Ra 88

Radium (Ra)

alkaline-earth-metal
周期: 7 族: 2 区: s

Solid

标准原子量

[226]

电子排布

[Rn] 7s2

熔点

699.85 °C

沸点

1139.85 °C

密度

5000 kg/m³

氧化态

+2

电负性(鲍林)

0.9

第一电离能

5.278424 eV

发现年份

1898

原子半径

215 pm

详细信息

名称来源 Latin: radius (ray).
发现国家 France
发现者 Pierre and Marie Curie

Radium is a heavy alkaline earth metal and the element below barium in group 2. All of its isotopes are radioactive; ²²⁶Ra, with a half-life of about 1600 years, is the best known and occurs in uranium ores as part of the ²³⁸U decay series. Its chemistry is dominated by the Ra²⁺ ion, which resembles Ba²⁺ but is less commonly handled because intense radioactivity limits direct study.

Radium is obtained commercially as bromide and chloride; it is doubtful if any appreciable stock of the isolated element now exists. The pure metal is brilliant white when freshly prepared, but blackens on exposure to air, probably due to formation of the nitride. It exhibits luminescence, as do its slats; it decomposes in water and is somewhat more volatile than barium. It is a member of the alkaline-earth group of metals. Radium imparts a carmine red color to a flame. Radium emits alpha, beta, and gamma rays and when mixed with beryllium produce neutrons. One gram of 226Ra undergoes 3.7 x 1010 disintegrations per second. The curie is defined as that amount of radioactivity which has the same disintegration rate as 1 g of 226Ra. Twenty five isotopes are now known; radium 226, the common isotope, has a half-life of 1600 years.

Radium was discovered by Marie Sklodowska Curie, a Polish chemist, and Pierre Curie, a French chemist, in 1898. Marie Curie obtained radium from pitchblende, a material that contains uranium, after noticing that unrefined pitchblende was more radioactive than the uranium that was separated from it. She reasoned that pitchblende must contain at least one other radioactive element. Curie needed to refine several tons of pitchblende in order to obtain tiny amounts of radium and polonium, another radioactive element discovered by Curie. One ton of uranium ore contains only about 0.14 grams of radium. Today, radium can be obtained as a byproduct of refining uranium and is usually sold as radium chloride (RaCl2) or radium bromide (RaBr2) and not as a pure material. Radium's most stable isotope, radium-226, has a half-life of about 1600 years. It decays into radon-222 through alpha decay or into lead-212 by ejecting a carbon-14 nucleus.

Radium was discovered in 1898 by Madame Curie in the pitchblende or uraninite of North Bohemia, where it occurs. There is about 1 g of radium in 7 tons of pitchblende. The element was isolated in 1911 by Mme. Curie and Debierne by the electrolysis of a solution of pure radium chloride employing a mercury cathode; on distillation in an atmosphere of hydrogen, this amalgam yielded the pure metal.

图片

性质

物理性质

原子半径(经验值)
215 pm 比较所有元素的原子半径(经验值) →
共价半径
221 pm 比较所有元素的共价半径 →
范德华半径
283 pm 比较所有元素的范德华半径 →
密度
5000 kg/m³ 比较所有元素的密度 →
摩尔体积
0.045 L/mol
标准温度和压力下的物相
固态 比较所有元素的标准温度和压力下的物相 →
熔点
699.85 °C 比较所有元素的熔点 →
沸点
1139.85 °C 比较所有元素的沸点 →

化学性质

电负性(鲍林)
0.9 比较所有元素的电负性(鲍林) →
电负性(Allen)
0.89
电子亲和能
0.096 eV
第一电离能
5.278424 eV 比较所有元素的第一电离能 →
第二电离能
10.147215 eV 比较所有元素的第二电离能 →
第三电离能
31.000107 eV 比较所有元素的第三电离能 →
第四电离能
41.000141 eV 比较所有元素的第四电离能 →
第五电离能
52.900182 eV 比较所有元素的第五电离能 →
氧化态
+2 比较所有元素的氧化态 →
价电子
2 比较所有元素的价电子 →
电子排布
[Rn] 7s2

热力学性质

熔化热
0.08291444 eV 比较所有元素的熔化热 →
汽化热
1.171167 eV 比较所有元素的汽化热 →
升华热
1.647925 eV
原子化热
1.647925 eV
原子化焓
1.647925 eV

核性质

质子
88 比较所有元素的质子 →
中子
138 比较所有元素的中子 →
已知同位素
35 比较所有元素的已知同位素 →
稳定同位素
0 比较所有元素的稳定同位素 →
质量数(最稳定同位素)
226
最稳定同位素
Ra-226
发现年份
1898

丰度

丰度(地壳)
9e-7 mg/kg 比较所有元素的丰度(地壳) →
丰度(海洋)
8.9 × 10−11 mg/L 比较所有元素的丰度(海洋) →

晶体结构

暂无

电子结构

各电子层电子数
2, 8, 18, 32, 18, 8, 2 比较所有元素的各电子层电子数 →

标识符

CAS登记号
7440-14-4 比较所有元素的CAS登记号 →
谱项符号
1S0
InChI
InChI=1S/Ra
InChI Key
HCWPIIXVSYCSAN-UHFFFAOYSA-N

电子排布 实测值

离子电荷
质子 88
电子 88
电荷 中性
电子排布 Ra: 7s²
电子排布
实测值
[Rn] 7s²
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d¹⁰ 6s² 6p⁶ 7s²
轨道图
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
2/2
4d
10/10
5p
6/6
6s
2/2
4f
14/14
5d
10/10
6p
6/6
7s
2/2
电子总数: 88 未配对: 0

原子模型

质子 88
中子 128
电子 88
质量数 216
稳定性 放射性

不同同位素的中子数、质量和稳定性不同,但中性原子的电子排布不变。

原子模型示意图,未按比例绘制。

原子指纹

发射 / 吸收光谱

25 / 50 (50 50条具有强度数据)
实测值
发射 可见光:380–750 nm

同位素分布

无稳定同位素。

质量数原子质量(u)天然丰度半衰期
206 放射性206.003828 ± 0.000019暂无240 ms
205 放射性205.006268 ± 0.000076暂无220 ms
216 放射性216.0035334 ± 0.0000094暂无172 ns
231 放射性231.041027 ± 0.000012暂无104 秒
230 放射性230.037055 ± 0.000011暂无93 分钟
实测值

物相 / 状态

1 atm / 101.325 kPa
固态 25 °C (298.15 K)

原因: 低于熔点(699.85 °C)674.9 °C

熔点 699.85 °C
沸点 1139.85 °C
低于熔点的温差 674.9 °C
0 K 当前温度: 25 °C 6000 K
物相变化轴

示意图,未按比例绘制

固态
液态
气态
熔化
沸腾
25°C
固态
液态
气态
当前

相变点

熔点 文献值
699.85 °C
沸点 文献值
1139.85 °C
当前物相 计算值
固态

相变能

熔化热 文献值
0.08291444 eV

在熔点熔化1 mol物质所需的能量

汽化热 文献值
1.171167 eV

在沸点汽化1 mol物质所需的能量

升华热 文献值
1.647925 eV

在升华点升华1 mol物质所需的能量

密度

参考密度 文献值
5000 kg/m³

标准条件下

当前密度 计算值
5000 kg/m³

标准条件下

原子光谱

已显示10项,共88项。 按离子电荷升序排列。

收录谱线 ?

离子电荷谱线总数跃迁概率能级标记
Ra I 014319112
Ra II +163963
NIST收录谱线 →

收录能级 ?

离子电荷能级
Ra I 082
Ra II +137
Ra III +22
Ra IV +32
Ra V +42
Ra VI +52
Ra VII +62
Ra VIII +72
Ra IX +82
Ra X +92
NIST收录能级 →
88 Ra 226

Radium — 原子轨道可视化工具

[Rn]7s2
能级 2 8 18 32 18 8 2
氧化态 +2
HOMO 7s n=7 · l=0 · m=0
Radium — 原子轨道可视化预览
Three.js仅在需要时加载
88 Ra 226

Radium — 晶体结构可视化工具

暂无晶体结构数据

离子半径

电荷配位自旋半径
+28暂无148 pm
+212暂无170 pm

化合物

Ra
226.025 u
Ra
226.025 u
Ra
228.031 u
Ra
224.020 u
Ra
223.018 u
Ra
225.024 u
Ra
227.029 u
Ra
222.015 u
Ra
220.011 u
Ra
230.037 u
Ra
212.000 u
Ra
233.048 u

同位素 (5)

质量数原子质量(u)天然丰度半衰期衰变方式
206 放射性206.003828 ± 0.000019暂无240 ms
α ≈100%β+ ?
205 放射性205.006268 ± 0.000076暂无220 ms
α ≈100%β+ ?
216 放射性216.0035334 ± 0.0000094暂无172 ns
α =100%ε<1e-8%
231 放射性231.041027 ± 0.000012暂无104 秒
β- =100%
230 放射性230.037055 ± 0.000011暂无93 分钟
β- =100%
206 放射性
原子质量(u) 206.003828 ± 0.000019
天然丰度 暂无
半衰期 240 ms
衰变方式
α ≈100%β+ ?
205 放射性
原子质量(u) 205.006268 ± 0.000076
天然丰度 暂无
半衰期 220 ms
衰变方式
α ≈100%β+ ?
216 放射性
原子质量(u) 216.0035334 ± 0.0000094
天然丰度 暂无
半衰期 172 ns
衰变方式
α =100%ε<1e-8%
231 放射性
原子质量(u) 231.041027 ± 0.000012
天然丰度 暂无
半衰期 104 秒
衰变方式
β- =100%
230 放射性
原子质量(u) 230.037055 ± 0.000011
天然丰度 暂无
半衰期 93 分钟
衰变方式
β- =100%

谱线

已显示50项,共90项。 默认仅显示具有实测强度的谱线。

波长(nm)强度电离级类型跃迁准确度来源
381.44219 nm200Ra IIemission7s 2S → 7p 2P*实测值NIST
468.22394 nm100Ra IIemission7s 2S → 7p 2P*实测值NIST
482.59281 nm100Ra Iemission7s2 1S → 7s.7p 1P*实测值NIST
566.0812 nm50Ra Iemission7s.6d 3D → 6d.7p 3F*实测值NIST
714.12167 nm50Ra Iemission7s2 1S → 7s.7p 3P*实测值NIST
453.3111 nm30Ra IIemission7p 2P* → 8s 2S实测值NIST
620.0304 nm30Ra Iemission7s.6d 3D → 6d.7p 3F*实测值NIST
443.6259 nm20Ra IIemission7p 2P* → 7d 2D实测值NIST
540.0231 nm20Ra Iemission7s.6d 3D → 6d.7p 3D*实测值NIST
540.6796 nm20Ra Iemission7s.6d 3D → 6d.7p 3D*实测值NIST
555.5852 nm20Ra Iemission7s.7p 3P* → 7s.7d 3D实测值NIST
581.3628 nm20Ra IIemission7p 2P* → 8s 2S实测值NIST
644.62 nm20Ra Iemission7s.7p 3P* → 7s.7d 3D实测值NIST
648.7319 nm20Ra Iemission7s.6d 3D → 6d.7p 3F*实测值NIST
698.0232 nm20Ra Iemission7s.6d 3D → 6d.7p 3F*实测值NIST
711.8486 nm20Ra Iemission7s.6d 3D → 6d.7p 3F*实测值NIST
722.5166 nm20Ra Iemission7s.6d 1D → 6d.7p 1D*实测值NIST
485.6071 nm10Ra Iemission7s.6d 3D → 7s.5f 3F*实测值NIST
485.942 nm10Ra IIemission5f 2F* → 6g 2G实测值NIST
492.752 nm10Ra IIemission5f 2F* → 6g 2G实测值NIST
520.5948 nm10Ra Iemission7s.6d 3D → 6d.7p 3D*实测值NIST
528.3277 nm10Ra Iemission7s.7p 3P* → 7s.7d 3D实测值NIST
532.029 nm10Ra Iemission7s.6d 3D → 6d.7p 3D*实测值NIST
539.9784 nm10Ra Iemission7s.6d 3D → 6d.7p 3D*实测值NIST
550.1985 nm10Ra Iemission7s.7p 3P* → 7p2? 3P实测值NIST
555.3574 nm10Ra Iemission7s.7p 3P* → 7s.7d 3D实测值NIST
561.6661 nm10Ra Iemission7s.6d 3D → 6d.7p 3D*实测值NIST
633.6899 nm10Ra Iemission7s.6d 1D → 7s.8p 1P*实测值NIST
659.3341 nm10Ra IIemission5f 2F* → 5g 2G实测值NIST
671.932 nm10Ra IIemission5f 2F* → 5g 2G实测值NIST
731.0269 nm10Ra Iemission7s.7p 3P* → 7s.8s 3S实测值NIST
419.4091 nm8Ra IIemission5f 2F* → 7g 2G实测值NIST
424.472 nm8Ra IIemission5f 2F* → 7g 2G实测值NIST
464.1284 nm8Ra Iemission7s.6d 3D → 7s.5f 3F*实测值NIST
469.9272 nm8Ra Iemission7s.6d 3D → 7s.5f 3F*实测值NIST
548.215 nm8Ra Iemission7s.6d 3D → 6d.7p 3D*实测值NIST
508.1036 nm6Ra Iemission7s.6d 3D → 6d.7p 3P*实测值NIST
566.165 nm6Ra IIemission8p 2P* → 9d 2D实测值NIST
389.455 nm5Ra IIemission5f 2F* → 8g 2G实测值NIST
497.179 nm5Ra Iemission7s.6d 3D → 6d.7p 3P*实测值NIST
504.154 nm5Ra Iemission7s.6d 3D → 6d.7p 3P*实测值NIST
560.143 nm5Ra Iemission7s.6d 3D → 7s.8p 3P*实测值NIST
577.824 nm5Ra Iemission7s.6d 1D → 6d.7p 3P*实测值NIST
579.5745 nm5Ra Iemission7s.7p 3P* → 7p2? 3P实测值NIST
581.1588 nm5Ra Iemission7s.6d 3D → 6d.7p 1D*实测值NIST
616.7051 nm5Ra Iemission7s.6d 3D → 6d.7p 1D*实测值NIST
707.79042 nm5Ra IIemission6d 2D → 7p 2P*实测值NIST
417.798 nm4Ra Iemission7s.6d 3D → 7s.6f 3F*实测值NIST
430.5 nm4Ra Iemission7s.6d 3D → 7s.6f 3F*实测值NIST
490.3263 nm4Ra Iemission7s.6d 3D → 6d.7p 3P*实测值NIST

扩展性质

共价半径(扩展)

共价半径(Pyykkö)
201 pm
共价半径(Pyykkö,双键)
173 pm
共价半径(Pyykkö,三键)
159 pm

范德华半径

Truhlar
283 pm
UFF
367.7 pm
MM3
327 pm

原子半径与金属半径

原子半径(Rahm)
292 pm

编号标度

Mendeleev
10
Pettifor
13
Glawe
13

电负性标度

Ghosh
0

极化率与色散

偶极极化率
246 a.u.
偶极极化率(不确定度)
4 a.u.

相变与同素异形体

熔点969.15 K

氧化态分类

+2 main

高级参考数据

晶体半径详情 (2)
电荷CN自旋rcrystal (pm)来源
2VIII162from r^3 vs V plots,
2XII184from r^3 vs V plots,
同位素衰变方式 (55)
同位素模式强度
201A100%
202A100%
203A100%
203B+—
204A100%
204B+—
205A100%
205B+—
206A100%
206B+—
X射线散射因子 (516)
能量 (eV)f₁f₂
10—0.04162
10.1617—0.04479
10.3261—0.0482
10.4931—0.05188
10.6628—0.05584
10.8353—0.0601
11.0106—0.06468
11.1886—0.06961
11.3696—0.07492
11.5535—0.08102

补充数据

Sources

Sources of this element.

Originally, radium was obtained from the rich pitchblende ore found in Joachimsthal, Bohemia. The carnotite sands of Colorado furnish some radium, but richer ores are found in the Republic of Zaire and the Great Lake region of Canada. Radium is present in all uranium minerals, and could be extracted, if desired, from the extensive wastes of uranium processing. Large uranium deposits are located in Ontario, New Mexico, Utah, Australia, and elsewhere.

参考文献 (1)

参考文献

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
Ra

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Radium

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

许可证说明: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Radium

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

许可证说明: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Radium

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Radium

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Radium

This section provides all form of data related to element Radium.

9 PubChem Elements
Radium

The element property data was retrieved from publications.

最后更新:

数据已核实:

内容已依据最新科学数据进行审核。