Rn 86

Radon (Rn)

noble-gas
Period: 6 Group: 18 Block: p

Gas

Standard Atomic Weight

[222]

Electron configuration

[Xe] 6s2 4f14 5d10 6p6

Melting point

-71.15 °C (202 K)

Boiling point

-61.7 °C (211.45 K)

Density

9.73 kg/m³

Oxidation states

0, +2, +6

Electronegativity (Pauling)

N/A

Ionization energy (1st)

Discovery year

1900

Atomic radius

N/A

Details

Name origin Variation of the name of another element, radium.
Discovery country Germany
Discoverers Fredrich Ernst Dorn

Radon is a radioactive noble gas and the heaviest naturally occurring member of group 18. It is chemically inert compared with most elements, but its radioactivity makes it environmentally and medically important. Natural radon is produced mainly in uranium and thorium decay chains, especially as ²²²Rn from radium-226. Its gaseous form lets it migrate from rocks, soils, and building materials into air and enclosed spaces.

Radon is present in the atomosphere at very low concentrations. See Wikipedia for discussion of concentration. At ordinary temperatures radon is a colorless gas; when cooled below the freezing point, radon exhibits a brilliant phosphorescence which becomes yellow as the temperature is lowered and orange-red at the temperature of liquid air. It has been reported that fluorine reacts with radon, forming a fluoride. Radon clathrates have also been reported.

Radon was discovered by Friedrich Ernst Dorn, a German chemist, in 1900 while studying radium's decay chain. Originally named niton after the Latin word for shining, nitens, radon has been known as radon since 1923. Today, radon is still primarily obtained through the decay of radium. At normal room temperatures, radon is a colorless, odorless, radioactive gas. The most common forms of radon decay through alpha decay. Alpha decay usually isn't considered to be a great radiological hazard since the alpha particles produced by the decay are easily stopped. However, since radon is a gas, it is easily inhaled and living tissue is directly exposed to the radiation. Although it has a relatively short half-life, radon decays into longer lived, solid, radioactive elements which can collect on dust particles and be inhaled as well. For these reasons, there is some concern as to the amount of radon present within homes. Radon seeps into houses as a result of the decay of radium, thorium or uranium ores underground and varies greatly from location to location. On average, the earth's atmosphere is 0.0000000000000000001% radon.

When cooled to its solid state, radon glows yellow. The glow becomes orange-red as the temperature is lowered.

Radon's most stable isotope, radon-222, has a half-life of about 3.8 days. It decays into polonium-218 through alpha decay.

The name was derived from radium; called niton at first, from the Latin word nitens meaning shining.The element was discovered in 1900 by Dorn, who called it radium emanation. In 1908 Ramsay and Gray, who named it niton, isolated the element and determined its density, finding it to be the heaviest known gas. It is essentially inert and occupies the last place in the zero group of gases in the Periodic Table. Since 1923, it has been called radon.

Images

Properties

Physical

Covalent radius 150 pm
Van der Waals radius 220 pm
Density
Phase at STP gas
Melting point -71.15 °C
Boiling point -61.7 °C
Thermal conductivity 0.004 W/(m·K)
Specific heat capacity 0.094 J/(g·K)
Molar heat capacity 20.786 J/(mol·K)
Crystal structure fcc

Chemical

Electronegativity (Allen) 2.6
Electron affinity
Ionization energy (1st)
Ionization energy (2nd)
Ionization energy (3rd)
Ionization energy (4th)
Ionization energy (5th)
Oxidation states 0, +2, +6
Valence electrons 8
Electron configuration
Electron configuration (semantic)

Thermodynamic

Triple point (temperature) -71 °C
Triple point (pressure) 5.100000e+4 Pa
Critical point (temperature) 104 °C
Critical point (pressure) 6.280000e+6 Pa
Heat of fusion 0.03109292 eV
Heat of vaporization 0.16582889 eV
Heat of atomization 0 eV

Nuclear

Stable isotopes 0
Mass number (most stable) 222
Discovery year 1900

Abundance

Abundance (Earth's crust) 4.000e-13 mg/kg
Abundance (ocean)

Reactivity

N/A

Crystal Structure

N/A

Electronic Structure

Electrons per shell 2, 8, 18, 32, 18, 8

Identifiers

CAS number 10043-92-2
Term symbol
InChI InChI=1S/Rn
InChI Key SYUHGPGVQRZVTB-UHFFFAOYSA-N

Electron Configuration Measured

Ion charge
Protons 86
Electrons 86
Charge Neutral
Configuration Rn: 4f¹⁴ 5d¹⁰ 6s² 6p⁶
Electron configuration
Measured
[Xe] 4f¹⁴ 5d¹⁰ 6s² 6p⁶
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d¹⁰ 6s² 6p⁶
Orbital diagram
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
2/2
4d
10/10
5p
6/6
6s
2/2
4f
14/14
5d
10/10
6p
6/6
Total electrons: 86 Unpaired: 0

Atomic model

Protons 86
Neutrons 119
Electrons 86
Mass number 205
Stability Radioactive

Isotopes change neutron count, mass, and stability — not the electron configuration of a neutral atom.

Schematic atomic model, not to scale.

Atomic Fingerprint

Emission / Absorption Spectrum

0 / 0 (0 with intensity)
Measured
Emission Visible: 380–750 nm

Isotope Distribution

No stable isotopes.

Mass numberAtomic mass (u)Natural abundanceHalf-life
194 Radioactive194.006144 ± 0.000018N/A780 us
217 Radioactive217.003928 ± 0.0000045N/A593 us
199 Radioactive198.99839 ± 0.000068N/A590 ms
214 Radioactive213.995363 ± 0.0000099N/A259 ns
205 Radioactive204.991719 ± 0.000054N/A170 seconds
Measured

Phase / State

1 atm / 101.325 kPa
Gas 25 °C (298.15 K)

Reason: 86.7 °C above boiling point (-61.7 °C)

Melting point -71.15 °C
Boiling point -61.7 °C
Above boiling by 86.7 °C
0 K Current temperature: 25 °C 6000 K
Phase timeline

Schematic, not to scale

Solid
Liquid
Gas
Melting
Boiling
25°C
Solid
Liquid
Gas
Current

Phase transition points

Melting point Literature
-71.15 °C
Boiling point Literature
-61.7 °C
Current phase Calculated
Gas

Transition energies

Heat of fusion Literature
0.03109292 eV

Energy required to melt 1 mol at melting point

Heat of vaporization Literature
0.16582889 eV

Energy required to vaporize 1 mol at boiling point

Density

Reference density Literature
9.73 kg/m³

At standard conditions

Current density Estimated
9.074038 kg/m³

Estimated via ideal gas law at current T

Advanced

Triple point Literature
-71 °C
Critical point Literature
104 °C

Atomic Spectra

Showing 10 of 86 Atomic Spectra. Sorted by ion charge (ascending).

Lines Holdings ?

IonChargeTotal linesTransition probabilitiesLevel designations
Rn I 067010
NIST Lines Holdings →

Levels Holdings ?

IonChargeLevels
Rn I 0127
Rn II +13
Rn III +22
Rn IV +32
Rn V +42
Rn VI +52
Rn VII +62
Rn VIII +72
Rn IX +82
Rn X +92
NIST Levels Holdings →
86 Rn 222

Radon — Atomic Orbital Visualizer

[Xe]6s24f145d106p6
Energy levels 2 8 18 32 18 8
Oxidation states 0, +2, +6
HOMO 6p n=6 · l=1 · m=-1
Radon — Atomic Orbital Visualizer Preview
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86 Rn 222

Radon — Crystal Structure Visualizer

No crystal structure at standard conditions — gas at 298 K, 1 atm

Crystal structure data not available for solid phase

Crystal structure: fcc

Compounds

Rn
222.018 u
Rn
222.018 u
Rn
220.011 u
Rn
219.009 u
Rn
226.031 u
Rn
218.006 u
Rn
229.042 u
Rn
228.038 u
Rn
224.024 u
Rn
210.991 u

Isotopes (5)

Thirty-nine isotopes are known. Radon-222 is the most common. It has a half-life of 3.823 days and is an alpha emitter. It is estimated that every square mile of soil to a depth of 6 inches contains about 1 g of radium, which releases radon in tiny amounts into the atmosphere. Radon gas can collect in buildings, creating a health risk. The Environmental Protection Agency estimates that responsible for an estimated 20,000 lung cancer deaths each year. More on radon and health. Radon is present in some spring waters, such as those at Hot Springs, Arkansas.

Mass numberAtomic mass (u)Natural abundanceHalf-lifeDecay mode
194 Radioactive194.006144 ± 0.000018N/A780 us
α ≈100%β+ ?
217 Radioactive217.003928 ± 0.0000045N/A593 us
α =100%
199 Radioactive198.99839 ± 0.000068N/A590 ms
α ≈100%β+ ?
214 Radioactive213.995363 ± 0.0000099N/A259 ns
α =100%
205 Radioactive204.991719 ± 0.000054N/A170 seconds
β+ =75.4±0.9%α =24.6±0.9%
194 Radioactive
Atomic mass (u) 194.006144 ± 0.000018
Natural abundance N/A
Half-life 780 us
Decay mode
α ≈100%β+ ?
217 Radioactive
Atomic mass (u) 217.003928 ± 0.0000045
Natural abundance N/A
Half-life 593 us
Decay mode
α =100%
199 Radioactive
Atomic mass (u) 198.99839 ± 0.000068
Natural abundance N/A
Half-life 590 ms
Decay mode
α ≈100%β+ ?
214 Radioactive
Atomic mass (u) 213.995363 ± 0.0000099
Natural abundance N/A
Half-life 259 ns
Decay mode
α =100%
205 Radioactive
Atomic mass (u) 204.991719 ± 0.000054
Natural abundance N/A
Half-life 170 seconds
Decay mode
β+ =75.4±0.9%α =24.6±0.9%

Extended Properties

Covalent Radii (Extended)

Covalent radius (Pyykkö)  
Covalent radius (Pyykkö, double)  
Covalent radius (Pyykkö, triple)  

Van der Waals Radii

Truhlar  
Alvarez  
UFF  
MM3  

Atomic & Metallic Radii

Atomic radius (Rahm)  

Numbering Scales

Mendeleev
Pettifor
Glawe

Electronegativity Scales

Ghosh
Gunnarsson–Lundqvist
Robles–Bartolotti

Polarizability & Dispersion

Dipole polarizability  
Dipole polarizability (unc.)  
C₆ (Gould–Bučko)  

Noble Gas Properties

Density (25 °C) 9.73 g/L
Reactions
HALOGENSRnF2

Phase Transitions & Allotropes

Melting point202.15 K
Boiling point211.45 K
Critical point (temperature)377.15 K
Critical point (pressure)6.28 MPa

Oxidation State Categories

+6 extended
+2 extended

Advanced Reference Data

Screening Constants (15)
nOrbitalσ
1s1.6659
2p4.562
2s22.5864
3d13.4027
3p23.7194
3s24.9149
4d38.0572
4f37.6688
4p36.6988
4s35.85
Isotope Decay Modes (59)
IsotopeModeIntensity
193A100%
194A100%
194B+
195A100%
196A100%
196B+
197A100%
197B+
198A93%
198B+
X‑ray Scattering Factors (516)
Energy (eV)f₁f₂
102.83964
10.16173.21791
10.32613.64656
10.49314.05083
10.66284.4288
10.83534.83437
11.01065.24445
11.18865.68932
11.36966.15277
11.55356.62072

Additional Data

References

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
Rn

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Radon

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

License note: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Radon

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

License note: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Radon

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Radon

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Radon

This section provides all form of data related to element Radon.

9 PubChem Elements
Radon

The element property data was retrieved from publications.

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