Pt 78

Platinum (Pt)

transition-metal
周期: 6 族: 10 区: d

Solid

标准原子量

195.084 u

电子排布

[Xe] 6s1 4f14 5d9

熔点

1768.4 °C

沸点

3824.85 °C

密度

2.146e+4 kg/m³

氧化态

−3, −2, −1, 0, +1, +2, +3, +4, +5, +6

电负性(鲍林)

2.28

第一电离能

8.95883 eV

发现年份

1735

原子半径

135 pm

详细信息

名称来源 Spanish: platina (little silver).
发现国家 Italy
发现者 Julius Scaliger

Platinum is a dense, silvery-white transition metal in group 10 and a member of the platinum-group elements. It is exceptionally resistant to corrosion and oxidation, yet it can catalyze many reactions at its surface. The metal is chemically noble in bulk but forms well-defined complexes, especially in the +2 and +4 oxidation states. Its combination of durability, catalytic activity, and electrical stability gives it technological importance disproportionate to its crustal abundance.

Platinum is a beautiful silvery-white metal, when pure, and is malleable and ductile. It has a coefficient of expansion almost equal to that of soda-lime-silica glass, and is therefore used to make sealed electrodes in glass systems. The metal does not oxidize in air at any temperature, but is corroded by halogens, cyanides, sulfur, and caustic alkalis.

It is insoluble in hydrochloric and nitric acid, but dissolves when they are mixed as aqua regia, forming chloroplatinic acid.

The name derives from the Spanish platina for "silver". In 1735, the Spanish astronomer Antonio de Ulloa found platinum in Peru, South America. In 1741, the English metallurgist Charles Wood found platinum from Colombia, South America. In 1750, the English physician William Brownrigg prepared purified platinum metal.

Used by the pre-Columbian Indians of South America, platinum wasn't noticed by western scientists until 1735. Platinum can occur free in nature and is sometimes found in deposits of gold-bearing sands, primarily those found in the Ural mountains, Columbia and the western United States. Platinum, in the form of the mineral sperrylite (PtAs2), is also obtained as a byproduct of the nickel mining operation in the Sudbury region of Ontario, Canada. Credit for the modern rediscovery of platinum is usually given to Antonio de Ulloa.

Discovered in South America by Ulloa in 1735 and by Wood in 1741. The metal was used by pre-Columbian Indians.

图片

性质

物理性质

原子半径(经验值)
135 pm 比较所有元素的原子半径(经验值) →
共价半径
136 pm 比较所有元素的共价半径 →
范德华半径
209 pm 比较所有元素的范德华半径 →
金属半径
130 pm 比较所有元素的金属半径 →
密度
2.146 × 104 kg/m³ 比较所有元素的密度 →
摩尔体积
0.0091 L/mol
标准温度和压力下的物相
固态 比较所有元素的标准温度和压力下的物相 →
熔点
1768.4 °C 比较所有元素的熔点 →
沸点
3824.85 °C 比较所有元素的沸点 →
热导率
71.6 W/(m·K) 比较所有元素的热导率 →
比热容
0.133 J/(g·K) 比较所有元素的比热容 →
摩尔热容
25.86 J/(mol·K) 比较所有元素的摩尔热容 →
晶体结构
面心立方 比较所有元素的晶体结构 →

化学性质

电负性(鲍林)
2.28 比较所有元素的电负性(鲍林) →
电负性(Allen)
1.72
电子亲和能
2.1228 eV
第一电离能
8.95883 eV 比较所有元素的第一电离能 →
第二电离能
18.560064 eV 比较所有元素的第二电离能 →
第三电离能
29.0001 eV 比较所有元素的第三电离能 →
第四电离能
43.000148 eV 比较所有元素的第四电离能 →
第五电离能
56.000193 eV 比较所有元素的第五电离能 →
氧化态
−3, −2, −1, 0, +1, +2, +3, +4, +5, +6 比较所有元素的氧化态 →
价电子
10 比较所有元素的价电子 →
电子排布
[Xe] 6s1 4f14 5d9

热力学性质

熔化热
0.20490232 eV 比较所有元素的熔化热 →
汽化热
4.860859 eV 比较所有元素的汽化热 →
升华热
5.845468 eV
原子化热
5.845468 eV
原子化焓
5.863088 eV

核性质

质子
78 比较所有元素的质子 →
中子
116 比较所有元素的中子 →
已知同位素
44 比较所有元素的已知同位素 →
稳定同位素
3 比较所有元素的稳定同位素 →
最稳定同位素
Pt-194
发现年份
1735

丰度

丰度(地壳)
0.005 mg/kg 比较所有元素的丰度(地壳) →

晶体结构

晶格常数a
392 pm

电子结构

各电子层电子数
2, 8, 18, 32, 17, 1 比较所有元素的各电子层电子数 →

标识符

CAS登记号
7440-06-4 比较所有元素的CAS登记号 →
谱项符号
3D3
InChI
InChI=1S/Pt
InChI Key
BASFCYQUMIYNBI-UHFFFAOYSA-N

电子排布 实测值

离子电荷
质子 78
电子 78
电荷 中性
电子排布 Pt: 4f¹⁴ 5d⁹ 6s¹
电子排布
实测值
[Xe] 4f¹⁴ 5d⁹ 6s¹
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d⁹ 6s¹
轨道图
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
2/2
4d
10/10
5p
6/6
6s
1/2 1↑
4f
14/14
5d
9/10 1↑
电子总数: 78 未配对: 2 ?

原子模型

质子 78
中子 116
电子 78
质量数 194
稳定性 稳定

不同同位素的中子数、质量和稳定性不同,但中性原子的电子排布不变。

原子模型示意图,未按比例绘制。

原子指纹

发射 / 吸收光谱

25 / 50 (50 50条具有强度数据)
实测值
发射 可见光:380–750 nm

同位素分布

19432.8600%19625.2100%1987.3560%质量数天然丰度(%)
质量数原子质量(u)天然丰度半衰期
194 稳定193.9626809 ± 0.00000132.8600%稳定
196 稳定195.96495209 ± 0.0000009925.2100%稳定
198 稳定197.9678949 ± 0.00000237.3560%稳定
实测值

物相 / 状态

1 atm / 101.325 kPa
固态 25 °C (298.15 K)

原因: 低于熔点(1768.4 °C)1743.4 °C

熔点 1768.4 °C
沸点 3824.85 °C
低于熔点的温差 1743.4 °C
0 K 当前温度: 25 °C 6000 K
物相变化轴

示意图,未按比例绘制

固态
液态
气态
熔化
沸腾
25°C
固态
液态
气态
当前

相变点

熔点 文献值
1768.4 °C
沸点 文献值
3824.85 °C
当前物相 计算值
固态

相变能

熔化热 文献值
0.20490232 eV

在熔点熔化1 mol物质所需的能量

汽化热 文献值
4.860859 eV

在沸点汽化1 mol物质所需的能量

升华热 文献值
5.845468 eV

在升华点升华1 mol物质所需的能量

密度

参考密度 文献值
2.146e+4 kg/m³

标准条件下

当前密度 计算值
2.146e+4 kg/m³

标准条件下

原子光谱

已显示10项,共78项。 按离子电荷升序排列。

收录谱线 ?

离子电荷谱线总数跃迁概率能级标记
Pt I 0995166995
Pt II +122681832268
Pt IV +3153115311531
Pt V +4172917291729
Pt VI +5146714671467
Pt VII +6786786786
Pt VIII +7360360360
NIST收录谱线 →

收录能级 ?

离子电荷能级
Pt I 0202
Pt II +1282
Pt III +22
Pt IV +3238
Pt V +4259
Pt VI +5251
Pt VII +6178
Pt VIII +780
Pt IX +82
Pt X +92
NIST收录能级 →
78 Pt 195.084

Platinum — 原子轨道可视化工具

[Xe]6s14f145d9
能级 2 8 18 32 17 1
氧化态 -3, -2, -1, 0, +1, +2, +3, +4, +5, +6
HOMO 6s n=6 · l=0 · m=0
Platinum — 原子轨道可视化预览
Three.js仅在需要时加载
78 Pt 195.084

Platinum — 晶体结构可视化工具

Face-Centered Cubic · 皮尔逊符号 cF4
实验数据
皮尔逊符号 cF4
配位数 12
堆积系数 74.000%
Platinum — 晶体结构可视化预览
Three.js仅在需要时加载

离子半径

电荷配位自旋半径
+24暂无60 pm
+26暂无80 pm
+46暂无62.5 pm
+56暂无56.99999999999999 pm

化合物

Pt
195.080 u
Pt+2
195.080 u
Pt+4
195.080 u
Pt
190.962 u
Pt
194.965 u
Pt
198.971 u
Pt
192.963 u
Pt
187.959 u
Pt
185.959 u
Pt
196.967 u
Pt
199.971 u
Pt
188.961 u
Pt+4
194.965 u

同位素 (3)

质量数原子质量(u)天然丰度半衰期衰变方式
194 稳定193.9626809 ± 0.00000132.8600% ± 0.4000%稳定
stable
196 稳定195.96495209 ± 0.0000009925.2100% ± 0.3400%稳定
stable
198 稳定197.9678949 ± 0.00000237.3560% ± 0.1300%稳定
stable
194 稳定
原子质量(u) 193.9626809 ± 0.000001
天然丰度 32.8600% ± 0.4000%
半衰期 稳定
衰变方式
stable
196 稳定
原子质量(u) 195.96495209 ± 0.00000099
天然丰度 25.2100% ± 0.3400%
半衰期 稳定
衰变方式
stable
198 稳定
原子质量(u) 197.9678949 ± 0.0000023
天然丰度 7.3560% ± 0.1300%
半衰期 稳定
衰变方式
stable

谱线

已显示50项,共264项。 默认仅显示具有实测强度的谱线。

波长(nm)强度电离级类型跃迁准确度来源
381.86875 nm8300Pt Iemission5d8.6s2 3F → 5d8.6s.(4F).6p a 5G*实测值NIST
676.00069 nm6500Pt Iemission5d9.6p 3F* → 5d9.7s 3D实测值NIST
530.10143 nm3900Pt Iemission5d8.6s.(4F).6p 5G* → 5d8.(3F<4>).6s.7s.(3S<1>) (4,1)实测值NIST
396.6357 nm3400Pt Iemission5d8.6s2 3F → 5d8.6s.(4F).6p a 5D*实测值NIST
416.45502 nm3300Pt Iemission5d8.6s2 3F → 5d9.6p 3F*实测值NIST
411.86745 nm3000Pt Iemission5d9.6s b 1D → 5d9.6p 3D*实测值NIST
652.34376 nm3000Pt Iemission5d9.6p b 3P* → 5d9.7s 1D实测值NIST
444.25477 nm2400Pt Iemission5d8.6s2 3F → 5d9.6p a 3P*实测值NIST
432.70524 nm2300Pt Iemission5d8.6s.(4F).6p a 5F* → 5d8.(3F<4>).6s.7s.(3S<1>) (4,1)实测值NIST
709.475 nm2300Pt Iemission5d8.6s.(4F).6p 3G* → 5d8.(3F<4>).6s.7s.(1S<0>) (4,0)实测值NIST
711.37244 nm2300Pt Iemission5d8.6s2 3P → 5d9.6p a 3P*实测值NIST
671.03998 nm2200Pt Iemission5d9.6p 3D* → 5d9.7s 1D实测值NIST
522.76459 nm2100Pt Iemission5d9.6s b 1D → 5d9.6p a 3P*实测值NIST
505.94815 nm1900Pt Iemission5d9.6p a 3P* → 5d9.7s 3D实测值NIST
547.57631 nm1900Pt Iemission5d9.6p 3F* → 5d9.7s 3D实测值NIST
584.01269 nm1800Pt Iemission5d8.6s2 3F → 5d9.6p a 3P*实测值NIST
419.24241 nm1700Pt Iemission5d9.6s b 1D → 5d9.6p b 3P*实测值NIST
547.84793 nm1500Pt Iemission5d8.6s.(4F).6p b 5F* → 5d8.(3F<4>).6s.7s.(3S<1>) (4,1)实测值NIST
684.25984 nm1500Pt Iemission5d9.6p 3D* → 5d9.7s 3D实测值NIST
449.8748 nm1100Pt Iemission5d9.6p 3F* → 5d9.6d 3G实测值NIST
539.07754 nm1100Pt Iemission5d9.6p 3F* → 5d9.7s 1D实测值NIST
632.6577 nm1100Pt Iemission5d8.6s2 1G → 5d9.6p 3D*实测值NIST
584.48054 nm1000Pt Iemission5d8.6s.(4F).6p b 5F* → 5d8.(3F<4>).6s.7s.(3S<1>) (4,1)实测值NIST
536.89866 nm960Pt Iemission5d8.6s2 3F → 5d9.6p 3F*实测值NIST
631.83662 nm930Pt Iemission5d9.6p 3P* → 5d9.7s 1D实测值NIST
602.60247 nm860Pt Iemission5d8.6s.(4F).6p 5F* → 5d8.(3F<4>).6s.7s.(3S<1>) (4,1)实测值NIST
695.7507 nm800Pt Iemission5d8.6s.(2F).6p a 3F* → 5d8.(3F<4>).6s.6d b (4,?)实测值NIST
455.24119 nm730Pt Iemission5d8.6s.(4F).6p a 5F* → 5d8.(3F<4>).6s.7s.(3S<1>) (4,1)实测值NIST
428.80508 nm680Pt Iemission5d8.6s2 3F → 5d8.6s.(2D).6p a 3F*实测值NIST
713.16333 nm650Pt Iemission5d8.6s.(2F).6p b 3D* → 5d9.7s 3D实测值NIST
689.67056 nm590Pt Iemission5d8.6s.(2F).6p a 3F* → 5d8.(3F<3>).6s.7s.(3S<1>) (3,1)实测值NIST
409.22515 nm580Pt Iemission5d8.6s.(4F).6p a 5D* → 5d9.6d a 3G实测值NIST
707.8062 nm580Pt Iemission5d8.6s.(4F).6p b 5D* → 5d8.(3F<4>).6s.7s.(3S<1>) (4,1)实测值NIST
401.37143 nm570Pt IIemission5d8.6p 76610* → 5d8.(3P).7s (2,1/2)实测值NIST
628.34779 nm570Pt Iemission5d8.6s.(2F).6p a 3D* → 5d9.7s 3D实测值NIST
683.80564 nm560Pt Iemission5d9.6p 3F* → 5d8.(3F<4>).6s.7s.(3S<1>) (4,1)实测值NIST
452.29919 nm550Pt Iemission5d9.6p 3D* → 5d9.6d 1F实测值NIST
664.83039 nm550Pt Iemission5d9.6p b 3P* → 5d9.7s 3D实测值NIST
703.00606 nm540Pt Iemission5d8.6s.(4P).6p a 5D* → 5d9.7s 3D实测值NIST
448.46871 nm520Pt Iemission5d9.6p 3F* → 5d9.6d 3F实测值NIST
748.60309 nm520Pt Iemission5d8.6s2 1G → 5d8.6s.(4F).6p a 5D*实测值NIST
576.3566 nm510Pt Iemission5d8.6s.(4F).6p a 5D* → 5d9.7s 1D实测值NIST
712.5028 nm500Pt Iemission5d7.(4F).6s2.6p a 3G* → 5d8.(3F<4>).6s.6d b (4,?)实测值NIST
427.3898 nm490Pt Iemission5d8.6s.(2F).6p a 3D* → 5d9.6d b 3G实测值NIST
439.18207 nm490Pt Iemission5d8.6s2 1G → 5d8.6s.(2F).6p a 3D*实测值NIST
392.53348 nm480Pt Iemission5d8.6s2 3F → 5d8.6s.(4F).6p 5G*实测值NIST
712.2889 nm480Pt Iemission5d8.6s.(4P).6p 5D* → 5d9.7d 3P实测值NIST
386.84222 nm470Pt Iemission5d8.6s.(4F).6p b 5F* → 5d8.(3F<4>).6s.6d b (4,?)实测值NIST
387.57161 nm470Pt Iemission5d8.6s.(4F).6p b 5F* → 5d8.(3F<4>).6s.6d b (4,?)实测值NIST
420.12097 nm470Pt Iemission5d9.6p 3P* → 5d9.7s 3D实测值NIST

扩展性质

共价半径(扩展)

共价半径(Pyykkö)
123 pm
共价半径(Pyykkö,双键)
112 pm
共价半径(Pyykkö,三键)
110 pm

范德华半径

Batsanov
205 pm
Alvarez
229 pm
UFF
275.4 pm
MM3
239 pm

原子半径与金属半径

原子半径(Rahm)
230 pm
金属半径(C12)
139 pm

编号标度

Mendeleev
69
Pettifor
68
Glawe
64

电负性标度

Ghosh
0
Miedema
6
Gunnarsson–Lundqvist
4
Robles–Bartolotti
3

极化率与色散

偶极极化率
48 a.u.
偶极极化率(不确定度)
4 a.u.
C₆ (Gould–Bučko)
470 Ha·Bohr6

Miedema参数

Miedema摩尔体积
9.1 cm3/mol
Miedema电子密度
6

供应风险与经济性

生产集中度
60
相对供应风险
8
储量分布
95
政治稳定性(最大生产国)
44
政治稳定性(最大储量国)
44

相变与同素异形体

熔点2041.35 K
沸点4098.15 K

氧化态分类

−3 extended
+6 extended
+1 extended
−2 extended
−1 extended
+3 extended
+5 extended
+2 main
+4 main
0 extended

高级参考数据

屏蔽常数 (14)
n轨道σ
1s1.506
2p4.4746
2s20.3702
3d13.5027
3p22.1139
3s23.0157
4d37.37
4f38.494
4p35.2696
4s34.3612
晶体半径详情 (4)
电荷CN自旋rcrystal (pm)来源
2IVSQ74
2VI94Ahrens (1952) ionic radius,
4VI76.5from r^3 vs V plots,
5VI71estimated, from r^3 vs V plots,
同位素衰变方式 (67)
同位素模式强度
165A100%
166A100%
167A100%
168A100%
168B+—
169A100%
169B+—
170A100%
170B+—
171A86%
X射线散射因子 (945)
能量 (eV)f₁f₂
0.1-0.00270.00979
0.13-0.00330.01359
0.15-0.00350.01538
0.17-0.00370.01722
0.2-0.00430.02103
0.22-0.00450.02279
0.25-0.00510.02656
0.28-0.00560.0304
0.3-0.00580.03194
0.32-0.00580.03342

补充数据

Sources

Sources of this element.

Platinum occurs natively, accompanied by small quantities of iridium, osmium, palladium, ruthenium, and rhodium, all belonging to the same group of metals. These are found in the alluvial deposits of the Ural mountains, of Columbia, and of certain western American states. Sperrylite, occurring with the nickel-bearing deposits of Sudbury, Ontario, is the source of a considerable amount of metal.

The large production of nickel makes up for the fact that is only one part of the platinum metals in two million parts of ore.

参考文献 (1)

参考文献

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
Pt

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Platinum

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

许可证说明: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Platinum

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

许可证说明: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Platinum

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Platinum

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Platinum

This section provides all form of data related to element Platinum.

9 PubChem Elements
Platinum

The element property data was retrieved from publications.

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