Platinum (Pt)
transition-metalSolid
标准原子量
195.084 u电子排布
[Xe] 6s1 4f14 5d9熔点
1768.4 °C沸点
3824.85 °C密度
2.146e+4 kg/m³氧化态
−3, −2, −1, 0, +1, +2, +3, +4, +5, +6电负性(鲍林)
2.28第一电离能
8.95883 eV发现年份
1735原子半径
135 pm详细信息
Platinum is a dense, silvery-white transition metal in group 10 and a member of the platinum-group elements. It is exceptionally resistant to corrosion and oxidation, yet it can catalyze many reactions at its surface. The metal is chemically noble in bulk but forms well-defined complexes, especially in the +2 and +4 oxidation states. Its combination of durability, catalytic activity, and electrical stability gives it technological importance disproportionate to its crustal abundance.
Platinum is a beautiful silvery-white metal, when pure, and is malleable and ductile. It has a coefficient of expansion almost equal to that of soda-lime-silica glass, and is therefore used to make sealed electrodes in glass systems. The metal does not oxidize in air at any temperature, but is corroded by halogens, cyanides, sulfur, and caustic alkalis.
It is insoluble in hydrochloric and nitric acid, but dissolves when they are mixed as aqua regia, forming chloroplatinic acid.
The name derives from the Spanish platina for "silver". In 1735, the Spanish astronomer Antonio de Ulloa found platinum in Peru, South America. In 1741, the English metallurgist Charles Wood found platinum from Colombia, South America. In 1750, the English physician William Brownrigg prepared purified platinum metal.
Used by the pre-Columbian Indians of South America, platinum wasn't noticed by western scientists until 1735. Platinum can occur free in nature and is sometimes found in deposits of gold-bearing sands, primarily those found in the Ural mountains, Columbia and the western United States. Platinum, in the form of the mineral sperrylite (PtAs2), is also obtained as a byproduct of the nickel mining operation in the Sudbury region of Ontario, Canada. Credit for the modern rediscovery of platinum is usually given to Antonio de Ulloa.
Discovered in South America by Ulloa in 1735 and by Wood in 1741. The metal was used by pre-Columbian Indians.
Pure platinum is a lustrous, silvery-white metal with a high density and a high melting point. It is ductile and malleable, and clean metal surfaces retain their metallic sheen in air because oxide formation is not favored under ordinary conditions.
Platinum is used chiefly as a catalyst, especially in automotive catalytic converters, petroleum refining, chemical synthesis, and fuel-cell electrodes. It is also used in jewelry, laboratory ware, electrical contacts, thermocouples, resistance thermometers, and high-stability electrodes. Some platinum coordination compounds are important anticancer drugs, including cisplatin, cis-[PtCl₂(NH₃)₂], although their medical use is compound-specific rather than a property of the metal itself.
Platinum is a soft, dense, ductile metal that is very resistant to corrosion. It is used to make jewelry, wire, electrical contacts and laboratory vessels. Platinum expands at nearly the same rate as soda-lime-silica glass, so it is used to make sealed electrodes in glass systems. Platinum is used to coat missile nose cones, jet engine fuel nozzles and other devices that must operate reliably for long periods of time at high temperatures. Platinum resistance wires are used in high temperature electric furnaces. Platinum anodes are used in cathodic protection systems to prevent ships, pipelines and steel piers from corroding in salt water.
Platinum is widely used as a catalyst. It will convert methyl alcohol vapors (CH4O) into formaldehyde (CH2O) on contact, glowing red hot in the process. This effect is used to make small hand warmers. Platinum is also used in a device called a catalytic converter, a device found in the exhaust systems of most cars. Catalytic converters combine carbon monoxide (CO) and unburned fuel from a car's exhaust with oxygen from the air, forming carbon dioxide (CO2) and water vapor (H2O). Platinum is also used as a catalyst in the production of sulfuric acid (H2SO4) and in the cracking of petroleum products. Fuel cells, devices that combine hydrogen and oxygen to produce electricity and water, also use platinum as a catalyst.
The metal is extensively used in jewelry, wire, and vessels for laboratory use, and in many valuable instruments including therocouple elements. It is also used for electrical contacts, corrosion-resistant apparatus, and in dentistry.
Platinum-cobalt alloys have magnetic properties. One such alloy made of 76.7% Pt and 23.3% Co, by weight, is an extremely powerful magnet that offers a B-H (max) almost twice that of Alnico V. Platinum resistance wires are used for constructing high-temperature electric furnaces.
The metal is used for coating missile nose cones, jet engine fuel nozzles, etc., which must perform reliably at high temperatures for long periods of time. The metal, like palladium, absorbs large volumes of hydrogen, retaining it at ordinary temperatures but giving it up when heated.
In the finely divided state platinum is an excellent catalyst, having long been used in the contact process for producing sulfuric acid. It is also used as a catalyst in cracking petroleum products. Much interest exists in using platinum as a catalyst in fuel cells and in antipollution devices for automobiles.
Platinum anodes are extensively used in cathodic protection systems for large ships and ocean-going vessels, pipelines, steel piers, etc. Fine platinum wire will glow red hot when placed in the vapor of methyl alcohol. It acts here as a catalyst, converting the alcohol to formaldehyde. The phenomenon has been used commercially to produce cigarette lighters and hand warmers. Hydrogen and oxygen explode in the presence of platinum.
Isotopes in Earth/Planetary Science
Astrophysicists have confirmed an anomaly in the isotopic composition of platinum in the chemically peculiar HgMn star χ Lupi, where the platinum isotopic composition was shown to be a mixture of 196Pt and 198Pt (Fig. IUPAC.78.1) [526] G. Kalus, S. Johansson, G. M. Wahlgren, D. S. Leckrone, A. P. Thorne, J. C. Brandt. Astrophys. J.494, 792 (1998)..
Isotopes in Geochronology
The decay of 190Pt (with a half-life of 4.9×1011 years) to 186Os over time has been used for dating rocks and iron meteorites [527] J. A. Coggona, G. M. Nowella, D. G. Pearsona, T. Oberthürb, J.-P. Lorandc, F. Melcherb, S. W. Parmand. Chem. Geol.302-303, 48 (2012)..
Isotopes in Medicine
195mPt (with a half-life of 4 days) is used for pharmacokinetic studies of platinum-based anti-tumor agents in cancer diagnosis and cancer therapy [188] S. J. Adelstein, F. J. Manning. Isotopes for Medicine and the Life Sciences, pp. 20–25, National Academy Press, Washington DC (1995).. The m in the superscript of 195mPt indicates a metastable state of the isotope. 195mPt can be produced from the stable isotopes 192Os or 195Pt via the 192Os (α, n) 195mPt reaction and the 195Pt (n, n′) 195mPt reaction, respectively.
Platinum chemistry is dominated by square-planar Pt(II) and octahedral Pt(IV) complexes, with lower and higher formal states known in specialized compounds. Chloroplatinic acid, H₂PtCl₆, and hexachloroplatinate salts are common precursors for catalysts and coordination chemistry. Platinum(II) chloride, PtCl₂, and platinum(IV) chloride, PtCl₄, illustrate its stable chlorides. Platinum forms many ammine, phosphine, carbonyl, and organometallic complexes; its ability to bind and activate H₂, CO, alkenes, and other small molecules underlies much of its catalytic value.
See more information at the Platinum compound page.
Massive platinum metal is generally of low chemical toxicity and is poorly reactive in the body, but finely divided platinum can be a fire or explosion hazard in some atmospheres and may catalyze unwanted reactions. Soluble platinum salts and some coordination compounds can cause allergic sensitization, asthma, skin reactions, or systemic toxicity. Industrial exposure risks are greatest during refining, catalyst manufacture, and handling of soluble or dusty forms.
Platinum occurs naturally at very low concentrations, mainly in ultramafic and mafic ore systems and in placer deposits with other platinum-group elements. In the environment it is mostly present as resistant metallic particles, sulfides, alloys, or strongly bound complexes. Road dust can contain platinum released from catalytic converters, but its mobility and bioavailability depend strongly on particle size, oxidation state, chloride content, and local chemistry.
Platinum is produced mostly as a by-product or co-product from ores rich in platinum-group elements, nickel, and copper. Mining and refining require concentration of very low-grade material followed by complex separation of closely related metals. Supply is geographically concentrated and sensitive to ore quality, energy costs, labor conditions, and refining capacity. Demand is led by emission-control catalysts, jewelry, chemical catalysts, electronics, and electrochemical technologies. Recycling from spent automotive catalysts and industrial catalysts is an important secondary source because the metal is valuable and durable.
Platinum occurs natively, accompanied by small quantities of iridium, osmium, palladium, ruthenium, and rhodium, all belonging to the same group of metals. These are found in the alluvial deposits of the Ural mountains, of Columbia, and of certain western American states. Sperrylite, occurring with the nickel-bearing deposits of Sudbury, Ontario, is the source of a considerable amount of metal.
The large production of nickel makes up for the fact that is only one part of the platinum metals in two million parts of ore.
Platinum is a rare heavy element in the cosmos, produced mainly by rapid neutron-capture processes in extreme astrophysical events. It is present in meteorites and planetary materials at trace levels, with siderophile behavior that caused much of Earth’s original inventory to partition into the core. Crustal platinum is therefore scarce and concentrated only by later geological processes.
- Platinum resists attack by most single mineral acids but dissolves in aqua regia.
- The international prototype metre and kilogram were made from a platinum-iridium alloy.
- Finely divided platinum can absorb and activate hydrogen at its surface.
- Native platinum commonly contains iron and other platinum-group metals rather than being perfectly pure.
- Platinum resistance thermometers are used because its electrical resistance is stable and reproducible.
图片
性质
物理性质
- 原子半径(经验值)
- 135 pm 比较所有元素的原子半径(经验值) →
- 共价半径
- 136 pm 比较所有元素的共价半径 →
- 范德华半径
- 209 pm 比较所有元素的范德华半径 →
- 金属半径
- 130 pm 比较所有元素的金属半径 →
- 密度
- 2.146 × 104 kg/m³ 比较所有元素的密度 →
- 摩尔体积
- 0.0091 L/mol
- 标准温度和压力下的物相
- 固态 比较所有元素的标准温度和压力下的物相 →
- 熔点
- 1768.4 °C 比较所有元素的熔点 →
- 沸点
- 3824.85 °C 比较所有元素的沸点 →
- 热导率
- 71.6 W/(m·K) 比较所有元素的热导率 →
- 比热容
- 0.133 J/(g·K) 比较所有元素的比热容 →
- 摩尔热容
- 25.86 J/(mol·K) 比较所有元素的摩尔热容 →
- 晶体结构
- 面心立方 比较所有元素的晶体结构 →
化学性质
- 电负性(鲍林)
- 2.28 比较所有元素的电负性(鲍林) →
- 电负性(Allen)
- 1.72
- 电子亲和能
- 2.1228 eV
- 第一电离能
- 8.95883 eV 比较所有元素的第一电离能 →
- 第二电离能
- 18.560064 eV 比较所有元素的第二电离能 →
- 第三电离能
- 29.0001 eV 比较所有元素的第三电离能 →
- 第四电离能
- 43.000148 eV 比较所有元素的第四电离能 →
- 第五电离能
- 56.000193 eV 比较所有元素的第五电离能 →
- 氧化态
- −3, −2, −1, 0, +1, +2, +3, +4, +5, +6 比较所有元素的氧化态 →
- 价电子
- 10 比较所有元素的价电子 →
- 电子排布
- [Xe] 6s1 4f14 5d9
热力学性质
- 熔化热
- 0.20490232 eV 比较所有元素的熔化热 →
- 汽化热
- 4.860859 eV 比较所有元素的汽化热 →
- 升华热
- 5.845468 eV
- 原子化热
- 5.845468 eV
- 原子化焓
- 5.863088 eV
核性质
- 质子
- 78 比较所有元素的质子 →
- 中子
- 116 比较所有元素的中子 →
- 已知同位素
- 44 比较所有元素的已知同位素 →
- 稳定同位素
- 3 比较所有元素的稳定同位素 →
- 最稳定同位素
- Pt-194
- 发现年份
- 1735
丰度
- 丰度(地壳)
- 0.005 mg/kg 比较所有元素的丰度(地壳) →
晶体结构
- 晶格常数a
- 392 pm
电子结构
- 各电子层电子数
- 2, 8, 18, 32, 17, 1 比较所有元素的各电子层电子数 →
标识符
- CAS登记号
- 7440-06-4 比较所有元素的CAS登记号 →
- 谱项符号
- 3D3
- InChI
- InChI=1S/Pt
- InChI Key
- BASFCYQUMIYNBI-UHFFFAOYSA-N
电子排布 实测值
Pt: 4f¹⁴ 5d⁹ 6s¹[Xe] 4f¹⁴ 5d⁹ 6s¹1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d⁹ 6s¹原子模型
不同同位素的中子数、质量和稳定性不同,但中性原子的电子排布不变。
原子模型示意图,未按比例绘制。
原子指纹
发射 / 吸收光谱
同位素分布
| 质量数 | 原子质量(u) | 天然丰度 | 半衰期 |
|---|---|---|---|
| 194 稳定 | 193.9626809 ± 0.000001 | 32.8600% | 稳定 |
| 196 稳定 | 195.96495209 ± 0.00000099 | 25.2100% | 稳定 |
| 198 稳定 | 197.9678949 ± 0.0000023 | 7.3560% | 稳定 |
物相 / 状态
原因: 低于熔点(1768.4 °C)1743.4 °C
示意图,未按比例绘制
相变点
相变能
在熔点熔化1 mol物质所需的能量
在沸点汽化1 mol物质所需的能量
在升华点升华1 mol物质所需的能量
密度
标准条件下
标准条件下
原子光谱
已显示10项,共78项。 按离子电荷升序排列。
收录谱线 ?
| 离子 | 电荷 | 谱线总数 | 跃迁概率 | 能级标记 |
|---|---|---|---|---|
| Pt I | 0 | 995 | 166 | 995 |
| Pt II | +1 | 2268 | 183 | 2268 |
| Pt IV | +3 | 1531 | 1531 | 1531 |
| Pt V | +4 | 1729 | 1729 | 1729 |
| Pt VI | +5 | 1467 | 1467 | 1467 |
| Pt VII | +6 | 786 | 786 | 786 |
| Pt VIII | +7 | 360 | 360 | 360 |
收录能级 ?
| 离子 | 电荷 | 能级 |
|---|---|---|
| Pt I | 0 | 202 |
| Pt II | +1 | 282 |
| Pt III | +2 | 2 |
| Pt IV | +3 | 238 |
| Pt V | +4 | 259 |
| Pt VI | +5 | 251 |
| Pt VII | +6 | 178 |
| Pt VIII | +7 | 80 |
| Pt IX | +8 | 2 |
| Pt X | +9 | 2 |
离子半径
| 电荷 | 配位 | 自旋 | 半径 |
|---|---|---|---|
| +2 | 4 | 暂无 | 60 pm |
| +2 | 6 | 暂无 | 80 pm |
| +4 | 6 | 暂无 | 62.5 pm |
| +5 | 6 | 暂无 | 56.99999999999999 pm |
化合物
同位素 (3)
| 质量数 | 原子质量(u) | 天然丰度 | 半衰期 | 衰变方式 | |
|---|---|---|---|---|---|
| 194 稳定 | 193.9626809 ± 0.000001 | 32.8600% ± 0.4000% | 稳定 | stable | |
| 196 稳定 | 195.96495209 ± 0.00000099 | 25.2100% ± 0.3400% | 稳定 | stable | |
| 198 稳定 | 197.9678949 ± 0.0000023 | 7.3560% ± 0.1300% | 稳定 | stable |
谱线
已显示50项,共264项。 默认仅显示具有实测强度的谱线。
| 波长(nm) | 强度 | 电离级 | 类型 | 跃迁 | 准确度 | 来源 | |
|---|---|---|---|---|---|---|---|
| 381.86875 nm | 8300 | Pt I | emission | 5d8.6s2 3F → 5d8.6s.(4F).6p a 5G* | 实测值 | NIST | |
| 676.00069 nm | 6500 | Pt I | emission | 5d9.6p 3F* → 5d9.7s 3D | 实测值 | NIST | |
| 530.10143 nm | 3900 | Pt I | emission | 5d8.6s.(4F).6p 5G* → 5d8.(3F<4>).6s.7s.(3S<1>) (4,1) | 实测值 | NIST | |
| 396.6357 nm | 3400 | Pt I | emission | 5d8.6s2 3F → 5d8.6s.(4F).6p a 5D* | 实测值 | NIST | |
| 416.45502 nm | 3300 | Pt I | emission | 5d8.6s2 3F → 5d9.6p 3F* | 实测值 | NIST | |
| 411.86745 nm | 3000 | Pt I | emission | 5d9.6s b 1D → 5d9.6p 3D* | 实测值 | NIST | |
| 652.34376 nm | 3000 | Pt I | emission | 5d9.6p b 3P* → 5d9.7s 1D | 实测值 | NIST | |
| 444.25477 nm | 2400 | Pt I | emission | 5d8.6s2 3F → 5d9.6p a 3P* | 实测值 | NIST | |
| 432.70524 nm | 2300 | Pt I | emission | 5d8.6s.(4F).6p a 5F* → 5d8.(3F<4>).6s.7s.(3S<1>) (4,1) | 实测值 | NIST | |
| 709.475 nm | 2300 | Pt I | emission | 5d8.6s.(4F).6p 3G* → 5d8.(3F<4>).6s.7s.(1S<0>) (4,0) | 实测值 | NIST | |
| 711.37244 nm | 2300 | Pt I | emission | 5d8.6s2 3P → 5d9.6p a 3P* | 实测值 | NIST | |
| 671.03998 nm | 2200 | Pt I | emission | 5d9.6p 3D* → 5d9.7s 1D | 实测值 | NIST | |
| 522.76459 nm | 2100 | Pt I | emission | 5d9.6s b 1D → 5d9.6p a 3P* | 实测值 | NIST | |
| 505.94815 nm | 1900 | Pt I | emission | 5d9.6p a 3P* → 5d9.7s 3D | 实测值 | NIST | |
| 547.57631 nm | 1900 | Pt I | emission | 5d9.6p 3F* → 5d9.7s 3D | 实测值 | NIST | |
| 584.01269 nm | 1800 | Pt I | emission | 5d8.6s2 3F → 5d9.6p a 3P* | 实测值 | NIST | |
| 419.24241 nm | 1700 | Pt I | emission | 5d9.6s b 1D → 5d9.6p b 3P* | 实测值 | NIST | |
| 547.84793 nm | 1500 | Pt I | emission | 5d8.6s.(4F).6p b 5F* → 5d8.(3F<4>).6s.7s.(3S<1>) (4,1) | 实测值 | NIST | |
| 684.25984 nm | 1500 | Pt I | emission | 5d9.6p 3D* → 5d9.7s 3D | 实测值 | NIST | |
| 449.8748 nm | 1100 | Pt I | emission | 5d9.6p 3F* → 5d9.6d 3G | 实测值 | NIST | |
| 539.07754 nm | 1100 | Pt I | emission | 5d9.6p 3F* → 5d9.7s 1D | 实测值 | NIST | |
| 632.6577 nm | 1100 | Pt I | emission | 5d8.6s2 1G → 5d9.6p 3D* | 实测值 | NIST | |
| 584.48054 nm | 1000 | Pt I | emission | 5d8.6s.(4F).6p b 5F* → 5d8.(3F<4>).6s.7s.(3S<1>) (4,1) | 实测值 | NIST | |
| 536.89866 nm | 960 | Pt I | emission | 5d8.6s2 3F → 5d9.6p 3F* | 实测值 | NIST | |
| 631.83662 nm | 930 | Pt I | emission | 5d9.6p 3P* → 5d9.7s 1D | 实测值 | NIST | |
| 602.60247 nm | 860 | Pt I | emission | 5d8.6s.(4F).6p 5F* → 5d8.(3F<4>).6s.7s.(3S<1>) (4,1) | 实测值 | NIST | |
| 695.7507 nm | 800 | Pt I | emission | 5d8.6s.(2F).6p a 3F* → 5d8.(3F<4>).6s.6d b (4,?) | 实测值 | NIST | |
| 455.24119 nm | 730 | Pt I | emission | 5d8.6s.(4F).6p a 5F* → 5d8.(3F<4>).6s.7s.(3S<1>) (4,1) | 实测值 | NIST | |
| 428.80508 nm | 680 | Pt I | emission | 5d8.6s2 3F → 5d8.6s.(2D).6p a 3F* | 实测值 | NIST | |
| 713.16333 nm | 650 | Pt I | emission | 5d8.6s.(2F).6p b 3D* → 5d9.7s 3D | 实测值 | NIST | |
| 689.67056 nm | 590 | Pt I | emission | 5d8.6s.(2F).6p a 3F* → 5d8.(3F<3>).6s.7s.(3S<1>) (3,1) | 实测值 | NIST | |
| 409.22515 nm | 580 | Pt I | emission | 5d8.6s.(4F).6p a 5D* → 5d9.6d a 3G | 实测值 | NIST | |
| 707.8062 nm | 580 | Pt I | emission | 5d8.6s.(4F).6p b 5D* → 5d8.(3F<4>).6s.7s.(3S<1>) (4,1) | 实测值 | NIST | |
| 401.37143 nm | 570 | Pt II | emission | 5d8.6p 76610* → 5d8.(3P).7s (2,1/2) | 实测值 | NIST | |
| 628.34779 nm | 570 | Pt I | emission | 5d8.6s.(2F).6p a 3D* → 5d9.7s 3D | 实测值 | NIST | |
| 683.80564 nm | 560 | Pt I | emission | 5d9.6p 3F* → 5d8.(3F<4>).6s.7s.(3S<1>) (4,1) | 实测值 | NIST | |
| 452.29919 nm | 550 | Pt I | emission | 5d9.6p 3D* → 5d9.6d 1F | 实测值 | NIST | |
| 664.83039 nm | 550 | Pt I | emission | 5d9.6p b 3P* → 5d9.7s 3D | 实测值 | NIST | |
| 703.00606 nm | 540 | Pt I | emission | 5d8.6s.(4P).6p a 5D* → 5d9.7s 3D | 实测值 | NIST | |
| 448.46871 nm | 520 | Pt I | emission | 5d9.6p 3F* → 5d9.6d 3F | 实测值 | NIST | |
| 748.60309 nm | 520 | Pt I | emission | 5d8.6s2 1G → 5d8.6s.(4F).6p a 5D* | 实测值 | NIST | |
| 576.3566 nm | 510 | Pt I | emission | 5d8.6s.(4F).6p a 5D* → 5d9.7s 1D | 实测值 | NIST | |
| 712.5028 nm | 500 | Pt I | emission | 5d7.(4F).6s2.6p a 3G* → 5d8.(3F<4>).6s.6d b (4,?) | 实测值 | NIST | |
| 427.3898 nm | 490 | Pt I | emission | 5d8.6s.(2F).6p a 3D* → 5d9.6d b 3G | 实测值 | NIST | |
| 439.18207 nm | 490 | Pt I | emission | 5d8.6s2 1G → 5d8.6s.(2F).6p a 3D* | 实测值 | NIST | |
| 392.53348 nm | 480 | Pt I | emission | 5d8.6s2 3F → 5d8.6s.(4F).6p 5G* | 实测值 | NIST | |
| 712.2889 nm | 480 | Pt I | emission | 5d8.6s.(4P).6p 5D* → 5d9.7d 3P | 实测值 | NIST | |
| 386.84222 nm | 470 | Pt I | emission | 5d8.6s.(4F).6p b 5F* → 5d8.(3F<4>).6s.6d b (4,?) | 实测值 | NIST | |
| 387.57161 nm | 470 | Pt I | emission | 5d8.6s.(4F).6p b 5F* → 5d8.(3F<4>).6s.6d b (4,?) | 实测值 | NIST | |
| 420.12097 nm | 470 | Pt I | emission | 5d9.6p 3P* → 5d9.7s 3D | 实测值 | NIST |
扩展性质
共价半径(扩展)
- 共价半径(Pyykkö)
- 123 pm
- 共价半径(Pyykkö,双键)
- 112 pm
- 共价半径(Pyykkö,三键)
- 110 pm
范德华半径
- Batsanov
- 205 pm
- Alvarez
- 229 pm
- UFF
- 275.4 pm
- MM3
- 239 pm
原子半径与金属半径
- 原子半径(Rahm)
- 230 pm
- 金属半径(C12)
- 139 pm
编号标度
- Mendeleev
- 69
- Pettifor
- 68
- Glawe
- 64
电负性标度
- Ghosh
- 0
- Miedema
- 6
- Gunnarsson–Lundqvist
- 4
- Robles–Bartolotti
- 3
极化率与色散
- 偶极极化率
- 48 a.u.
- 偶极极化率(不确定度)
- 4 a.u.
- C₆ (Gould–Bučko)
- 470 Ha·Bohr6
Miedema参数
- Miedema摩尔体积
- 9.1 cm3/mol
- Miedema电子密度
- 6
供应风险与经济性
- 生产集中度
- 60
- 相对供应风险
- 8
- 储量分布
- 95
- 政治稳定性(最大生产国)
- 44
- 政治稳定性(最大储量国)
- 44
相变与同素异形体
| 熔点 | 2041.35 K |
| 沸点 | 4098.15 K |
氧化态分类
高级参考数据
屏蔽常数 (14)
| n | 轨道 | σ |
|---|---|---|
| 1 | s | 1.506 |
| 2 | p | 4.4746 |
| 2 | s | 20.3702 |
| 3 | d | 13.5027 |
| 3 | p | 22.1139 |
| 3 | s | 23.0157 |
| 4 | d | 37.37 |
| 4 | f | 38.494 |
| 4 | p | 35.2696 |
| 4 | s | 34.3612 |
晶体半径详情 (4)
| 电荷 | CN | 自旋 | rcrystal (pm) | 来源 |
|---|---|---|---|---|
| 2 | IVSQ | 74 | ||
| 2 | VI | 94 | Ahrens (1952) ionic radius, | |
| 4 | VI | 76.5 | from r^3 vs V plots, | |
| 5 | VI | 71 | estimated, from r^3 vs V plots, |
同位素衰变方式 (67)
| 同位素 | 模式 | 强度 |
|---|---|---|
| 165 | A | 100% |
| 166 | A | 100% |
| 167 | A | 100% |
| 168 | A | 100% |
| 168 | B+ | — |
| 169 | A | 100% |
| 169 | B+ | — |
| 170 | A | 100% |
| 170 | B+ | — |
| 171 | A | 86% |
X射线散射因子 (945)
| 能量 (eV) | f₁ | f₂ |
|---|---|---|
| 0.1 | -0.0027 | 0.00979 |
| 0.13 | -0.0033 | 0.01359 |
| 0.15 | -0.0035 | 0.01538 |
| 0.17 | -0.0037 | 0.01722 |
| 0.2 | -0.0043 | 0.02103 |
| 0.22 | -0.0045 | 0.02279 |
| 0.25 | -0.0051 | 0.02656 |
| 0.28 | -0.0056 | 0.0304 |
| 0.3 | -0.0058 | 0.03194 |
| 0.32 | -0.0058 | 0.03342 |
补充数据
Estimated Crustal Abundance
The estimated element abundance in the earth's crust.
5×10-3 milligrams per kilogram
参考文献 (1)
- [5] Platinum https://education.jlab.org/itselemental/ele078.html
Estimated Oceanic Abundance
The estimated element abundance in the earth's oceans.
Not Applicable
参考文献 (1)
- [5] Platinum https://education.jlab.org/itselemental/ele078.html
Sources
Sources of this element.
Platinum occurs natively, accompanied by small quantities of iridium, osmium, palladium, ruthenium, and rhodium, all belonging to the same group of metals. These are found in the alluvial deposits of the Ural mountains, of Columbia, and of certain western American states. Sperrylite, occurring with the nickel-bearing deposits of Sudbury, Ontario, is the source of a considerable amount of metal.
The large production of nickel makes up for the fact that is only one part of the platinum metals in two million parts of ore.
参考文献 (1)
- [6] Platinum https://periodic.lanl.gov/78.shtml
参考文献
(9)
Data deposited in or computed by PubChem
The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.
Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.
The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.
Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/
The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.
The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database
This section provides all form of data related to element Platinum.
The element property data was retrieved from publications.

