K 19

Potassium (K)

alkali-metal
Period: 4 Group: 1 Block: s

Solid

Standard Atomic Weight

39.0983 u

Electron configuration

[Ar] 4s1

Melting point

63.38 °C

Boiling point

758.85 °C

Density

890 kg/m³

Oxidation states

−1, +1

Electronegativity (Pauling)

0.82

Ionization energy (1st)

4.340664 eV

Discovery year

1807

Atomic radius

220 pm

Details

Name origin English: pot ash; symbol from Latin: kalium, (alkali).
Discovery country England
Discoverers Sir Humphrey Davy

Potassium is an alkali metal and a major rock-forming and biological element. It occurs naturally only in compounds, chiefly as K⁺ in salts, feldspars, micas, and clay minerals. The metal is highly electropositive, reacts vigorously with water, and is stored away from air and moisture. In living cells, potassium is the principal intracellular cation and is central to osmotic balance and electrical signaling.

It is one of the most reactive and electropositive of metals. Except for lithium, it is the lightest known metal. It is soft, easily cut with a knife, and is silvery in appearance immediately after a fresh surface is exposed. It rapidly oxidizes in air and must be preserved in a mineral oil such as kerosene.

As with other metals of the alkali group, it decomposes in water with the evolution of hydrogen. It catches fire spontaneously on water. Potassium and its salts impart a violet color to flames.

The name derives from the English "potash" or "pot ashes" because it is found in caustic potash (KOH). The symbol K derives from the Latin kalium via the Arabic qali for alkali. It was first isolated by the British chemist Humphry Davy in 1807 from electrolysis of potash (KOH).

Although potassium is the eighth most abundant element on earth and comprises about 2.1% of the earth's crust, it is a very reactive element and is never found free in nature. Metallic potassium was first isolated by Sir Humphry Davy in 1807 through the electrolysis of molten caustic potash (KOH). A few months after discovering potassium, Davy used the same method to isolate sodium. Potassium can be obtained from the minerals sylvite (KCl), carnallite (KCl·MgCl2·6H2O), langbeinite (K2Mg2(SO4)3) and polyhalite (K2Ca2Mg(SO4)4·2H2O). These minerals are often found in ancient lake and sea beds. Caustic potash, another important source of potassium, is primarily mined in Germany, New Mexico, California and Utah. Pure potassium is a soft, waxy metal that can be easily cut with a knife. It reacts with oxygen to form potassium superoxide (KO2) and with water to form potassium hydroxide (KOH), hydrogen gas and heat. Enough heat is produced to ignite the hydrogen gas. To prevent it from reacting with the oxygen and water in the air, samples of metallic potassium are usually stored submerged in mineral oil.

From the English word, potash - pot ashes; Latin kalium, Arab qali, alkali. Discovered in 1807 by Davy, who obtained it from caustic potash (KOH); this was the first metal isolated by electrolysis.

Images

Properties

Physical

Atomic radius (empirical)
220 pm Compare Atomic radius (empirical) of all elements →
Covalent radius
203 pm Compare Covalent radius of all elements →
Van der Waals radius
275 pm Compare Van der Waals radius of all elements →
Metallic radius
203 pm Compare Metallic radius of all elements →
Density
890 kg/m³ Compare Density of all elements →
Molar volume
0.0453 L/mol
Phase at STP
Solid Compare Phase at STP of all elements →
Melting point
63.38 °C Compare Melting point of all elements →
Boiling point
758.85 °C Compare Boiling point of all elements →
Thermal conductivity
79 W/(m·K) Compare Thermal conductivity of all elements →
Specific heat capacity
0.757 J/(g·K) Compare Specific heat capacity of all elements →
Molar heat capacity
29.6 J/(mol·K) Compare Molar heat capacity of all elements →
Crystal structure
Body-centered cubic Compare Crystal structure of all elements →

Chemical

Electronegativity (Pauling)
0.82 Compare Electronegativity (Pauling) of all elements →
Electronegativity (Allen)
0.734
Electron affinity
0.5014 eV
Ionization energy (1st)
4.340664 eV Compare Ionization energy (1st) of all elements →
Ionization energy (2nd)
31.625109 eV Compare Ionization energy (2nd) of all elements →
Ionization energy (3rd)
45.803258 eV Compare Ionization energy (3rd) of all elements →
Ionization energy (4th)
60.91721 eV Compare Ionization energy (4th) of all elements →
Ionization energy (5th)
82.660285 eV Compare Ionization energy (5th) of all elements →
Oxidation states
−1, +1 Compare Oxidation states of all elements →
Valence electrons
1 Compare Valence electrons of all elements →
Electron configuration
[Ar] 4s1

Thermodynamic

Critical point (temperature)
1950 °C
Critical point (pressure)
1.6e+7 Pa
Heat of fusion
0.02414883 eV Compare Heat of fusion of all elements →
Heat of vaporization
0.79701508 eV Compare Heat of vaporization of all elements →
Heat of sublimation
0.92449604 eV
Heat of atomization
0.92449604 eV
Atomization enthalpy
0.92242317 eV

Nuclear

Protons
19 Compare Protons of all elements →
Neutrons
20 Compare Neutrons of all elements →
Known isotopes
29 Compare Known isotopes of all elements →
Stable isotopes
2 Compare Stable isotopes of all elements →
Most stable isotope
K-39
Discovery year
1807

Abundance

Abundance (Earth's crust)
2.09e+4 mg/kg Compare Abundance (Earth's crust) of all elements →
Abundance (ocean)
399 mg/L Compare Abundance (ocean) of all elements →

Crystal Structure

Lattice constant a
523 pm

Electronic Structure

Electrons per shell
2, 8, 8, 1 Compare Electrons per shell of all elements →

Identifiers

CAS number
7440-09-7 Compare CAS number of all elements →
Term symbol
2S1/2
InChI
InChI=1S/K
InChI Key
ZLMJMSJWJFRBEC-UHFFFAOYSA-N

Electron Configuration Measured

Ion charge
Protons 19
Electrons 19
Charge Neutral
Configuration K: 4s¹
Electron configuration
Measured
[Ar] 4s¹
1s² 2s² 2p⁶ 3s² 3p⁶ 4s¹
Orbital diagram
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
1/2 1↑
Total electrons: 19 Unpaired: 1 ?

Atomic model

Protons 19
Neutrons 20
Electrons 19
Mass number 39
Stability Stable

Isotopes change neutron count, mass, and stability — not the electron configuration of a neutral atom.

Schematic atomic model, not to scale.

Atomic Fingerprint

Emission / Absorption Spectrum

25 / 50 (50 50 with intensity)
Measured
Emission Visible: 380–750 nm

Isotope Distribution

3993.2581%416.7302%Mass numberNatural abundance (%)
Mass numberAtomic mass (u)Natural abundanceHalf-life
39 Stable38.9637064864 ± 0.000000004993.2581%Stable
41 Stable40.9618252579 ± 0.00000000416.7302%Stable
Measured

Phase / State

1 atm / 101.325 kPa
Solid 25 °C (298.15 K)

Reason: 38.4 °C below melting point (63.38 °C)

Melting point 63.38 °C
Boiling point 758.85 °C
Below melting by 38.4 °C
0 K Current temperature: 25 °C 6000 K
Phase timeline

Schematic, not to scale

Solid
Liquid
Gas
Melting
Boiling
25°C
Solid
Liquid
Gas
Current

Phase transition points

Melting point Literature
63.38 °C
Boiling point Literature
758.85 °C
Current phase Calculated
Solid

Transition energies

Heat of fusion Literature
0.02414883 eV

Energy required to melt 1 mol at melting point

Heat of vaporization Literature
0.79701508 eV

Energy required to vaporize 1 mol at boiling point

Heat of sublimation Literature
0.92449604 eV

Energy required to sublime 1 mol at sublimation point

Density

Reference density Literature
890 kg/m³

At standard conditions

Current density Calculated
890 kg/m³

At standard conditions

Advanced

Critical point Literature
1950 °C

Atomic Spectra

Showing 10 of 22. Sorted by ion charge (ascending).

Levels Holdings ?

IonChargeLevels
41K I Isotope08
40K I Isotope03
39K I Isotope0123
K I 0299
K II +197
K III +240
K IV +338
K V +440
K VI +528
K VII +681
NIST Levels Holdings →
19 K 39.0983

Potassium — Atomic Orbital Visualizer

[Ar]4s1
Energy levels 2 8 8 1
Oxidation states -1, +1
HOMO 4s n=4 · l=0 · m=0
Potassium — Atomic Orbital Visualizer Preview
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19 K 39.0983

Potassium — Crystal Structure Visualizer

Body-Centered Cubic · Pearson cI2
Experimental
Pearson cI2
Coord. № 8
Packing 68.000%
Potassium — Crystal Structure Visualizer Preview
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Ionic Radii

ChargeCoordinationSpinRadius
+14N/A137 pm
+16N/A138 pm
+17N/A146 pm
+18N/A151 pm
+19N/A155 pm
+110N/A159 pm
+112N/A164 pm

Compounds

K+
39.098 u
K
39.098 u
K
39.964 u
K
42.961 u
K
41.962 u
K
37.969 u
K
38.964 u
K
43.962 u
K
44.961 u
K+
39.964 u
K+
37.969 u
K+
38.964 u
K+
42.961 u
K+
41.962 u
K
40.962 u

Isotopes (2)

Seventeen isotopes of potassium are known. Ordinary potassium is composed of three isotopes, one of which is 40°K (0.0118%), a radioactive isotope with a half-life of 1.28 x 109 years.

Mass numberAtomic mass (u)Natural abundanceHalf-lifeDecay mode
39 Stable38.9637064864 ± 0.000000004993.2581% ± 0.0044%Stable
stable
41 Stable40.9618252579 ± 0.00000000416.7302% ± 0.0044%Stable
stable
39 Stable
Atomic mass (u) 38.9637064864 ± 0.0000000049
Natural abundance 93.2581% ± 0.0044%
Half-life Stable
Decay mode
stable
41 Stable
Atomic mass (u) 40.9618252579 ± 0.0000000041
Natural abundance 6.7302% ± 0.0044%
Half-life Stable
Decay mode
stable

Spectral Lines

Showing 50 of 141. Only spectral lines with measured intensity are shown by default.

Wavelength (nm)IntensityIon stageTypeTransitionAccuracySource
693.8764 nm20K Iemission3p6.4p 2P* → 3p6.6s 2SMeasuredNIST
691.10815 nm19K Iemission3p6.4p 2P* → 3p6.6s 2SMeasuredNIST
404.41422 nm18K Iemission3p6.4s 2S → 3p6.5p 2P*MeasuredNIST
404.72132 nm17K Iemission3p6.4s 2S → 3p6.5p 2P*MeasuredNIST
580.17662 nm17K Iemission3p6.4p 2P* → 3p6.7s 2SMeasuredNIST
583.18899 nm17K Iemission3p6.4p 2P* → 3p6.5d 2DMeasuredNIST
578.23999 nm16K Iemission3p6.4p 2P* → 3p6.7s 2SMeasuredNIST
581.21521 nm15K Iemission3p6.4p 2P* → 3p6.5d 2DMeasuredNIST
535.95761 nm14K Iemission3p6.4p 2P* → 3p6.6d 2DMeasuredNIST
533.96873 nm13K Iemission3p6.4p 2P* → 3p6.8s 2SMeasuredNIST
511.225448 nm12K Iemission3p6.4p 2P* → 3p6.7d 2DMeasuredNIST
532.32786 nm12K Iemission3p6.4p 2P* → 3p6.8s 2SMeasuredNIST
534.29693 nm12K Iemission3p6.4p 2P* → 3p6.6d 2DMeasuredNIST
693.62861 nm12K Iemission3p6.4p 2P* → 3p6.4d 2DMeasuredNIST
696.46903 nm12K Iemission3p6.4p 2P* → 3p6.4d 2DMeasuredNIST
464.23725 nm11K Iemission3p6.4s 2S → 3p6.3d 2DMeasuredNIST
509.717137 nm11K Iemission3p6.4p 2P* → 3p6.7d 2DMeasuredNIST
509.920005 nm11K Iemission3p6.4p 2P* → 3p6.9s 2SMeasuredNIST
464.1875 nm10K Iemission3p6.4s 2S → 3p6.3d 2DMeasuredNIST
496.503213 nm10K Iemission3p6.4p 2P* → 3p6.8d 2DMeasuredNIST
508.423399 nm10K Iemission3p6.4p 2P* → 3p6.9s 2SMeasuredNIST
482.924 nm9K IIemission3p5.4s 3P* → 3p5.4p 3SMeasuredNIST
486.975897 nm9K Iemission3p6.4p 2P* → 3p6.9d 2DMeasuredNIST
495.081801 nm9K Iemission3p6.4p 2P* → 3p6.8d 2DMeasuredNIST
495.614802 nm9K Iemission3p6.4p 2P* → 3p6.10s 2SMeasuredNIST
389.7896 nm8K IIemission3p5.4s 3P* → 3p5.4p 1DMeasuredNIST
418.6232 nm8K IIemission3p5.4s 3P* → 3p5.4p 3DMeasuredNIST
460.849 nm8K IIemission3p5.4s 1P* → 3p5.4p 1DMeasuredNIST
480.43395 nm8K Iemission3p6.4p 2P* → 3p6.10d 2DMeasuredNIST
485.609209 nm8K Iemission3p6.4p 2P* → 3p6.9d 2DMeasuredNIST
486.348075 nm8K Iemission3p6.4p 2P* → 3p6.11s 2SMeasuredNIST
500.564 nm8K IIemission3p5.4s 3P* → 3p5.4p 3SMeasuredNIST
612.028 nm8K IIemission3p5.3d 3F* → 3p5.4p 3DMeasuredNIST
381.7547 nm7K IIemission3p5.4p 3D → 3p5.(2P*<3/2>).5s 2[3/2]*MeasuredNIST
400.122 nm7K IIemission3p5.4s 3P* → 3p5.4p 3PMeasuredNIST
413.4705 nm7K IIemission3p5.4s 3P* → 3p5.4p 3DMeasuredNIST
422.296 nm7K IIemission3p5.4s 1P* → 3p5.4p 3PMeasuredNIST
422.566 nm7K IIemission3p5.3d 3P* → 3p5.4p 1DMeasuredNIST
426.334 nm7K IIemission3p5.4s 3P* → 3p5.4p 3DMeasuredNIST
430.498 nm7K IIemission3p5.3d 3P* → 3p5.4p 1DMeasuredNIST
430.911 nm7K IIemission3p5.4s 1P* → 3p5.4p 3PMeasuredNIST
438.816 nm7K IIemission3p5.4s 1P* → 3p5.4p 1PMeasuredNIST
475.737719 nm7K Iemission3p6.4p 2P* → 3p6.11d 2DMeasuredNIST
479.104132 nm7K Iemission3p6.4p 2P* → 3p6.10d 2DMeasuredNIST
484.98645 nm7K Iemission3p6.4p 2P* → 3p6.11s 2SMeasuredNIST
505.625 nm7K IIemission3p5.3d 3P* → 3p5.4p 3SMeasuredNIST
630.728 nm7K IIemission3p5.3d 3F* → 3p5.4p 3DMeasuredNIST
696.41712 nm7K Iemission3p6.4p 2P* → 3p6.4d 2DMeasuredNIST
380.0162 nm6K IIemission3p5.4p 3D → 3p5.(2P*<3/2>).5s 2[3/2]*MeasuredNIST
381.657 nm6K IIemission3p5.4p 3P → 3p5.4d 3P*MeasuredNIST

Extended Properties

Covalent Radii (Extended)

Covalent radius (Pyykkö)
196 pm
Covalent radius (Pyykkö, double)
193 pm
Covalent radius (Bragg)
207 pm

Van der Waals Radii

Bondi
275 pm
Batsanov
280 pm
Alvarez
273 pm
UFF
381.2 pm
MM3
309 pm

Atomic & Metallic Radii

Atomic radius (Rahm)
234 pm
Metallic radius (C12)
235 pm

Numbering Scales

Mendeleev
3
Pettifor
10
Glawe
10

Electronegativity Scales

Ghosh
0
Miedema
2
Gunnarsson–Lundqvist
2
Robles–Bartolotti
1

Polarizability & Dispersion

Dipole polarizability
289.7 a.u.
Dipole polarizability (unc.)
0.3 a.u.
C₆
3923 Ha·Bohr6
C₆ (Gould–Bučko)
3910 Ha·Bohr6

Miedema Parameters

Miedema molar volume
45.63 cm3/mol
Miedema electron density
0

Supply Risk & Economics

Production concentration
21
Relative supply risk
5
Reserve distribution
61
Political stability (top producer)
81
Political stability (top reserve)
81

Phase Transitions & Allotropes

Melting point336.65 K
Boiling point1032.15 K
Critical point (temperature)2223.15 K
Critical point (pressure)16 MPa

Oxidation State Categories

+1 main
−1 extended

Advanced Reference Data

Screening Constants (6)
nOrbitalσ
1s0.5105
2p3.9728
2s5.9938
3p11.2744
3s10.3201
4s15.5048
Crystal Radii Detail (7)
ChargeCNSpinrcrystal (pm)Origin
1IV151
1VI152
1VII160
1VIII165
1IX169
1X173
1XII178
Isotope Decay Modes (53)
IsotopeModeIntensity
313p100%
32p—
33p—
34p—
35B+100%
35B+p0.4%
36B+100%
36B+p0%
36B+A0%
37B+100%
X‑ray Scattering Factors (503)
Energy (eV)f₁f₂
10—0.03426
10.1617—0.03529
10.3261—0.03635
10.4931—0.03744
10.6628—0.03856
10.8353—0.03972
11.0106—0.04091
11.1886—0.04214
11.3696—0.0434
11.5535—0.04471

Additional Data

Sources

Sources of this element.

The metal is the seventh most abundant and makes up about 2.4% by weight of the earth's crust. Most potassium minerals are insoluble and the metal is obtained from them only with great difficulty.

Certain minerals, however, such as sylvite, carnallite, langbeinite, and polyhalite are found in ancient lake and sea beds and form rather extensive deposits from which potassium and its salts can readily be obtained. Potash is mined in Germany, New Mexico, California, Utah, and elsewhere. Large deposits of potash, found at a depth of some 3000 ft in Saskatchewan, promise to be important in coming years.

Potassium is also found in the ocean, but is present only in relatively small amounts, compared to sodium.

References (1)

Production

Production of this element (from raw materials or other compounds containing the element).

Potassium is never found free in nature, but is obtained by electrolysis of the hydroxide, much in the same manner as prepared by Davy's first process. Thermal methods also are commonly used to produce potassium (such as by reduction of potassium compounds with CaC2, C, Si, or Na).

References (1)

References

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
K

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Potassium

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

License note: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Potassium

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

License note: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Potassium

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Potassium

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Potassium

This section provides all form of data related to element Potassium.

9 PubChem Elements
Potassium

The element property data was retrieved from publications.

Last updated:

Data verified:

Content is reviewed against latest scientific data.