Ho 67

Holmium (Ho)

lanthanide
Period: 6 Block: s

Solid

Standard Atomic Weight

164.93033 u

Electron configuration

[Xe] 6s2 4f11

Melting point

1473.85 °C (1747 K)

Boiling point

2699.85 °C (2973 K)

Density

8800 kg/m³

Oxidation states

0, +1, +2, +3

Electronegativity (Pauling)

1.23

Ionization energy (1st)

Discovery year

1878

Atomic radius

175 pm

Details

Name origin From Holmia, the Latinized name for Stockholm, Sweden.
Discovery country Switzerland
Discoverers J.L. Soret

Holmium is a lanthanide metal and one of the heavy rare earth elements. In compounds it is almost always trivalent, forming Ho³⁺ salts with the pink, yellow, or pale colors typical of f-electron transitions. Natural holmium is monoisotopic, consisting essentially of stable ¹⁶⁵Ho. Its large magnetic moment gives the element and some of its compounds unusual magnetic behavior at low temperature.

Pure holmium has a metallic to bright silver luster. It is relatively soft and malleable and is stable in dry air at room temperature but rapidly oxidizes in moist air and at elevated temperatures. The metal has unusual magnetic properties. Few uses have yet been found for the element. The element, as with other rare earths, seems to have a low acute toxic rating.

The name derives from the Latin holmia for Stockholm. It was discovered in erbia earth by the Swiss chemist J. L. Soret in 1878, who referred to it as element X. It was later independently discovered by the Swedish chemist Per Theodor Cleve in 1879. It was first isolated in 1911 by Homberg, who proposed the name holmium either to recognize the discoverer Per Cleve, who was from Stockholm, or perhaps to establish his own name in history.

Holmium was discovered by Per Theodor Cleve, a Swedish chemist, in 1879. Cleve used the same method Carl Gustaf Mosander used to discover lanthanum, erbium and terbium, he looked for impurities in the oxides of other rare earth elements. He started with erbia, the oxide of erbium (Er2O3), and removed all of the known contaminants. After further processing, he obtained two new materials, one brown and the other green. Cleve named the brown material holmia and the green material thulia. Holmia is the oxide of the element holmium and thulia is the oxide of the element thulium. Holmium's absorption spectrum was observed earlier that year by J. L. Soret and M. Delafontaine, Swiss chemists. Today, holmium is primarily obtained through an ion exchange process from monazite sand ((Ce, La, Th, Nd, Y)PO4), a material rich in rare earth elements that can contain as much as 0.05% holmium. Holmium has no commercial applications, although it has unusual magnetic properties that could be exploited in the future.

Holmium forms no commercially important compounds. Some of holmium's compounds include: holmium oxide (Ho2O3), holmium fluoride (HoF3) and holmium iodide (HoI3).

From the Latin word Holmia meaning Stockholm. The special absorption bands of holmium were noticed in 1878 by the Swiss chemists Delafontaine and Soret, who announced the existence of an "Element X." Cleve, of Sweden, later independently discovered the element while working on erbia earth. The element is named after Cleve's native city. Holmia, the yellow oxide, was prepared by Homberg in 1911. Holmium occurs in gadolinite, monazite, and in other rare-earth minerals. It is commercially obtained from monazite, occurring in that mineral to the extent of about 0.05%. It has been isolated by the reduction of its anhydrous chloride or fluoride with calcium metal.

Images

Properties

Physical

Atomic radius (empirical) 175 pm
Covalent radius 192 pm
Van der Waals radius 216 pm
Density
Molar volume 0.0187 L/mol
Phase at STP solid
Melting point 1473.85 °C
Boiling point 2699.85 °C
Specific heat capacity 0.165 J/(g·K)
Molar heat capacity 27.15 J/(mol·K)
Crystal structure hcp

Chemical

Electronegativity (Pauling) 1.23
Electron affinity
Ionization energy (1st)
Ionization energy (2nd)
Ionization energy (3rd)
Ionization energy (4th)
Ionization energy (5th)
Oxidation states 0, +1, +2, +3
Valence electrons 3
Electron configuration
Electron configuration (semantic)

Thermodynamic

Heat of fusion 0.11608022 eV
Heat of vaporization 2.591076 eV
Heat of sublimation 3.119656 eV
Heat of atomization 3.119656 eV
Atomization enthalpy

Nuclear

Stable isotopes 1
Discovery year 1878

Abundance

Abundance (Earth's crust) 1.3 mg/kg
Abundance (ocean)

Reactivity

N/A

Crystal Structure

Lattice constant a 358 pm

Electronic Structure

Electrons per shell 2, 8, 18, 29, 8, 2

Identifiers

CAS number 7440-60-0
Term symbol
InChI InChI=1S/Ho
InChI Key KJZYNXUDTRRSPN-UHFFFAOYSA-N

Electron Configuration Measured

Ion charge
Protons 67
Electrons 67
Charge Neutral
Configuration Ho: 4f¹¹ 6s²
Electron configuration
Measured
[Xe] 4f¹¹ 6s²
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹¹ 6s²
Orbital diagram
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
2/2
4d
10/10
5p
6/6
6s
2/2
4f
11/14 3↑
Total electrons: 67 Unpaired: 3 ?

Atomic model

Protons 67
Neutrons 98
Electrons 67
Mass number 165
Stability Stable

Isotopes change neutron count, mass, and stability — not the electron configuration of a neutral atom.

Schematic atomic model, not to scale.

Atomic Fingerprint

Emission / Absorption Spectrum

0 / 0 (0 with intensity)
Measured
Emission Visible: 380–750 nm

Isotope Distribution

Monoisotopic element
Only naturally occurring isotope: 165 — 100.0000%
165100.0000%Mass numberNatural abundance (%)
Mass numberAtomic mass (u)Natural abundanceHalf-life
165 Stable164.9303288 ± 0.0000021100.0000%Stable
Measured

Phase / State

1 atm / 101.325 kPa
Solid 25 °C (298.15 K)

Reason: 1448.8 °C below melting point (1473.85 °C)

Melting point 1473.85 °C
Boiling point 2699.85 °C
Below melting by 1448.8 °C
0 K Current temperature: 25 °C 6000 K
Phase timeline

Schematic, not to scale

Solid
Liquid
Gas
Melting
Boiling
25°C
Solid
Liquid
Gas
Current

Phase transition points

Melting point Literature
1473.85 °C
Boiling point Literature
2699.85 °C
Current phase Calculated
Solid

Transition energies

Heat of fusion Literature
0.11608022 eV

Energy required to melt 1 mol at melting point

Heat of vaporization Literature
2.591076 eV

Energy required to vaporize 1 mol at boiling point

Heat of sublimation Literature
3.119656 eV

Energy required to sublime 1 mol at sublimation point

Density

Reference density Literature
8800 kg/m³

At standard conditions

Current density Calculated
8800 kg/m³

At standard conditions

Atomic Spectra

Showing 10 of 67 Atomic Spectra. Sorted by ion charge (ascending).

Lines Holdings ?

IonChargeTotal linesTransition probabilitiesLevel designations
Ho I 02821313
Ho II +1284412
NIST Lines Holdings →

Levels Holdings ?

IonChargeLevels
Ho I 0234
Ho II +155
Ho III +2126
Ho IV +321
Ho V +42
Ho VI +52
Ho VII +62
Ho VIII +72
Ho IX +82
Ho X +92
NIST Levels Holdings →
67 Ho 164.93033

Holmium — Atomic Orbital Visualizer

[Xe]6s24f11
Energy levels 2 8 18 29 8 2
Oxidation states 0, +1, +2, +3
HOMO 4f n=4 · l=3 · m=-3
Holmium — Atomic Orbital Visualizer Preview
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67 Ho 164.93033

Holmium — Crystal Structure Visualizer

Primitive Hexagonal · Pearson hP2
Experimental
Pearson hP2
Coord. № 12
Packing 78.104%
Holmium — Crystal Structure Visualizer Preview
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Ionic Radii

ChargeCoordinationSpinRadius
+36N/A90.10000000000001 pm
+38N/A101.49999999999999 pm
+39N/A107.2 pm
+310N/A112.00000000000001 pm

Compounds

Ho
164.930 u
Ho+3
164.930 u
Ho
165.932 u
Ho
160.928 u
Ho
166.933 u
Ho
154.929 u
Ho
161.929 u
Ho
163.930 u
Ho
158.928 u
Ho
156.928 u
Ho
155.930 u
Ho+3
165.932 u

Isotopes (1)

Mass numberAtomic mass (u)Natural abundanceHalf-lifeDecay mode
165 Stable164.9303288 ± 0.0000021100.0000%Stable
stable
165 Stable
Atomic mass (u) 164.9303288 ± 0.0000021
Natural abundance 100.0000%
Half-life Stable
Decay mode
stable

Extended Properties

Covalent Radii (Extended)

Covalent radius (Pyykkö)  
Covalent radius (Pyykkö, double)  

Van der Waals Radii

Alvarez  
UFF  
MM3  

Atomic & Metallic Radii

Atomic radius (Rahm)  

Numbering Scales

Mendeleev
Pettifor
Glawe

Electronegativity Scales

Ghosh
Miedema
Gunnarsson–Lundqvist
Robles–Bartolotti

Polarizability & Dispersion

Dipole polarizability  
Dipole polarizability (unc.)  
C₆ (Gould–Bučko)  

Miedema Parameters

Miedema molar volume  
Miedema electron density

Supply Risk & Economics

Production concentration
Relative supply risk
Reserve distribution
Political stability (top producer)
Political stability (top reserve)

Phase Transitions & Allotropes

Melting point1745.15 K
Boiling point2973.15 K

Oxidation State Categories

0 extended
+3 main
+1 extended
+2 extended

Advanced Reference Data

Screening Constants (13)
nOrbitalσ
1s1.3088
2p4.3332
2s17.5444
3d13.6531
3p20.2546
3s20.7649
4d35.3284
4f39.5304
4p32.4372
4s31.688
Crystal Radii Detail (4)
ChargeCNSpinrcrystal (pm)Origin
3VI104.1from r^3 vs V plots,
3VIII115.5from r^3 vs V plots,
3IX121.2from r^3 vs V plots,
3X126
Isotope Decay Modes (57)
IsotopeModeIntensity
140p
140B+
140B+p
141p100%
141B+
141B+p
142B+100%
142B+p
142p0%
143B+
X‑ray Scattering Factors (514)
Energy (eV)f₁f₂
100.16762
10.16170.17164
10.32610.17576
10.49310.17997
10.66280.18429
10.83530.1887
11.01060.19366
11.18860.20086
11.36960.20833
11.55350.21608

Additional Data

References

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
Ho

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Holmium

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

License note: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Holmium

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

License note: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Holmium

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Holmium

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Holmium

This section provides all form of data related to element Holmium.

9 PubChem Elements
Holmium

The element property data was retrieved from publications.

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