Tungsten (W)
transition-metalSolid
Standart Atom Ağırlığı
183,84 uElektron dizilimi
[Xe] 6s2 4f14 5d4Erime noktası
3421,85 °CKaynama noktası
5554,85 °CYoğunluk
1,93e+4 kg/m³Yükseltgenme basamakları
−4, −2, −1, 0, +1, +2, +3, +4, +5, +6Elektronegatiflik (Pauling)
2,36İyonlaşma enerjisi (1.)
7,86403 eVKeşif yılı
1781Atom yarıçapı
135 pmAyrıntılar
Tungsten is a dense, refractory transition metal in group 6. It has the highest melting point of any element and retains strength at temperatures where most engineering metals soften. Chemically it is best known for stable high oxidation states, especially +6, and for forming hard carbides and complex oxoanions. Natural tungsten occurs mainly in tungstate minerals rather than as the native metal.
Pure tungsten is a steel-gray to tin-white metal. Very pure tungsten can be cut with a hacksaw, forged, spun, drawn, and extruded. The impure metal is brittle and can be worked only with difficulty. Tungsten has the highest melting point of all metals, and at temperatures over 1650°C has the highest tensile strength. The metal oxidizes in air and must be protected at elevated temperatures. It has excellent corrosion resistance and is attacked only slightly by most mineral acids. The thermal expansion is about the same as borosilicate glass, which makes the metal useful for glass-to-metal seals.
The name derives from the Swedish tungsten for "heavy stone". The symbol W derives from the German wolfram, which was found with tin and interfered with the smelting of tin. It was said to eat up tin like a wolf eats up sheep. The element was discovered by the Swedish pharmacist and chemist Carl-Wilhelm Scheele in 1781. Tungsten metal was first isolated by the Spanish chemists Fausto Elhuyar and his brother Juan José in 1783.
Tungsten was discovered by Juan José and Fausto Elhuyar, Spanish chemists and brothers, in 1783 in samples of the mineral wolframite ((Fe, Mn)WO4). Today, tungsten is primarily obtained from wolframite and scheelite (CaWO4) using the same basic method developed by José and Elhuyar. Tungsten ores are crushed, cleaned and treated with alkalis to form tungsten trioxide (WO3). Tungsten trioxide is then heated with carbon or hydrogen gas (H2), forming tungsten metal and carbon dioxide (CO2) or tungsten metal and water vapor (H2O).
From Swedish, tung sten meanig heavy stone. In 1779 Peter Woulfe examined the mineral now known as wolframite and concluded it must contain a new substance. Scheele, in 1781, found that a new acid could be made from tungsten (a name first applied about 1758 to a mineral now known as scheelite). Scheele and Berman suggested the possibility of obtaining a new metal by reducing this acid. The de Elhuyar brothers found acid in wolframite in 1783 that was identical to the acid of tungsten (tungstic acid) of Scheele, and in that year they succeeded in obtaining the element by reduction of this acid with charcoal. Tungsten occurs in wolframite, scheelite, huebnertie, and ferberite. Important deposits of tungsten occur in California, Colorado, South Korea, Bolivia, Russia, and Portugal. China is reported to have about 75% of the world's tungsten resources. Natural tungsten contains five stable isotopes. Twenty one other unstable isotopes are recognized. The metal is obtained commercially be reducing tungsten oxide with hydrogen or carbon.
Pure tungsten is a steel-gray to silvery-white metal with a metallic luster. It is hard and brittle when impure or cold-worked, but sufficiently pure tungsten can be drawn into wire after suitable processing. The metal is solid under ordinary conditions and has an exceptionally high density.
Tungsten metal is used where very high temperature strength, low vapor pressure, and resistance to arc erosion are needed. Important uses include filaments and electrodes in specialized lamps and vacuum devices, contacts, heating elements, and parts for high-temperature furnaces. Tungsten carbide is central to cutting tools, mining bits, dies, and wear-resistant components. Heavy tungsten alloys are used for counterweights, radiation shielding, vibration damping, and some kinetic-energy applications.
Pure tungsten is a light gray or whitish metal that is soft enough to be cut with a hacksaw and ductile enough to be drawn into wire or extruded into various shapes. If contaminated with other materials, tungsten becomes brittle and difficult to work with. Tungsten has the highest melting point of all metallic elements and is used to make filaments for incandescent light bulbs, fluorescent light bulbs and television tubes. Tungsten expands at nearly the same rate as borosilicate glass and is used to make metal to glass seals. Tungsten is also used as a target for X-ray production, as heating elements in electric furnaces and for parts of spacecraft and missiles which must withstand high temperatures.
Tungsten is alloyed with steel to form tough metals that are stable at high temperatures. Tungsten-steel alloys are used to make such things as high speed cutting tools and rocket engine nozzles.
Tungsten carbide (WC) is an extremely hard tungsten compound. It is used in the tips of drill bits, high speed cutting tools and in mining machinery. Tungsten disulfide (WS2) is a dry lubricant that can be used to temperatures as high as 500°C. Tungsten forms compounds with calcium and magnesium that have phosphorescent properties and are used in fluorescent light bulbs.
Tungsten and its alloys are used extensively for filaments for electric lamps, electron and television tubes, and for metal evaporation work; for electrical contact points for automobile distributors; X-ray targets; windings and heating elements for electrical furnaces; and for numerous spacecraft and high-temperature applications. High-speed tool steels, Hastelloy(R), Stellite(R), and many other alloys contain tungsten. Tungsten carbide is of great importance to the metal-working, mining, and petroleum industries. Calcium and magnesium tungstates are widely used in fluorescent lighting; other salts of tungsten are used in the chemical and tanning industries. Tungsten disulfide is a dry, high-temperature lubricant, stable to 500C. Tungsten bronzes and other tungsten compounds are used in paints.
Isotopes in Earth/Planetary Science
182W is the stable product of the decay of 182Hf, which has a half-life of 8.9×106 years. Although 182Hf was present at the dawn of the Solar System, this isotope has long since decayed. During the formation of the planets, including Earth, the elements hafnium and tungsten were partitioned into silicate minerals (rock forming minerals with silicon-oxygen bonds that constitute more than 90 percent of the Earth’s crust) and metal phases, respectively. The measurement of excessive amounts of 182W, arising from the decay of 182Hf that accumulated in silicate minerals, has been used to estimate the time that elapsed between the formation of the Solar System and accretion of the planets (Fig. IUPAC.74.1) [512] E. B. Norman, D. N. Schramm. Nature304, 515 (1983)., [513] C. Vockenhuber, F. Oberli, M. Bichler, I. Ahmad, G. Quitté, M. Meier, A. N. Halliday, D. C. Lee, W. Kutschera, P. Steier, R. J. Gehrke, R. G. Helmer. Phys. Rev. Lett.93, 172501-1 (2004)..
Isotopes Used as a Source of Radioactive Isotope(s)
Tungsten-rhenium generators use 188W, which is produced from 186W, via the following double neutron capture reaction 186W (n, γ) 187W (n, γ) 188W.
Tungsten chemistry is dominated by oxidation states from 0 to +6, with +6 the most common in air-stable compounds. Tungsten(VI) oxide, WO₃, is an important oxide used in pigments, electrochromic devices, and as a precursor to metal powder. Tungstates contain the tungstate ion, WO₄²⁻, and include calcium tungstate, CaWO₄, and sodium tungstate, Na₂WO₄. Tungsten hexafluoride, WF₆, is a volatile +6 compound used in chemical vapor deposition. Tungsten carbide, WC, is a hard interstitial compound rather than a typical salt.
See more information at the Tungsten compound page.
Massive tungsten metal has low acute toxicity and is not easily absorbed, but fine powders can present dust, fire, or explosion hazards under some conditions. Soluble tungstate salts are more biologically available and should not be treated as harmless. Tungsten carbide tools may contain cobalt or nickel binders that add important occupational hazards. Tungsten is not radioactive as a natural element in practical terms, though artificial radioisotopes require isotope-specific controls.
Tungsten enters the environment mainly through weathering of tungstate minerals and through mining, milling, metalworking, and disposal of hard-metal products. In oxidizing waters it commonly forms tungstate species, which can be more mobile than many heavy-metal ions. Its biological role is limited but real in some microorganisms, where tungsten enzymes are known. Environmental behavior depends strongly on pH, redox conditions, and adsorption to iron or manganese oxides.
Tungsten is produced chiefly from scheelite and wolframite concentrates. Ore is converted to ammonium paratungstate and then to tungsten oxide or tungsten metal powder, with powder metallurgy used for many products because of the metal’s very high melting point. Supply is strategically important because deposits and refining capacity are geographically concentrated. Demand is led by cemented carbides, followed by alloy, mill-product, and chemical uses. Recycling of carbide scrap and heavy alloys is significant because tungsten is valuable and often recoverable from industrial products.
Occurs in the minerals scheelite (CaWO4) and wolframite [(Fe,Mn)WO4].
Tungsten is a rare heavy element in the cosmos. Its stable isotopes are made mainly by slow and rapid neutron-capture processes in evolved stars and explosive stellar events, rather than by ordinary stellar fusion. In planets it is lithophile under oxidizing conditions but can partition into metal under reducing conditions. Hafnium-tungsten isotope systematics are used to study early Solar System chronology and core formation.
- The symbol W comes from wolfram, a name still reflected in wolframite ores.
- Tungsten wire was crucial to long-lived incandescent lamps after ductile wire production became practical.
- Tungsten has an unusually low vapor pressure at very high temperature.
- Cemented tungsten carbide is usually a composite with a metallic binder, not pure WC alone.
- The isotope ¹⁸²W is important in hafnium-tungsten geochronology.
- Tungsten compounds can form polyoxometalates with large, cage-like anions.
Görseller
Özellikler
Fiziksel
- Atom yarıçapı (ampirik)
- 135 pm Tüm elementlerin Atom yarıçapı (ampirik) değerlerini karşılaştır →
- Kovalent yarıçap
- 162 pm Tüm elementlerin Kovalent yarıçap değerlerini karşılaştır →
- Van der Waals yarıçapı
- 210 pm Tüm elementlerin Van der Waals yarıçapı değerlerini karşılaştır →
- Metalik yarıçap
- 130 pm Tüm elementlerin Metalik yarıçap değerlerini karşılaştır →
- Yoğunluk
- 1,93 × 104 kg/m³ Tüm elementlerin Yoğunluk değerlerini karşılaştır →
- Molar hacim
- 0,00953 L/mol
- STP'deki faz
- Katı Tüm elementlerin STP'deki faz değerlerini karşılaştır →
- Erime noktası
- 3421,85 °C Tüm elementlerin Erime noktası değerlerini karşılaştır →
- Kaynama noktası
- 5554,85 °C Tüm elementlerin Kaynama noktası değerlerini karşılaştır →
- Isıl iletkenlik
- 173 W/(m·K) Tüm elementlerin Isıl iletkenlik değerlerini karşılaştır →
- Özgül ısı kapasitesi
- 0,132 J/(g·K) Tüm elementlerin Özgül ısı kapasitesi değerlerini karşılaştır →
- Molar ısı kapasitesi
- 24,27 J/(mol·K) Tüm elementlerin Molar ısı kapasitesi değerlerini karşılaştır →
- Kristal yapı
- Hacim merkezli kübik Tüm elementlerin Kristal yapı değerlerini karşılaştır →
Kimyasal
- Elektronegatiflik (Pauling)
- 2,36 Tüm elementlerin Elektronegatiflik (Pauling) değerlerini karşılaştır →
- Elektronegatiflik (Allen)
- 1,47
- Elektron ilgisi
- 0,815 eV
- İyonlaşma enerjisi (1.)
- 7,86403 eV Tüm elementlerin İyonlaşma enerjisi (1.) değerlerini karşılaştır →
- İyonlaşma enerjisi (2.)
- 16,370056 eV Tüm elementlerin İyonlaşma enerjisi (2.) değerlerini karşılaştır →
- İyonlaşma enerjisi (3.)
- 26,000089 eV Tüm elementlerin İyonlaşma enerjisi (3.) değerlerini karşılaştır →
- İyonlaşma enerjisi (4.)
- 38,200131 eV Tüm elementlerin İyonlaşma enerjisi (4.) değerlerini karşılaştır →
- İyonlaşma enerjisi (5.)
- 51,600178 eV Tüm elementlerin İyonlaşma enerjisi (5.) değerlerini karşılaştır →
- Yükseltgenme basamakları
- −4, −2, −1, 0, +1, +2, +3, +4, +5, +6 Tüm elementlerin Yükseltgenme basamakları değerlerini karşılaştır →
- Değerlik elektronları
- 6 Tüm elementlerin Değerlik elektronları değerlerini karşılaştır →
- Elektron dizilimi
- [Xe] 6s2 4f14 5d4
Termodinamik
- Erime ısısı
- 0,36482355 eV Tüm elementlerin Erime ısısı değerlerini karşılaştır →
- Buharlaşma ısısı
- 8,360885 eV Tüm elementlerin Buharlaşma ısısı değerlerini karşılaştır →
- Süblimleşme ısısı
- 8,803441 eV
- Atomlaşma ısısı
- 8,803441 eV
- Atomlaşma entalpisi
- 8,820024 eV
Nükleer
- Protonlar
- 74 Tüm elementlerin Protonlar değerlerini karşılaştır →
- Nötronlar
- 110 Tüm elementlerin Nötronlar değerlerini karşılaştır →
- Bilinen izotoplar
- 41 Tüm elementlerin Bilinen izotoplar değerlerini karşılaştır →
- Kararlı izotoplar
- 0 Tüm elementlerin Kararlı izotoplar değerlerini karşılaştır →
- En kararlı izotop
- W-184
- Keşif yılı
- 1781
Bolluk
- Bolluk (yer kabuğu)
- 1,25 mg/kg Tüm elementlerin Bolluk (yer kabuğu) değerlerini karşılaştır →
- Bolluk (okyanus)
- 1 × 10−4 mg/L Tüm elementlerin Bolluk (okyanus) değerlerini karşılaştır →
Kristal Yapı
- Örgü sabiti a
- 316 pm
Elektronik Yapı
- Kabuk başına elektron sayısı
- 2, 8, 18, 32, 12, 2 Tüm elementlerin Kabuk başına elektron sayısı değerlerini karşılaştır →
Tanımlayıcılar
- CAS numarası
- 7440-33-7 Tüm elementlerin CAS numarası değerlerini karşılaştır →
- Terim simgesi
- 5D0
- InChI
- InChI=1S/W
- InChI Anahtarı
- WFKWXMTUELFFGS-UHFFFAOYSA-N
Elektron Dizilimi Ölçülmüş
W: 4f¹⁴ 5d⁴ 6s²[Xe] 4f¹⁴ 5d⁴ 6s²1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d⁴ 6s²Atom modeli
İzotoplar nötron sayısını, kütleyi ve kararlılığı değiştirir; nötr bir atomun elektron dizilimini değiştirmez.
Şematik atom modeli, ölçekli değildir.
Atomik Parmak İzi
Emisyon / Soğurma Spektrumu
İzotop Dağılımı
Kararlı izotop yok.
| Kütle numarası | Atom kütlesi (u) | Doğal bolluk | Yarı ömür |
|---|---|---|---|
| 183 Radyoaktif | 182,95022275 ± 0,0000009 | 14,3100% | 670 Ey |
| 161 Radyoaktif | 160,9672 ± 0,00021 | Mevcut değil | 409 ms |
| 157 Radyoaktif | 156,97884 ± 0,00043 | Mevcut değil | 275 ms |
| 177 Radyoaktif | 176,946643 ± 0,00003 | Mevcut değil | 132.4 dakika |
| 181 Radyoaktif | 180,9481978 ± 0,0000051 | Mevcut değil | 120.956 gün |
Faz / Hâl
Neden: erime noktasının (3421,85 °C) 3396,8 °C altında
Şematik, ölçekli değil
Faz geçiş noktaları
Geçiş enerjileri
Erime noktasında 1 mol maddeyi eritmek için gereken enerji
Kaynama noktasında 1 mol maddeyi buharlaştırmak için gereken enerji
Süblimleşme noktasında 1 mol maddeyi süblimleştirmek için gereken enerji
Yoğunluk
Standart koşullarda
Standart koşullarda
Atomik Spektrumlar
74 kayıttan 10 tanesi gösteriliyor. İyon yüküne göre sıralandı (artan).
Spektral Çizgi Kayıtları ?
| İyon | Yük | Toplam çizgi sayısı | Geçiş olasılıkları | Düzey gösterimleri |
|---|---|---|---|---|
| W I | 0 | 7049 | 522 | 5852 |
| W II | +1 | 2838 | 211 | 2838 |
| W III | +2 | 2644 | 37 | 2644 |
| W IV | +3 | 791 | 0 | 791 |
| W V | +4 | 193 | 0 | 193 |
| W VI | +5 | 17 | 0 | 17 |
| W VII | +6 | 397 | 0 | 397 |
| W VIII | +7 | 193 | 187 | 193 |
Enerji Düzeyi Kayıtları ?
| İyon | Yük | Düzeyler |
|---|---|---|
| W I | 0 | 509 |
| W II | +1 | 264 |
| W III | +2 | 236 |
| W IV | +3 | 106 |
| W V | +4 | 60 |
| W VI | +5 | 15 |
| W VII | +6 | 113 |
| W VIII | +7 | 103 |
| W IX | +8 | 3 |
| W X | +9 | 2 |
İyon Yarıçapları
| Yük | Koordinasyon | Spin | Yarıçap |
|---|---|---|---|
| +4 | 6 | Mevcut değil | 66 pm |
| +5 | 6 | Mevcut değil | 62 pm |
| +6 | 4 | Mevcut değil | 42 pm |
| +6 | 5 | Mevcut değil | 51 pm |
| +6 | 6 | Mevcut değil | 60 pm |
Bileşikler
İzotoplar (5)
| Kütle numarası | Atom kütlesi (u) | Doğal bolluk | Yarı ömür | Bozunma türü | |
|---|---|---|---|---|---|
| 183 Radyoaktif | 182,95022275 ± 0,0000009 | 14,3100% ± 0,0400% | 670 Ey | IS =14.31±0.4%α ? | |
| 161 Radyoaktif | 160,9672 ± 0,00021 | Mevcut değil | 409 ms | α =73±0.3%β+ =27±0.3% | |
| 157 Radyoaktif | 156,97884 ± 0,00043 | Mevcut değil | 275 ms | β+ =100%α =0% | |
| 177 Radyoaktif | 176,946643 ± 0,00003 | Mevcut değil | 132.4 dakika | β+ =100% | |
| 181 Radyoaktif | 180,9481978 ± 0,0000051 | Mevcut değil | 120.956 gün | ε =100% |
Spektral Çizgiler
2460 kayıttan 50 tanesi gösteriliyor. Varsayılan olarak yalnızca şiddeti ölçülmüş spektral çizgiler gösterilir.
| Dalga boyu (nm) | Şiddet | İyonlaşma aşaması | Tür | Geçiş | Doğruluk | Kaynak | |
|---|---|---|---|---|---|---|---|
| 400.8749 nm | 1000 | W I | emission | 5d5.(6S).6s 7S → 5d5.(6S).6p 7P* | Ölçülmüş | NIST | |
| 429.4605 nm | 800 | W I | emission | 5d5.(6S).6s 7S → 5d5.(6S).6p 7P* | Ölçülmüş | NIST | |
| 386.7982 nm | 600 | W I | emission | 5d5.(6S).6s 7S → 5d4.6s.(6D).6p 7D* | Ölçülmüş | NIST | |
| 407.4357 nm | 600 | W I | emission | 5d5.(6S).6s 7S → 5d5.(6S).6p 7P* | Ölçülmüş | NIST | |
| 381.7484 nm | 400 | W I | emission | 5d5.(6S).6s 7S → 5d4.6s.(6D).6p 5F* | Ölçülmüş | NIST | |
| 484.381 nm | 400 | W I | emission | 5d4.6s2 5D → 5d4.6s.(6D).6p 7D* | Ölçülmüş | NIST | |
| 505.328 nm | 400 | W I | emission | 5d4.6s2 5D → 5d4.6s.(6D).6p 7D* | Ölçülmüş | NIST | |
| 384.6213 nm | 300 | W I | emission | 5d4.6s2 5D → 5d4.6s.(6D).6p 5F* | Ölçülmüş | NIST | |
| 525.9338 nm | 300 | W I | emission | 5d5.(6S).6p 7P* → 5d4.6s.(6D).7s 7D | Ölçülmüş | NIST | |
| 551.4684 nm | 300 | W I | emission | 5d4.6s2 5D → 5d4.6s.(6D).6p 7D* | Ölçülmüş | NIST | |
| 383.5052 nm | 250 | W I | emission | 5d4.6s2 5D → 5d4.6s.(6D).6p 5P* | Ölçülmüş | NIST | |
| 388.1394 nm | 250 | W I | emission | 5d4.6s2 5D → 5d4.6s.(6D).6p 5P* | Ölçülmüş | NIST | |
| 522.4661 nm | 250 | W I | emission | 5d4.6s2 5D → 5d4.6s.(6D).6p 7D* | Ölçülmüş | NIST | |
| 524.2973 nm | 250 | W I | emission | 5d4.6s2 3G → * | Ölçülmüş | NIST | |
| 424.4367 nm | 200 | W I | emission | 5d4.6s2 5D → 5d4.6s.(6D).6p 7D* | Ölçülmüş | NIST | |
| 426.9384 nm | 200 | W I | emission | 5d5.(6S).6s 7S → * | Ölçülmüş | NIST | |
| 430.2103 nm | 200 | W I | emission | 5d5.(6S).6s 7S → 5d4.6s.(6D).6p 7D* | Ölçülmüş | NIST | |
| 488.6902 nm | 200 | W I | emission | 5d4.6s2 5D → 5d4.6s.(6D).6p 7F* | Ölçülmüş | NIST | |
| 498.2586 nm | 200 | W I | emission | 5d4.6s2 5D → 5d4.6s.(6D).6p 7F* | Ölçülmüş | NIST | |
| 380.9234 nm | 150 | W I | emission | 5d5.(6S).6s 7S → 5d4.6s.(6D).6p 5D* | Ölçülmüş | NIST | |
| 384.749 nm | 150 | W I | emission | 5d4.6s2 5D → 5d4.6s.(6D).6p 5F* | Ölçülmüş | NIST | |
| 505.4594 nm | 150 | W I | emission | 5d4.6s2 5D → 5d4.6s.(6D).6p 7F* | Ölçülmüş | NIST | |
| 507.1736 nm | 150 | W I | emission | 5d4.6s.(6D).6p 7F* → 5d4.6s.(6D).7s 7D | Ölçülmüş | NIST | |
| 523.352 nm | 150 | W I | emission | 5d4.6s2 3P2 → * | Ölçülmüş | NIST | |
| 527.5538 nm | 150 | W I | emission | 5d5.(4G).6s 5G → * | Ölçülmüş | NIST | |
| 549.2315 nm | 150 | W I | emission | 5d4.6s.(6D).6p 7D* → 5d4.6s.(6D).7s 7D | Ölçülmüş | NIST | |
| 381.0796 nm | 120 | W I | emission | 5d4.6s2 3F2 → * | Ölçülmüş | NIST | |
| 506.9123 nm | 120 | W I | emission | 5d4.6s2 5D → 5d4.6s.(6D).6p 7F* | Ölçülmüş | NIST | |
| 525.5401 nm | 120 | W I | emission | 5d5.(4D).6s 5D → * | Ölçülmüş | NIST | |
| 434.811303 nm | 109 | W II | emission | 5d4.(5D).6s 4D | Ölçülmüş | NIST | |
| 381.0385 nm | 100 | W I | emission | 5d5.(4G).6s 5G → * | Ölçülmüş | NIST | |
| 401.5216 nm | 100 | W I | emission | 5d5.(4G).6s 5G → * | Ölçülmüş | NIST | |
| 404.56 nm | 100 | W I | emission | 5d5.(6S).6s 7S → 5d4.6s.(6D).6p 5F* | Ölçülmüş | NIST | |
| 410.2701 nm | 100 | W I | emission | 5d4.6s2 5D → 5d4.6s.(6D).6p 5P* | Ölçülmüş | NIST | |
| 424.1444 nm | 100 | W I | emission | 5d4.6s2 3D → * | Ölçülmüş | NIST | |
| 427.4553 nm | 100 | W I | emission | 5d4.6s.(6D).6p 7F* → 5d4.6s.(6D).7s 7D | Ölçülmüş | NIST | |
| 525.4544 nm | 100 | W I | emission | 5d4.6s2 3D → * | Ölçülmüş | NIST | |
| 526.3195 nm | 100 | W I | emission | 5d5.(4D).6s 5D → * | Ölçülmüş | NIST | |
| 526.9315 nm | 100 | W I | emission | 5d4.6s2 3F2 → * | Ölçülmüş | NIST | |
| 543.5042 nm | 100 | W I | emission | 5d4.6s2 5D → 5d4.6s.(6D).6p 7F* | Ölçülmüş | NIST | |
| 395.105951 nm | 91 | W II | emission | 5d4.(5D).6s 4D → 5d3.(4F).6s.(5F).6p 6G* | Ölçülmüş | NIST | |
| 406.9948 nm | 80 | W I | emission | 5d4.6s2 5D → 5d4.6s.(6D).6p 5P* | Ölçülmüş | NIST | |
| 413.7464 nm | 80 | W I | emission | 5d4.6s2 5D → 5d5.(6S).6p 7P* | Ölçülmüş | NIST | |
| 421.9375 nm | 80 | W I | emission | 5d4.6s2 5D → 5d4.6s.(6D).6p 5D* | Ölçülmüş | NIST | |
| 425.9363 nm | 80 | W I | emission | 5d4.6s.(6D).6p 7F* → 5d4.6s.(6D).7s 7D | Ölçülmüş | NIST | |
| 468.0513 nm | 80 | W I | emission | 5d4.6s2 5D → 5d4.6s.(6D).6p 7D* | Ölçülmüş | NIST | |
| 498.6924 nm | 80 | W I | emission | 5d4.6s2 3H → * | Ölçülmüş | NIST | |
| 526.8545 nm | 80 | W I | emission | 5d4.6s2 3F2 → * | Ölçülmüş | NIST | |
| 547.7798 nm | 80 | W I | emission | 5d4.6s2 3P2 → 5d4.6s.(6D).6p 5D* | Ölçülmüş | NIST | |
| 667.838 nm | 80 | W I | emission | 5d5.(4G).6s 5G → * | Ölçülmüş | NIST |
Genişletilmiş Özellikler
Kovalent Yarıçaplar (Genişletilmiş)
- Kovalent yarıçap (Pyykkö)
- 137 pm
- Kovalent yarıçap (Pyykkö, çift bağ)
- 120 pm
- Kovalent yarıçap (Pyykkö, üçlü bağ)
- 115 pm
Van der Waals Yarıçapları
- Batsanov
- 210 pm
- Alvarez
- 257 pm
- UFF
- 309,6 pm
- MM3
- 239 pm
Atom ve Metalik Yarıçaplar
- Atom yarıçapı (Rahm)
- 253 pm
- Metalik yarıçap (C12)
- 139 pm
Numaralandırma Ölçekleri
- Mendeleev
- 53
- Pettifor
- 56
- Glawe
- 57
Elektronegatiflik Ölçekleri
- Ghosh
- 0
- Miedema
- 5
- Gunnarsson–Lundqvist
- 6
- Robles–Bartolotti
- 5
Kutuplanabilirlik ve Dispersiyon
- Dipol kutuplanabilirliği
- 68 a.u.
- Dipol kutuplanabilirliği (belirsizlik)
- 15 a.u.
- C₆ (Gould–Bučko)
- 757 Ha·Bohr6
Miedema Parametreleri
- Miedema molar hacmi
- 9,55 cm3/mol
- Miedema elektron yoğunluğu
- 6
Tedarik Riski ve Ekonomi
- Üretim yoğunlaşması
- 84
- Göreli tedarik riski
- 10
- Rezerv dağılımı
- 61
- Siyasi istikrar (en büyük üretici)
- 24
- Siyasi istikrar (en büyük rezerv sahibi)
- 24
Faz Geçişleri ve Allotroplar
| Erime noktası | 3687,15 K |
| Kaynama noktası | 5828,15 K |
Yükseltgenme Basamağı Kategorileri
İleri Düzey Referans Verileri
Perdeleme Sabitleri (14)
| n | Orbital | σ |
|---|---|---|
| 1 | s | 1,4343 |
| 2 | p | 4,4258 |
| 2 | s | 19,3302 |
| 3 | d | 13,5476 |
| 3 | p | 21,3824 |
| 3 | s | 22,13 |
| 4 | d | 36,8268 |
| 4 | f | 39,2892 |
| 4 | p | 34,4516 |
| 4 | s | 33,4412 |
Kristal Yarıçaplarının Ayrıntıları (5)
| Yük | CN | Spin | rcrystal (pm) | Köken |
|---|---|---|---|---|
| 4 | VI | 80 | from r^3 vs V plots, from metallic oxides, | |
| 5 | VI | 76 | from r^3 vs V plots, | |
| 6 | IV | 56 | ||
| 6 | V | 65 | ||
| 6 | VI | 74 |
İzotop Bozunma Türleri (54)
| İzotop | Mod | Şiddet |
|---|---|---|
| 157 | B+ | 100% |
| 157 | A | 0% |
| 158 | A | 100% |
| 159 | A | 100% |
| 159 | B+ | — |
| 160 | A | 87% |
| 160 | B+ | — |
| 161 | A | 73% |
| 161 | B+ | 27% |
| 162 | B+ | — |
X Işını Saçılma Faktörleri (541)
| Enerji (eV) | f₁ | f₂ |
|---|---|---|
| 10 | — | 1,92551 |
| 10,1617 | — | 2,00949 |
| 10,3261 | — | 2,09714 |
| 10,4931 | — | 2,18428 |
| 10,6628 | — | 2,26758 |
| 10,8353 | — | 2,35405 |
| 11,0105 | — | 2,44381 |
| 11,1886 | — | 2,537 |
| 11,3696 | — | 2,63375 |
| 11,5535 | — | 2,73418 |
Ek Veriler
Estimated Crustal Abundance
The estimated element abundance in the earth's crust.
1.25 milligrams per kilogram
Kaynaklar (1)
- [5] Tungsten https://education.jlab.org/itselemental/ele074.html
Estimated Oceanic Abundance
The estimated element abundance in the earth's oceans.
1×10-4 milligrams per liter
Kaynaklar (1)
- [5] Tungsten https://education.jlab.org/itselemental/ele074.html
Kaynaklar
(9)
Data deposited in or computed by PubChem
The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.
Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.
The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.
Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/
The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.
The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database
This section provides all form of data related to element Tungsten.
The element property data was retrieved from publications.