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B 5

Boron (B)

metalloid
Período: 2 Grupo: 13 Bloco: p

Solid

Peso atômico padrão

10,81 u [10,806, 10,821]

Configuração eletrônica

[He] 2s2 2p1

Ponto de fusão

2074,85 °C

Ponto de ebulição

3999,85 °C

Densidade

2370 kg/m³

Estados de oxidação

−5, −1, 0, +1, +2, +3

Eletronegatividade (Pauling)

2,04

Energia de ionização (1ª)

8,298019 eV

Ano da descoberta

1808

Raio atômico

85 pm

Detalhes

Origem do nome From Arabic and Persian words for borax.
País da descoberta England/France
Descobridores Sir H. Davy, J.L. Gay-Lussac, L.J. Thénard

Boron is a light metalloid in group 13, notable for electron-deficient bonding and a rich cluster chemistry. It occurs naturally only in compounds, mainly as borates in evaporite minerals and brines. Elemental boron is difficult to prepare in high purity and has several allotropes built from B₁₂ icosahedra. Technologically, boron is most important through borate minerals, borosilicate glass, detergents, ceramics, fertilizers, and neutron-absorbing materials.

An element of group 13 of the periodic table. There are two allotropes, amorphous boron is a brown power, but metallic boron is black. The metallic form is hard (9.3 on Mohs' scale) and a bad conductor in room temperatures. It is never found free in nature. Boron-10 is used in nuclear reactor control rods and shields. It was discovered in 1808 by Sir Humphry Davy and by J.L. Gay-Lussac and L.J. Thenard.

The name derives from the Arabic buraq for "white". Although its compounds were known for thousands of years, it was not isolated until 1808 by the French chemists Louis-Joseph Gay-Lussac and Louis-Jacques Thenard.

Boron was discovered by Joseph-Louis Gay-Lussac and Louis-Jaques Thénard, French chemists, and independently by Sir Humphry Davy, an English chemist, in 1808. They all isolated boron by combining boric acid (H3BO3) with potassium. Today, boron is obtained by heating borax (Na2B4O7·10H2O) with carbon, although other methods are used if high-purity boron is required.

From the Arabic word Buraq, Persian Burah. Boron compounds have been known for thousands of years, but the element was not discovered until 1808 by Sir Humphry Davy and by Gay-Lussac and Thenard.

Imagens

Propriedades

Química

Eletronegatividade (Pauling)
2,04 Comparar Eletronegatividade (Pauling) de todos os elementos →
Eletronegatividade (Allen)
2,051
Afinidade eletrônica
0,27972 eV
Energia de ionização (1ª)
8,298019 eV Comparar Energia de ionização (1ª) de todos os elementos →
Energia de ionização (2ª)
25,154917 eV Comparar Energia de ionização (2ª) de todos os elementos →
Energia de ionização (3ª)
37,930721 eV Comparar Energia de ionização (3ª) de todos os elementos →
Energia de ionização (4ª)
259,375272 eV Comparar Energia de ionização (4ª) de todos os elementos →
Energia de ionização (5ª)
340,227194 eV Comparar Energia de ionização (5ª) de todos os elementos →
Estados de oxidação
−5, −1, 0, +1, +2, +3 Comparar Estados de oxidação de todos os elementos →
Elétrons de valência
3 Comparar Elétrons de valência de todos os elementos →
Configuração eletrônica
[He] 2s2 2p1

Termodinâmica

Calor de fusão
0,52028813 eV Comparar Calor de fusão de todos os elementos →
Calor de vaporização
4,974867 eV Comparar Calor de vaporização de todos os elementos →
Calor de sublimação
5,855833 eV
Calor de atomização
5,855833 eV
Entalpia de atomização
5,855833 eV

Abundância

Abundância (crosta terrestre)
10 mg/kg Comparar Abundância (crosta terrestre) de todos os elementos →
Abundância (oceano)
4,44 mg/L Comparar Abundância (oceano) de todos os elementos →

Estrutura cristalina

Constante de rede a
873 pm

Estrutura eletrônica

Elétrons por camada
2, 3 Comparar Elétrons por camada de todos os elementos →

Identificadores

Número CAS
7440-42-8 Comparar Número CAS de todos os elementos →
Símbolo de termo
2P°1/2
InChI
InChI=1S/B
Chave InChI
ZOXJGFHDIHLPTG-UHFFFAOYSA-N

Configuração eletrônica Medido

Carga do íon
Prótons 5
Elétrons 5
Carga Neutro
Configuração B: 2s² 2p¹
Configuração eletrônica
Medido
[He] 2s² 2p¹
1s² 2s² 2p¹
Diagrama de orbitais
1s
2/2
2s
2/2
2p
1/6 1↑
Total de elétrons: 5 Desemparelhados: 1 ?

Modelo atômico

Prótons 5
Nêutrons 6
Elétrons 5
Número de massa 11
Estabilidade Estável

Os isótopos alteram o número de nêutrons, a massa e a estabilidade — não a configuração eletrônica de um átomo neutro.

Modelo atômico esquemático, sem escala.

Assinatura atômica

Espectro de emissão / absorção

25 / 227 (32 32 com intensidade)
Medido
Emissão Visível: 380–750 nm

Distribuição isotópica

1180,1000%1019,9000%Número de massaAbundância natural (%)
Número de massaMassa atômica (u)Abundância naturalMeia-vida
10 Estável10,01293695 ± 0,0000004119,9000%Estável
11 Estável11,00930536 ± 0,0000004580,1000%Estável
Medido

Fase / Estado

1 atm / 101,325 kPa
Sólido 25 °C (298,15 K)

Motivo: 2049,8 °C abaixo do ponto de fusão (2074,85 °C)

Ponto de fusão 2074,85 °C
Ponto de ebulição 3999,85 °C
Abaixo do ponto de fusão em 2049,8 °C
0 K Temperatura atual: 25 °C 6000 K
Linha do tempo das fases

Esquemático, sem escala

Sólido
Líquido
Gás
Fusão
Ebulição
25°C
Sólido
Líquido
Gás
Atual

Pontos de transição de fase

Ponto de fusão Literatura
2074,85 °C
Ponto de ebulição Literatura
3999,85 °C
Fase atual Calculado
Sólido

Energias de transição

Calor de fusão Literatura
0,52028813 eV

Energia necessária para fundir 1 mol no ponto de fusão

Calor de vaporização Literatura
4,974867 eV

Energia necessária para vaporizar 1 mol no ponto de ebulição

Calor de sublimação Literatura
5,855833 eV

Energia necessária para sublimar 1 mol no ponto de sublimação

Densidade

Densidade de referência Literatura
2370 kg/m³

Em condições padrão

Densidade atual Calculado
2370 kg/m³

Em condições padrão

Espectros atômicos

Dados de linhas disponíveis ?

ÍonCargaTotal de linhasProbabilidades de transiçãoDesignações dos níveis
B I 0371269371
11B I Isótopo053053
10B I Isótopo011011
B II +1592435592
10B II Isótopo+1909
11B II Isótopo+1909
B III +2390106390
B IV +3478234478
B V +4258240258
Dados de linhas disponíveis no NIST →

Dados de níveis disponíveis ?

ÍonCargaNíveis
B I 0125
11B I Isótopo069
10B I Isótopo029
B II +1157
10B II Isótopo+110
11B II Isótopo+110
B III +2150
B IV +3174
B V +4101
Dados de níveis disponíveis no NIST →
5 B 10.8135

Boron — Visualizador de orbitais atômicos

[He]2s22p1
Níveis de energia 2 3
Estados de oxidação -5, -1, 0, +1, +2, +3
HOMO 2p n=2 · l=1 · m=-1
Boron — Prévia do visualizador de orbitais atômicos
O Three.js é carregado apenas quando solicitado
5 B 10.8135

Boron — Visualizador de estruturas cristalinas

Trigonal · Pearson N/A
Experimental
Pearson N/A
Boron — Prévia do visualizador de estruturas cristalinas
O Three.js é carregado apenas quando solicitado

Raios iônicos

CargaCoordenaçãoSpinRaio
+33N/D1 pm
+34N/D11 pm
+36N/D27 pm

Compostos

B
10,810 u
B
10,013 u
B
11,009 u
B-
10,810 u
B
17,047 u
B
12,014 u
B-
10,013 u
B
13,018 u
B-
11,009 u

Isótopos (2)

Número de massaMassa atômica (u)Abundância naturalMeia-vidaModo de decaimento
10 Estável10,01293695 ± 0,0000004119,9000% ± 0,7000%Estável
stable
11 Estável11,00930536 ± 0,0000004580,1000% ± 0,7000%Estável
stable
10 Estável
Massa atômica (u) 10,01293695 ± 0,00000041
Abundância natural 19,9000% ± 0,7000%
Meia-vida Estável
Modo de decaimento
stable
11 Estável
Massa atômica (u) 11,00930536 ± 0,00000045
Abundância natural 80,1000% ± 0,7000%
Meia-vida Estável
Modo de decaimento
stable

Linhas espectrais

Comprimento de onda (nm)IntensidadeEstágio de ionizaçãoTipoTransiçãoExatidãoFonte
391.482 nmN/DB IIemission1s2.2s.2p 1P* → 1s2.2p2 3PMedidaNIST
391.687 nmN/DB IIemission1s2.2s.2p 1P* → 1s2.2p2 3PMedidaNIST
391.817 nmN/DB IIemission1s2.2s.2p 1P* → 1s2.2p2 3PMedidaNIST
394.447 nmN/DB IIemission1s2.2p.3d 3F* → 1s2.2p.4f 3FMedidaNIST
394.587 nmN/DB IIemission1s2.2p.3d 3F* → 1s2.2p.4f 3FMedidaNIST
394.82 nmN/DB IIemission1s2.2p.3d 3F* → 1s2.2p.4f 3FMedidaNIST
395.038 nm18B IIemission1s2.2p.3d 1D* → 1s2.2p.4f 1FMedidaNIST
395.1698 nmN/DB IIemission1s2.2p2 1D → 1s2.2p2 1SMedidaNIST
399.024 nm70B IIemission1s2.2s.4p 1P* → 1s2.2s.8d 1DMedidaNIST
400.017 nm136B IIIemission1s.2s.(3S).4d 4D → 1s.2s.(3S).5f 4F*MedidaNIST
412.1928 nmN/DB IIemission1s2.2s.3d 3D → 1s2.2s.4f 3F*MedidaNIST
412.1928 nmN/DB IIemission1s2.2s.3d 3D → 1s2.2s.4f 3F*MedidaNIST
412.1928 nmN/DB IIemission1s2.2s.3d 3D → 1s2.2s.4f 3F*MedidaNIST
412.1928 nmN/DB IIemission1s2.2s.3d 3D → 1s2.2s.4f 3F*MedidaNIST
412.1928 nmN/DB IIemission1s2.2s.3d 3D → 1s2.2s.4f 3F*MedidaNIST
412.1928 nmN/DB IIemission1s2.2s.3d 3D → 1s2.2s.4f 3F*MedidaNIST
414.697 nmN/DB IIIemission1s2.5d 2D → 1s2.8f 2F*MedidaNIST
414.708 nmN/DB IIIemission1s2.5d 2D → 1s2.8f 2F*MedidaNIST
414.708 nmN/DB IIIemission1s2.5d 2D → 1s2.8f 2F*MedidaNIST
415.284 nmN/DB IIemission1s2.2s.4p 3P* → 1s2.2p.3p 3PMedidaNIST
415.284 nmN/DB IIemission1s2.2s.4p 3P* → 1s2.2p.3p 3PMedidaNIST
415.471 nmN/DB IIemission1s2.2s.4p 3P* → 1s2.2p.3p 3PMedidaNIST
415.471 nmN/DB IIemission1s2.2s.4p 3P* → 1s2.2p.3p 3PMedidaNIST
415.471 nmN/DB IIemission1s2.2s.4p 3P* → 1s2.2p.3p 3PMedidaNIST
415.584 nmN/DB IIemission1s2.2s.4p 3P* → 1s2.2p.3p 3PMedidaNIST
417.896 nmN/DB Iemission2s2.3p 2P* → 2s.2p2 2PMedidaNIST
417.927 nmN/DB Iemission2s2.3p 2P* → 2s.2p2 2PMedidaNIST
418.099 nmN/DB Iemission2s2.3p 2P* → 2s.2p2 2PMedidaNIST
418.13 nmN/DB Iemission2s2.3p 2P* → 2s.2p2 2PMedidaNIST
419.4792 nm180B IIemission1s2.2s.3p 1P* → 1s2.2s.4s 1SMedidaNIST
419.773 nm30B IVemission1s.5s 3S → 1s.6p 3P*MedidaNIST
424.3 nm300B IIIemission1s2.4p 2P* → 1s2.5d 2DMedidaNIST
424.359 nmN/DB IIIemission1s2.4p 2P* → 1s2.5d 2DMedidaNIST
424.37 nmN/DB IIIemission1s2.4p 2P* → 1s2.5d 2DMedidaNIST
427.274 nm50B IIemission1s2.2s.4s 3S → 1s2.2s.6p 3P*MedidaNIST
429.571 nm50B IIemission1s2.2s.4p 1P* → 1s2.2s.7d 1DMedidaNIST
436.147 nm60B IIIemission1s.2p.(3P*).4f 2F → 1s.2p.(3P*).5g 2G*MedidaNIST
436.61 nm100B IIIemission1s.2p.(3P*).4f 4F → 1s.2p.(3P*).5g 4G*MedidaNIST
443.11 nmN/DB IIemission1s2.2p.3d 3D* → 1s2.2p.4f 3FMedidaNIST
443.185 nmN/DB IIemission1s2.2p.3d 3D* → 1s2.2p.4f 3FMedidaNIST
443.291 nmN/DB IIemission1s2.2p.3d 3D* → 1s2.2p.4f 3FMedidaNIST
445.943 nmN/DB IVemission1s.5p 3P* → 1s.6d 3DMedidaNIST
445.943 nmN/DB IVemission1s.5p 3P* → 1s.6d 3DMedidaNIST
445.943 nmN/DB IVemission1s.5p 3P* → 1s.6d 3DMedidaNIST
447.112 nmN/DB IIIemission1s2.5s 2S → 1s2.7p 2P*MedidaNIST
447.112 nmN/DB IIIemission1s2.5s 2S → 1s2.7p 2P*MedidaNIST
447.2029 nmN/DB IIemission1s2.2s.3p 3P* → 1s2.2s.4s 3SMedidaNIST
447.2151 nmN/DB IIemission1s2.2s.3p 3P* → 1s2.2s.4s 3SMedidaNIST
447.2862 nm470B IIemission1s2.2s.3p 3P* → 1s2.2s.4s 3SMedidaNIST
448.692 nmN/DB IIIemission1s2.4d 2D → 1s2.5f 2F*MedidaNIST
448.71 nmN/DB IIIemission1s2.4d 2D → 1s2.5f 2F*MedidaNIST
449.09 nm20B IVemission1s.2s 1S → 1s.2p 1P*MedidaNIST
449.773 nm1700B IIIemission1s2.4f 2F* → 1s2.5g 2GMedidaNIST
449.853 nmN/DB IIIemission1s2.4f 2F* → 1s2.5f 2F*MedidaNIST
449.859 nmN/DB IIIemission1s2.4f 2F* → 1s2.5f 2F*MedidaNIST
450.481 nmN/DB IIIemission1s2.4f 2F* → 1s2.5d 2DMedidaNIST
450.482 nmN/DB IIIemission1s2.4f 2F* → 1s2.5d 2DMedidaNIST
451.9912773 nmN/DB Vemission7i 2I → 9k 2K*MedidaNIST
451.9946377 nmN/DB Vemission7i 2I → 9k 2K*MedidaNIST
453.229 nmN/DB IIemission1s2.2s.4f 1F* → 1s2.2p.3p 1DMedidaNIST
459.72 nmN/DB IIIemission1s.2s.(3S).4d 4D → 1s.2s.(3S).5p 4P*MedidaNIST
459.73 nmN/DB IIIemission1s.2p.(3P*).4p 4P → 1s.2p.(3P*).5s 4P*MedidaNIST
461.114 nmN/DB IIemission1s2.2s.4p 3P* → 1s2.2p.3p 3SMedidaNIST
461.114 nmN/DB IIemission1s2.2s.4p 3P* → 1s2.2p.3p 3SMedidaNIST
461.114 nmN/DB IIemission1s2.2s.4p 3P* → 1s2.2p.3p 3SMedidaNIST
461.32 nmN/DB IVemission1s.5d 3D → 1s.6p 1P*MedidaNIST
463.217 nmN/DB IIIemission1s2.4d 2D → 1s2.5p 2P*MedidaNIST
463.243 nmN/DB IIIemission1s2.4d 2D → 1s2.5p 2P*MedidaNIST
463.263 nmN/DB IIIemission1s2.4d 2D → 1s2.5p 2P*MedidaNIST
464.69 nmN/DB IVemission1s.5d 3D → 1s.6f 1F*MedidaNIST
464.69 nmN/DB IVemission1s.5d 3D → 1s.6f 1F*MedidaNIST
464.701 nmN/DB IVemission1s.5d 3D → 1s.6f 3F*MedidaNIST
464.701 nmN/DB IVemission1s.5d 3D → 1s.6f 3F*MedidaNIST
464.701 nmN/DB IVemission1s.5d 3D → 1s.6f 3F*MedidaNIST
464.701 nmN/DB IVemission1s.5d 3D → 1s.6f 3F*MedidaNIST
464.701 nmN/DB IVemission1s.5d 3D → 1s.6f 3F*MedidaNIST
464.701 nmN/DB IVemission1s.5d 3D → 1s.6f 3F*MedidaNIST
465.58 nmN/DB IVemission1s.5d 1D → 1s.6f 1F*MedidaNIST
465.786 nmN/DB IVemission1s.5f 3F* → 1s.6g 3GMedidaNIST
465.786 nmN/DB IVemission1s.5f 3F* → 1s.6g 3GMedidaNIST
465.786 nmN/DB IVemission1s.5f 3F* → 1s.6g 3GMedidaNIST
465.8 nmN/DB IVemission1s.5f 1F* → 1s.6g 3GMedidaNIST
465.815 nmN/DB IVemission1s.5g 3G → 1s.6h 3H*MedidaNIST
465.815 nmN/DB IVemission1s.5g 3G → 1s.6h 3H*MedidaNIST
465.815 nmN/DB IVemission1s.5g 3G → 1s.6h 3H*MedidaNIST
465.815 nmN/DB IVemission1s.5g 1G → 1s.6h 3H*MedidaNIST
465.92 nmN/DB IVemission1s.5g 1G → 1s.6f 1F*MedidaNIST
465.92 nmN/DB IVemission1s.5g 3G → 1s.6f 1F*MedidaNIST
465.92 nmN/DB IVemission1s.5g 3G → 1s.6f 1F*MedidaNIST
465.927 nmN/DB IVemission1s.5g 3G → 1s.6f 3F*MedidaNIST
465.927 nmN/DB IVemission1s.5g 3G → 1s.6f 3F*MedidaNIST
465.927 nmN/DB IVemission1s.5g 3G → 1s.6f 3F*MedidaNIST
465.927 nmN/DB IVemission1s.5g 1G → 1s.6f 3F*MedidaNIST
468.31 nmN/DB IVemission1s.5p 1P* → 1s.6p 1P*MedidaNIST
468.481 nmN/DB IVemission1s.6g 3G → 1s.8h 3H*MedidaNIST
468.489 nmN/DB IVemission1s.6f 3F* → 1s.8g 3GMedidaNIST
468.489 nmN/DB IVemission1s.6f 3F* → 1s.8g 3GMedidaNIST
468.489 nmN/DB IVemission1s.6f 3F* → 1s.8g 3GMedidaNIST
468.5 nmN/DB IVemission1s.6h 3H* → 1s.8i 3IMedidaNIST
471.612 nm15B IIemission1s2.2p.3d 1D* → 1s2.2p.4p 1PMedidaNIST
471.99 nmN/DB IVemission1s.5p 1P* → 1s.6d 1DMedidaNIST
477.384 nmN/DB IVemission1s.5d 3D → 1s.6p 3P*MedidaNIST
477.384 nmN/DB IVemission1s.5d 3D → 1s.6p 3P*MedidaNIST
477.384 nmN/DB IVemission1s.5d 3D → 1s.6p 3P*MedidaNIST
478.42 nmN/DB IIemission1s2.2s.3d 3D → 1s2.2s.4p 3P*MedidaNIST
478.42 nmN/DB IIemission1s2.2s.3d 3D → 1s2.2s.4p 3P*MedidaNIST
478.4203 nmN/DB IIemission1s2.2s.3d 3D → 1s2.2s.4p 3P*MedidaNIST
478.4203 nmN/DB IIemission1s2.2s.3d 3D → 1s2.2s.4p 3P*MedidaNIST
478.4203 nmN/DB IIemission1s2.2s.3d 3D → 1s2.2s.4p 3P*MedidaNIST
478.4203 nmN/DB IIemission1s2.2s.3d 3D → 1s2.2s.4p 3P*MedidaNIST
481.276 nmN/DB IVemission1s.5p 3P* → 1s.6s 3SMedidaNIST
481.276 nmN/DB IVemission1s.5p 3P* → 1s.6s 3SMedidaNIST
481.276 nmN/DB IVemission1s.5p 3P* → 1s.6s 3SMedidaNIST
491.746 nm500B IIIemission1s2.4p 2P* → 1s2.5s 2SMedidaNIST
491.84 nm500B IIIemission1s2.4p 2P* → 1s2.5s 2SMedidaNIST
494.0365 nm440B IIemission1s2.2s.3d 1D → 1s2.2s.4f 1F*MedidaNIST
494.4788284 nmN/DB Vemission6h 2H* → 7i 2IMedidaNIST
494.4864305 nmN/DB Vemission6h 2H* → 7i 2IMedidaNIST
498.848 nmN/DB IIIemission1s2.5p 2P* → 1s2.7d 2DMedidaNIST
498.901 nmN/DB IIIemission1s2.5p 2P* → 1s2.7d 2DMedidaNIST
512.579 nmN/DB IIemission1s2.2s.4d 3D → 1s2.2s.7f 3F*MedidaNIST
512.579 nmN/DB IIemission1s2.2s.4d 3D → 1s2.2s.7f 3F*MedidaNIST
512.579 nmN/DB IIemission1s2.2s.4d 3D → 1s2.2s.7f 3F*MedidaNIST
515.776 nmN/DB IIIemission1s2.5d 2D → 1s2.7f 2F*MedidaNIST
515.793 nmN/DB IIIemission1s2.5d 2D → 1s2.7f 2F*MedidaNIST
516.57 nmN/DB IIIemission1s2.5f 2F* → 1s2.7g 2GMedidaNIST
516.579 nmN/DB IIIemission1s2.5f 2F* → 1s2.7g 2GMedidaNIST
522.65 nmN/DB IIIemission1s2.5d 2D → 1s2.7p 2P*MedidaNIST
522.65 nmN/DB IIIemission1s2.5d 2D → 1s2.7p 2P*MedidaNIST
522.667 nmN/DB IIIemission1s2.5d 2D → 1s2.7p 2P*MedidaNIST
526.311 nmN/DB IIemission1s2.2s.4f 3F* → 1s2.2s.7g 3GMedidaNIST
526.311 nmN/DB IIemission1s2.2s.4f 3F* → 1s2.2s.7g 3GMedidaNIST
526.311 nmN/DB IIemission1s2.2s.4f 3F* → 1s2.2s.7g 3GMedidaNIST
529.28 nmN/DB IIIemission1s2.5p 2P* → 1s2.7s 2SMedidaNIST
529.34 nmN/DB IIIemission1s2.5p 2P* → 1s2.7s 2SMedidaNIST
534.765 nm15B IIemission1s2.2s.4s 1S → 1s2.2p.3s 1P*MedidaNIST
539.322 nm30B IIemission1s2.2s.4p 1P* → 1s2.2p.3p 1PMedidaNIST
550.4527 nmN/DB Iemission2s.2p2 2D → 2s2.11f 2F*MedidaNIST
550.4622 nmN/DB Iemission2s.2p2 2D → 2s2.11f 2F*MedidaNIST
556.3146 nmN/DB Iemission2s.2p2 2D → 2s2.10f 2F*MedidaNIST
556.3244 nmN/DB Iemission2s.2p2 2D → 2s2.10f 2F*MedidaNIST
563.30717 nmN/DB Iemission2s2.3s 2S → 2s2.4p 2P*MedidaNIST
563.32732 nmN/DB Iemission2s2.3s 2S → 2s2.4p 2P*MedidaNIST
564.4278 nmN/DB Iemission2s.2p2 2D → 2s2.9f 2F*MedidaNIST
564.4379 nmN/DB Iemission2s.2p2 2D → 2s2.9f 2F*MedidaNIST
576.1901 nmN/DB Iemission2s.2p2 2D → 2s2.8f 2F*MedidaNIST
576.1901 nmN/DB Iemission2s.2p2 2D → 2s2.8f 2F*MedidaNIST
576.2006 nmN/DB Iemission2s.2p2 2D → 2s2.8f 2F*MedidaNIST
578.747 nmN/DB IIemission1s2.2s.4s 3S → 1s2.2s.5p 3P*MedidaNIST
578.747 nmN/DB IIemission1s2.2s.4s 3S → 1s2.2s.5p 3P*MedidaNIST
578.747 nmN/DB IIemission1s2.2s.4s 3S → 1s2.2s.5p 3P*MedidaNIST
581.833 nm60B Iemission2s.2p2 2P → 2s.2p.(3P*).3d 2D*MedidaNIST
582.116 nm100B Iemission2s.2p2 2P → 2s.2p.(3P*).3d 2D*MedidaNIST
582.228 nm10B Iemission2s.2p2 2P → 2s.2p.(3P*).3d 2D*MedidaNIST
594.2619 nmN/DB Iemission2s.2p2 2D → 2s2.7f 2F*MedidaNIST
594.2619 nmN/DB Iemission2s.2p2 2D → 2s2.7f 2F*MedidaNIST
594.2731 nmN/DB Iemission2s.2p2 2D → 2s2.7f 2F*MedidaNIST
601.35 nmN/DB IIemission1s2.2s.4p 3P* → 1s2.2s.6s 3SMedidaNIST
601.35 nmN/DB IIemission1s2.2s.4p 3P* → 1s2.2s.6s 3SMedidaNIST
601.35 nmN/DB IIemission1s2.2s.4p 3P* → 1s2.2s.6s 3SMedidaNIST
602.772 nmN/DB Iemission2s2.3p 2P* → 2s2.8d 2DMedidaNIST
602.837 nmN/DB Iemission2s2.3p 2P* → 2s2.8d 2DMedidaNIST
602.837 nmN/DB Iemission2s2.3p 2P* → 2s2.8d 2DMedidaNIST
608.039 nm85B IIemission1s2.2p2 1S → 1s2.2s.3p 1P*MedidaNIST
612.224 nmN/DB IIemission1s2.2p2 1S → 1s2.2s.3p 3P*MedidaNIST
612.508 nm93B IIIemission1s.2s.(3S).3s 4S → 1s.2s.(3S).3p 4P*MedidaNIST
612.752 nmN/DB IIIemission1s.2s.(3S).3s 4S → 1s.2s.(3S).3p 4P*MedidaNIST
612.797 nmN/DB IIIemission1s.2s.(3S).3s 4S → 1s.2s.(3S).3p 4P*MedidaNIST
614.891 nmN/DB IIemission1s2.2s.4d 3D → 1s2.2s.6f 3F*MedidaNIST
614.891 nmN/DB IIemission1s2.2s.4d 3D → 1s2.2s.6f 3F*MedidaNIST
614.891 nmN/DB IIemission1s2.2s.4d 3D → 1s2.2s.6f 3F*MedidaNIST
614.891 nmN/DB IIemission1s2.2s.4d 3D → 1s2.2s.6f 3F*MedidaNIST
614.891 nmN/DB IIemission1s2.2s.4d 3D → 1s2.2s.6f 3F*MedidaNIST
614.891 nmN/DB IIemission1s2.2s.4d 3D → 1s2.2s.6f 3F*MedidaNIST
617.867 nmN/DB Iemission2s2.3p 2P* → 2s2.8s 2SMedidaNIST
617.936 nmN/DB Iemission2s2.3p 2P* → 2s2.8s 2SMedidaNIST
618.638 nmN/DB IIemission1s2.2s.4f 3F* → 1s2.2p.3p 3DMedidaNIST
618.638 nmN/DB IIemission1s2.2s.4f 3F* → 1s2.2p.3p 3DMedidaNIST
618.638 nmN/DB IIemission1s2.2s.4f 3F* → 1s2.2p.3p 3DMedidaNIST
619.359 nmN/DB IIemission1s2.2s.4f 3F* → 1s2.2p.3p 3DMedidaNIST
619.359 nmN/DB IIemission1s2.2s.4f 3F* → 1s2.2p.3p 3DMedidaNIST
619.735 nmN/DB IIemission1s2.2s.4f 3F* → 1s2.2p.3p 3DMedidaNIST
622.745 nmN/DB Iemission2s2.3p 2P* → 2s2.7d 2DMedidaNIST
622.815 nmN/DB Iemission2s2.3p 2P* → 2s2.7d 2DMedidaNIST
622.815 nmN/DB Iemission2s2.3p 2P* → 2s2.7d 2DMedidaNIST
624.4557 nmN/DB Iemission2s.2p2 2D → 2s2.6f 2F*MedidaNIST
624.4557 nmN/DB Iemission2s.2p2 2D → 2s2.6f 2F*MedidaNIST
624.4681 nmN/DB Iemission2s.2p2 2D → 2s2.6f 2F*MedidaNIST
628.551 nm30B IIemission1s2.2s.3d 1D → 1s2.2s.4p 1P*MedidaNIST
634.927 nmN/DB IIemission1s2.2s.4f 3F* → 1s2.2s.6g 3GMedidaNIST
634.927 nmN/DB IIemission1s2.2s.4f 3F* → 1s2.2s.6g 3GMedidaNIST
634.927 nmN/DB IIemission1s2.2s.4f 3F* → 1s2.2s.6g 3GMedidaNIST
635.676 nm1B IIemission1s2.2s.4f 1F* → 1s2.2s.6g 1GMedidaNIST
643.151 nmN/DB Iemission2s2.3p 2P* → 2s2.7s 2SMedidaNIST
643.225 nmN/DB Iemission2s2.3p 2P* → 2s2.7s 2SMedidaNIST
652.056 nmN/DB IIemission1s2.2s.4s 3S → 1s2.2p.3s 3P*MedidaNIST
652.959 nmN/DB IIemission1s2.2s.4s 3S → 1s2.2p.3s 3P*MedidaNIST
653.371 nmN/DB IIemission1s2.2s.4s 3S → 1s2.2p.3s 3P*MedidaNIST
656.269 nmN/DB Iemission2s2.3p 2P* → 2s2.6d 2DMedidaNIST
656.345 nmN/DB Iemission2s2.3p 2P* → 2s2.6d 2DMedidaNIST
656.345 nmN/DB Iemission2s2.3p 2P* → 2s2.6d 2DMedidaNIST
657.112 nm0.5B IIemission1s2.2s.5p 1P* → 1s2.2p.3p 1DMedidaNIST
671.765 nm0.5B IIemission1s2.2s.4d 1D → 1s2.2s.6f 1F*MedidaNIST
677.866 nmN/DB Iemission2s2.4p 2P* → 2s.2p2 2PMedidaNIST
677.895 nmN/DB Iemission2s2.4p 2P* → 2s.2p2 2PMedidaNIST
678.401 nmN/DB Iemission2s2.4p 2P* → 2s.2p2 2PMedidaNIST
678.431 nmN/DB Iemission2s2.4p 2P* → 2s.2p2 2PMedidaNIST
678.614 nm0.5B IIemission1s2.2s.4p 1P* → 1s2.2s.5d 1DMedidaNIST
681.95167 nmN/DB Iemission2s.2p2 2D → 2s2.5f 2F*MedidaNIST
681.95167 nmN/DB Iemission2s.2p2 2D → 2s2.5f 2F*MedidaNIST
681.96637 nmN/DB Iemission2s.2p2 2D → 2s2.5f 2F*MedidaNIST
697.688 nmN/DB IIemission1s2.2s.3s 3S → 1s2.2s.3p 1P*MedidaNIST
703.027 nm4B IIemission1s2.2s.3s 3S → 1s2.2s.3p 3P*MedidaNIST
703.203 nm3B IIemission1s2.2s.3s 3S → 1s2.2s.3p 3P*MedidaNIST
703.233 nm2B IIemission1s2.2s.3s 3S → 1s2.2s.3p 3P*MedidaNIST
715.955 nmN/DB IIemission1s2.2p.3s 3P* → 1s2.2p.3p 3PMedidaNIST
716.016 nmN/DB IIemission1s2.2p.3s 3P* → 1s2.2p.3p 3PMedidaNIST
716.511 nmN/DB IIemission1s2.2p.3s 3P* → 1s2.2p.3p 3PMedidaNIST
716.846 nmN/DB IIemission1s2.2p.3s 3P* → 1s2.2p.3p 3PMedidaNIST
717.045 nmN/DB IIemission1s2.2p.3s 3P* → 1s2.2p.3p 3PMedidaNIST
717.602 nmN/DB IIemission1s2.2p.3s 3P* → 1s2.2p.3p 3PMedidaNIST
720.593 nmN/DB Iemission2s2.3p 2P* → 2s2.5d 2DMedidaNIST
720.685 nmN/DB Iemission2s2.3p 2P* → 2s2.5d 2DMedidaNIST
720.685 nmN/DB Iemission2s2.3p 2P* → 2s2.5d 2DMedidaNIST
720.766 nmN/DB Iemission2s2.3p 2P* → 2s2.6s 2SMedidaNIST
720.859 nmN/DB Iemission2s2.3p 2P* → 2s2.6s 2SMedidaNIST
722.85 nmN/DB IIemission1s2.2s.4s 1S → 1s2.2s.5p 1P*MedidaNIST

Propriedades ampliadas

Raios covalentes (dados ampliados)

Raio covalente (Pyykkö)
85 pm
Raio covalente (Pyykkö, ligação dupla)
78 pm
Raio covalente (Pyykkö, ligação tripla)
73 pm

Raios de van der Waals

Truhlar
192 pm
Batsanov
180 pm
Alvarez
191 pm
UFF
408,3 pm
MM3
215 pm
Dreiding
402 pm

Raios atômicos e metálicos

Raio atômico (Rahm)
205 pm
Raio metálico (C12)
98 pm

Escalas de numeração

Mendeleev
81
Pettifor
86
Glawe
86

Escalas de eletronegatividade

Ghosh
0
Miedema
5
Gunnarsson–Lundqvist
4
Robles–Bartolotti
4

Polarizabilidade e dispersão

Polarizabilidade dipolar
20,5 a.u.
Polarizabilidade dipolar (incerteza)
0,1 a.u.
C₆
99,5 Ha·Bohr6
C₆ (Gould–Bučko)
99,2 Ha·Bohr6

Parâmetros de Miedema

Volume molar de Miedema
4,7 cm3/mol
Densidade eletrônica de Miedema
5

Risco de abastecimento e economia

Concentração da produção
34
Risco relativo de abastecimento
5
Estabilidade política (maior produtor)
12
Estabilidade política (detentor das maiores reservas)
12

Transições de fase e alótropos

Ponto de fusão2350,15 K
Ponto de ebulição4273,15 K

Categorias de estados de oxidação

−5 extended
+2 extended
+3 main
0 extended
−1 extended
+1 extended

Dados de referência avançados

Constantes de blindagem (3)
nOrbitalσ
1s0,3205
2p2,5786
2s2,4238
Detalhes dos raios cristalinos (3)
CargaCNSpinrcrystal (pm)Origem
3III15
3IV25
3VI41calculated,
Modos de decaimento dos isótopos (30)
IsótopoModoIntensidade
62p—
7p100%
8B+100%
8B+A100%
9p100%
12B-100%
12B-A0,6%
13B-100%
13B-n0,3%
14B-100%
Fatores de espalhamento de raios X (502)
Energia (eV)f₁f₂
10—1,48933
10,1617—1,48084
10,3261—1,4724
10,4931—1,46401
10,6628—1,45567
10,8353—1,44738
11,0106—1,43913
11,1886—1,43093
11,3696—1,42278
11,5535—1,41467

Dados adicionais

Sources

Sources of this element.

The element is not found free in nature, but occurs as orthoboric acid usually found in certain volcanic spring waters and as borates in boron and colemantie.

Important sources of boron are ore rasorite (kernite) and tincal (borax ore). Both of these ores are found in the Mojave Desert. Tincal is the most important source of boron from the Mojave. Extensive borax deposits are also found in Turkey.

Boron exists naturally as 19.78% 10B isotope and 80.22% 11B isotope. High-purity crystalline boron may be prepared by the vapor phase reduction of boron trichloride or tribromide with hydrogen on electrically heated filaments. The impure or amorphous, boron, a brownish-black powder, can be obtained by heating the trioxide with magnesium powder.

Boron of 99.9999% purity has been produced and is available commercially. Elemental boron has an energy band gap of 1.50 to 1.56 eV, which is higher than that of either silicon or germanium.

Referências (1)

Referências

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
B

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Boron

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

Nota sobre a licença: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Boron

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

Nota sobre a licença: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Boron

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Boron

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Boron

This section provides all form of data related to element Boron.

9 PubChem Elements
Boron

The element property data was retrieved from publications.

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