H 1

Hydrogen (H)

nonmetal
Period: 1 Group: 1 Block: s

Gas

Standard Atomic Weight

1.008 u [1.00784, 1.00811]

Electron configuration

1s1

Melting point

-259.34 °C (13.81 K)

Boiling point

-252.87 °C (20.28 K)

Density

0.08988 kg/m³

Oxidation states

−1, +1

Electronegativity (Pauling)

2.2

Ionization energy (1st)

Discovery year

1766

Atomic radius

25 pm

Details

Name origin Greek: hydro (water) and genes (generate)
Discovery country England
Discoverers Henry Cavendish

The lightest chemical element, hydrogen sits above the alkali metals but is a nonmetal under ordinary conditions. Its single proton and one electron make it the simplest atom and a reference point for much of chemistry. On Earth it is usually bound in water and organic matter, while industry uses it as a chemical feedstock, reducing agent, fuel, and energy carrier.

Colourless, odourless gaseous chemical element. Lightest and most abundant element in the universe. Present in water and in all organic compounds. Chemically reacts with most elements. Discovered by Henry Cavendish in 1776.

The name derives from the Greek hydro for "water" and genes for "forming" because it burned in air to form water. Hydrogen was discovered by the English physicist Henry Cavendish in 1766.

Scientists had been producing hydrogen for years before it was recognized as an element. Written records indicate that Robert Boyle produced hydrogen gas as early as 1671 while experimenting with iron and acids. Hydrogen was first recognized as a distinct element by Henry Cavendish in 1766. Composed of a single proton and a single electron, hydrogen is the simplest and most abundant element in the universe. It is estimated that 90% of the visible universe is composed of hydrogen.

Hydrogen is the raw fuel that most stars 'burn' to produce energy. The same process, known as fusion, is being studied as a possible power source for use on earth. The sun's supply of hydrogen is expected to last another 5 billion years.

From the Greek word hydro (water), and genes (forming). Hydrogen was recognized as a distinct substance by Henry Cavendish in 1776. Diagram of a simple hydrogen atom.

Hydrogen is the most abundant of all elements in the universe. The heavier elements were originally made from hydrogen atoms or from other elements that were originally made from hydrogen atoms.

Images

Properties

Physical

Atomic radius (empirical) 25 pm
Covalent radius 31 pm
Van der Waals radius 120 pm
Density
Molar volume 0.0141 L/mol
Phase at STP gas
Melting point -259.34 °C
Boiling point -252.87 °C
Thermal conductivity 0.181 W/(m·K)
Specific heat capacity 14.304 J/(g·K)
Molar heat capacity 28.836 J/(mol·K)
Crystal structure hcp

Chemical

Electronegativity (Pauling) 2.2
Electronegativity (Allen) 2.3
Electron affinity
Ionization energy (1st)
Oxidation states −1, +1
Valence electrons 1
Electron configuration
Electron configuration (semantic)

Thermodynamic

Triple point (temperature) -259.3467 °C
Triple point (pressure) 7041 Pa
Critical point (temperature) -240.212 °C
Critical point (pressure) 1.285800e+6 Pa
Heat of fusion 0.00121262 eV
Heat of vaporization 0.00936933 eV
Heat of atomization 2.259398 eV
Atomization enthalpy

Nuclear

Stable isotopes 2
Discovery year 1766

Abundance

Abundance (Earth's crust) 1400 mg/kg
Abundance (ocean)

Reactivity

N/A

Crystal Structure

Lattice constant a 375 pm

Electronic Structure

Electrons per shell 1

Identifiers

CAS number 1333-74-0
Term symbol
InChI InChI=1S/H
InChI Key YZCKVEUIGOORGS-UHFFFAOYSA-N

Electron Configuration Measured

Ion charge
Protons 1
Electrons 1
Charge Neutral
Configuration H: 1s¹
Electron configuration
Measured
1s¹
1s¹
Orbital diagram
1s
1/2 1↑
Total electrons: 1 Unpaired: 1 ?

Atomic model

Protons 1
Neutrons 0
Electrons 1
Mass number 1
Stability Stable

Isotopes change neutron count, mass, and stability — not the electron configuration of a neutral atom.

Schematic atomic model, not to scale.

Atomic Fingerprint

Emission / Absorption Spectrum

25 / 91 (7 with intensity)
Measured
Emission Visible: 380–750 nm

Isotope Distribution

199.9885%20.0115%Mass numberNatural abundance (%)
Mass numberAtomic mass (u)Natural abundanceHalf-life
1 Stable1.00782503223 ± 0.0000000000999.9885%Stable
2 Stable2.01410177812 ± 0.000000000120.0115%Stable
Measured

Phase / State

1 atm / 101.325 kPa
Gas 25 °C (298.15 K)

Reason: 277.9 °C above boiling point (-252.87 °C)

Melting point -259.34 °C
Boiling point -252.87 °C
Above boiling by 277.9 °C
0 K Current temperature: 25 °C 6000 K
Phase timeline

Schematic, not to scale

Solid
Liquid
Gas
Melting
Boiling
25°C
Solid
Liquid
Gas
Current

Phase transition points

Melting point Literature
-259.34 °C
Boiling point Literature
-252.87 °C
Current phase Calculated
Gas

Transition energies

Heat of fusion Literature
0.00121262 eV

Energy required to melt 1 mol at melting point

Heat of vaporization Literature
0.00936933 eV

Energy required to vaporize 1 mol at boiling point

Density

Reference density Literature
0.08988 kg/m³

At standard conditions

Current density Estimated
0.04120002 kg/m³

Estimated via ideal gas law at current T

Advanced

Triple point Literature
-259.3467 °C
Critical point Literature
-240.212 °C

Atomic Spectra

Lines Holdings ?

IonChargeTotal linesTransition probabilitiesLevel designations
D I Isotope0364161341
H I 0568441535
T I Isotope0111111
NIST Lines Holdings →

Levels Holdings ?

IonChargeLevels
D I Isotope078
H I 0106
T I Isotope010
NIST Levels Holdings →
1 H 1.007975

Hydrogen — Atomic Orbital Visualizer

1s1
Energy levels 1
Oxidation states -1, +1
HOMO 1s n=1 · l=0 · m=0
Hydrogen — Atomic Orbital Visualizer Preview
Three.js loads only on request
1 H 1.007975

Hydrogen — Crystal Structure Visualizer

Primitive Hexagonal · Pearson hP2
Experimental
Pearson hP2
Coord. № 12
Packing 74.048%
No crystal structure at standard conditions — gas at 298 K, 1 atm
Solid phase structure at 293 K
Hydrogen — Crystal Structure Visualizer Preview
Three.js loads only on request

Compounds

H+
1.008 u
H
1.008 u
H-
1.008 u
H+
1.008 u
H+
2.014 u
H+
3.016 u
H
3.016 u
H
2.014 u
H-
3.016 u
H-
2.014 u
H-
1.008 u
H
1.008 u

Isotopes (2)

The ordinary isotope of hydrogen, H, is known as Protium, the other two isotopes are Deuterium (a proton and a neutron) and Tritium (a protron and two neutrons). Hydrogen is the only element whose isotopes have been given different names. Deuterium and Tritium are both used as fuel in nuclear fusion reactors. One atom of Deuterium is found in about 6000 ordinary hydrogen atoms.

Mass numberAtomic mass (u)Natural abundanceHalf-lifeDecay mode
1 Stable1.00782503223 ± 0.0000000000999.9885% ± 0.0070%Stable
stable
2 Stable2.01410177812 ± 0.000000000120.0115% ± 0.0070%Stable
stable
1 Stable
Atomic mass (u) 1.00782503223 ± 0.00000000009
Natural abundance 99.9885% ± 0.0070%
Half-life Stable
Decay mode
stable
2 Stable
Atomic mass (u) 2.01410177812 ± 0.00000000012
Natural abundance 0.0115% ± 0.0070%
Half-life Stable
Decay mode
stable

Spectral Lines

Wavelength (nm)IntensityIon stageTypeTransitionAccuracySource
383.5355892 nmN/AH Iemission2p 2P* → 9d 2DMeasuredNIST
383.5356424 nmN/AH Iemission2p 2P* → 9s 2SMeasuredNIST
383.53587 nmN/AH IemissionN/AMeasuredNIST
383.5361082 nmN/AH Iemission2s 2S → 9p 2P*MeasuredNIST
383.5361616 nmN/AH Iemission2s 2S → 9s 2SMeasuredNIST
383.5361673 nmN/AH Iemission2s 2S → 9p 2P*MeasuredNIST
383.53839 nmN/AH IemissionN/AMeasuredNIST
383.53909 nm30000H Iemission2 → 9MeasuredNIST
383.5409535 nmN/AH Iemission2p 2P* → 9d 2DMeasuredNIST
383.54096 nmN/AH IemissionN/AMeasuredNIST
383.5409732 nmN/AH Iemission2p 2P* → 9d 2DMeasuredNIST
383.5410263 nmN/AH Iemission2p 2P* → 9s 2SMeasuredNIST
388.9019815 nmN/AH Iemission2p 2P* → 8d 2DMeasuredNIST
388.9020595 nmN/AH Iemission2p 2P* → 8s 2SMeasuredNIST
388.90227 nmN/AH IemissionN/AMeasuredNIST
388.9024865 nmN/AH Iemission2s 2S → 8d 2DMeasuredNIST
388.9025152 nmN/AH Iemission2s 2S → 8p 2P*MeasuredNIST
388.9025154 nmN/AH Iemission2s 2S → 8d 2DMeasuredNIST
388.9025933 nmN/AH Iemission2s 2S → 8s 2SMeasuredNIST
388.9026017 nmN/AH Iemission2s 2S → 8p 2P*MeasuredNIST
388.90486 nmN/AH IemissionN/AMeasuredNIST
388.90557 nm70000H Iemission2 → 8MeasuredNIST
388.9074883 nmN/AH Iemission2p 2P* → 8d 2DMeasuredNIST
388.90749 nmN/AH IemissionN/AMeasuredNIST
388.9075172 nmN/AH Iemission2p 2P* → 8d 2DMeasuredNIST
388.9075951 nmN/AH Iemission2p 2P* → 8s 2SMeasuredNIST
397.0041763 nmN/AH Iemission2p 2P* → 7d 2DMeasuredNIST
397.0042976 nmN/AH Iemission2p 2P* → 7s 2SMeasuredNIST
397.00448 nmN/AH IemissionN/AMeasuredNIST
397.0047325 nmN/AH Iemission2s 2S → 7p 2P*MeasuredNIST
397.0048539 nmN/AH Iemission2s 2S → 7s 2SMeasuredNIST
397.004867 nmN/AH Iemission2s 2S → 7p 2P*MeasuredNIST
397.00719 nmN/AH IemissionN/AMeasuredNIST
397.00788 nm30000H Iemission2 → 7MeasuredNIST
397.0099002 nmN/AH Iemission2p 2P* → 7d 2DMeasuredNIST
397.00991 nmN/AH IemissionN/AMeasuredNIST
397.009945 nmN/AH Iemission2p 2P* → 7d 2DMeasuredNIST
397.0100663 nmN/AH Iemission2p 2P* → 7s 2SMeasuredNIST
410.1702284 nmN/AH Iemission2p 2P* → 6d 2DMeasuredNIST
410.1704339 nmN/AH Iemission2p 2P* → 6s 2SMeasuredNIST
410.17056 nmN/AH IemissionN/AMeasuredNIST
410.1707462 nmN/AH Iemission2s 2S → 6d 2DMeasuredNIST
410.1708218 nmN/AH Iemission2s 2S → 6p 2P*MeasuredNIST
410.1710277 nmN/AH Iemission2s 2S → 6s 2SMeasuredNIST
410.1710499 nmN/AH Iemission2s 2S → 6p 2P*MeasuredNIST
410.17346 nmN/AH IemissionN/AMeasuredNIST
410.17415 nm70000H Iemission2 → 6MeasuredNIST
410.17631 nmN/AH Iemission2p 2P* → 6d 2DMeasuredNIST
410.17632 nmN/AH IemissionN/AMeasuredNIST
410.176386 nmN/AH Iemission2p 2P* → 6d 2DMeasuredNIST
410.1765915 nmN/AH Iemission2p 2P* → 6s 2SMeasuredNIST
434.0426937 nmN/AH Iemission2p 2P* → 5d 2DMeasuredNIST
434.04309 nmN/AH IemissionN/AMeasuredNIST
434.0430904 nmN/AH Iemission2p 2P* → 5s 2SMeasuredNIST
434.0433568 nmN/AH Iemission2s 2S → 5p 2P*MeasuredNIST
434.0437554 nmN/AH Iemission2s 2S → 5s 2SMeasuredNIST
434.0437982 nmN/AH Iemission2s 2S → 5p 2P*MeasuredNIST
434.04634 nmN/AH IemissionN/AMeasuredNIST
434.0471 nm90000H Iemission2 → 5MeasuredNIST
434.0494419 nmN/AH Iemission2p 2P* → 5d 2DMeasuredNIST
434.04947 nmN/AH IemissionN/AMeasuredNIST
434.0495889 nmN/AH Iemission2p 2P* → 5d 2DMeasuredNIST
434.0499857 nmN/AH Iemission2p 2P* → 5s 2SMeasuredNIST
486.1278624 nmN/AH Iemission2p 2P* → 4d 2DMeasuredNIST
486.1283363 nmN/AH Iemission2s 2S → 4d 2DMeasuredNIST
486.12841 nmN/AH IemissionN/AMeasuredNIST
486.1286949 nmN/AH Iemission2s 2S → 4p 2P*MeasuredNIST
486.128837 nmN/AH Iemission2p 2P* → 4s 2SMeasuredNIST
486.1296711 nmN/AH Iemission2s 2S → 4s 2SMeasuredNIST
486.1297761 nmN/AH Iemission2s 2S → 4p 2P*MeasuredNIST
486.1325 nmN/AH IemissionN/AMeasuredNIST
486.1333 nm180000H Iemission2 → 4MeasuredNIST
486.1361516 nmN/AH Iemission2p 2P* → 4d 2DMeasuredNIST
486.13622 nmN/AH IemissionN/AMeasuredNIST
486.1365118 nmN/AH Iemission2p 2P* → 4d 2DMeasuredNIST
486.1374864 nmN/AH Iemission2p 2P* → 4s 2SMeasuredNIST
656.27097 nmN/AH Iemission2p 2P* → 3d 2DMeasuredNIST
656.2714 nmN/AH IemissionN/AMeasuredNIST
656.2722 nmN/AH IemissionN/AMeasuredNIST
656.272483 nmN/AH Iemission2s 2S → 3p 2P*MeasuredNIST
656.275181 nmN/AH Iemission2p 2P* → 3s 2SMeasuredNIST
656.276701 nmN/AH Iemission2s 2S → 3s 2SMeasuredNIST
656.277 nmN/AH IemissionN/AMeasuredNIST
656.277153 nmN/AH Iemission2s 2S → 3p 2P*MeasuredNIST
656.2795 nmN/AH IemissionN/AMeasuredNIST
656.2819 nm500000H Iemission2 → 3MeasuredNIST
656.285177 nmN/AH Iemission2p 2P* → 3d 2DMeasuredNIST
656.28533 nmN/AH IemissionN/AMeasuredNIST
656.2854 nmN/AH IemissionN/AMeasuredNIST
656.286734 nmN/AH Iemission2p 2P* → 3d 2DMeasuredNIST
656.290944 nmN/AH Iemission2p 2P* → 3s 2SMeasuredNIST

Extended Properties

Covalent Radii (Extended)

Covalent radius (Pyykkö)  

Van der Waals Radii

Bondi  
Alvarez  
UFF  
MM3  
Dreiding  
Rowland–Taylor  

Atomic & Metallic Radii

Atomic radius (Rahm)  
Metallic radius (C12)  

Numbering Scales

Mendeleev
Pettifor
Glawe

Electronegativity Scales

Ghosh
Miedema
Gunnarsson–Lundqvist
Robles–Bartolotti

Polarizability & Dispersion

Dipole polarizability  
Dipole polarizability (unc.)  
C₆  
C₆ (Gould–Bučko)  

Miedema Parameters

Miedema molar volume  
Miedema electron density

Phase Transitions & Allotropes

Melting point13.99 K
Boiling point20.27 K
Critical point (temperature)32.94 K
Critical point (pressure)1.29 MPa
Triple point (temperature)13.8 K
Triple point (pressure)7.04 kPa

Oxidation State Categories

+1 main
−1 main

Advanced Reference Data

Screening Constants (1)
nOrbitalσ
1s0
Crystal Radii Detail (2)
ChargeCNSpinrcrystal (pm)Origin
1I-24
1II-4
Isotope Decay Modes (6)
IsotopeModeIntensity
3B-100%
4n100%
52n100%
6n
63n
72n
X‑ray Scattering Factors (501)
Energy (eV)f₁f₂
100
10.16170
10.32610
10.49310
10.66280
10.83530
11.01060
11.18860
11.36960
11.55350

Additional Data

Sources

Sources of this element.

Hydrogen is estimated to make up more than 90% of all the atoms three quarters of the mass of the universe! This element is found in the stars, and plays an important part in powering the universe through both the proton-proton reaction and carbon-nitrogen cycle. Stellar hydrogen fusion processes release massive amounts of energy by combining hydrogens to form helium.

Production of hydrogen in the U.S. alone amounts to about 3 billion cubic feet per year. Hydrogen is prepared by

▸ steam on heated carbon,

▸ decomposition of certain hydrocarbons with heat,

▸ reaction of sodium or potassium hydroxide on aluminum

▸ electrolysis of water, or

▸ displacement from acids by certain metals.

Liquid hydrogen is important in cryogenics and in the study of superconductivity, as its melting point is only 20 degrees above absolute zero.

Tritium is readily produced in nuclear reactors and is used in the production of the hydrogen bomb.

Hydrogen is the primary component of Jupiter and the other gas giant planets. At some depth in the planet's interior the pressure is so great that solid molecular hydrogen is converted to solid metallic hydrogen.

In 1973, a group of Russian experimenters may have produced metallic hydrogen at a pressure of 2.8 Mbar. At the transition the density changed from 1.08 to 1.3 g/cm3. Earlier, in 1972, at Livermore, California, a group also reported on a similar experiment in which they observed a pressure-volume point centered at 2 Mbar. Predictions say that metallic hydrogen may be metastable; others have predicted it would be a superconductor at room temperature.

References (1)

Isotopes in Forensic Science and Anthropology

Information on the use of this element's isotopes in forensic science and anthropology.

Measurements of relative 2H abundances are used to determine the breeding grounds of many species of migrant songbirds. These species of songbirds only grow their feathers before migration, and they grow them on or close to their breeding grounds. Therefore, the isotopic composition of a bird’s feathers correlates to the isotopic composition of the growing season’s precipitation [18] [18] Z. D. Sharp, V. Atudorei, H. O. Panarello, J. Fernández, C. Douthitt. J. Archaeolog. Sci.30, 1709 (2003).[18] Z. D. Sharp, V. Atudorei, H. O. Panarello, J. Fernández, C. Douthitt. J. Archaeolog. Sci.30, 1709 (2003)., [19] [19] K. A. Hobson. Oecologia120, 314 (1999).[19] K. A. Hobson. Oecologia120, 314 (1999)., [20] [20] K. A. Hobson, L. I. Wassenaar. Oecologia.109, 142 (1996).[20] K. A. Hobson, L. I. Wassenaar. Oecologia.109, 142 (1996)..

Measurements of relative 2H abundances of human hair samples collected at archeological sites are used to determine the geographic region in which a subject lived based on the hydrogen isotopic composition of the water they drank. This is possible because hair stores a daily record of the hydrogen isotopic composition of intake water, which correlates to local meteoric water [18] [18] Z. D. Sharp, V. Atudorei, H. O. Panarello, J. Fernández, C. Douthitt. J. Archaeolog. Sci.30, 1709 (2003).[18] Z. D. Sharp, V. Atudorei, H. O. Panarello, J. Fernández, C. Douthitt. J. Archaeolog. Sci.30, 1709 (2003)., [21] [21] T. B. Coplen, H. Qi. Forensic Sci. Int.266, 222 (2016).[21] T. B. Coplen, H. Qi. Forensic Sci. Int.266, 222 (2016)..

References (5)
  • [18] Z. D. Sharp, V. Atudorei, H. O. Panarello, J. Fernández, C. Douthitt. J. Archaeolog. Sci.30, 1709 (2003).
  • [19] K. A. Hobson. Oecologia120, 314 (1999).
  • [20] K. A. Hobson, L. I. Wassenaar. Oecologia.109, 142 (1996).
  • [21] T. B. Coplen, H. Qi. Forensic Sci. Int.266, 222 (2016).
  • [4] IUPAC Periodic Table of the Elements and Isotopes (IPTEI) https://doi.org/10.1515/pac-2015-0703

References

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
H

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Hydrogen

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

License note: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Hydrogen

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

License note: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Hydrogen

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Hydrogen

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Hydrogen

This section provides all form of data related to element Hydrogen.

9 PubChem Elements
Hydrogen

The element property data was retrieved from publications.

Last updated:

Data verified:

Content is reviewed against latest scientific data.