Fr 87

Francium (Fr)

alkali-metal
周期: 7 族: 1 区: s

Solid

标准原子量

[223]

电子排布

[Rn] 7s1

熔点

26.85 °C

沸点

暂无

密度

1870 kg/m³

氧化态

+1

电负性(鲍林)

0.7

第一电离能

4.072741 eV

发现年份

1939

原子半径

暂无

详细信息

名称来源 Named for France, the nation of its discovery.
发现国家 France
发现者 Marguerite Derey

Francium is the heaviest known alkali metal and a member of group 1. All of its isotopes are radioactive, and the element occurs naturally only as fleeting decay products in uranium and thorium series minerals. Its chemistry is expected and partly observed to resemble an extremely electropositive form of caesium, dominated by the +1 oxidation state. Because the longest-lived isotope, ²²³Fr, has a half-life of only about 22 minutes, francium has no bulk technological role.

Francium was discovered in 1939 by Marguerite Perey, a physicist at the Curie Institute in Paris, France (Fig. IUPAC.87.1). 223Fr (with a half-life of 22 min) occurs naturally in uranium minerals as a result of actinium decay. However, it is estimated that no more than approximately 30 g of francium is present in the Earth’s crust at any time. Francium can be produced artificially for research by bombarding thorium with protons. Francium was named in honor of Perey’s home country, France [575], [576], [577]. Francium has no known isotopic applications outside of scientific research.

Francium was discovered by Marguerite Catherine Perey, a French chemist, in 1939 while analyzing actinium's decay sequence. Although considered a natural element, scientists estimate that there is no more than one ounce of francium in the earth's crust at one time. Since there is so little naturally occurring francium on earth, scientists must produce francium in order to study it. Francium can be produced by bombarding thorium with protons or by bombarding radium with neutrons. Francium's most stable isotope, francium-223, has a half-life of about 22 minutes. It decays into radium-223 through beta decay or into astatine-219 through alpha decay.

Discovered in 1939 by Mlle. Marguerite Perey of the Curie Institute, Paris. Francium, the heaviest known member of the alkali metals series, occurs as a result of an alpha disintegration of actinium. It can also be made artificially by bombarding thorium with protons. While it occurs naturally in uranium minerals, there is probably less than an ounce of francium at any time in the total crust of the earth. It has the highest equivalent weight of any element, and is the most unstable of the first 101 elements of the periodic system. Thirty-three isotopes of francium are recognized. The longest lived 223Fr (Ac, K), a daughter of 227Ac, has a half-life of 22 min. This is the only isotope of francium occurring in nature. Because all known isotopes of francium are highly unstable, knowledge of the chemical properties of this element comes from radiochemical techniques. No weighable quantity of the element has been prepared or isolated. The chemical properties of francium most resemble cesium.

图片

性质

物理性质

共价半径
260 pm 比较所有元素的共价半径 →
范德华半径
348 pm 比较所有元素的范德华半径 →
密度
1870 kg/m³ 比较所有元素的密度 →
标准温度和压力下的物相
固态 比较所有元素的标准温度和压力下的物相 →
熔点
26.85 °C 比较所有元素的熔点 →
晶体结构
体心立方 比较所有元素的晶体结构 →

化学性质

电负性(鲍林)
0.7 比较所有元素的电负性(鲍林) →
电负性(Allen)
0.67
电子亲和能
0.491 eV
第一电离能
4.072741 eV 比较所有元素的第一电离能 →
第二电离能
22.400077 eV 比较所有元素的第二电离能 →
第三电离能
33.500115 eV 比较所有元素的第三电离能 →
第四电离能
39.100135 eV 比较所有元素的第四电离能 →
第五电离能
50.000172 eV 比较所有元素的第五电离能 →
氧化态
+1 比较所有元素的氧化态 →
价电子
1 比较所有元素的价电子 →
电子排布
[Rn] 7s1

热力学性质

熔化热
0.02072861 eV 比较所有元素的熔化热 →
汽化热
0.67367985 eV 比较所有元素的汽化热 →
升华热
0.74622998 eV
原子化热
0.74622998 eV

核性质

质子
87 比较所有元素的质子 →
中子
136 比较所有元素的中子 →
已知同位素
37 比较所有元素的已知同位素 →
稳定同位素
0 比较所有元素的稳定同位素 →
质量数(最稳定同位素)
223
最稳定同位素
Fr-223
发现年份
1939

丰度

暂无

晶体结构

暂无

电子结构

各电子层电子数
2, 8, 18, 32, 18, 8, 1 比较所有元素的各电子层电子数 →

标识符

CAS登记号
7440-73-5 比较所有元素的CAS登记号 →
谱项符号
2S1/2
InChI
InChI=1S/Fr
InChI Key
KLMCZVJOEAUDNE-UHFFFAOYSA-N

电子排布 实测值

离子电荷
质子 87
电子 87
电荷 中性
电子排布 Fr: 7s¹
电子排布
实测值
[Rn] 7s¹
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d¹⁰ 6s² 6p⁶ 7s¹
轨道图
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
2/2
4d
10/10
5p
6/6
6s
2/2
4f
14/14
5d
10/10
6p
6/6
7s
1/2 1↑
电子总数: 87 未配对: 1 ?

原子模型

质子 87
中子 128
电子 87
质量数 215
稳定性 放射性

不同同位素的中子数、质量和稳定性不同,但中性原子的电子排布不变。

原子模型示意图,未按比例绘制。

原子指纹

发射 / 吸收光谱

25 / 94 (0 0条具有强度数据)
实测值
发射 可见光:380–750 nm

同位素分布

无稳定同位素。

质量数原子质量(u)天然丰度半衰期
233 放射性233.05264 ± 0.00032暂无900 ms
216 放射性216.0031899 ± 0.0000045暂无700 ns
203 放射性203.0009407 ± 0.0000067暂无550 ms
202 放射性202.00332 ± 0.000055暂无372 ms
215 放射性215.0003418 ± 0.0000076暂无90 ns
实测值

物相 / 状态

1 atm / 101.325 kPa
固态 25 °C (298.15 K)

原因: 低于熔点(26.85 °C)1.9 °C

熔点 26.85 °C
0 K 当前温度: 25 °C 6000 K
物相变化轴

示意图,未按比例绘制

固态
液态 + 气态
熔化
25°C
固态
液态
气态
当前

相变点

熔点 文献值
26.85 °C
当前物相 计算值
固态

相变能

熔化热 文献值
0.02072861 eV

在熔点熔化1 mol物质所需的能量

汽化热 文献值
0.67367985 eV

在沸点汽化1 mol物质所需的能量

升华热 文献值
0.74622998 eV

在升华点升华1 mol物质所需的能量

密度

参考密度 文献值
1870 kg/m³

标准条件下

当前密度 计算值
1870 kg/m³

标准条件下

原子光谱

已显示10项,共87项。 按离子电荷升序排列。

收录谱线 ?

离子电荷谱线总数跃迁概率能级标记
Fr I 0149149149
NIST收录谱线 →

收录能级 ?

离子电荷能级
Fr I 0123
Fr II +12
Fr III +22
Fr IV +32
Fr V +42
Fr VI +52
Fr VII +62
Fr VIII +72
Fr IX +82
Fr X +92
NIST收录能级 →
87 Fr 223

Francium — 原子轨道可视化工具

[Rn]7s1
能级 2 8 18 32 18 8 1
氧化态 +1
HOMO 7s n=7 · l=0 · m=0
Francium — 原子轨道可视化预览
Three.js仅在需要时加载
87 Fr 223

Francium — 晶体结构可视化工具

暂无晶体结构数据

晶体结构: bcc

离子半径

电荷配位自旋半径
+16暂无180 pm

化合物

Fr
223.020 u
Fr
221.014 u
Fr
223.020 u
Fr
222.018 u
Fr
220.012 u

同位素 (5)

质量数原子质量(u)天然丰度半衰期衰变方式
233 放射性233.05264 ± 0.00032暂无900 ms
β- =100%β-n ?
216 放射性216.0031899 ± 0.0000045暂无700 ns
α =100%β+ ?
203 放射性203.0009407 ± 0.0000067暂无550 ms
α ≈100%β+ ?
202 放射性202.00332 ± 0.000055暂无372 ms
α ≈100%β+ ?
215 放射性215.0003418 ± 0.0000076暂无90 ns
α =100%
233 放射性
原子质量(u) 233.05264 ± 0.00032
天然丰度 暂无
半衰期 900 ms
衰变方式
β- =100%β-n ?
216 放射性
原子质量(u) 216.0031899 ± 0.0000045
天然丰度 暂无
半衰期 700 ns
衰变方式
α =100%β+ ?
203 放射性
原子质量(u) 203.0009407 ± 0.0000067
天然丰度 暂无
半衰期 550 ms
衰变方式
α ≈100%β+ ?
202 放射性
原子质量(u) 202.00332 ± 0.000055
天然丰度 暂无
半衰期 372 ms
衰变方式
α ≈100%β+ ?
215 放射性
原子质量(u) 215.0003418 ± 0.0000076
天然丰度 暂无
半衰期 90 ns
衰变方式
α =100%

谱线

波长(nm)强度电离级类型跃迁准确度来源
422.56552 nm暂无Fr Iemission7s 2S → 8p 2P*实测值NIST
432.53607 nm暂无Fr Iemission7s 2S → 8p 2P*实测值NIST
494.61573 nm暂无Fr Iemission7p 2P* → 20d 2D实测值NIST
495.91444 nm暂无Fr Iemission7p 2P* → 19d 2D实测值NIST
496.90308 nm暂无Fr Iemission7p 2P* → 20s 2S实测值NIST
497.49878 nm暂无Fr Iemission7p 2P* → 18d 2D实测值NIST
498.7192 nm暂无Fr Iemission7p 2P* → 19s 2S实测值NIST
499.45999 nm暂无Fr Iemission7p 2P* → 17d 2D实测值NIST
500.99176 nm暂无Fr Iemission7p 2P* → 18s 2S实测值NIST
501.92929 nm暂无Fr Iemission7p 2P* → 16d 2D实测值NIST
503.88964 nm暂无Fr Iemission7p 2P* → 17s 2S实测值NIST
505.10105 nm暂无Fr Iemission7p 2P* → 15d 2D实测值NIST
507.66912 nm暂无Fr Iemission7p 2P* → 16s 2S实测值NIST
509.27532 nm暂无Fr Iemission7p 2P* → 14d 2D实测值NIST
512.73622 nm暂无Fr Iemission7p 2P* → 15s 2S实测值NIST
514.93307 nm暂无Fr Iemission7p 2P* → 13d 2D实测值NIST
519.7664 nm暂无Fr Iemission7p 2P* → 14s 2S实测值NIST
522.89168 nm暂无Fr Iemission7p 2P* → 12d 2D实测值NIST
529.95916 nm暂无Fr Iemission7p 2P* → 13s 2S实测值NIST
534.64166 nm暂无Fr Iemission7p 2P* → 11d 2D实测值NIST
539.61762 nm暂无Fr Iemission7p 2P* → 20d 2D实测值NIST
539.6469 nm暂无Fr Iemission7p 2P* → 20d 2D实测值NIST
541.15779 nm暂无Fr Iemission7p 2P* → 19d 2D实测值NIST
541.19321 nm暂无Fr Iemission7p 2P* → 19d 2D实测值NIST
542.37083 nm暂无Fr Iemission7p 2P* → 20s 2S实测值NIST
543.03716 nm暂无Fr Iemission7p 2P* → 18d 2D实测值NIST
543.08061 nm暂无Fr Iemission7p 2P* → 18d 2D实测值NIST
544.53524 nm暂无Fr Iemission7p 2P* → 19s 2S实测值NIST
545.36417 nm暂无Fr Iemission7p 2P* → 17d 2D实测值NIST
545.4185 nm暂无Fr Iemission7p 2P* → 17d 2D实测值NIST
545.63748 nm暂无Fr Iemission7p 2P* → 12s 2S实测值NIST
547.24565 nm暂无Fr Iemission7p 2P* → 18s 2S实测值NIST
548.29545 nm暂无Fr Iemission7p 2P* → 16d 2D实测值NIST
548.36447 nm暂无Fr Iemission7p 2P* → 16d 2D实测值NIST
550.70515 nm暂无Fr Iemission7p 2P* → 17s 2S实测值NIST
552.06365 nm暂无Fr Iemission7p 2P* → 15d 2D实测值NIST
552.15244 nm暂无Fr Iemission7p 2P* → 15d 2D实测值NIST
553.17161 nm暂无Fr Iemission7p 2P* → 10d 2D实测值NIST
555.22268 nm暂无Fr Iemission7p 2P* → 16s 2S实测值NIST
557.02549 nm暂无Fr Iemission7p 2P* → 14d 2D实测值NIST
557.14445 nm暂无Fr Iemission7p 2P* → 14d 2D实测值NIST
561.28917 nm暂无Fr Iemission7p 2P* → 15s 2S实测值NIST
563.7589 nm暂无Fr Iemission7p 2P* → 13d 2D实测值NIST
563.92284 nm暂无Fr Iemission7p 2P* → 13d 2D实测值NIST
569.72475 nm暂无Fr Iemission7p 2P* → 14s 2S实测值NIST
571.87464 nm暂无Fr Iemission7p 2P* → 11s 2S实测值NIST
573.24676 nm暂无Fr Iemission7p 2P* → 12d 2D实测值NIST
573.48185 nm暂无Fr Iemission7p 2P* → 12d 2D实测值NIST
585.3491 nm暂无Fr Iemission7p 2P* → 9d 2D实测值NIST
587.29 nm暂无Fr Iemission7p 2P* → 11d 2D实测值NIST
587.64619 nm暂无Fr Iemission7p 2P* → 11d 2D实测值NIST
600.95745 nm暂无Fr Iemission7p 2P* → 12s 2S实测值NIST
609.52762 nm暂无Fr Iemission7p 2P* → 10d 2D实测值NIST
610.10952 nm暂无Fr Iemission7p 2P* → 10d 2D实测值NIST
618.5596 nm暂无Fr Iemission6d 2D → 20p 2P*实测值NIST
618.7831 nm暂无Fr Iemission6d 2D → 20p 2P*实测值NIST
621.0658 nm暂无Fr Iemission6d 2D → 19p 2P*实测值NIST
621.3414 nm暂无Fr Iemission6d 2D → 19p 2P*实测值NIST
621.98126 nm暂无Fr Iemission7p 2P* → 10s 2S实测值NIST
624.178 nm暂无Fr Iemission6d 2D → 18p 2P*实测值NIST
624.5235 nm暂无Fr Iemission6d 2D → 18p 2P*实测值NIST
626.3009 nm暂无Fr Iemission6d 2D → 20p 2P*实测值NIST
628.1118 nm暂无Fr Iemission6d 2D → 17p 2P*实测值NIST
628.5529 nm暂无Fr Iemission6d 2D → 17p 2P*实测值NIST
628.8704 nm暂无Fr Iemission6d 2D → 19p 2P*实测值NIST
632.0616 nm暂无Fr Iemission6d 2D → 18p 2P*实测值NIST
632.9403 nm暂无Fr Iemission7p 2P* → 11s 2S实测值NIST
633.1901 nm暂无Fr Iemission6d 2D → 16p 2P*实测值NIST
633.7661 nm暂无Fr Iemission6d 2D → 16p 2P*实测值NIST
636.0957 nm暂无Fr Iemission6d 2D → 17p 2P*实测值NIST
639.9141 nm暂无Fr Iemission6d 2D → 15p 2P*实测值NIST
640.6887 nm暂无Fr Iemission6d 2D → 15p 2P*实测值NIST
641.3044 nm暂无Fr Iemission6d 2D → 16p 2P*实测值NIST
648.2027 nm暂无Fr Iemission6d 2D → 15p 2P*实测值NIST
648.421 nm暂无Fr Iemission7p 2P* → 9d 2D实测值NIST
649.103 nm暂无Fr Iemission6d 2D → 14p 2P*实测值NIST
649.4876 nm暂无Fr Iemission7p 2P* → 9d 2D实测值NIST
650.1812 nm暂无Fr Iemission6d 2D → 14p 2P*实测值NIST
650.7242 nm暂无Fr Iemission7p 2P* → 8d 2D实测值NIST
657.633 nm暂无Fr Iemission6d 2D → 14p 2P*实测值NIST
662.174 nm暂无Fr Iemission6d 2D → 13p 2P*实测值NIST
663.746 nm暂无Fr Iemission6d 2D → 13p 2P*实测值NIST
671.054 nm暂无Fr Iemission6d 2D → 13p 2P*实测值NIST
681.787 nm暂无Fr Iemission6d 2D → 12p 2P*实测值NIST
684.222 nm暂无Fr Iemission6d 2D → 12p 2P*实测值NIST
691.204 nm暂无Fr Iemission6d 2D → 12p 2P*实测值NIST
694.8987 nm暂无Fr Iemission7p 2P* → 10s 2S实测值NIST
713.491 nm暂无Fr Iemission6d 2D → 11p 2P*实测值NIST
717.615 nm暂无Fr Iemission6d 2D → 11p 2P*实测值NIST
717.98664 nm暂无Fr Iemission7s 2S → 7p 2P*实测值NIST
723.811 nm暂无Fr Iemission6d 2D → 11p 2P*实测值NIST
728.5892 nm暂无Fr Iemission7p 2P* → 8d 2D实测值NIST
730.9713 nm暂无Fr Iemission7p 2P* → 8d 2D实测值NIST
744.1976 nm暂无Fr Iemission7p 2P* → 9s 2S实测值NIST

扩展性质

共价半径(扩展)

共价半径(Pyykkö)
223 pm
共价半径(Pyykkö,双键)
218 pm

范德华半径

Truhlar
348 pm
UFF
490 pm
MM3
364 pm

原子半径与金属半径

原子半径(Rahm)
258 pm

编号标度

Mendeleev
6
Pettifor
7
Glawe
7

电负性标度

Ghosh
0

极化率与色散

偶极极化率
317.8 a.u.
偶极极化率(不确定度)
2.4 a.u.

相变与同素异形体

熔点294.15 K

氧化态分类

+1 main

高级参考数据

晶体半径详情 (1)
电荷CN自旋rcrystal (pm)来源
1VI194Ahrens (1952) ionic radius,
同位素衰变方式 (60)
同位素模式强度
197A100%
198A100%
199A100%
199B+—
200A100%
200B+—
200B+SF—
201A100%
201B+—
202A100%
X射线散射因子 (516)
能量 (eV)f₁f₂
10—0.05044
10.1617—0.06059
10.3261—0.07277
10.4931—0.08938
10.6628—0.11712
10.8353—0.15347
11.0106—0.20109
11.1886—0.26349
11.3696—0.40321
11.5535—0.63759

补充数据

参考文献

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
Fr

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Francium

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

许可证说明: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Francium

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

许可证说明: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Francium

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Francium

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Francium

This section provides all form of data related to element Francium.

9 PubChem Elements
Francium

The element property data was retrieved from publications.

最后更新:

数据已核实:

内容已依据最新科学数据进行审核。