K 19

Potassium (K)

alkali-metal
周期: 4 族: 1 区: s

Solid

标准原子量

39.0983 u

电子排布

[Ar] 4s1

熔点

63.38 °C

沸点

758.85 °C

密度

890 kg/m³

氧化态

−1, +1

电负性(鲍林)

0.82

第一电离能

4.340664 eV

发现年份

1807

原子半径

220 pm

详细信息

名称来源 English: pot ash; symbol from Latin: kalium, (alkali).
发现国家 England
发现者 Sir Humphrey Davy

Potassium is an alkali metal and a major rock-forming and biological element. It occurs naturally only in compounds, chiefly as K⁺ in salts, feldspars, micas, and clay minerals. The metal is highly electropositive, reacts vigorously with water, and is stored away from air and moisture. In living cells, potassium is the principal intracellular cation and is central to osmotic balance and electrical signaling.

It is one of the most reactive and electropositive of metals. Except for lithium, it is the lightest known metal. It is soft, easily cut with a knife, and is silvery in appearance immediately after a fresh surface is exposed. It rapidly oxidizes in air and must be preserved in a mineral oil such as kerosene.

As with other metals of the alkali group, it decomposes in water with the evolution of hydrogen. It catches fire spontaneously on water. Potassium and its salts impart a violet color to flames.

The name derives from the English "potash" or "pot ashes" because it is found in caustic potash (KOH). The symbol K derives from the Latin kalium via the Arabic qali for alkali. It was first isolated by the British chemist Humphry Davy in 1807 from electrolysis of potash (KOH).

Although potassium is the eighth most abundant element on earth and comprises about 2.1% of the earth's crust, it is a very reactive element and is never found free in nature. Metallic potassium was first isolated by Sir Humphry Davy in 1807 through the electrolysis of molten caustic potash (KOH). A few months after discovering potassium, Davy used the same method to isolate sodium. Potassium can be obtained from the minerals sylvite (KCl), carnallite (KCl·MgCl2·6H2O), langbeinite (K2Mg2(SO4)3) and polyhalite (K2Ca2Mg(SO4)4·2H2O). These minerals are often found in ancient lake and sea beds. Caustic potash, another important source of potassium, is primarily mined in Germany, New Mexico, California and Utah. Pure potassium is a soft, waxy metal that can be easily cut with a knife. It reacts with oxygen to form potassium superoxide (KO2) and with water to form potassium hydroxide (KOH), hydrogen gas and heat. Enough heat is produced to ignite the hydrogen gas. To prevent it from reacting with the oxygen and water in the air, samples of metallic potassium are usually stored submerged in mineral oil.

From the English word, potash - pot ashes; Latin kalium, Arab qali, alkali. Discovered in 1807 by Davy, who obtained it from caustic potash (KOH); this was the first metal isolated by electrolysis.

图片

性质

物理性质

原子半径(经验值)
220 pm 比较所有元素的原子半径(经验值) →
共价半径
203 pm 比较所有元素的共价半径 →
范德华半径
275 pm 比较所有元素的范德华半径 →
金属半径
203 pm 比较所有元素的金属半径 →
密度
890 kg/m³ 比较所有元素的密度 →
摩尔体积
0.0453 L/mol
标准温度和压力下的物相
固态 比较所有元素的标准温度和压力下的物相 →
熔点
63.38 °C 比较所有元素的熔点 →
沸点
758.85 °C 比较所有元素的沸点 →
热导率
79 W/(m·K) 比较所有元素的热导率 →
比热容
0.757 J/(g·K) 比较所有元素的比热容 →
摩尔热容
29.6 J/(mol·K) 比较所有元素的摩尔热容 →
晶体结构
体心立方 比较所有元素的晶体结构 →

化学性质

电负性(鲍林)
0.82 比较所有元素的电负性(鲍林) →
电负性(Allen)
0.734
电子亲和能
0.5014 eV
第一电离能
4.340664 eV 比较所有元素的第一电离能 →
第二电离能
31.625109 eV 比较所有元素的第二电离能 →
第三电离能
45.803258 eV 比较所有元素的第三电离能 →
第四电离能
60.91721 eV 比较所有元素的第四电离能 →
第五电离能
82.660285 eV 比较所有元素的第五电离能 →
氧化态
−1, +1 比较所有元素的氧化态 →
价电子
1 比较所有元素的价电子 →
电子排布
[Ar] 4s1

热力学性质

临界点(温度)
1950 °C
临界点(压力)
1.6e+7 Pa
熔化热
0.02414883 eV 比较所有元素的熔化热 →
汽化热
0.79701508 eV 比较所有元素的汽化热 →
升华热
0.92449604 eV
原子化热
0.92449604 eV
原子化焓
0.92242317 eV

核性质

质子
19 比较所有元素的质子 →
中子
20 比较所有元素的中子 →
已知同位素
29 比较所有元素的已知同位素 →
稳定同位素
2 比较所有元素的稳定同位素 →
最稳定同位素
K-39
发现年份
1807

丰度

丰度(地壳)
2.09e+4 mg/kg 比较所有元素的丰度(地壳) →
丰度(海洋)
399 mg/L 比较所有元素的丰度(海洋) →

晶体结构

晶格常数a
523 pm

电子结构

各电子层电子数
2, 8, 8, 1 比较所有元素的各电子层电子数 →

标识符

CAS登记号
7440-09-7 比较所有元素的CAS登记号 →
谱项符号
2S1/2
InChI
InChI=1S/K
InChI Key
ZLMJMSJWJFRBEC-UHFFFAOYSA-N

电子排布 实测值

离子电荷
质子 19
电子 19
电荷 中性
电子排布 K: 4s¹
电子排布
实测值
[Ar] 4s¹
1s² 2s² 2p⁶ 3s² 3p⁶ 4s¹
轨道图
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
1/2 1↑
电子总数: 19 未配对: 1 ?

原子模型

质子 19
中子 20
电子 19
质量数 39
稳定性 稳定

不同同位素的中子数、质量和稳定性不同,但中性原子的电子排布不变。

原子模型示意图,未按比例绘制。

原子指纹

发射 / 吸收光谱

25 / 50 (50 50条具有强度数据)
实测值
发射 可见光:380–750 nm

同位素分布

3993.2581%416.7302%质量数天然丰度(%)
质量数原子质量(u)天然丰度半衰期
39 稳定38.9637064864 ± 0.000000004993.2581%稳定
41 稳定40.9618252579 ± 0.00000000416.7302%稳定
实测值

物相 / 状态

1 atm / 101.325 kPa
固态 25 °C (298.15 K)

原因: 低于熔点(63.38 °C)38.4 °C

熔点 63.38 °C
沸点 758.85 °C
低于熔点的温差 38.4 °C
0 K 当前温度: 25 °C 6000 K
物相变化轴

示意图,未按比例绘制

固态
液态
气态
熔化
沸腾
25°C
固态
液态
气态
当前

相变点

熔点 文献值
63.38 °C
沸点 文献值
758.85 °C
当前物相 计算值
固态

相变能

熔化热 文献值
0.02414883 eV

在熔点熔化1 mol物质所需的能量

汽化热 文献值
0.79701508 eV

在沸点汽化1 mol物质所需的能量

升华热 文献值
0.92449604 eV

在升华点升华1 mol物质所需的能量

密度

参考密度 文献值
890 kg/m³

标准条件下

当前密度 计算值
890 kg/m³

标准条件下

高级

临界点 文献值
1950 °C

原子光谱

已显示10项,共22项。 按离子电荷升序排列。

收录能级 ?

离子电荷能级
41K I 同位素08
40K I 同位素03
39K I 同位素0123
K I 0299
K II +197
K III +240
K IV +338
K V +440
K VI +528
K VII +681
NIST收录能级 →
19 K 39.0983

Potassium — 原子轨道可视化工具

[Ar]4s1
能级 2 8 8 1
氧化态 -1, +1
HOMO 4s n=4 · l=0 · m=0
Potassium — 原子轨道可视化预览
Three.js仅在需要时加载
19 K 39.0983

Potassium — 晶体结构可视化工具

体心立方 · 皮尔逊符号 cI2
实验数据
皮尔逊符号 cI2
配位数 8
堆积系数 68.000%
Potassium — 晶体结构可视化预览
Three.js仅在需要时加载

离子半径

电荷配位自旋半径
+14暂无137 pm
+16暂无138 pm
+17暂无146 pm
+18暂无151 pm
+19暂无155 pm
+110暂无159 pm
+112暂无164 pm

化合物

K+
39.098 u
K
39.098 u
K
39.964 u
K
42.961 u
K
41.962 u
K
37.969 u
K
38.964 u
K
43.962 u
K
44.961 u
K+
39.964 u
K+
37.969 u
K+
38.964 u
K+
42.961 u
K+
41.962 u
K
40.962 u

同位素 (2)

Seventeen isotopes of potassium are known. Ordinary potassium is composed of three isotopes, one of which is 40°K (0.0118%), a radioactive isotope with a half-life of 1.28 x 109 years.

质量数原子质量(u)天然丰度半衰期衰变方式
39 稳定38.9637064864 ± 0.000000004993.2581% ± 0.0044%稳定
stable
41 稳定40.9618252579 ± 0.00000000416.7302% ± 0.0044%稳定
stable
39 稳定
原子质量(u) 38.9637064864 ± 0.0000000049
天然丰度 93.2581% ± 0.0044%
半衰期 稳定
衰变方式
stable
41 稳定
原子质量(u) 40.9618252579 ± 0.0000000041
天然丰度 6.7302% ± 0.0044%
半衰期 稳定
衰变方式
stable

谱线

已显示50项,共141项。 默认仅显示具有实测强度的谱线。

波长(nm)强度电离级类型跃迁准确度来源
693.8764 nm20K Iemission3p6.4p 2P* → 3p6.6s 2S实测值NIST
691.10815 nm19K Iemission3p6.4p 2P* → 3p6.6s 2S实测值NIST
404.41422 nm18K Iemission3p6.4s 2S → 3p6.5p 2P*实测值NIST
404.72132 nm17K Iemission3p6.4s 2S → 3p6.5p 2P*实测值NIST
580.17662 nm17K Iemission3p6.4p 2P* → 3p6.7s 2S实测值NIST
583.18899 nm17K Iemission3p6.4p 2P* → 3p6.5d 2D实测值NIST
578.23999 nm16K Iemission3p6.4p 2P* → 3p6.7s 2S实测值NIST
581.21521 nm15K Iemission3p6.4p 2P* → 3p6.5d 2D实测值NIST
535.95761 nm14K Iemission3p6.4p 2P* → 3p6.6d 2D实测值NIST
533.96873 nm13K Iemission3p6.4p 2P* → 3p6.8s 2S实测值NIST
511.225448 nm12K Iemission3p6.4p 2P* → 3p6.7d 2D实测值NIST
532.32786 nm12K Iemission3p6.4p 2P* → 3p6.8s 2S实测值NIST
534.29693 nm12K Iemission3p6.4p 2P* → 3p6.6d 2D实测值NIST
693.62861 nm12K Iemission3p6.4p 2P* → 3p6.4d 2D实测值NIST
696.46903 nm12K Iemission3p6.4p 2P* → 3p6.4d 2D实测值NIST
464.23725 nm11K Iemission3p6.4s 2S → 3p6.3d 2D实测值NIST
509.717137 nm11K Iemission3p6.4p 2P* → 3p6.7d 2D实测值NIST
509.920005 nm11K Iemission3p6.4p 2P* → 3p6.9s 2S实测值NIST
464.1875 nm10K Iemission3p6.4s 2S → 3p6.3d 2D实测值NIST
496.503213 nm10K Iemission3p6.4p 2P* → 3p6.8d 2D实测值NIST
508.423399 nm10K Iemission3p6.4p 2P* → 3p6.9s 2S实测值NIST
482.924 nm9K IIemission3p5.4s 3P* → 3p5.4p 3S实测值NIST
486.975897 nm9K Iemission3p6.4p 2P* → 3p6.9d 2D实测值NIST
495.081801 nm9K Iemission3p6.4p 2P* → 3p6.8d 2D实测值NIST
495.614802 nm9K Iemission3p6.4p 2P* → 3p6.10s 2S实测值NIST
389.7896 nm8K IIemission3p5.4s 3P* → 3p5.4p 1D实测值NIST
418.6232 nm8K IIemission3p5.4s 3P* → 3p5.4p 3D实测值NIST
460.849 nm8K IIemission3p5.4s 1P* → 3p5.4p 1D实测值NIST
480.43395 nm8K Iemission3p6.4p 2P* → 3p6.10d 2D实测值NIST
485.609209 nm8K Iemission3p6.4p 2P* → 3p6.9d 2D实测值NIST
486.348075 nm8K Iemission3p6.4p 2P* → 3p6.11s 2S实测值NIST
500.564 nm8K IIemission3p5.4s 3P* → 3p5.4p 3S实测值NIST
612.028 nm8K IIemission3p5.3d 3F* → 3p5.4p 3D实测值NIST
381.7547 nm7K IIemission3p5.4p 3D → 3p5.(2P*<3/2>).5s 2[3/2]*实测值NIST
400.122 nm7K IIemission3p5.4s 3P* → 3p5.4p 3P实测值NIST
413.4705 nm7K IIemission3p5.4s 3P* → 3p5.4p 3D实测值NIST
422.296 nm7K IIemission3p5.4s 1P* → 3p5.4p 3P实测值NIST
422.566 nm7K IIemission3p5.3d 3P* → 3p5.4p 1D实测值NIST
426.334 nm7K IIemission3p5.4s 3P* → 3p5.4p 3D实测值NIST
430.498 nm7K IIemission3p5.3d 3P* → 3p5.4p 1D实测值NIST
430.911 nm7K IIemission3p5.4s 1P* → 3p5.4p 3P实测值NIST
438.816 nm7K IIemission3p5.4s 1P* → 3p5.4p 1P实测值NIST
475.737719 nm7K Iemission3p6.4p 2P* → 3p6.11d 2D实测值NIST
479.104132 nm7K Iemission3p6.4p 2P* → 3p6.10d 2D实测值NIST
484.98645 nm7K Iemission3p6.4p 2P* → 3p6.11s 2S实测值NIST
505.625 nm7K IIemission3p5.3d 3P* → 3p5.4p 3S实测值NIST
630.728 nm7K IIemission3p5.3d 3F* → 3p5.4p 3D实测值NIST
696.41712 nm7K Iemission3p6.4p 2P* → 3p6.4d 2D实测值NIST
380.0162 nm6K IIemission3p5.4p 3D → 3p5.(2P*<3/2>).5s 2[3/2]*实测值NIST
381.657 nm6K IIemission3p5.4p 3P → 3p5.4d 3P*实测值NIST

扩展性质

共价半径(扩展)

共价半径(Pyykkö)
196 pm
共价半径(Pyykkö,双键)
193 pm
共价半径(Bragg)
207 pm

范德华半径

Bondi
275 pm
Batsanov
280 pm
Alvarez
273 pm
UFF
381.2 pm
MM3
309 pm

原子半径与金属半径

原子半径(Rahm)
234 pm
金属半径(C12)
235 pm

编号标度

Mendeleev
3
Pettifor
10
Glawe
10

电负性标度

Ghosh
0
Miedema
2
Gunnarsson–Lundqvist
2
Robles–Bartolotti
1

极化率与色散

偶极极化率
289.7 a.u.
偶极极化率(不确定度)
0.3 a.u.
C₆
3923 Ha·Bohr6
C₆ (Gould–Bučko)
3910 Ha·Bohr6

Miedema参数

Miedema摩尔体积
45.63 cm3/mol
Miedema电子密度
0

供应风险与经济性

生产集中度
21
相对供应风险
5
储量分布
61
政治稳定性(最大生产国)
81
政治稳定性(最大储量国)
81

相变与同素异形体

熔点336.65 K
沸点1032.15 K
临界点(温度)2223.15 K
临界点(压力)16 MPa

氧化态分类

+1 main
−1 extended

高级参考数据

屏蔽常数 (6)
n轨道σ
1s0.5105
2p3.9728
2s5.9938
3p11.2744
3s10.3201
4s15.5048
晶体半径详情 (7)
电荷CN自旋rcrystal (pm)来源
1IV151
1VI152
1VII160
1VIII165
1IX169
1X173
1XII178
同位素衰变方式 (53)
同位素模式强度
313p100%
32p—
33p—
34p—
35B+100%
35B+p0.4%
36B+100%
36B+p0%
36B+A0%
37B+100%
X射线散射因子 (503)
能量 (eV)f₁f₂
10—0.03426
10.1617—0.03529
10.3261—0.03635
10.4931—0.03744
10.6628—0.03856
10.8353—0.03972
11.0106—0.04091
11.1886—0.04214
11.3696—0.0434
11.5535—0.04471

补充数据

Sources

Sources of this element.

The metal is the seventh most abundant and makes up about 2.4% by weight of the earth's crust. Most potassium minerals are insoluble and the metal is obtained from them only with great difficulty.

Certain minerals, however, such as sylvite, carnallite, langbeinite, and polyhalite are found in ancient lake and sea beds and form rather extensive deposits from which potassium and its salts can readily be obtained. Potash is mined in Germany, New Mexico, California, Utah, and elsewhere. Large deposits of potash, found at a depth of some 3000 ft in Saskatchewan, promise to be important in coming years.

Potassium is also found in the ocean, but is present only in relatively small amounts, compared to sodium.

参考文献 (1)

Production

Production of this element (from raw materials or other compounds containing the element).

Potassium is never found free in nature, but is obtained by electrolysis of the hydroxide, much in the same manner as prepared by Davy's first process. Thermal methods also are commonly used to produce potassium (such as by reduction of potassium compounds with CaC2, C, Si, or Na).

参考文献 (1)

参考文献

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
K

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Potassium

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

许可证说明: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Potassium

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

许可证说明: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Potassium

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Potassium

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Potassium

This section provides all form of data related to element Potassium.

9 PubChem Elements
Potassium

The element property data was retrieved from publications.

最后更新:

数据已核实:

内容已依据最新科学数据进行审核。