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Y 39

Yttrium (Y)

transition-metal
Periode: 5 Golongan: 3 Blok: d

Solid

Bobot Atom Standar

88,90584 u

Konfigurasi elektron

[Kr] 5s2 4d1

Titik lebur

1521,85 °C

Titik didih

3344,85 °C

Massa jenis

4470 kg/m³

Bilangan oksidasi

0, +1, +2, +3

Keelektronegatifan (Pauling)

1,22

Energi ionisasi (ke-1)

6,21726 eV

Tahun penemuan

1794

Jari-jari atom

180 pm

Detail

Asal nama From the Swedish village, Ytterby, where one of its minerals was first found.
Negara penemuan Finland
Penemu Johann Gadolin

Yttrium is a silvery transition metal grouped with the rare-earth elements because it commonly occurs with lanthanides and forms predominantly trivalent cations. Its chemistry is close to the heavier lanthanides, especially holmium and erbium, rather than to scandium. Although not itself a lanthanide, yttrium is a key component of phosphors, ceramics, lasers, and high-temperature oxide materials.

Yttrium has a silver-metallic luster and is relatively stable in air. Turnings of the metal, however, ignite in air if their temperature exceeds 400°C. Finely divided yttrium is very unstable in air.

The name derives from the Swedish village of Ytterby where the mineral gadolinite was found. In 1794, the Finnish chemist Johan Gadolin discovered yttrium in the mineral ytterbite, which was later renamed gadolinite for Gadolin. Gadolin originally called the element ytterbium after ytterbite. The name was subsequently shortened to yttrium, and later another element was given the name ytterbium.

Yttrium was discovered by Johan Gadolin, a Finnish chemist, while analyzing the composition of the mineral gadolinite ((Ce, La, Nd, Y)2FeBe2Si2O10) in 1789. Gadolinite, which was named for Johan Gadolin, was discovered several years earlier in a quarry near the town of Ytterby, Sweden. Today, yttrium is primarily obtained through an ion exchange process from monazite sand ((Ce, La, Th, Nd, Y)PO4), a material rich in rare earth elements.

Namded after Ytterby, a village in Sweden near Vauxholm. Yttria earth containing yttrium was discovered by Gadolin in 1794. Ytterby is the site of a quarry which yielded many unusual minerals containing rare earths and other elements. This small town, near Stockholm, bears the honor of giving names to erbium, terbium, and ytterbium as well as yttrium.

In 1843 Mosander showed that yttira could be resolved into the oxides (or earths) of three elements. The name yttria was reserved for the most basic one; the others were named erbia and terbia.

Gambar

Sifat

Fisika

Jari-jari atom (empiris)
180 pm Bandingkan Jari-jari atom (empiris) semua unsur →
Jari-jari kovalen
190 pm Bandingkan Jari-jari kovalen semua unsur →
Jari-jari van der Waals
219 pm Bandingkan Jari-jari van der Waals semua unsur →
Jari-jari logam
162 pm Bandingkan Jari-jari logam semua unsur →
Massa jenis
4470 kg/m³ Bandingkan Massa jenis semua unsur →
Volume molar
0,0198 L/mol
Fase pada STP
Padat Bandingkan Fase pada STP semua unsur →
Titik lebur
1521,85 °C Bandingkan Titik lebur semua unsur →
Titik didih
3344,85 °C Bandingkan Titik didih semua unsur →
Kapasitas kalor spesifik
0,298 J/(g·K) Bandingkan Kapasitas kalor spesifik semua unsur →
Kapasitas kalor molar
26,53 J/(mol·K) Bandingkan Kapasitas kalor molar semua unsur →
Struktur kristal
Heksagonal susunan rapat Bandingkan Struktur kristal semua unsur →

Kimia

Keelektronegatifan (Pauling)
1,22 Bandingkan Keelektronegatifan (Pauling) semua unsur →
Keelektronegatifan (Allen)
1,12
Afinitas elektron
0,307 eV
Energi ionisasi (ke-1)
6,21726 eV Bandingkan Energi ionisasi (ke-1) semua unsur →
Energi ionisasi (ke-2)
12,223642 eV Bandingkan Energi ionisasi (ke-2) semua unsur →
Energi ionisasi (ke-3)
20,524481 eV Bandingkan Energi ionisasi (ke-3) semua unsur →
Energi ionisasi (ke-4)
60,607409 eV Bandingkan Energi ionisasi (ke-4) semua unsur →
Energi ionisasi (ke-5)
75,350259 eV Bandingkan Energi ionisasi (ke-5) semua unsur →
Bilangan oksidasi
0, +1, +2, +3 Bandingkan Bilangan oksidasi semua unsur →
Elektron valensi
3 Bandingkan Elektron valensi semua unsur →
Konfigurasi elektron
[Kr] 5s2 4d1

Termodinamika

Kalor peleburan
0,11836037 eV Bandingkan Kalor peleburan semua unsur →
Kalor penguapan
3,762243 eV Bandingkan Kalor penguapan semua unsur →
Kalor sublimasi
4,394465 eV
Kalor atomisasi
4,394465 eV
Entalpi atomisasi
4,40172 eV

Nuklir

Proton
39 Bandingkan Proton semua unsur →
Neutron
50 Bandingkan Neutron semua unsur →
Isotop yang diketahui
35 Bandingkan Isotop yang diketahui semua unsur →
Isotop stabil
1 Bandingkan Isotop stabil semua unsur →
Isotop paling stabil
Y-89
Tahun penemuan
1794

Kelimpahan

Kelimpahan (kerak Bumi)
33 mg/kg Bandingkan Kelimpahan (kerak Bumi) semua unsur →
Kelimpahan (samudra)
1,3 × 10−5 mg/L Bandingkan Kelimpahan (samudra) semua unsur →

Struktur Kristal

Konstanta kisi a
365 pm

Struktur Elektronik

Elektron per kulit
2, 8, 18, 9, 2 Bandingkan Elektron per kulit semua unsur →

Pengenal

Nomor CAS
7440-65-5 Bandingkan Nomor CAS semua unsur →
Simbol term
2D3/2
InChI
InChI=1S/Y
Kunci InChI
VWQVUPCCIRVNHF-UHFFFAOYSA-N

Konfigurasi Elektron Diukur

Muatan ion
Proton 39
Elektron 39
Muatan Netral
Konfigurasi Y: 4d¹ 5s²
Konfigurasi elektron
Diukur
[Kr] 4d¹ 5s²
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹ 5s²
Diagram orbital
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
2/2
4d
1/10 1↑
Total elektron: 39 Tidak berpasangan: 1 ?

Model atom

Proton 39
Neutron 50
Elektron 39
Nomor massa 89
Kestabilan Stabil

Isotop mengubah jumlah neutron, massa, dan kestabilan — bukan konfigurasi elektron atom netral.

Model atom skematis, tidak sesuai skala.

Sidik Jari Atom

Spektrum Emisi / Absorpsi

25 / 50 (50 50 dengan intensitas)
Diukur
Emisi Tampak: 380–750 nm

Distribusi Isotop

Unsur monoisotopik
Satu-satunya isotop yang terdapat di alam: 89 — 100,0000%
89100,0000%Nomor massaKelimpahan alami (%)
Nomor massaMassa atom (u)Kelimpahan alamiWaktu paruh
89 Stabil88,9058403 ± 0,0000024100,0000%Stabil
Diukur

Fase / Wujud

1 atm / 101.325 kPa
Padat 25 °C (298,15 K)

Alasan: 1496,8 °C di bawah titik lebur (1521,85 °C)

Titik lebur 1521,85 °C
Titik didih 3344,85 °C
Di bawah titik lebur sebesar 1496,8 °C
0 K Suhu saat ini: 25 °C 6000 K
Linimasa fase

Skematis, tidak sesuai skala

Padat
Cair
Gas
Peleburan
Pendidihan
25°C
Padat
Cair
Gas
Saat ini

Titik transisi fase

Titik lebur Literatur
1521,85 °C
Titik didih Literatur
3344,85 °C
Fase saat ini Dihitung
Padat

Energi transisi

Kalor peleburan Literatur
0,11836037 eV

Energi yang diperlukan untuk meleburkan 1 mol pada titik lebur

Kalor penguapan Literatur
3,762243 eV

Energi yang diperlukan untuk menguapkan 1 mol pada titik didih

Kalor sublimasi Literatur
4,394465 eV

Energi yang diperlukan untuk menyublimkan 1 mol pada titik sublimasi

Massa jenis

Massa jenis referensi Literatur
4470 kg/m³

Pada kondisi standar

Massa jenis saat ini Dihitung
4470 kg/m³

Pada kondisi standar

Spektrum Atom

Menampilkan 10 dari 39. Diurutkan berdasarkan muatan ion (menaik).

Data Garis Spektrum ?

IonMuatanTotal garisProbabilitas transisiPenamaan tingkat energi
Y I 0361189351
Y II +111666116
Y III +211300
Y IV +32500
Y V +4632632632
Y VII +6168168168
Y VIII +7707070
Data Garis Spektrum NIST →

Data Tingkat Energi ?

IonMuatanTingkat energi
Y I 0194
Y II +1249
Y III +251
Y IV +3130
Y V +4114
Y VI +52
Y VII +657
Y VIII +733
Y IX +82
Y X +92
Data Tingkat Energi NIST →
39 Y 88.90584

Yttrium — Visualisasi Orbital Atom

[Kr]5s24d1
Tingkat energi 2 8 18 9 2
Bilangan oksidasi 0, +1, +2, +3
HOMO 4d n=4 · l=2 · m=-2
Yttrium — Pratinjau Visualisasi Orbital Atom
Three.js hanya dimuat saat diminta
39 Y 88.90584

Yttrium — Visualisasi Struktur Kristal

Heksagonal Primitif · Pearson hP2
Eksperimental
Pearson hP2
No. Koord. 12
Pengemasan 75.071%
Yttrium — Pratinjau Visualisasi Struktur Kristal
Three.js hanya dimuat saat diminta

Jari-jari Ion

MuatanKoordinasiSpinJari-jari
+36Tidak tersedia90 pm
+37Tidak tersedia96 pm
+38Tidak tersedia101.89999999999999 pm
+39Tidak tersedia107.5 pm

Senyawa

Y
88,906 u
Y
89,907 u
Y+3
88,906 u
Y
90,907 u
Y
87,909 u
Y
85,915 u
Y
86,911 u
Y
88,906 u
Y
92,910 u
Y
91,909 u
Y
94,913 u
Y
93,912 u
Y+3
89,907 u
Y+3
88,906 u
Y
98,924 u
Y+3
85,915 u

Isotop (1)

Natural yttrium contains one isotope, 89Y. Nineteen other unstable isotopes have been characterized.

Nomor massaMassa atom (u)Kelimpahan alamiWaktu paruhMode peluruhan
89 Stabil88,9058403 ± 0,0000024100,0000%Stabil
stable
89 Stabil
Massa atom (u) 88,9058403 ± 0,0000024
Kelimpahan alami 100,0000%
Waktu paruh Stabil
Mode peluruhan
stable

Garis Spektrum

Menampilkan 50 dari 266. Secara bawaan, hanya garis spektrum dengan intensitas terukur yang ditampilkan.

Panjang gelombang (nm)IntensitasTahap ionisasiJenisTransisiAkurasiSumber
410.23691 nm9900Y Iemission4d.5s2 a 2D → 4d.5s.(1D).5p y 2F*DiukurNIST
407.735998 nm9400Y Iemission4d.5s2 a 2D → 4d.5s.(1D).5p y 2F*DiukurNIST
412.829876 nm8900Y Iemission4d.5s2 a 2D → 4d.5s.(1D).5p y 2D*DiukurNIST
414.28358 nm7500Y Iemission4d.5s2 a 2D → 4d.5s.(1D).5p y 2D*DiukurNIST
404.76281 nm2400Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p y 2P*DiukurNIST
416.750671 nm2400Y Iemission4d.5s2 a 2D → 4d.5s.(1D).5p y 2F*DiukurNIST
423.5934 nm2200Y Iemission4d.5s2 a 2D → 4d.5s.(1D).5p y 2D*DiukurNIST
408.37033 nm2000Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p y 2P*DiukurNIST
417.41339 nm2000Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p y 2P*DiukurNIST
464.368813 nm2000Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p z 2F*DiukurNIST
467.48486 nm2000Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p z 2F*DiukurNIST
619.17183 nm1200Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p z 2D*DiukurNIST
643.50036 nm1000Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p z 2D*DiukurNIST
403.982219 nm940Y Iemission4d.5s2 a 2D → 4d.5s.(1D).5p y 2D*DiukurNIST
452.72342 nm890Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4D*DiukurNIST
483.9861 nm770Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4F*DiukurNIST
552.75472 nm740Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p z 4G*DiukurNIST
546.6464 nm710Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p z 4G*DiukurNIST
558.18694 nm620Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p z 4G*DiukurNIST
563.01301 nm560Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p z 4G*DiukurNIST
484.56655 nm550Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4F*DiukurNIST
450.59441 nm500Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4D*DiukurNIST
452.77815 nm440Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4D*DiukurNIST
476.09753 nm410Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p z 2F*DiukurNIST
485.26766 nm410Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4F*DiukurNIST
485.98428 nm330Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4F*DiukurNIST
425.11994 nm300Y Iemission4d.5s.(3D).5p z 4F* → 4d.5s.(3D).5d e 4GDiukurNIST
448.74634 nm300Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4D*DiukurNIST
550.3466 nm300Y Iemission4d2.(3F).5s a 2F → 4d2.(3F).5p x 2F*DiukurNIST
622.25784 nm300Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p z 2D*DiukurNIST
543.82242 nm190Y Iemission4d2.(3F).5s a 2F → 4d2.(3F).5p x 2D*DiukurNIST
546.62434 nm190Y Iemission4d.5s.(3D).5p z 4F* → 4d.5s.(3D).6s e 4DDiukurNIST
679.37029 nm190Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p z 4F*DiukurNIST
524.08001 nm181Y Iemission4d2.(1G).5s a 2G → 4d2.(1G).5p z 2H*DiukurNIST
447.69471 nm180Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p x 2F*DiukurNIST
469.67994 nm180Y Iemission4d2.(1D).5s b 2D → 4d2.(1D).5p w 2F*DiukurNIST
479.92999 nm180Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4F*DiukurNIST
513.51993 nm180Y Iemission4d2.(1G).5s a 2G → 4d2.(1G).5p z 2H*DiukurNIST
557.74153 nm180Y Iemission4d2.(3F).5s a 2F → 4d2.(3F).5p z 2G*DiukurNIST
447.57178 nm170Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4D*DiukurNIST
472.8516 nm170Y Iemission5s2.5p z 2P* → 5s2.6s e 2SDiukurNIST
478.68762 nm170Y Iemission4d2.(3P).5s a 4P → 4d2.(3P).5p x 4D*DiukurNIST
421.77985 nm160Y Iemission5s2.5p z 2P* → 5s2.(2D).5d e 2DDiukurNIST
447.74436 nm160Y Iemission4d2.(3F).5s a 4F → 4d2.(3F).5p y 4D*DiukurNIST
475.2787 nm160Y Iemission4d2.(3F).5s a 2F → 4d2.(3P).5p x 4D*DiukurNIST
570.67133 nm160Y Iemission4d.5s.(3D).5p z 4F* → 4d.5s.(3D).6s e 4DDiukurNIST
492.18769 nm150Y Iemission5s2.5p z 2P* → 5s2.6s e 2SDiukurNIST
613.84349 nm150Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p z 4D*DiukurNIST
668.75669 nm150Y Iemission4d.5s2 a 2D → 4d.5s.(3D).5p z 4F*DiukurNIST
465.37837 nm140Y Iemission4d2.(1D).5s b 2D → 4d2.(3P).5p y 4P*DiukurNIST

Sifat Lanjutan

Jari-jari Kovalen (Lanjutan)

Jari-jari kovalen (Pyykkö)
163 pm
Jari-jari kovalen (Pyykkö, ikatan rangkap dua)
130 pm
Jari-jari kovalen (Pyykkö, ikatan rangkap tiga)
124 pm

Jari-jari van der Waals

Batsanov
240 pm
Alvarez
275 pm
UFF
334,5 pm
MM3
271 pm

Jari-jari Atom & Logam

Jari-jari atom (Rahm)
274 pm
Jari-jari logam (C12)
180 pm

Skala Penomoran

Mendeleev
12
Pettifor
19
Glawe
21

Skala Keelektronegatifan

Ghosh
0
Miedema
3
Gunnarsson–Lundqvist
3
Robles–Bartolotti
3

Polarizabilitas & Dispersi

Polarizabilitas dipol
162 a.u.
Polarizabilitas dipol (ketidakpastian)
12 a.u.
C₆ (Gould–Bučko)
2600 Ha·Bohr6

Afinitas Kimia

Afinitas proton
967 kJ/mol
Kebasaan fase gas
945,9 kJ/mol

Parameter Miedema

Volume molar Miedema
19,9 cm3/mol
Kerapatan elektron Miedema
2

Risiko Pasokan & Ekonomi

Konsentrasi produksi
97
Risiko pasokan relatif
10
Distribusi cadangan
50
Stabilitas politik (produsen terbesar)
24
Stabilitas politik (pemilik cadangan terbesar)
24

Transisi Fase & Alotrop

Titik lebur1795,15 K
Titik didih3618,15 K

Kategori Bilangan Oksidasi

+2 extended
+1 extended
+3 main
0 extended

Data Referensi Lanjutan

Konstanta Pemerisaian (10)
nOrbitalσ
1s0,8244
2p3,9968
2s10,3778
3d13,6029
3p15,9075
3s15,4485
4d23,0416
4p26,2544
4s24,7364
5s32,744
Detail Jari-jari Kristal (4)
MuatanCNSpinrcrystal (pm)Asal
3VI104from r^3 vs V plots,
3VII110
3VIII115,9from r^3 vs V plots,
3IX121,5from r^3 vs V plots,
Mode Peluruhan Isotop (60)
IsotopModeIntensitas
75B+—
75B+p—
75p—
76B+—
76p—
76B+p—
77B+100%
77B+p—
77p—
78B+100%
Faktor Hamburan Sinar-X (619)
Energi (eV)f₁f₂
10—2,26036
10,1617—2,25621
10,3261—2,25207
10,4931—2,24793
10,6628—2,2438
10,8353—2,23968
11,0105—2,23344
11,1886—2,21122
11,3696—2,18921
11,5535—2,16742

Data Tambahan

Sources

Sources of this element.

Yttrium occurs in nearly all of the rare-earth minerals. Analysis of lunar rock samples obtained during the Apollo missions show a relatively high yttrium content.

It is recovered commercially from monazite sand, which contains about 3%, and from bastnasite, which contains about 0.2%. Wohler obtained the impure element in 1828 by reduction of the anhydrous chloride with potassium. The metal is now produced commercially by reduction of the fluoride with calcium metal. It can also be prepared by other techniques.

Referensi (1)

Referensi

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
Y

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Yttrium

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

Catatan lisensi: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Yttrium

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

Catatan lisensi: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Yttrium

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Yttrium

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Yttrium

This section provides all form of data related to element Yttrium.

9 PubChem Elements
Yttrium

The element property data was retrieved from publications.

Terakhir diperbarui:

Data terverifikasi:

Konten ditinjau berdasarkan data ilmiah terbaru.