Thorium (Th)
actinideSolid
Nguyên tử khối chuẩn
232,0377 uCấu hình electron
[Rn] 7s2 6d2Nhiệt độ nóng chảy
1749,85 °CNhiệt độ sôi
4787,85 °CKhối lượng riêng
1,172e+4 kg/m³Trạng thái oxi hóa
−1, +1, +2, +3, +4Độ âm điện (Pauling)
1,3Năng lượng ion hóa (lần 1)
6,3067 eVNăm phát hiện
1828Bán kính nguyên tử
180 pmChi tiết
Thorium is a naturally occurring actinide metal with atomic number 90. It is weakly radioactive and is found mainly as ²³²Th, an isotope with a very long half-life. Chemically it is dominated by the +4 oxidation state and often resembles the tetravalent lanthanides more than uranium or plutonium. Its main technological interest is as a fertile nuclear material that can be converted to fissile ²³³U in reactors.
When pure, thorium is a silvery-white metal that is air-stable and retains its luster for several months. When contaminated with the oxide, thorium slowly tarnishes in air, becoming gray and finally black. The physical properties of thorium are greatly influenced by the degree of contamination with the oxide. The purest specimens often contain several tenths of a percent of the oxide. High-purity thorium has been made. Pure thorium is soft, very ductile, and can be cold-rolled, swaged, and drawn. Thorium is dimorphic, changing at 1400°C from a cubic to a body-centered cubic structure. Thorium oxide has a melting point of 3300°C, which is the highest of all oxides. Only a few elements, such as tungsten, and a few compounds, such as tantalum carbide, have higher melting points. Thorium is slowly attacked by water, but does not dissolve readily in most common acids, except hydrochloric. Powdered thorium metal is often pyrophoric and should be handled carefully. When heated in air, thorium turnings ignite and burn brilliantly with a white light.
The name derives from Thor, the Scandinavian god of thunder. It was discovered in the mineral thorite (ThSiO4) by the Swedish chemist Jöns Jacob Berzelius in 1828. Thorium was first isolated by the chemists D. Lely, Jr. and L. Hamburger in 1914.
Thorium was discovered by Jöns Jacob Berzelius, a Swedish chemist, in 1828. He discovered it in a sample of a mineral that was given to him by the Reverend Has Morten Thrane Esmark, who suspected that it contained an unknown substance. Esmark's mineral is now known as thorite (ThSiO4). Thorium makes up about 0.0007% of the earth's crust and is primarily obtained from thorite, thorianite (ThO2) and monazite ((Ce, La, Th, Nd, Y)PO4).
Morten Esmark found a black mineral on Løvøya island, Norway and gave a sample to his father Jens Esmark, a noted mineralogist. The elder Esmark was not able to identify it and sent a sample to Swedish chemist Jöns Jakob Berzelius for examination in 1828. In 1829 Berzelius determined that it contained a new element, which he named thorium after Thor, the Norse god of thunder. The metal had no practical uses until 1885 when Carl Auer von Welsbach invented the gas mantle. Thorium was first observed to be radioactive in 1898, independently, by Polish-French physicist Marie Curie and German chemist Gerhard Carl Schmidt. Between 1900 and 1903, Ernest Rutherford and Frederick Soddy showed how thorium decayed at a fixed rate over time into a series of other elements. This observation led to the identification of half-life as one of the outcomes of the alpha particle experiments that led to their disintegration theory of radioactivity. The crystal bar process (or "iodide process") was discovered by Anton Eduard van Arkel and Jan Hendrik de Boer in 1925 to produce high-purity metallic thorium. Because of health concerns, the thorium in classic lantern mantles has been replaced by rare-earth elements that also produce intense light without the radioactivity.
Pure thorium is a silvery, soft, ductile metal when freshly prepared. It tarnishes slowly in air, forming a protective oxide film, and finely divided material can be more reactive. Macroscopic metal is uncommon outside specialized laboratories and nuclear materials work.
Thorium dioxide has been used in high-temperature ceramics, laboratory crucibles, optical glass, and older incandescent gas mantles, although most such uses have declined because of radioactivity controls. Small additions of thorium to tungsten improved electron emission in thoriated welding electrodes and some vacuum-tube components. Thorium is also studied as a fertile fuel material in nuclear systems, but it is not a widely deployed commercial reactor fuel.
Thorium is used as an alloying agent to improve magnesium's strength at high temperatures. Thorium is also used to coat tungsten filaments used in electronic devices, such at television sets. When bombarded with neutrons, thorium-232 becomes thorium-233, which eventually decays into uranium-233 through a series of beta decays. Uranium-233 is a fissionable material and can be used as a nuclear fuel.
Thorium oxide (ThO2), one of thorium's compounds, has many uses. It is primarily used in a type of lantern mantel known as a Welsbach mantle. This mantle, which also contains about 1% cerium oxide, glows with a bright white light when it is heated in a gas flame. Thorium oxide has a very high melting point, about 3300°C, and is used to make high temperature crucibles. Thorium oxide is also used to make glass with a high index of refraction that is used to make high quality camera lenses. Thorium oxide is used as a catalyst in the production of sulfuric acid (H2SO4), in the cracking of petroleum products and in the conversion of ammonia (NH3) to nitric acid (HNO3).
Thorium's most stable isotope, thorium-232, has a half-life of about 14,050,000,000 years. It decays into radium-228 through alpha decay or decays through spontaneous fission.
The principal historic use of thorium has been in the preparation of the Welsbach mantle, used for portable gaslights. These mantles, consisting of thorium oxide with about 1% cerium oxide and other ingredients, glow with a dazzling light when heated in a gas flame. Thorium is an important alloying element in magnesium, imparting high strength and creep resistance at elevated temperatures. Because thorium has a low work-function and high electron emission, it is used to coat tungsten wire used in electronic equipment. The oxide is also used to control the grain size of tungsten used for electric lamps; it is also used for high-temperature laboratory crucibles. Glasses containing thorium oxide have a high refractive index and low dispersion. Consequently, they find application in high quality lenses for cameras and scientific instruments. Thorium oxide has also found use as a catalyst in the conversion of ammonia to nitric acid, in petroleum cracking, and in producing sulfuric acid. Thorium metal is a source of nuclear power. There is probably more energy available for use from thorium in the minerals of the earth's crust than from both uranium and fossil fuels. Any sizable demand from thorium as a nuclear fuel is still several years in the future. Work has been done in developing thorium cycle converter-reactor systems. Several prototypes, including the HTGR (high-temperature gas-cooled reactor) and MSRE (molten salt converter reactor experiment), have operated. While the HTGR reactors are efficient, they are not expected to become important commercially for many years because of certain operating difficulties.
Isotopes in Earth/Planetary Science
234Th (with a half-life of 24 days) has been used as a tracer for estimating the flux of organic carbon in the ocean (Fig. IUPAC.90.1) [589] B. Ghaleb. IOP Conf. Ser. Earth Environ. Sci.5, (2009)., [590] J. K. Cochran, K. O. Buesseler, M. P. Bacon, H. W. Wang, D. J. Hirschberg, L. Ball, J. Andrews, G. Crossin, A. Fleer. Deep-Sea Res. II47, 3451 (2000).. 234Th has been used for estimating the residence time of suspended particulate matter (SPM) in water columns [589] B. Ghaleb. IOP Conf. Ser. Earth Environ. Sci.5, (2009)..
Isotopes in Geochronology
The decay of 232Th (with a half-life of 1.40×1010 years) to 208Pb is used to date rocks based on the accumulation of the stable daughter product 208Pb. The half-lives of the isotopes between the parent radionuclide 232Th and stable endpoint 208Pb all have much shorter half-lives than thorium. Therefore, the amount of 208Pb that accumulates in a sample is determined primarily by the amount of 232Th parent radionuclide present when the mineral was formed and the time that has elapsed since the mineral solidified [591] R. R. Parrish, S. R. Noble. Rev. Mineral. Geochem.53, 183 (2003)..
Another dating method, the 230Th/ 234U method, is based on the hypothesis that the sample contains uranium, but no 230Th at the time of its formation. Then, the age of the specimen is determined mainly by the amount of 230Th in the specimen. Reliable ages with this method range from several thousand to approximately 350 thousand years [292] M. A. Geyh, H. Schleicher. Absolute Age Determination: Physical and Chemical Dating Methods and Their Application, p. 503, Springer-Verlag, Berlin (1990)..
Isotopes in Industry
The most precise time and frequency measurements are performed with optical atomic clocks that use as a frequency standard the optical frequency generated as electrons change energy levels. It has been proposed that a nuclear clock, using a nuclear transition could outperform an electron transition. 229mTh, with a half-life of 13.9 h, has been confirmed as a possible candidate for a nuclear clock [592] L. von der Wense, B. Seiferle, M. Laatiaoui, J. B. Neumayr, H. J. Maier, H. F. Wirth, C. Mokry, J. Runke, K. Eberhardt, C. E. Düllmann, N. G. Trautmann, P. G. Thirolf. Nature533, 47 (2016).. The m in 229mTh indicates a metastable state of the isotope. The further development of a nuclear frequency standard will require more precise determinations of the energy and half-life of the isomer.
Thorium chemistry is strongly centered on Th⁴⁺. Thorium dioxide, ThO₂, is a very refractory oxide with high melting point and low solubility, important in ceramics and nuclear fuel research. Thorium nitrate, Th(NO₃)₄, was historically used to impregnate gas mantles. Thorium tetrafluoride, ThF₄, and thorium tetrachloride, ThCl₄, are representative halides and intermediates in metal preparation or molten-salt chemistry. Lower oxidation states are uncommon and generally require strongly reducing conditions.
See more information at the Thorium compound page.
Thorium is an alpha-emitting radioactive element, and the hazard depends on isotope, chemical form, and route of exposure. External radiation from bulk ²³²Th is usually limited, but inhaled or ingested dust can deliver internal alpha dose, especially as decay products accumulate. Thorium compounds are also heavy-metal toxicants. Machining, powder handling, and legacy mantles or electrodes require controls for contamination and radioactive waste.
Thorium occurs naturally in trace to minor amounts in many rocks and soils, chiefly in resistant minerals such as monazite and thorite. Th⁴⁺ is relatively immobile under many surface conditions because it hydrolyzes strongly and binds to oxides, phosphates, and organic matter. Weathering tends to concentrate thorium in heavy-mineral sands and sediments rather than in groundwater. It has no known biological function.
Thorium is not traded as a major commodity metal. It is obtained mainly as a by-product or potential by-product of rare-earth and heavy-mineral processing, especially from monazite concentrates, where radioactivity can complicate handling and permitting. Demand is limited because many former applications have been replaced by nonradioactive materials. Nuclear-fuel interest has led to research stocks and pilot-scale processing, but no large, mature thorium fuel market exists. Recycling is mostly relevant to controlled industrial or nuclear materials rather than general commerce.
Thorium-232 is a primordial nuclide, having existed in its current form for over 4.5 billion years, a half-life is comparable to the age of the Universe and thus predating the formation of the Earth. Thorium was forged in the cores of dying stars through the r-process and scattered across the galaxy by supernovas. Thorium is found in small amounts in most rocks and soils. Soil commonly contains an average of around 6 parts per million (ppm) of thorium. Thorium occurs in several minerals including thorite (ThSiO4), thorianite (ThO2 + UO2) and monazite. Thorianite is a rare mineral and may contain up to about 12% thorium oxide. Monazite contains 2.5% thorium, allanite has 0.1 to 2% thorium and zircon can have up to 0.4% thorium.[66] Thorium-containing minerals occur on all continents. Thorium is now thought to be about three times as abundant as uranium and about as abundant as lead or molybdenum. Thorium is recovered commercially from the mineral monazite, which contains from 3 to 9% ThO2 along with rare-earth minerals.
Thorium is produced in the rapid neutron-capture process and is one of the longest-lived naturally occurring radioactive elements heavier than bismuth. Its abundance in the Solar System is low, but it is measurable in meteorites, lunar samples, and stellar spectra. Ratios involving thorium and other r-process elements are used in cosmochronology because ²³²Th decays on a timescale comparable to the age of the universe.
- Nearly all natural thorium is ²³²Th, with a half-life of about 14 billion years.
- Thorium dioxide, ThO₂, is among the most refractory known oxides.
- Old gas mantles could contain enough thorium to be measurably radioactive.
- Thorium metal powder can present both radiological and pyrophoric hazards.
- The thorium fuel cycle breeds fissile ²³³U rather than using thorium itself as a fissile nuclide.
Hình ảnh
Tính chất
Vật lý
- Bán kính nguyên tử (thực nghiệm)
- 180 pm So sánh Bán kính nguyên tử (thực nghiệm) của tất cả nguyên tố →
- Bán kính cộng hóa trị
- 206 pm So sánh Bán kính cộng hóa trị của tất cả nguyên tố →
- Bán kính van der Waals
- 237 pm So sánh Bán kính van der Waals của tất cả nguyên tố →
- Khối lượng riêng
- 1,172 × 104 kg/m³ So sánh Khối lượng riêng của tất cả nguyên tố →
- Thể tích mol
- 0,0198 L/mol
- Pha ở STP
- Rắn So sánh Pha ở STP của tất cả nguyên tố →
- Nhiệt độ nóng chảy
- 1749,85 °C So sánh Nhiệt độ nóng chảy của tất cả nguyên tố →
- Nhiệt độ sôi
- 4787,85 °C So sánh Nhiệt độ sôi của tất cả nguyên tố →
- Nhiệt dung riêng
- 0,118 J/(g·K) So sánh Nhiệt dung riêng của tất cả nguyên tố →
- Nhiệt dung mol
- 27,32 J/(mol·K) So sánh Nhiệt dung mol của tất cả nguyên tố →
- Cấu trúc tinh thể
- Lập phương tâm mặt So sánh Cấu trúc tinh thể của tất cả nguyên tố →
Hóa học
- Độ âm điện (Pauling)
- 1,3 So sánh Độ âm điện (Pauling) của tất cả nguyên tố →
- Ái lực electron
- 0,607 eV
- Năng lượng ion hóa (lần 1)
- 6,3067 eV So sánh Năng lượng ion hóa (lần 1) của tất cả nguyên tố →
- Năng lượng ion hóa (lần 2)
- 12,100042 eV So sánh Năng lượng ion hóa (lần 2) của tất cả nguyên tố →
- Năng lượng ion hóa (lần 3)
- 18,320063 eV So sánh Năng lượng ion hóa (lần 3) của tất cả nguyên tố →
- Năng lượng ion hóa (lần 4)
- 28,648099 eV So sánh Năng lượng ion hóa (lần 4) của tất cả nguyên tố →
- Năng lượng ion hóa (lần 5)
- 58,0002 eV So sánh Năng lượng ion hóa (lần 5) của tất cả nguyên tố →
- Trạng thái oxi hóa
- −1, +1, +2, +3, +4 So sánh Trạng thái oxi hóa của tất cả nguyên tố →
- Electron hóa trị
- 3 So sánh Electron hóa trị của tất cả nguyên tố →
- Cấu hình electron
- [Rn] 7s2 6d2
Nhiệt động lực học
- Nhiệt nóng chảy
- 0,16696896 eV So sánh Nhiệt nóng chảy của tất cả nguyên tố →
- Nhiệt hóa hơi
- 5,327253 eV So sánh Nhiệt hóa hơi của tất cả nguyên tố →
- Nhiệt thăng hoa
- 5,938747 eV
- Nhiệt nguyên tử hóa
- 5,938747 eV
- Enthalpy nguyên tử hóa
- 6,239312 eV
Hạt nhân
- Proton
- 90 So sánh Proton của tất cả nguyên tố →
- Neutron
- 142 So sánh Neutron của tất cả nguyên tố →
- Các đồng vị đã biết
- 32 So sánh Các đồng vị đã biết của tất cả nguyên tố →
- Đồng vị bền
- 0 So sánh Đồng vị bền của tất cả nguyên tố →
- Đồng vị bền nhất
- Th-232
- Năm phát hiện
- 1828
Độ phổ biến
- Độ phổ biến (vỏ Trái Đất)
- 9,6 mg/kg So sánh Độ phổ biến (vỏ Trái Đất) của tất cả nguyên tố →
- Độ phổ biến (đại dương)
- 1 × 10−6 mg/L So sánh Độ phổ biến (đại dương) của tất cả nguyên tố →
Cấu trúc tinh thể
- Hằng số mạng a
- 508 pm
Cấu trúc electron
- Số electron trong mỗi lớp
- 2, 8, 18, 32, 18, 10, 2 So sánh Số electron trong mỗi lớp của tất cả nguyên tố →
Mã định danh
- Số CAS
- 7440-29-1 So sánh Số CAS của tất cả nguyên tố →
- Ký hiệu số hạng
- 3F2
- InChI
- InChI=1S/Th
- Khóa InChI
- ZSLUVFAKFWKJRC-UHFFFAOYSA-N
Cấu hình electron Đo đạc
Th: 6d² 7s²[Rn] 6d² 7s²1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d¹⁰ 6s² 6p⁶ 6d² 7s²Mô hình nguyên tử
Các đồng vị khác nhau về số neutron, khối lượng và độ bền — không khác nhau về cấu hình electron của nguyên tử trung hòa.
Mô hình nguyên tử minh họa, không theo tỷ lệ.
Dấu vân tay nguyên tử
Phổ phát xạ / hấp thụ
Phân bố đồng vị
Không có đồng vị bền.
| Số khối | Khối lượng nguyên tử (u) | Độ phổ biến tự nhiên | Chu kỳ bán rã |
|---|---|---|---|
| 223 Phóng xạ | 223,0208119 ± 0,0000099 | Không có | 600 ms |
| 217 Phóng xạ | 217,013117 ± 0,000022 | Không có | 248 us |
| 213 Phóng xạ | 213,013009 ± 0,000076 | Không có | 144 ms |
| 218 Phóng xạ | 218,013276 ± 0,000011 | Không có | 122 ns |
| 214 Phóng xạ | 214,0115 ± 0,000017 | Không có | 87 ms |
Pha / Trạng thái
Lý do: thấp hơn nhiệt độ nóng chảy (1749,85 °C) một lượng 1724,8 °C
Sơ đồ minh họa, không theo tỷ lệ
Điểm chuyển pha
Năng lượng chuyển pha
Năng lượng cần để làm nóng chảy 1 mol tại nhiệt độ nóng chảy
Năng lượng cần để hóa hơi 1 mol tại nhiệt độ sôi
Năng lượng cần để làm thăng hoa 1 mol tại nhiệt độ thăng hoa
Khối lượng riêng
Ở điều kiện chuẩn
Ở điều kiện chuẩn
Phổ nguyên tử
Đang hiển thị 10 trên 90. Sắp xếp theo điện tích ion (tăng dần).
Dữ liệu vạch phổ ?
| Ion | Điện tích | Tổng số vạch | Xác suất chuyển mức | Ký hiệu mức năng lượng |
|---|---|---|---|---|
| Th I | 0 | 13387 | 0 | 13387 |
| Th II | +1 | 6502 | 0 | 6502 |
| Th III | +2 | 227 | 0 | 227 |
| Th IV | +3 | 27 | 0 | 0 |
Dữ liệu mức năng lượng ?
| Ion | Điện tích | Mức năng lượng |
|---|---|---|
| Th I | 0 | 788 |
| Th II | +1 | 517 |
| Th III | +2 | 176 |
| Th IV | +3 | 2 |
| Th V | +4 | 2 |
| Th VI | +5 | 2 |
| Th VII | +6 | 2 |
| Th VIII | +7 | 2 |
| Th IX | +8 | 2 |
| Th X | +9 | 2 |
Bán kính ion
| Điện tích | Phối trí | Spin | Bán kính |
|---|---|---|---|
| +3 | 9 | Không có | 120.9 pm |
| +4 | 6 | Không có | 94 pm |
| +4 | 8 | Không có | 105 pm |
| +4 | 9 | Không có | 109.00000000000001 pm |
| +4 | 10 | Không có | 112.99999999999999 pm |
| +4 | 11 | Không có | 118 pm |
| +4 | 12 | Không có | 121 pm |
Hợp chất
Đồng vị (5)
Twenty-seven thorium radioisotopes have been characterized, with a range in atomic weight from 210 to 236. All are unstable with the most stable being 232Th with a half-life of 14.05 billion years. Thorium-232 represents all but a trace of naturally occurring thorium. It is an alpha emitter and goes through six alpha and four beta decay steps before becoming the stable isotope 208Pb. 232Th is sufficiently radioactive to expose a photographic plate in a few hours. Other isotopes of thorium are short-lived intermediates in the decay chains of higher elements, and only found in trace amounts. The longer-lived of these trace isotopes include: 230Th with a half-life of 75,380 years which is a daughter product of 238U decay; 229Th with a half-life of 7340 years and 228Th with a half-life of 1.92 years. All of the remaining radioactive isotopes have half-lives that are less than thirty days and the majority of these have half-lives less than ten minutes. Much of the internal heat the earth produces has been attributed to thorium and uranium.
| Số khối | Khối lượng nguyên tử (u) | Độ phổ biến tự nhiên | Chu kỳ bán rã | Kiểu phân rã | |
|---|---|---|---|---|---|
| 223 Phóng xạ | 223,0208119 ± 0,0000099 | Không có | 600 ms | α =100% | |
| 217 Phóng xạ | 217,013117 ± 0,000022 | Không có | 248 us | α =100% | |
| 213 Phóng xạ | 213,013009 ± 0,000076 | Không có | 144 ms | α ≈100%β+ ? | |
| 218 Phóng xạ | 218,013276 ± 0,000011 | Không có | 122 ns | α =100% | |
| 214 Phóng xạ | 214,0115 ± 0,000017 | Không có | 87 ms | α ≈100%β+ ? |
Vạch phổ
Đang hiển thị 50 trên 9955. Theo mặc định, chỉ hiển thị các vạch phổ có cường độ đã được đo.
| Bước sóng (nm) | Cường độ | Bậc ion hóa | Loại | Chuyển mức | Độ chính xác | Nguồn | |
|---|---|---|---|---|---|---|---|
| 576.055056 nm | 53000 | Th I | emission | 6d2.7s2 3F → 5f.6d.7s2 3D* | Đo đạc | NIST | |
| 645.728238 nm | 44000 | Th I | emission | 5f.6d.7s2 3H* → 5f.6d.7s.7p 5I | Đo đạc | NIST | |
| 395.039509 nm | 42000 | Th I | emission | 6d2.7s2 3F → * | Đo đạc | NIST | |
| 618.262159 nm | 38000 | Th I | emission | 6d2.7s2 3F → 6d.7s2.7p 3P* | Đo đạc | NIST | |
| 658.390575 nm | 32000 | Th I | emission | 6d2.7s2 3F → 6d.7s2.7p 3F* | Đo đạc | NIST | |
| 572.018265 nm | 31000 | Th I | emission | 6d2.7s2 → 5f.6d.7s2 3D* | Đo đạc | NIST | |
| 698.965521 nm | 31000 | Th I | emission | 5f.6d.7s2 3H* → 5f.6d.7s.7p 5I | Đo đạc | NIST | |
| 716.889496 nm | 30000 | Th I | emission | 6d2.7s2 3F → 6d.7s2.7p 3F* | Đo đạc | NIST | |
| 449.3333668 nm | 28000 | Th I | emission | 6d2.7s2 3F → * | Đo đạc | NIST | |
| 658.853947 nm | 26000 | Th I | emission | 6d2.7s2 3P → 6d.7s2.7p 3P* | Đo đạc | NIST | |
| 691.12262 nm | 25000 | Th I | emission | 6d2.7s2 3F → 6d2.7s.7p 5G* | Đo đạc | NIST | |
| 380.307494 nm | 24000 | Th I | emission | 6d2.7s2 3F → 6d2.7s.7p 3D* | Đo đạc | NIST | |
| 403.6047645 nm | 24000 | Th I | emission | 6d2.7s2 3F → * | Đo đạc | NIST | |
| 659.148431 nm | 21000 | Th I | emission | 6d2.7s2 3F → 6d2.7s.7p 5G* | Đo đạc | NIST | |
| 401.912876 nm | 20000 | Th II | emission | 6d.7s2 2D → 6d.7s.(3D).7p * | Đo đạc | NIST | |
| 558.702644 nm | 20000 | Th I | emission | 6d2.7s2 3F → * | Đo đạc | NIST | |
| 411.2754309 nm | 18000 | Th I | emission | 6d2.7s2 3F → * | Đo đạc | NIST | |
| 470.398977 nm | 18000 | Th I | emission | 6d2.7s2 3F → * | Đo đạc | NIST | |
| 580.414105 nm | 18000 | Th I | emission | 6d2.7s2 3F → 6d2.7s.7p 5F* | Đo đạc | NIST | |
| 616.982198 nm | 18000 | Th I | emission | 6d2.7s2 3F → 5f.6d.7s2 3D* | Đo đạc | NIST | |
| 597.366467 nm | 17000 | Th I | emission | 6d2.7s2 → 6d.7s2.7p 3P* | Đo đạc | NIST | |
| 653.134169 nm | 17000 | Th I | emission | 6d3.(4F).7s 5F → 6d2.7s.7p 5P* | Đo đạc | NIST | |
| 383.969505 nm | 16000 | Th I | emission | 6d2.7s2 3F → * | Đo đạc | NIST | |
| 421.092303 nm | 16000 | Th I | emission | 6d2.7s2 3F → * | Đo đạc | NIST | |
| 515.86042 nm | 16000 | Th I | emission | 6d2.7s2 3F → * | Đo đạc | NIST | |
| 620.349239 nm | 16000 | Th I | emission | 6d2.7s2 3F → 6d2.7s.7p 5F* | Đo đạc | NIST | |
| 666.22685 nm | 16000 | Th I | emission | 6d3.(4F).7s 5F → 6d2.7s.7p 5P* | Đo đạc | NIST | |
| 394.8030341 nm | 15000 | Th I | emission | 6d2.7s2 3F → * | Đo đạc | NIST | |
| 403.0842224 nm | 15000 | Th I | emission | 6d2.7s2 3F → * | Đo đạc | NIST | |
| 410.0341193 nm | 15000 | Th I | emission | 6d2.7s2 3F → * | Đo đạc | NIST | |
| 467.366094 nm | 15000 | Th I | emission | 6d2.7s2 3F → * | Đo đạc | NIST | |
| 506.797381 nm | 15000 | Th I | emission | 5f.6d.7s2 3H* | Đo đạc | NIST | |
| 523.115956 nm | 15000 | Th I | emission | 6d2.7s2 3P → 6d2.7s.7p 5P* | Đo đạc | NIST | |
| 634.285945 nm | 15000 | Th I | emission | 6d3.(4F).7s 5F → * | Đo đạc | NIST | |
| 382.838452 nm | 14000 | Th I | emission | 6d2.7s2 3F → * | Đo đạc | NIST | |
| 472.3438197 nm | 14000 | Th I | emission | 6d2.7s2 3F → 5f.6d.7s2 3D* | Đo đạc | NIST | |
| 553.926178 nm | 14000 | Th I | emission | 6d3.(4F).7s 5F → * | Đo đạc | NIST | |
| 694.361046 nm | 14000 | Th I | emission | 6d3.(4F).7s 5F → * | Đo đạc | NIST | |
| 720.80062 nm | 14000 | Th I | emission | 6d3.(4F).7s 5F → * | Đo đạc | NIST | |
| 425.0314489 nm | 13000 | Th I | emission | 6d2.7s2 3F → * | Đo đạc | NIST | |
| 489.495493 nm | 13000 | Th I | emission | 6d2.7s2 3F → 6d.7s2.7p 3P* | Đo đạc | NIST | |
| 387.382217 nm | 12000 | Th I | emission | 6d2.7s2 3F → * | Đo đạc | NIST | |
| 423.5463454 nm | 12000 | Th I | emission | 6d2.7s2 3F → * | Đo đạc | NIST | |
| 480.81337 nm | 12000 | Th I | emission | 6d2.7s2 3F → * | Đo đạc | NIST | |
| 541.748576 nm | 12000 | Th I | emission | 6d2.7s2 → * | Đo đạc | NIST | |
| 599.412865 nm | 12000 | Th I | emission | 6d2.7s2 3P → 6d.7s2.7p 3P* | Đo đạc | NIST | |
| 659.393903 nm | 12000 | Th I | emission | 6d3.(4F).7s 5F → * | Đo đạc | NIST | |
| 708.416896 nm | 12000 | Th I | emission | 6d3.(4F).7s 5F → * | Đo đạc | NIST | |
| 738.550045 nm | 12000 | Th I | emission | 6d2.7s2 → 6d2.7s.7p 5F* | Đo đạc | NIST | |
| 392.440084 nm | 11000 | Th I | emission | 6d2.7s2 → * | Đo đạc | NIST |
Tính chất mở rộng
Bán kính cộng hóa trị (mở rộng)
- Bán kính cộng hóa trị (Pyykkö)
- 175 pm
- Bán kính cộng hóa trị (Pyykkö, liên kết đôi)
- 143 pm
- Bán kính cộng hóa trị (Pyykkö, liên kết ba)
- 136 pm
Bán kính van der Waals
- Batsanov
- 240 pm
- Alvarez
- 293 pm
- UFF
- 339,6 pm
- MM3
- 274 pm
Bán kính nguyên tử và kim loại
- Bán kính nguyên tử (Rahm)
- 288 pm
Các thang đánh số
- Mendeleev
- 16
- Pettifor
- 47
- Glawe
- 34
Các thang độ âm điện
- Ghosh
- 0
- Miedema
- 3
Độ phân cực hóa và tán sắc
- Độ phân cực hóa lưỡng cực
- 217 a.u.
- Độ phân cực hóa lưỡng cực (độ không đảm bảo)
- 54 a.u.
Thông số Miedema
- Thể tích mol Miedema
- 19,8 cm3/mol
- Mật độ electron Miedema
- 2
Rủi ro nguồn cung và kinh tế
- Mức độ tập trung sản xuất
- 80
- Rủi ro nguồn cung tương đối
- 8
- Phân bố trữ lượng
- 31
- Ổn định chính trị (quốc gia sản xuất lớn nhất)
- 11
- Ổn định chính trị (quốc gia có trữ lượng lớn nhất)
- 57
Chuyển pha và các dạng thù hình
| Nhiệt độ nóng chảy | 2023,15 K |
| Nhiệt độ sôi | 5058,15 K |
Phân loại trạng thái oxi hóa
Dữ liệu tham khảo chuyên sâu
Chi tiết bán kính tinh thể (7)
| Điện tích | CN | Spin | rcrystal (pm) | Nguồn gốc |
|---|---|---|---|---|
| 4 | VI | 108 | calculated, | |
| 4 | VIII | 119 | from r^3 vs V plots, calculated, | |
| 4 | IX | 123 | ||
| 4 | X | 127 | estimated, | |
| 4 | XI | 132 | calculated, | |
| 4 | XII | 135 | calculated, | |
| 3 | IX | — | 134,9 |
Các kiểu phân rã đồng vị (52)
| Đồng vị | Chế độ | Cường độ |
|---|---|---|
| 208 | A | 100% |
| 209 | A | — |
| 209 | B+ | — |
| 210 | A | 100% |
| 210 | B+ | — |
| 211 | A | 100% |
| 211 | B+ | — |
| 212 | A | 100% |
| 212 | B+ | — |
| 213 | A | 100% |
Hệ số tán xạ tia X (516)
| Năng lượng (eV) | f₁ | f₂ |
|---|---|---|
| 10 | — | 3,14769 |
| 10,1617 | — | 3,1007 |
| 10,3261 | — | 3,05442 |
| 10,4931 | — | 3,00883 |
| 10,6628 | — | 2,96392 |
| 10,8353 | — | 2,91968 |
| 11,0106 | — | 2,87611 |
| 11,1886 | — | 2,83318 |
| 11,3696 | — | 2,79089 |
| 11,5535 | — | 2,74024 |
Dữ liệu bổ sung
Estimated Crustal Abundance
The estimated element abundance in the earth's crust.
9.6 milligrams per kilogram
Tài liệu tham khảo (1)
Estimated Oceanic Abundance
The estimated element abundance in the earth's oceans.
1×10-6 milligrams per liter
Tài liệu tham khảo (1)
Sources
Sources of this element.
Thorium-232 is a primordial nuclide, having existed in its current form for over 4.5 billion years, a half-life is comparable to the age of the Universe and thus predating the formation of the Earth. Thorium was forged in the cores of dying stars through the r-process and scattered across the galaxy by supernovas. Thorium is found in small amounts in most rocks and soils. Soil commonly contains an average of around 6 parts per million (ppm) of thorium. Thorium occurs in several minerals including thorite (ThSiO4), thorianite (ThO2 + UO2) and monazite. Thorianite is a rare mineral and may contain up to about 12% thorium oxide. Monazite contains 2.5% thorium, allanite has 0.1 to 2% thorium and zircon can have up to 0.4% thorium.[66] Thorium-containing minerals occur on all continents. Thorium is now thought to be about three times as abundant as uranium and about as abundant as lead or molybdenum. Thorium is recovered commercially from the mineral monazite, which contains from 3 to 9% ThO2 along with rare-earth minerals.
Tài liệu tham khảo (1)
- [6] Thorium https://periodic.lanl.gov/90.shtml
Production
Production of this element (from raw materials or other compounds containing the element).
Production
Several methods are available for producing thorium metal; it can be obtained by reducing thorium oxide with calcium, by electrolysis of anhydrous thorium chloride in a fused mixture of sodium and potassium chlorides, by calcium reduction of thorium tetrachloride mixed with anhydrous zinc chloride, and by reduction of thorium tetrachloride with an alkali metal.
Tài liệu tham khảo (1)
- [6] Thorium https://periodic.lanl.gov/90.shtml
Tài liệu tham khảo
(9)
Data deposited in or computed by PubChem
The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.
Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.
The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.
Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/
The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.
The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database
This section provides all form of data related to element Thorium.
The element property data was retrieved from publications.