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Nb 41

Niobium (Nb)

transition-metal
Periode: 5 Golongan: 5 Blok: d

Solid

Bobot Atom Standar

92,90637 u

Konfigurasi elektron

[Kr] 5s1 4d4

Titik lebur

2476,85 °C

Titik didih

4743,85 °C

Massa jenis

8570 kg/m³

Bilangan oksidasi

−3, −1, 0, +1, +2, +3, +4, +5

Keelektronegatifan (Pauling)

1,6

Energi ionisasi (ke-1)

6,75885 eV

Tahun penemuan

1801

Jari-jari atom

145 pm

Detail

Asal nama From Niobe; daughter of the mythical Greek king Tantalus.
Negara penemuan England
Penemu Charles Hatchet

Niobium is a refractory transition metal of group 5, chemically similar to tantalum and commonly occurring with it in oxide minerals. It is valued for its ability to strengthen steel at very small additions and for forming superconducting intermetallic compounds. In most compounds niobium is pentavalent, but lower oxidation states are well established, especially in halides and cluster chemistry.

Niobium is a shiny, white, soft, and ductile metal, and takes on a bluish cast when exposed to air at room temperatures for a long time. The metal starts to oxidize in air at 200°C, and when processed at even moderate temperatures must be placed in a protective atmosphere.

The name derives from the Greek mythological character Niobe, who was the daughter of Tantalus, because the elements niobium and tantalum were originally thought to be identical. Niobium was discovered in a black mineral from America called columbite by the British chemist and manufacturer Charles Hatchett in 1801 and he called the element columbium. In 1809, the English chemist William Hyde Wollaston claimed that columbium and tantalum were identical.

Forty years later, the German chemist and pharmacist, Heinrich Rose, determined that they were two different elements in 1846 and gave the name niobium because it was so difficult to distinguish it from tantalum. The name columbium continued to be used in America and niobium in Europe until IUPAC adopted the name niobium in 1949. Niobium was first isolated by the chemist C. W. Blomstrand in 1846.

The story of niobium's discovery is a bit confusing. The first governor of Connecticut, John Winthrop the Younger, discovered a new mineral around 1734. He named the mineral columbite ((Fe, Mn, Mg)(Nb, Ta)2O6) and sent a sample of it to the British Museum in London, England. The columbite sat in the museum's mineral collection for years until it was analyzed by Charles Hatchett in 1801. Hatchett could tell that there was an unknown element in the columbite, but he was not able to isolate it. He named the new element columbium. The fate of columbium took a drastic turn in 1809 when William Hyde Wollaston, an English chemist and physicist, compared the minerals columbite and tantalite ((Fe, Mn)(Ta, Nb)2O6) and declared that columbium was actually the element tantalum. This confusion arose because tantalum and niobium are similar metals, are always found together and are very difficult to isolate.

Niobium was rediscovered and renamed by Heinrich Rose in 1844 when he produced two new acids, niobic acid and pelopic acid, from samples of columbite and tantalite. These acids are very similar to each other and it took another twenty-two years and a Swiss chemist named Jean Charles Galissard de Marignac to prove that these were two distinct chemicals produced from two different elements. Metallic niobium was finally isolated by the Swedish chemist Christian Wilhelm Blomstrand in 1864. Today, niobium is primarily obtained from the minerals columbite and pyrochlore ((Ca, Na)2Nb2O6(O, OH, F)).

Named after Niobe, the daughter of Tantalu. Discovered in 1801 by Hatchett in an ore sent to England. The metal was first prepared in 1864 by Blomstrand, who reduced the chloride by heating it in a hydrogen atmosphere. The name niobium was adopted by the International Union of Pure and Applied Chemicstry (IUPAC) in 1950 after 100 years of controversy. Many leading chemical societies and government organizations refer to it by this name. Most metallurgists, leading metal societies, and all but one of the leading U.S. commercial producers, however, still refer to the metal as "columbium."

Gambar

Sifat

Fisika

Jari-jari atom (empiris)
145 pm Bandingkan Jari-jari atom (empiris) semua unsur →
Jari-jari kovalen
164 pm Bandingkan Jari-jari kovalen semua unsur →
Jari-jari van der Waals
207 pm Bandingkan Jari-jari van der Waals semua unsur →
Jari-jari logam
134 pm Bandingkan Jari-jari logam semua unsur →
Massa jenis
8570 kg/m³ Bandingkan Massa jenis semua unsur →
Volume molar
0,0108 L/mol
Fase pada STP
Padat Bandingkan Fase pada STP semua unsur →
Titik lebur
2476,85 °C Bandingkan Titik lebur semua unsur →
Titik didih
4743,85 °C Bandingkan Titik didih semua unsur →
Konduktivitas termal
53,7 W/(m·K) Bandingkan Konduktivitas termal semua unsur →
Kapasitas kalor spesifik
0,265 J/(g·K) Bandingkan Kapasitas kalor spesifik semua unsur →
Kapasitas kalor molar
24,6 J/(mol·K) Bandingkan Kapasitas kalor molar semua unsur →
Struktur kristal
Kubik berpusat badan Bandingkan Struktur kristal semua unsur →

Kimia

Keelektronegatifan (Pauling)
1,6 Bandingkan Keelektronegatifan (Pauling) semua unsur →
Keelektronegatifan (Allen)
1,41
Afinitas elektron
0,893 eV
Energi ionisasi (ke-1)
6,75885 eV Bandingkan Energi ionisasi (ke-1) semua unsur →
Energi ionisasi (ke-2)
14,320049 eV Bandingkan Energi ionisasi (ke-2) semua unsur →
Energi ionisasi (ke-3)
25,040086 eV Bandingkan Energi ionisasi (ke-3) semua unsur →
Energi ionisasi (ke-4)
37,611129 eV Bandingkan Energi ionisasi (ke-4) semua unsur →
Energi ionisasi (ke-5)
50,572974 eV Bandingkan Energi ionisasi (ke-5) semua unsur →
Bilangan oksidasi
−3, −1, 0, +1, +2, +3, +4, +5 Bandingkan Bilangan oksidasi semua unsur →
Elektron valensi
5 Bandingkan Elektron valensi semua unsur →
Konfigurasi elektron
[Kr] 5s1 4d4

Termodinamika

Kalor peleburan
0,27776338 eV Bandingkan Kalor peleburan semua unsur →
Kalor penguapan
7,151371 eV Bandingkan Kalor penguapan semua unsur →
Kalor sublimasi
7,617764 eV
Kalor atomisasi
7,617764 eV
Entalpi atomisasi
7,597036 eV

Nuklir

Proton
41 Bandingkan Proton semua unsur →
Neutron
52 Bandingkan Neutron semua unsur →
Isotop yang diketahui
38 Bandingkan Isotop yang diketahui semua unsur →
Isotop stabil
1 Bandingkan Isotop stabil semua unsur →
Isotop paling stabil
Nb-93
Tahun penemuan
1801

Kelimpahan

Kelimpahan (kerak Bumi)
20 mg/kg Bandingkan Kelimpahan (kerak Bumi) semua unsur →
Kelimpahan (samudra)
1 × 10−5 mg/L Bandingkan Kelimpahan (samudra) semua unsur →

Struktur Kristal

Konstanta kisi a
330 pm

Struktur Elektronik

Elektron per kulit
2, 8, 18, 12, 1 Bandingkan Elektron per kulit semua unsur →

Pengenal

Nomor CAS
7440-03-1 Bandingkan Nomor CAS semua unsur →
Simbol term
6D1/2
InChI
InChI=1S/Nb
Kunci InChI
GUCVJGMIXFAOAE-UHFFFAOYSA-N

Konfigurasi Elektron Diukur

Muatan ion
Proton 41
Elektron 41
Muatan Netral
Konfigurasi Nb: 4d⁴ 5s¹
Konfigurasi elektron
Diukur
[Kr] 4d⁴ 5s¹
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d⁴ 5s¹
Diagram orbital
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
1/2 1↑
4d
4/10 4↑
Total elektron: 41 Tidak berpasangan: 5 ?

Model atom

Proton 41
Neutron 52
Elektron 41
Nomor massa 93
Kestabilan Stabil

Isotop mengubah jumlah neutron, massa, dan kestabilan — bukan konfigurasi elektron atom netral.

Model atom skematis, tidak sesuai skala.

Sidik Jari Atom

Spektrum Emisi / Absorpsi

24 / 24 (22 22 dengan intensitas)
Diukur
Emisi Tampak: 380–750 nm

Distribusi Isotop

Unsur monoisotopik
Satu-satunya isotop yang terdapat di alam: 93 — 100,0000%
93100,0000%Nomor massaKelimpahan alami (%)
Nomor massaMassa atom (u)Kelimpahan alamiWaktu paruh
93 Stabil92,906373 ± 0,000002100,0000%Stabil
Diukur

Fase / Wujud

1 atm / 101.325 kPa
Padat 25 °C (298,15 K)

Alasan: 2451,8 °C di bawah titik lebur (2476,85 °C)

Titik lebur 2476,85 °C
Titik didih 4743,85 °C
Di bawah titik lebur sebesar 2451,8 °C
0 K Suhu saat ini: 25 °C 6000 K
Linimasa fase

Skematis, tidak sesuai skala

Padat
Cair
Gas
Peleburan
Pendidihan
25°C
Padat
Cair
Gas
Saat ini

Titik transisi fase

Titik lebur Literatur
2476,85 °C
Titik didih Literatur
4743,85 °C
Fase saat ini Dihitung
Padat

Energi transisi

Kalor peleburan Literatur
0,27776338 eV

Energi yang diperlukan untuk meleburkan 1 mol pada titik lebur

Kalor penguapan Literatur
7,151371 eV

Energi yang diperlukan untuk menguapkan 1 mol pada titik didih

Kalor sublimasi Literatur
7,617764 eV

Energi yang diperlukan untuk menyublimkan 1 mol pada titik sublimasi

Massa jenis

Massa jenis referensi Literatur
8570 kg/m³

Pada kondisi standar

Massa jenis saat ini Dihitung
8570 kg/m³

Pada kondisi standar

Spektrum Atom

Menampilkan 10 dari 41. Diurutkan berdasarkan muatan ion (menaik).

Data Garis Spektrum ?

IonMuatanTotal garisProbabilitas transisiPenamaan tingkat energi
Nb I 050900
Nb II +115000
Nb III +210800
Nb IV +3819819819
Nb V +41200
Data Garis Spektrum NIST →

Data Tingkat Energi ?

IonMuatanTingkat energi
Nb I 0395
Nb II +1354
Nb III +2189
Nb IV +3183
Nb V +431
Nb VI +5105
Nb VII +632
Nb VIII +72
Nb IX +82
Nb X +92
Data Tingkat Energi NIST →
41 Nb 92.90637

Niobium — Visualisasi Orbital Atom

[Kr]5s14d4
Tingkat energi 2 8 18 12 1
Bilangan oksidasi -3, -1, 0, +1, +2, +3, +4, +5
HOMO 5s n=5 · l=0 · m=0
Niobium — Pratinjau Visualisasi Orbital Atom
Three.js hanya dimuat saat diminta
41 Nb 92.90637

Niobium — Visualisasi Struktur Kristal

Kubik Berpusat Badan · Pearson cI2
Eksperimental
Pearson cI2
No. Koord. 8
Pengemasan 68.000%
Niobium — Pratinjau Visualisasi Struktur Kristal
Three.js hanya dimuat saat diminta

Jari-jari Ion

MuatanKoordinasiSpinJari-jari
+36Tidak tersedia72 pm
+46Tidak tersedia68 pm
+48Tidak tersedia79 pm
+54Tidak tersedia48 pm
+56Tidak tersedia64 pm
+57Tidak tersedia69 pm
+58Tidak tersedia74 pm

Senyawa

Nb
92,906 u
Nb
94,907 u
Nb
89,911 u
Nb
93,907 u
Nb
96,908 u
Nb
87,918 u
Nb
88,913 u
Nb
97,910 u
Nb
95,908 u
Nb
92,906 u
Nb
91,907 u
Nb+5
92,906 u
Nb+3
92,906 u
Nb+2
92,906 u

Isotop (1)

Eighteen isotopes of niobium are known. The metal can be isolated from tantalum, and prepared in several ways.

Nomor massaMassa atom (u)Kelimpahan alamiWaktu paruhMode peluruhan
93 Stabil92,906373 ± 0,000002100,0000%Stabil
stable
93 Stabil
Massa atom (u) 92,906373 ± 0,000002
Kelimpahan alami 100,0000%
Waktu paruh Stabil
Mode peluruhan
stable

Garis Spektrum

Panjang gelombang (nm)IntensitasTahap ionisasiJenisTransisiAkurasiSumber
382.5416 nm5000Nb IVemission4d.5d 3P → 4d.6p 1P*DiukurNIST
382.5694 nm200000Nb IVemission4d.6p 1F* → 4d.6d 3DDiukurNIST
382.5875 nm250000Nb IVemission4d.6p 3P* → 4d.6d 3DDiukurNIST
383.106 nm15000Nb IVemission4d.5d 3D → 4d.6p 1D*DiukurNIST
385.2874 nm60000Nb IVemission4d.6p 3P* → 4d.6d 3DDiukurNIST
385.5325 nm10000Nb IVemission4d.6p 1P* → 4d.6d 3PDiukurNIST
386.9546 nm8000Nb IVemission4d.6p 3P* → 4d.6d 1PDiukurNIST
387.5455 nm100000Nb IVemission4d.5d 3G → 4d.6p 1D*DiukurNIST
388.2203 nm60000Nb IVemission4d.6p 1P* → 4d.6d 1SDiukurNIST
389.8028 nm100000Nb IVemission4d.5d 3S → 4d.6p 3P*DiukurNIST
390.0115 nm25000Nb IVemission4d.6p 3P* → 4d.6d 3DDiukurNIST
391.6922 nm8000Nb IVemission4d.5d 3F → 4d.6p 1F*DiukurNIST
392.1878 nm5000Nb IVemission4d.5d 1P → 4d.6p 3D*DiukurNIST
394.057 nm25000Nb IVemission4d.6p 3P* → 4d.6d 3DDiukurNIST
394.3315 nm20000Nb IVemission4d.5d 3F → 4d.6p 3F*DiukurNIST
398.5759 nm5000Nb IVemission4d.(2D<3/2>).6s 2[3/2] → 4d.6p 1P*DiukurNIST
400.1839 nm4000Nb IVemission4d.6p 3P* → 4d.6d 3DDiukurNIST
403.2233 nm40000Nb IVemission4d.5d 3F → 4d.6p 3D*DiukurNIST
404.998 nm10000Nb IVemission4d.5d 3F → 4d.6p 3F*DiukurNIST
405.2616 nm15000Nb IVemission4d.5d 1P → 4d.6p 1D*DiukurNIST
406.3412 nm200000Nb IVemission4d.5d 3F → 4d.6p 3F*DiukurNIST
406.4694 nmTidak tersediaNb IVemission4d.6p 1P* → 4d.6d 1DDiukurNIST
409.6529 nm7000Nb IVemission4d.6p 3P* → 4d.6d 3DDiukurNIST
459.6 nmTidak tersediaID 841emission2p 2P* → 2s 2SDiukurNIST

Sifat Lanjutan

Jari-jari Kovalen (Lanjutan)

Jari-jari kovalen (Pyykkö)
147 pm
Jari-jari kovalen (Pyykkö, ikatan rangkap dua)
125 pm
Jari-jari kovalen (Pyykkö, ikatan rangkap tiga)
116 pm

Jari-jari van der Waals

Batsanov
215 pm
Alvarez
256 pm
UFF
316,5 pm
MM3
243 pm

Jari-jari Atom & Logam

Jari-jari atom (Rahm)
251 pm
Jari-jari logam (C12)
146 pm

Skala Penomoran

Mendeleev
48
Pettifor
52
Glawe
53

Skala Keelektronegatifan

Ghosh
0
Miedema
4
Gunnarsson–Lundqvist
4
Robles–Bartolotti
2

Polarizabilitas & Dispersi

Polarizabilitas dipol
98 a.u.
Polarizabilitas dipol (ketidakpastian)
8 a.u.
C₆ (Gould–Bučko)
1140 Ha·Bohr6

Parameter Miedema

Volume molar Miedema
10,87 cm3/mol
Kerapatan elektron Miedema
4

Risiko Pasokan & Ekonomi

Konsentrasi produksi
98
Risiko pasokan relatif
8
Distribusi cadangan
97
Stabilitas politik (produsen terbesar)
48
Stabilitas politik (pemilik cadangan terbesar)
48

Transisi Fase & Alotrop

Titik lebur2750,15 K
Titik didih5014,15 K

Kategori Bilangan Oksidasi

−1 extended
+4 extended
+2 extended
+3 extended
+1 extended
0 extended
+5 main
−3 extended

Data Referensi Lanjutan

Konstanta Pemerisaian (10)
nOrbitalσ
1s0,8577
2p4,0178
2s10,8748
3d14,753
3p16,3844
3s15,8285
4d29,7624
4p26,9156
4s25,7172
5s35,079
Detail Jari-jari Kristal (7)
MuatanCNSpinrcrystal (pm)Asal
3VI86
4VI82from r^3 vs V plots, estimated,
4VIII93
5IV62calculated,
5VI78
5VII83calculated,
5VIII88
Mode Peluruhan Isotop (67)
IsotopModeIntensitas
79p—
79B+—
79B+p—
80p—
80B+—
80B+p—
81p—
81B+—
81B+p—
82B+100%
Faktor Hamburan Sinar-X (757)
Energi (eV)f₁f₂
0,5—0,09113
0,5079—0,09258
0,516—0,09406
0,5242—0,09557
0,5325—0,0971
0,5409—0,09865
0,5495—0,10023
0,5582—0,10161
0,5671—0,103
0,5761—0,10441

Data Tambahan

Sources

Sources of this element.

The element is found in niobite (or columbite), niobite-tantalite, parochlore, and euxenite. Large deposits of niobium have been found associated with carbonatites (carbon-silicate rocks), as a constituent of parochlore. Extensive ore reserves are found in Canada, Brazil, Nigeria, Zaire, and in Russia.

Referensi (1)

Referensi

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
Nb

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Niobium

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

Catatan lisensi: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Niobium

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

Catatan lisensi: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Niobium

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Niobium

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Niobium

This section provides all form of data related to element Niobium.

9 PubChem Elements
Niobium

The element property data was retrieved from publications.

Terakhir diperbarui:

Data terverifikasi:

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