovalen semua unsur →
Jari-jari van der Waals
186 pm Bandingkan Jari-jari van der Waals semua unsur →
Jari-jari logam
145 pm Bandingkan Jari-jari logam semua unsur →
Massa jenis
6520 kg/m³ Bandingkan Massa jenis semua unsur →
Volume molar
0,0141 L/mol
Fase pada STP
Padat Bandingkan Fase pada STP semua unsur →
Titik lebur
1854,85 °C Bandingkan Titik lebur semua unsur →
Titik didih
4408,85 °C Bandingkan Titik didih semua unsur →
Konduktivitas termal
22,7 W/(m·K) Bandingkan Konduktivitas termal semua unsur →
Kapasitas kalor spesifik
0,278 J/(g·K) Bandingkan Kapasitas kalor spesifik semua unsur →
Kapasitas kalor molar
25,36 J/(mol·K) Bandingkan Kapasitas kalor molar semua unsur →
Struktur kristal
Heksagonal susunan rapat Bandingkan Struktur kristal semua unsur →

Kimia

Keelektronegatifan (Pauling)
1,33 Bandingkan Keelektronegatifan (Pauling) semua unsur →
Keelektronegatifan (Allen)
1,32
Afinitas elektron
0,426 eV
Energi ionisasi (ke-1)
6,634126 eV Bandingkan Energi ionisasi (ke-1) semua unsur →
Energi ionisasi (ke-2)
13,130045 eV Bandingkan Energi ionisasi (ke-2) semua unsur →
Energi ionisasi (ke-3)
23,17008 eV Bandingkan Energi ionisasi (ke-3) semua unsur →
Energi ionisasi (ke-4)
34,418478 eV Bandingkan Energi ionisasi (ke-4) semua unsur →
Energi ionisasi (ke-5)
80,348277 eV Bandingkan Energi ionisasi (ke-5) semua unsur →
Bilangan oksidasi
+1, +2, +3, +4 Bandingkan Bilangan oksidasi semua unsur →
Elektron valensi
4 Bandingkan Elektron valensi semua unsur →
Konfigurasi elektron
[Kr] 5s2 4d2

Termodinamika

Kalor peleburan
0,17515676 eV Bandingkan Kalor peleburan semua unsur →
Kalor penguapan
5,938747 eV Bandingkan Kalor penguapan semua unsur →
Kalor sublimasi
6,311862 eV
Kalor atomisasi
6,311862 eV
Entalpi atomisasi
6,322226 eV

Nuklir

Proton
40 Bandingkan Proton semua unsur →
Neutron
50 Bandingkan Neutron semua unsur →
Isotop yang diketahui
37 Bandingkan Isotop yang diketahui semua unsur →
Isotop stabil
3 Bandingkan Isotop stabil semua unsur →
Isotop paling stabil
Zr-90
Tahun penemuan
1789

Kelimpahan

Kelimpahan (kerak Bumi)
165 mg/kg Bandingkan Kelimpahan (kerak Bumi) semua unsur →
Kelimpahan (samudra)
3 × 10−5 mg/L Bandingkan Kelimpahan (samudra) semua unsur →

Struktur Kristal

Konstanta kisi a
323 pm

Struktur Elektronik

Elektron per kulit
2, 8, 18, 10, 2 Bandingkan Elektron per kulit semua unsur →

Pengenal

Nomor CAS
7440-67-7 Bandingkan Nomor CAS semua unsur →
Simbol term
3F2
InChI
InChI=1S/Zr
Kunci InChI
QCWXUUIWCKQGHC-UHFFFAOYSA-N

Konfigurasi Elektron Diukur

Muatan ion
Proton 40
Elektron 40
Muatan Netral
Konfigurasi Zr: 4d² 5s²
Konfigurasi elektron
Diukur
[Kr] 4d² 5s²
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d² 5s²
Diagram orbital
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
2/2
4d
2/10 2↑
Total elektron: 40 Tidak berpasangan: 2 ?

Model atom

Proton 40
Neutron 50
Elektron 40
Nomor massa 90
Kestabilan Stabil

Isotop mengubah jumlah neutron, massa, dan kestabilan — bukan konfigurasi elektron atom netral.

Model atom skematis, tidak sesuai skala.

Sidik Jari Atom

Spektrum Emisi / Absorpsi

25 / 51 (50 50 dengan intensitas)
Diukur
Emisi Tampak: 380–750 nm

Distribusi Isotop

9051,4500%9217,1500%9111,2200%Nomor massaKelimpahan alami (%)
Nomor massaMassa atom (u)Kelimpahan alamiWaktu paruh
90 Stabil89,9046977 ± 0,00000251,4500%Stabil
91 Stabil90,9056396 ± 0,00000211,2200%Stabil
92 Stabil91,9050347 ± 0,00000217,1500%Stabil
Diukur

Fase / Wujud

1 atm / 101.325 kPa
Padat 25 °C (298,15 K)

Alasan: 1829,8 °C di bawah titik lebur (1854,85 °C)

Titik lebur 1854,85 °C
Titik didih 4408,85 °C
Di bawah titik lebur sebesar 1829,8 °C
0 K Suhu saat ini: 25 °C 6000 K
Linimasa fase

Skematis, tidak sesuai skala

Padat
Cair
Gas
Peleburan
Pendidihan
25°C
Padat
Cair
Gas
Saat ini

Titik transisi fase

Titik lebur Literatur
1854,85 °C
Titik didih Literatur
4408,85 °C
Fase saat ini Dihitung
Padat

Energi transisi

Kalor peleburan Literatur
0,17515676 eV

Energi yang diperlukan untuk meleburkan 1 mol pada titik lebur

Kalor penguapan Literatur
5,938747 eV

Energi yang diperlukan untuk menguapkan 1 mol pada titik didih

Kalor sublimasi Literatur
6,311862 eV

Energi yang diperlukan untuk menyublimkan 1 mol pada titik sublimasi

Massa jenis

Massa jenis referensi Literatur
6520 kg/m³

Pada kondisi standar

Massa jenis saat ini Dihitung
6520 kg/m³

Pada kondisi standar

Spektrum Atom

Menampilkan 10 dari 40. Diurutkan berdasarkan muatan ion (menaik).

Data Garis Spektrum ?

IonMuatanTotal garisProbabilitas transisiPenamaan tingkat energi
Zr I 045900
Zr II +120700
Zr III +2490490490
Zr IV +376076
Zr V +410400
Zr VI +5427427427
Data Garis Spektrum NIST →

Data Tingkat Energi ?

IonMuatanTingkat energi
Zr I 0262
Zr II +1136
Zr III +2140
Zr IV +335
Zr V +4102
Zr VI +597
Zr VII +62
Zr VIII +72
Zr IX +82
Zr X +92
Data Tingkat Energi NIST →
40 Zr 91.224

Zirconium — Visualisasi Orbital Atom

[Kr]5s24d2
Tingkat energi 2 8 18 10 2
Bilangan oksidasi +1, +2, +3, +4
HOMO 4d n=4 · l=2 · m=-2
Zirconium — Pratinjau Visualisasi Orbital Atom
Three.js hanya dimuat saat diminta
40 Zr 91.224

Zirconium — Visualisasi Struktur Kristal

Heksagonal Primitif · Pearson hP2
Eksperimental
Pearson hP2
No. Koord. 12
Pengemasan 75.514%
Zirconium — Pratinjau Visualisasi Struktur Kristal
Three.js hanya dimuat saat diminta

Jari-jari Ion

MuatanKoordinasiSpinJari-jari
+44Tidak tersedia59 pm
+45Tidak tersedia66 pm
+46Tidak tersedia72 pm
+47Tidak tersedia78 pm
+48Tidak tersedia84 pm
+49Tidak tersedia89 pm

Senyawa

Zr
91,220 u
Zr+4
91,220 u
Zr
88,909 u
Zr
94,908 u
Zr
92,906 u
Zr
87,910 u
Zr
96,911 u
Zr
85,916 u
Zr
89,905 u
Zr+2
91,220 u
Zr+3
91,220 u
Zr+4
88,909 u
Zr+4
93,906 u
Zr
93,906 u
Zr+4
89,905 u
Zr
90,906 u
Zr
91,905 u
Zr
95,908 u

Isotop (3)

Naturally occurring zirconium contains five isotopes. Fifteen other isotopes are known to exist. Zircon, ZrSiO4, the principal ore, is pure ZrO2 in crystalline form having a hafnium content of about 1%. Zirconium also occurs in some 30 other recognized mineral species. Zirconium is produced commercially by reduction of chloride with magnesium (the Kroll Process), and by other methods. It is a grayish-white lustrous metal. When finely divided, the metal may ignite spontaneously in air, especially at elevated temperatures. The solid metal is much more difficult to ignite. The inherent toxicity of zirconium compounds is low. Hafnium is invariably found in zirconium ores, and the separation is difficult.

Nomor massaMassa atom (u)Kelimpahan alamiWaktu paruhMode peluruhan
90 Stabil89,9046977 ± 0,00000251,4500% ± 0,4000%Stabil
stable
91 Stabil90,9056396 ± 0,00000211,2200% ± 0,0500%Stabil
stable
92 Stabil91,9050347 ± 0,00000217,1500% ± 0,0800%Stabil
stable
90 Stabil
Massa atom (u) 89,9046977 ± 0,000002
Kelimpahan alami 51,4500% ± 0,4000%
Waktu paruh Stabil
Mode peluruhan
stable
91 Stabil
Massa atom (u) 90,9056396 ± 0,000002
Kelimpahan alami 11,2200% ± 0,0500%
Waktu paruh Stabil
Mode peluruhan
stable
92 Stabil
Massa atom (u) 91,9050347 ± 0,000002
Kelimpahan alami 17,1500% ± 0,0800%
Waktu paruh Stabil
Mode peluruhan
stable

Garis Spektrum

Panjang gelombang (nm)IntensitasTahap ionisasiJenisTransisiAkurasiSumber
382.0196 nm5Zr IIIemission4d.4f 3G* → 4d.(2D<5/2>).5g 2[7/2]DiukurNIST
382.4611 nm250Zr IIIemission4d.4f 3H* → 4d.(2D<3/2>).5g 2[9/2]DiukurNIST
382.7722 nm300Zr IIIemission4d.4f 3F* → 4d.(2D<3/2>).5g 2[7/2]DiukurNIST
382.923 nm600Zr IIIemission4d.4f 3H* → 4d.(2D<3/2>).5g 2[11/2]DiukurNIST
383.0087 nm250Zr IIIemission4d.4f 1D* → 4d.(2D<5/2>).5g 2[7/2]DiukurNIST
383.7038 nm10Zr IIIemission4d.4f 3G* → 4d.(2D<5/2>).5g 2[9/2]DiukurNIST
384.2399 nm270Zr IIIemission4d.4f 3F* → 4d.(2D<3/2>).5g 2[9/2]DiukurNIST
390.7626 nm5Zr IIIemission4d.4f 3G* → 4d.(2D<5/2>).5g 2[7/2]DiukurNIST
391.0786 nm3Zr IIIemission4d.4f 3G* → 4d.(2D<5/2>).5g 2[13/2]DiukurNIST
391.6928 nm100Zr IIIemission4d.4f 3F* → 4d.(2D<3/2>).5g 2[9/2]DiukurNIST
392.0624 nm400Zr IIIemission4d.4f 3G* → 4d.(2D<5/2>).5g 2[11/2]DiukurNIST
392.5804 nm200Zr IIIemission4d.4f 3G* → 4d.(2D<5/2>).5g 2[9/2]DiukurNIST
392.694 nm120Zr IIIemission4d.4f 3G* → 4d.(2D<5/2>).5g 2[9/2]DiukurNIST
393.1478 nm100Zr IIIemission5s.5p 3P* → 4d.5d 3SDiukurNIST
396.3178 nm500Zr IIIemission4d.4f 3G* → 4d.(2D<5/2>).5g 2[11/2]DiukurNIST
396.5231 nm10Zr IIIemission4d.4f 3G* → 4d.(2D<5/2>).5g 2[11/2]DiukurNIST
397.1691 nm200Zr IIIemission4d.4f 3G* → 4d.(2D<5/2>).5g 2[9/2]DiukurNIST
397.3984 nm220Zr IIIemission4d.4f 1D* → 4d.(2D<3/2>).5g 2[5/2]DiukurNIST
398.854 nm10Zr IIIemission4d.4f 3D* → 4d.(2D<5/2>).5g 2[5/2]DiukurNIST
401.632 nm20Zr IIIemission4d.4f 3G* → 4d.(2D<3/2>).5g 2[7/2]DiukurNIST
401.6949 nm35Zr IIIemission4d.4f 3G* → 4d.(2D<3/2>).5g 2[7/2]DiukurNIST
401.7561 nm3Zr IIIemission4d.4f 1F* → 4d.(2D<5/2>).5g 2[7/2]DiukurNIST
401.8142 nm140Zr IIIemission4d.4f 1F* → 4d.(2D<5/2>).5g 2[7/2]DiukurNIST
403.2482 nm400Zr IIIemission4d.4f 3G* → 4d.(2D<3/2>).5g 2[9/2]DiukurNIST
403.3591 nm180Zr IIIemission4d.4f 3D* → 4d.(2D<5/2>).5g 2[7/2]DiukurNIST
403.6779 nm200Zr IIIemission4d.4f 1F* → 4d.(2D<5/2>).5g 2[9/2]DiukurNIST
408.0264 nm5Zr IIIemission4d.4f 3G* → 4d.(2D<3/2>).5g 2[11/2]DiukurNIST
408.7114 nm150Zr IIIemission4d.4f 3D* → 4d.(2D<5/2>).5g 2[5/2]DiukurNIST
412.5432 nm200Zr IIIemission4d.4f 3G* → 4d.(2D<3/2>).5g 2[11/2]DiukurNIST
412.6379 nm400Zr IIIemission4d.4f 3D* → 4d.(2D<5/2>).5g 2[7/2]DiukurNIST
413.2087 nm200Zr IIIemission4d.4f 3G* → 4d.(2D<3/2>).5g 2[9/2]DiukurNIST
413.7442 nm500Zr IVemission4p6.5d 2D → 4p6.6p 2P*DiukurNIST
414.6654 nm20Zr IIIemission4d.4f 3D* → 4d.(2D<5/2>).5g 2[9/2]DiukurNIST
415.3368 nm2Zr IIIemission4d.4f 3P* → 4d.(2D<5/2>).5g 2[3/2]DiukurNIST
416.0827 nm250Zr IIIemission4d.4f 3D* → 4d.(2D<3/2>).5g 2[5/2]DiukurNIST
416.5293 nm15Zr IIIemission4d.4f 3P* → 4d.(2D<5/2>).5g 2[5/2]DiukurNIST
417.1353 nm20Zr IIIemission4d.4f 3P* → 4d.(2D<5/2>).5g 2[3/2]DiukurNIST
417.2872 nm300Zr IIIemission4d.4f 3P* → 4d.(2D<5/2>).5g 2[5/2]DiukurNIST
419.3504 nm275Zr IIIemission4d.4f 3D* → 4d.(2D<3/2>).5g 2[5/2]DiukurNIST
419.7309 nm15Zr IIIemission4d.4f 3P* → 4d.(2D<5/2>).5g 2[3/2]DiukurNIST
419.8266 nm3000Zr IVemission4p6.5d 2D → 4p6.6p 2P*DiukurNIST
420.3546 nm200Zr IIIemission4d.4f 3P* → 4d.(2D<5/2>).5g 2[5/2]DiukurNIST
423.5695 nm275Zr IIIemission4d.4f 1F* → 4d.(2D<3/2>).5g 2[7/2]DiukurNIST
431.7077 nm2000Zr IVemission4p6.5d 2D → 4p6.6p 2P*DiukurNIST
434.2686 nm400Zr IIIemission4d.4f 1H* → 4d.(2D<5/2>).5g 2[13/2]DiukurNIST
440.7385 nm20Zr IIIemission4d.4f 1H* → 4d.(2D<5/2>).5g 2[11/2]DiukurNIST
456.1637 nm50Zr IIIemission4d.4f 1P* → 4d.(2D<5/2>).5g 2[3/2]DiukurNIST
456.922 nm1800Zr IVemission4p6.5g 2G → 4p6.6h 2H*DiukurNIST
456.927 nm1800Zr IVemission4p6.5g 2G → 4p6.6h 2H*DiukurNIST
460.8973 nm60Zr IIIemission4d.4f 1H* → 4d.(2D<3/2>).5g 2[11/2]DiukurNIST
500.71 nmTidak tersediaID 803emission2p 2P* → 2s 2SDiukurNIST

Sifat Lanjutan

Jari-jari Kovalen (Lanjutan)

Jari-jari kovalen (Pyykkö)
154 pm
Jari-jari kovalen (Pyykkö, ikatan rangkap dua)
127 pm
Jari-jari kovalen (Pyykkö, ikatan rangkap tiga)
121 pm

Jari-jari van der Waals

Batsanov
230 pm
Alvarez
252 pm
UFF
312,4 pm
MM3
254 pm

Jari-jari Atom & Logam

Jari-jari atom (Rahm)
269 pm
Jari-jari logam (C12)
160 pm

Skala Penomoran

Mendeleev
44
Pettifor
49
Glawe
49

Skala Keelektronegatifan

Ghosh
0
Miedema
3
Gunnarsson–Lundqvist
5
Robles–Bartolotti
4

Polarizabilitas & Dispersi

Polarizabilitas dipol
112 a.u.
Polarizabilitas dipol (ketidakpastian)
13 a.u.
C₆ (Gould–Bučko)
1360 Ha·Bohr6

Parameter Miedema

Volume molar Miedema
14 cm3/mol
Kerapatan elektron Miedema
3

Risiko Pasokan & Ekonomi

Konsentrasi produksi
39
Risiko pasokan relatif
6
Distribusi cadangan
40
Stabilitas politik (produsen terbesar)
75
Stabilitas politik (pemilik cadangan terbesar)
75

Transisi Fase & Alotrop

Titik lebur2127,15 K
Titik didih4679,15 K

Kategori Bilangan Oksidasi

+4 main
+2 extended
+3 extended
+1 extended

Data Referensi Lanjutan

Konstanta Pemerisaian (10)
nOrbitalσ
1s0,841
2p4,0072
2s10,6262
3d14,4331
3p16,1545
3s15,6385
4d26,9284
4p26,54
4s25,0984
5s33,5545
Detail Jari-jari Kristal (6)
MuatanCNSpinrcrystal (pm)Asal
4IV73from r^3 vs V plots,
4V80calculated,
4VI86from r^3 vs V plots,
4VII92
4VIII98
4IX103
Mode Peluruhan Isotop (56)
IsotopModeIntensitas
77B+—
77B+p—
77p—
78B+—
78B+p—
79B+100%
79B+p—
80B+100%
81B+100%
81B+p0,1%
Faktor Hamburan Sinar-X (724)
Energi (eV)f₁f₂
1—0,18706
1,0149—0,19051
1,0299—0,19402
1,0452—0,1976
1,0608—0,20124
1,0765—0,20499
1,0925—0,20885
1,1087—0,21277
1,1252—0,21677
1,142—0,22085

Data Tambahan

Sources

Sources of this element.

Zirconium is produced from the mineral zircon (ZrSiO4). It is found in abundance in S-type stars, and has been identified in the sun and meteorites. Analysis of lunar rock samples obtained during the various Apollo missions to the moon show a surprisingly high zirconium oxide content, compared with terrestrial rocks.

Referensi (1)

Referensi

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
Zr

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Zirconium

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

Catatan lisensi: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Zirconium

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

Catatan lisensi: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Zirconium

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Zirconium

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Zirconium

This section provides all form of data related to element Zirconium.

9 PubChem Elements
Zirconium

The element property data was retrieved from publications.

Terakhir diperbarui:

Data terverifikasi:

Konten ditinjau berdasarkan data ilmiah terbaru.