Ruthenium (Ru)
transition-metalSolid
Peso atômico padrão
101,07 uConfiguração eletrônica
[Kr] 5s1 4d7Ponto de fusão
2333,85 °CPonto de ebulição
4149,85 °CDensidade
1,21e+4 kg/m³Estados de oxidação
−4, −2, +1, +2, +3, +4, +5, +6, +7, +8Eletronegatividade (Pauling)
2,2Energia de ionização (1ª)
7,3605 eVAno da descoberta
1828Raio atômico
130 pmDetalhes
Ruthenium is a hard, platinum-group transition metal with atomic number 44. It is rare in the crust and is recovered chiefly with platinum and nickel-copper sulfide ores. Chemically it is notable for a wide range of oxidation states, especially +2, +3, +4, +6, and +8, and for forming many coordination and organometallic compounds. Metallic ruthenium improves hardness and corrosion resistance in some platinum and palladium alloys, while its oxides and complexes are important in catalysis and electrochemistry.
Ruthenium is a hard, white metal and has four crystal modifications. It does not tarnish at room temperatures, but oxidizes explosively. It is attacked by halogens, hydroxides, etc. Ruthenium can be plated by electrodeposition or by thermal decomposition methods. The metal is one of the most effective hardeners for platinum and palladium, and is alloyed with these metals to make electrical contacts for severe wear resistance. A ruthenium-molybdenum alloy is said to be superconductive at 10.6 K. The corrosion resistance of titanium is improved a hundredfold by addition of 0.1% ruthenium. It is a versatile catalyst. Hydrogen sulfide can be split catalytically by light using an aqueous suspension of CdS particles loaded with ruthenium dioxide. It is thought this may have application to removal of H2S from oil refining and other industrial processes. Compounds in at least eight oxidation states have been found, but of these, the +2, +3, and +4 states are the most common. Ruthenium tetroxide, like osmium tetroxide, is highly toxic. In addition, it may explode. Ruthenium compounds show a marked resemblance to those of cadmium.
The name derives from the Latin ruthenia for the old name of Russia. It was discovered in a crude platinum ore by the Russian chemist Gottfried Wilhelm Osann in 1828. Osann thought that he had found three new metals in the sample, pluranium, ruthenium, and polinium. In 1844, Russian chemist Karl Karlovich Klaus was able to show that Osann's mistake was due to the impurity of the sample, and Klaus was able to isolate the ruthenium metal.
Ruthenium was discovered by Karl Karlovich Klaus, a Russian chemist, in 1844 while analyzing the residue of a sample of platinum ore obtained from the Ural mountains. Apparently, Jedrzej Sniadecki, a Polish chemist, had produced ruthenium in 1807 but he withdrew his claim of discovery after other scientists failed to replicate his results. Ruthenium tends to occur along with deposits of platinum and is primarily obtained as a byproduct of mining and refining platinum. Ruthenium is also obtained as a byproduct of the nickel mining operation in the Sudbury region of Ontario, Canada.
From the Latin word Ruthenia, Russia. In 1827, Berzelius and Osann examined the residues left after dissolving crude platinum from the Ural mountains in aqua regia. While Berzelius found no unusual metals, Osann thought he found three new metals, one of which he named ruthenium. In 1844 Klaus, generally recognized as the discoverer, showed that Osann's ruthenium oxide was very impure and that it contained a new metal. Klaus obtained 6 g of ruthenium from the portion of crude platinum that is insoluble in aqua regia.
Pure ruthenium is a silvery gray, lustrous metal. It is hard and brittle at ordinary temperatures, has a high melting point, and resists attack by air, water, and many acids. Finely divided metal has a much larger reactive surface than compact metal.
Small additions of ruthenium harden platinum and palladium alloys used for wear-resistant electrical contacts, jewelry alloys, and some laboratory or industrial components. Ruthenium-containing materials are used in thick-film resistors and pastes for electronic circuits. Ruthenium dioxide, RuO₂, is an electrically conducting oxide used in electrochemical electrodes and as a catalyst component. Ruthenium complexes are also used as homogeneous catalysts, including catalysts for olefin metathesis and transfer hydrogenation. The radioisotope ¹⁰⁶Ru has been used in ophthalmic brachytherapy sources.
Ruthenium is primarily used as an alloying agent. Adding 0.1% ruthenium to titanium makes titanium 100 times more resistant to corrosion. Small amounts of ruthenium are added to platinum and palladium to strengthen them. These alloys are used in jewelry and in electrical contacts that must resist wear.
Isotopes in Earth/Planetary Science
100Ru is the product of a rare (and hence very long-lived) nuclear decay process from the double beta decay of 100Mo. A careful measurement of the half-life for this decay, which is 7.1×1018 years, can be used to place an upper limit on the mass of the electron neutrino, which is a neutral and weakly interacting subatomic particle first postulated by Wolfgang Pauli in 1930 [326] M. J. Hornish, L. De Braeckeleer, A. S. Barabash, V. I. Umatov. Phys. Rev. C74, 044314 (2006)..
Ruthenium and molybdenum share many similarities. They both have seven isotopes (96, 98, 99, 100, 101, 102, and 104 for ruthenium and 92, 94, 95, 96, 97, 98, and 100 for molybdenum), and their isotopes are formed by the same nucleosynthesisp-processes, r-processes, and s-processes, namely, p, r, s and r, s only, s and r, s and r, and r, respectively. The molybdenum and ruthenium isotopic composition of most meteorites lie along a mixing line (Fig. IUPAC.44.1). The ruthenium and molybdenum of silicates in the Earth also lie on this line, which supports the hypothesis that the Earth accreted homogeneously. That is, the feeding zone of the Earth did not change substantially over time as both the bulk of the Earth and the late veneer accreted from material having the same ruthenium-molybdenum isotopic reservoir [327] N. Dauphas, A. M. Davis, B. Marty, L. Reisberg. Earth Planet. Sci. Lett.226, 465 (2004)..
Isotopes in Medicine
106Ru plaque brachytherapy has been used for eye preservation and tumor control of uveal (the middle layer of the wall of the eye) melanoma [333] L. Tarmann, W. Wackernagel, A. Avian, C. Mayer, M. Schneider, P. Winkler, G. Langmann. Br. J. Ophthalmol.99, 1644 (2015).. The half-life of 106Ru is 373 days.
Isotopes Used as a Source of Radioactive Isotope(s)
96Ru is used to produce radioisotopes 94Ru (with a half-life of 52 min) and 95Ru (with half-life of about 1.64 h) via the reactions 96Ru (n, 3n) 94Ru and 96Ru (n, 2n) 95Ru, respectively (Fig. IUPAC.44.2) [334] A. R. Ketring, G. J. Ehrhardt, M. F. Embree, T. T. Tyler, J. A. Gawenis, S. S. Jurisson, H. P. Engelbrecht, C. J. Smith, C. S. Cutler. Alasbimn J.5 (19), (2003)., [335] J. W. Arblaster. Platinum Met. Rev.55, 124 (2011).. 104Ru is used to produce the radioisotope 105Rh (with a half-life of about 35 h) via the reaction 104Ru (p, γ) 105Rh. 105Rh has been used in the treatment of bone pain [334] A. R. Ketring, G. J. Ehrhardt, M. F. Embree, T. T. Tyler, J. A. Gawenis, S. S. Jurisson, H. P. Engelbrecht, C. J. Smith, C. S. Cutler. Alasbimn J.5 (19), (2003)..
Ruthenium chemistry spans many oxidation states, with +2, +3, and +4 common in coordination compounds and oxides. Ruthenium(III) chloride, RuCl₃, is a common precursor for laboratory synthesis, although commercial material may be hydrated or non-stoichiometric. Ruthenium dioxide, RuO₂, is a stable, conductive oxide with rutile-type structure. Ruthenium tetroxide, RuO₄, contains ruthenium in the +8 state and is a volatile, powerful oxidant. Organometallic ruthenium compounds include arene complexes and carbene complexes used in catalysis.
See more information at the Ruthenium compound page.
Bulk ruthenium metal is relatively inert, but dusts and powders can be fire or inhalation hazards in industrial handling. Soluble ruthenium salts and many complexes should be treated as toxic unless specifically characterized. Ruthenium tetroxide, RuO₄, is especially hazardous because it is volatile, strongly oxidizing, and damaging to tissue. Radioactive isotopes such as ¹⁰⁶Ru present isotope-specific radiation and contamination risks, particularly if dispersed as fine particles or volatile species.
Ruthenium occurs naturally at very low concentrations, mainly associated with platinum-group minerals and sulfide ore systems rather than as a major independent mineral resource. In surface environments it is generally immobile as metal or insoluble oxide, but soluble complexes can behave differently under oxidizing or complexing conditions. Anthropogenic releases are normally small and localized, except in special cases involving mining, refining, industrial catalysts, or nuclear fission products.
Ruthenium is produced as a by-product during refining of platinum-group metal concentrates and, to a lesser extent, nickel-copper sulfide ores. Supply is therefore tied to the mining and refining of other metals rather than to primary ruthenium mining. Demand is modest compared with platinum, palladium, and rhodium, but specialized uses in electronics, catalysts, electrochemical materials, and alloys can require high purity. Recycling occurs from some spent catalysts, electronic materials, and precious-metal alloys, although recovery depends strongly on concentration and process economics.
A member of the platinum group, ruthenium occurs native with other members of the group in ores found in the Ural mountains and in North and South America. It is also found along with other platinum metals in small but commercial quantities in pentlandite in the Sudbury, Ontario nickel-mining region, and in the pyroxinite deposits of South Africa.
Ruthenium is a heavy element formed mainly by neutron-capture nucleosynthesis in earlier generations of stars. It is far less abundant cosmically than iron-group elements, but it is present in meteorites and planetary materials at trace levels. Its association with other platinum-group elements reflects both nucleosynthetic origin and geochemical partitioning into metal-rich and sulfide-rich phases.
- Ruthenium was named from Ruthenia, a historical Latin name associated with parts of Eastern Europe.
- It is one of the least abundant stable platinum-group metals in Earth’s crust.
- Ruthenium tetroxide, RuO₄, is volatile despite being an oxide of a heavy metal.
- The metal can form a passive oxide surface that contributes to corrosion resistance.
- Some commercial RuCl₃ is not a simple anhydrous compound but a mixture of hydrated chloride species.
- Ruthenium catalysts are central to many well-known olefin metathesis reactions.
Imagens
Propriedades
Física
- Raio atômico (empírico)
- 130 pm Comparar Raio atômico (empírico) de todos os elementos →
- Raio covalente
- 146 pm Comparar Raio covalente de todos os elementos →
- Raio de van der Waals
- 207 pm Comparar Raio de van der Waals de todos os elementos →
- Raio metálico
- 125 pm Comparar Raio metálico de todos os elementos →
- Densidade
- 1,21 × 104 kg/m³ Comparar Densidade de todos os elementos →
- Volume molar
- 0,0083 L/mol
- Fase nas CNTP
- Sólido Comparar Fase nas CNTP de todos os elementos →
- Ponto de fusão
- 2333,85 °C Comparar Ponto de fusão de todos os elementos →
- Ponto de ebulição
- 4149,85 °C Comparar Ponto de ebulição de todos os elementos →
- Condutividade térmica
- 117 W/(m·K) Comparar Condutividade térmica de todos os elementos →
- Capacidade calorífica específica
- 0,238 J/(g·K) Comparar Capacidade calorífica específica de todos os elementos →
- Capacidade calorífica molar
- 24,06 J/(mol·K) Comparar Capacidade calorífica molar de todos os elementos →
- Estrutura cristalina
- Hexagonal compacta Comparar Estrutura cristalina de todos os elementos →
Química
- Eletronegatividade (Pauling)
- 2,2 Comparar Eletronegatividade (Pauling) de todos os elementos →
- Eletronegatividade (Allen)
- 1,54
- Afinidade eletrônica
- 1,05 eV
- Energia de ionização (1ª)
- 7,3605 eV Comparar Energia de ionização (1ª) de todos os elementos →
- Energia de ionização (2ª)
- 16,760058 eV Comparar Energia de ionização (2ª) de todos os elementos →
- Energia de ionização (3ª)
- 28,470098 eV Comparar Energia de ionização (3ª) de todos os elementos →
- Energia de ionização (4ª)
- 45,000155 eV Comparar Energia de ionização (4ª) de todos os elementos →
- Energia de ionização (5ª)
- 59,000203 eV Comparar Energia de ionização (5ª) de todos os elementos →
- Estados de oxidação
- −4, −2, +1, +2, +3, +4, +5, +6, +7, +8 Comparar Estados de oxidação de todos os elementos →
- Elétrons de valência
- 8 Comparar Elétrons de valência de todos os elementos →
- Configuração eletrônica
- [Kr] 5s1 4d7
Termodinâmica
- Calor de fusão
- 0,24874333 eV Comparar Calor de fusão de todos os elementos →
- Calor de vaporização
- 6,166762 eV Comparar Calor de vaporização de todos os elementos →
- Calor de sublimação
- 6,736798 eV
- Calor de atomização
- 6,736798 eV
- Entalpia de atomização
- 6,743017 eV
Nuclear
- Prótons
- 44 Comparar Prótons de todos os elementos →
- Nêutrons
- 58 Comparar Nêutrons de todos os elementos →
- Isótopos conhecidos
- 41 Comparar Isótopos conhecidos de todos os elementos →
- Isótopos estáveis
- 6 Comparar Isótopos estáveis de todos os elementos →
- Isótopo mais estável
- Ru-102
- Ano da descoberta
- 1828
Abundância
- Abundância (crosta terrestre)
- 0,001 mg/kg Comparar Abundância (crosta terrestre) de todos os elementos →
- Abundância (oceano)
- 7 × 10−7 mg/L Comparar Abundância (oceano) de todos os elementos →
Estrutura cristalina
- Constante de rede a
- 270 pm
Estrutura eletrônica
- Elétrons por camada
- 2, 8, 18, 15, 1 Comparar Elétrons por camada de todos os elementos →
Identificadores
- Número CAS
- 7440-18-8 Comparar Número CAS de todos os elementos →
- Símbolo de termo
- 5F5
- InChI
- InChI=1S/Ru
- Chave InChI
- KJTLSVCANCCWHF-UHFFFAOYSA-N
Configuração eletrônica Medido
Ru: 4d⁷ 5s¹[Kr] 4d⁷ 5s¹1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d⁷ 5s¹Modelo atômico
Os isótopos alteram o número de nêutrons, a massa e a estabilidade — não a configuração eletrônica de um átomo neutro.
Modelo atômico esquemático, sem escala.
Assinatura atômica
Espectro de emissão / absorção
Distribuição isotópica
| Número de massa | Massa atômica (u) | Abundância natural | Meia-vida |
|---|---|---|---|
| 98 Estável | 97,9052868 ± 0,0000069 | 1,8700% | Estável |
| 99 Estável | 98,9059341 ± 0,0000011 | 12,7600% | Estável |
| 100 Estável | 99,9042143 ± 0,0000011 | 12,6000% | Estável |
| 101 Estável | 100,9055769 ± 0,0000012 | 17,0600% | Estável |
| 102 Estável | 101,9043441 ± 0,0000012 | 31,5500% | Estável |
| 104 Estável | 103,9054275 ± 0,0000028 | 18,6200% | Estável |
Fase / Estado
Motivo: 2308,8 °C abaixo do ponto de fusão (2333,85 °C)
Esquemático, sem escala
Pontos de transição de fase
Energias de transição
Energia necessária para fundir 1 mol no ponto de fusão
Energia necessária para vaporizar 1 mol no ponto de ebulição
Energia necessária para sublimar 1 mol no ponto de sublimação
Densidade
Em condições padrão
Em condições padrão
Espectros atômicos
Mostrando 10 de 44. Ordenado por carga do íon (ordem crescente).
Dados de linhas disponíveis ?
| Íon | Carga | Total de linhas | Probabilidades de transição | Designações dos níveis |
|---|---|---|---|---|
| Ru I | 0 | 541 | 11 | 519 |
| Ru II | +1 | 59 | 8 | 59 |
| Ru III | +2 | 93 | 0 | 0 |
Dados de níveis disponíveis ?
| Íon | Carga | Níveis |
|---|---|---|
| Ru I | 0 | 329 |
| Ru II | +1 | 235 |
| Ru III | +2 | 26 |
| Ru IV | +3 | 2 |
| Ru V | +4 | 2 |
| Ru VI | +5 | 2 |
| Ru VII | +6 | 2 |
| Ru VIII | +7 | 2 |
| Ru IX | +8 | 2 |
| Ru X | +9 | 2 |
Raios iônicos
| Carga | Coordenação | Spin | Raio |
|---|---|---|---|
| +3 | 6 | N/D | 68 pm |
| +4 | 6 | N/D | 62 pm |
| +5 | 6 | N/D | 56.49999999999999 pm |
| +7 | 4 | N/D | 38 pm |
| +8 | 4 | N/D | 36 pm |
Compostos
Isótopos (6)
| Número de massa | Massa atômica (u) | Abundância natural | Meia-vida | Modo de decaimento | |
|---|---|---|---|---|---|
| 98 Estável | 97,9052868 ± 0,0000069 | 1,8700% ± 0,0300% | Estável | stable | |
| 99 Estável | 98,9059341 ± 0,0000011 | 12,7600% ± 0,1400% | Estável | stable | |
| 100 Estável | 99,9042143 ± 0,0000011 | 12,6000% ± 0,0700% | Estável | stable | |
| 101 Estável | 100,9055769 ± 0,0000012 | 17,0600% ± 0,0200% | Estável | stable | |
| 102 Estável | 101,9043441 ± 0,0000012 | 31,5500% ± 0,1400% | Estável | stable | |
| 104 Estável | 103,9054275 ± 0,0000028 | 18,6200% ± 0,2700% | Estável | stable |
Propriedades ampliadas
Raios covalentes (dados ampliados)
- Raio covalente (Pyykkö)
- 125 pm
- Raio covalente (Pyykkö, ligação dupla)
- 114 pm
- Raio covalente (Pyykkö, ligação tripla)
- 103 pm
Raios de van der Waals
- Batsanov
- 205 pm
- Alvarez
- 246 pm
- UFF
- 296,3 pm
- MM3
- 234 pm
Raios atômicos e metálicos
- Raio atômico (Rahm)
- 237 pm
- Raio metálico (C12)
- 134 pm
Escalas de numeração
- Mendeleev
- 60
- Pettifor
- 63
- Glawe
- 61
Escalas de eletronegatividade
- Ghosh
- 0
- Miedema
- 5
- Gunnarsson–Lundqvist
- 4
- Robles–Bartolotti
- 3
Polarizabilidade e dispersão
- Polarizabilidade dipolar
- 72 a.u.
- Polarizabilidade dipolar (incerteza)
- 10 a.u.
- C₆ (Gould–Bučko)
- 809 Ha·Bohr6
Afinidade química
- Afinidade protônica
- 774 kJ/mol
- Basicidade em fase gasosa
- 751,4 kJ/mol
Parâmetros de Miedema
- Volume molar de Miedema
- 8,2 cm3/mol
- Densidade eletrônica de Miedema
- 6
Risco de abastecimento e economia
- Concentração da produção
- 60
- Risco relativo de abastecimento
- 8
- Distribuição das reservas
- 95
- Estabilidade política (maior produtor)
- 44
- Estabilidade política (detentor das maiores reservas)
- 44
Transições de fase e alótropos
| Ponto de fusão | 2606,15 K |
| Ponto de ebulição | 4420,15 K |
Categorias de estados de oxidação
Dados de referência avançados
Constantes de blindagem (10)
| n | Orbital | σ |
|---|---|---|
| 1 | s | 0,9077 |
| 2 | p | 4,0492 |
| 2 | s | 11,6202 |
| 3 | d | 14,6411 |
| 3 | p | 16,7789 |
| 3 | s | 16,3988 |
| 4 | d | 31,1872 |
| 4 | p | 27,5652 |
| 4 | s | 26,344 |
| 5 | s | 37,5155 |
Detalhes dos raios cristalinos (5)
| Carga | CN | Spin | rcrystal (pm) | Origem |
|---|---|---|---|---|
| 3 | VI | 82 | ||
| 4 | VI | 76 | from r^3 vs V plots, from metallic oxides, | |
| 5 | VI | 70,5 | estimated, from r^3 vs V plots, | |
| 7 | IV | 52 | ||
| 8 | IV | 50 |
Modos de decaimento dos isótopos (62)
| Isótopo | Modo | Intensidade |
|---|---|---|
| 85 | B+ | — |
| 85 | B+p | — |
| 85 | p | — |
| 86 | B+ | — |
| 86 | B+p | — |
| 87 | B+ | — |
| 87 | B+p | — |
| 88 | B+ | 100% |
| 88 | B+p | 3,6% |
| 89 | B+ | 100% |
Fatores de espalhamento de raios X (615)
| Energia (eV) | f₁ | f₂ |
|---|---|---|
| 10 | — | 1,51919 |
| 10,1617 | — | 1,51438 |
| 10,3261 | — | 1,51486 |
| 10,4931 | — | 1,54335 |
| 10,6628 | — | 1,57238 |
| 10,8353 | — | 1,60195 |
| 11,0105 | — | 1,63207 |
| 11,1886 | — | 1,66277 |
| 11,3696 | — | 1,7032 |
| 11,5535 | — | 1,79614 |
Dados adicionais
Estimated Crustal Abundance
The estimated element abundance in the earth's crust.
1×10-3 milligrams per kilogram
Referências (1)
- [5] Ruthenium https://education.jlab.org/itselemental/ele044.html
Estimated Oceanic Abundance
The estimated element abundance in the earth's oceans.
7×10-7 milligrams per liter
Referências (1)
- [5] Ruthenium https://education.jlab.org/itselemental/ele044.html
Sources
Sources of this element.
A member of the platinum group, ruthenium occurs native with other members of the group in ores found in the Ural mountains and in North and South America. It is also found along with other platinum metals in small but commercial quantities in pentlandite in the Sudbury, Ontario nickel-mining region, and in the pyroxinite deposits of South Africa.
Referências (1)
- [6] Ruthenium https://periodic.lanl.gov/44.shtml
Production
Production of this element (from raw materials or other compounds containing the element).
The metal is isolated commercially by a complex chemical process, the final stage of which is the hydrogen reduction of ammonium ruthenium chloride, which yields a powder. The powder is consolidated by powder metallurgy techniques or by argon-arc welding.
Referências (1)
- [6] Ruthenium https://periodic.lanl.gov/44.shtml
Referências
(9)
Data deposited in or computed by PubChem
The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.
Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.
The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.
Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/
The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.
The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database
This section provides all form of data related to element Ruthenium.
The element property data was retrieved from publications.