Zinc (Zn)
transition-metalSolid
Peso atômico padrão
65,38 uConfiguração eletrônica
[Ar] 4s2 3d10Ponto de fusão
419,53 °CPonto de ebulição
906,85 °CDensidade
7134 kg/m³Estados de oxidação
−2, 0, +1, +2Eletronegatividade (Pauling)
1,65Energia de ionização (1ª)
9,394197 eVAno da descoberta
1746Raio atômico
135 pmDetalhes
Zinc is a moderately reactive, bluish-white transition metal with a filled 3d shell and chemistry dominated by the +2 oxidation state. It is an essential trace element for living organisms and an important industrial metal, especially for corrosion protection of steel. In minerals it occurs chiefly as sulfide and carbonate ores, and in technology it is valued for sacrificial galvanic behavior, alloy formation, and stable, often colorless Zn²⁺ compounds.
Zinc is a bluish-white, lustrous metal. It is brittle at ordinary temperatures but malleable at 100 to 150°C. It is a fair conductor of electricity, and burns in air at high red heat with evolution of white clouds of the oxide.
It exhibits superplasticity. Neither zinc nor zirconium is ferromagnetic; but ZrZn2 exhibits ferromagnetism at temperatures below 35°K. It has unusual electrical, thermal, optical, and solid-state properties that have not been fully investigated.
The name derives from the German zink of unknown origin. It was first used in prehistoric times, where its compounds were used for healing wounds and sore eyes and for making brass. Zinc was recognized as a metal as early as 1374.
Although zinc compounds have been used for at least 2,500 years in the production of brass, zinc wasn't recognized as a distinct element until much later. Metallic zinc was first produced in India sometime in the 1400s by heating the mineral calamine (ZnCO3) with wool. Zinc was rediscovered by Andreas Sigismund Marggraf in 1746 by heating calamine with charcoal. Today, most zinc is produced through the electrolysis of aqueous zinc sulfate (ZnSO4).
From the German word Zink, of obscure origin. Centuries before zinc was recognized as a distinct element, zinc ores were used for making brass. An alloy containing 87 percent zinc has been found in prehistoric ruins in Transylvania.
Metallic zinc was produced in the 13th century A.D. India by reducing calamine with organic substances such as wool. The metal was rediscovered in Europe by Marggraf in 1746. He demonstrated that zinc could be obtained by reducing calamine with charcoal.
Pure zinc is a lustrous bluish-white metal when freshly cut, but it dulls in air as a thin protective surface film forms. It is brittle near room temperature in coarse cast form, becomes more workable when warmed, and melts at a comparatively low temperature for a structural metal.
The largest use of zinc is galvanizing, where a zinc coating protects iron and steel by forming a barrier and by acting as a sacrificial anode. Zinc is also used in brass and other alloys, die-cast components, roofing sheet, and anodes for batteries. Zinc oxide is used in rubber, ceramics, pigments, sunscreens, and topical preparations. Zinc is essential in nutrition, but supplemental or medicinal uses depend on specific compounds and doses rather than the metal itself.
Roughly one third of all metallic zinc produced today is used in a process known as galvanization. During galvanization, an object that is subject to corrosion, such as an iron nail, is given a protective coating of zinc. The zinc can be applied to an object by dipping it in a pool of molten zinc, but it is most often applied through an electroplating process. Sacrificial zinc anodes are used in cathodic protection systems to protect exposed iron from corrosion. Metallic zinc is also used to make dry cell batteries, roof cladding and die castings.
Zinc is used to make many useful alloys. Brass, an alloy of zinc that contains between 55% and 95% copper, is probably the best known zinc alloy. Brass was first used about 2,500 years ago and was widely used by the ancient Romans, who used it to make such things as coins, kettles and decorative items. Brass is still used today, particularly in musical instruments, screws and other hardware that must resist corrosion. Zinc is alloyed with lead and tin to make solder, a metal with a relatively low melting point used to join electrical components, pipes and other metallic items. Prestal®, an alloy containing 78% zinc and 22% aluminum, is a strange material that is nearly as strong as steel but is molded as easily as plastic. Nickel silver, typewriter metal, spring brass and German silver are other common zinc alloys.
Zinc oxide (ZnO), a common zinc compound, forms when metallic zinc is exposed to the air and forms a protective coating that protects the rest of the metal. Zinc oxide is used in paints, some rubber products, cosmetics, pharmaceuticals, plastics, printing inks, soap and batteries, among other things. Zinc sulfide (ZnS), another zinc compound, glows when it is exposed to ultraviolet light, X-rays or electrons and is used to make luminous watch dials, television screens and fluorescent light bulbs. Zinc chloride (ZnCl2) is another zinc compound that is used to protect wood from decay and insects.
The metal is employed to form numerous alloys with other metals. Brass, nickel silver, typewriter metal, commercial bronze, spring bronze, German silver, soft solder, and aluminum solder are some of the more important alloys.
Large quantities of zinc are used to produce die castings, which are used extensively by the automotive, electrical, and hardware industries. An alloy called Prestal(R), consisting of 78 percent zinc and 22 percent aluminum, is reported to be almost as strong as steel and as easy to mold as plastic. The alloy said to be so moldable that it can be molded into form using inexpensive ceramics or cement die casts.
Zinc is also used extensively to galvanize other metals such as iron to prevent corrosion. Zinc oxide is a unique and very useful material for modern civilization. It is widely used in the manufacture of paints, rubber products, cosmetics, pharmaceuticals, floor coverings, plastics, printing inks, soap, storage batteries, textiles, electrical equipment, and other products. Lithopone, a mixture of zinc sulfide and barium sulfate, is an important pigment.
Zinc sulfide is used in making luminous dials, X-ray and TV screens, and fluorescent lights.
The chloride and chromate are also important compounds. Zinc is an essential element in the growth of human beings and animals. Tests show that zinc-deficient animals require 50 percent more food to gain the same weight as an animal supplied with sufficient zinc.
Isotopes in Earth/Planetary Science
Molecules, atoms, and ions of the stable isotopes of zinc possess slightly different physical and chemical properties, and they commonly will be fractionated during physical, chemical, and biological processes, giving rise to variations in isotopic abundances and in atomic weights. There are measureable variations in the isotopic abundances of zinc in natural terrestrial materials (Fig. IUPAC.30.1). Stable zinc isotopes have been used as tracers to investigate biogeochemical and chemical processes in environmental contamination sites [243] M. Bigalke, S. Weyer, J. Kobza, W. Wilcke. Geochim. Cosmochim. Acta74, 6801 (2010).. The isotope-amount ratio n(66Zn)/n(64Zn) can be used as an environmental tracer for detecting the pathways of anthropogenic zinc [244] Y. Sivry, J. Riotte, J. E. Sonke, S. Audry, J. Schafer, J. Viers, G. Blanc, R. Freydier, B. Dupre. Chem. Geol.255, 295 (2008)., [245] C. Cloquet, J. Carignan, G. Libourel. Environ. Sci. Technol.40, 6594 (2006)., [246] J. Chen, J. Gaillardet, P. Louvat. Environ. Sci. Technol.42, 6494 (2008)..
Isotopes in Medicine
Oral tracers of enriched 67Zn and intravenously injected stable isotopic tracers with enriched 70Zn are used simultaneously to determine the fraction of dietary zinc absorbed in humans, maintaining the amount or concentration of a nutrient or biomolecule in organs and body fluids. For example, zinc-isotope tracers can be administered to humans to determine if zinc absorption in their bodies may be impaired by ingestion of certain foods, food components, or dietary supplements. One such study conducted with Peruvian women showed that prenatal iron supplements affected the absorption of zinc during pregnancy. Another isotope tracer study investigated zinc deficiency in children with Crohn’s disease (an inflammatory disease of the intestines, especially the colon and ileum) [249] K. O’Brien, N. Zavaleta, L. Caulfield, J. Wen, S. Abrams. J. Nutr.130, 2251 (2000)., [250] I. J. Griffin, S. C. Kim, P. D. Hicks, L. K. Liang, S. A. Abrams. Pediatr. Res.56, 235 (2004).. Zinc radioisotopes (e.g. 65Zn, with a half-life of 244 days) can also be used for determining zinc absorption in humans, but they are now used rarely because of radiation hazards [251] K. B. Payton, P. R. Flanagan, E. A. Stinson, D. P. Chodirker, M. J. Chamberlain, L. S. Valberg. Gastroenterology83, 1264 (1982)., [252] N. M. Lowe, L. R. Woodhouse, J. S. Matel, J. C. King. Am. J. Clin. Nutr.71, 523 (2000).. ZnO nanoparticles enriched with 67Zn have been used as biological/environmental nanotoxicity tracers [253] A. D. Dybowska, M. N. Croteau, S. K. Misra, D. Berhanu, S. N. Luoma, P. Christian, P. O’Brien, E. Valsami-Jones. Environ. Pollut.159, 266 (2011)..
Isotopes Used as a Source of Radioactive Isotope(s)
The 68Zn (p, 2p) 67Cu (with a half-life of 62 h) reaction in which targets with zinc enriched in 68Zn are irradiated and the neutron induced reaction 67Zn (n, p) 67Cu are both processes for producing 67Cu for radiotherapy [254] T. Katabuchi, S. Watanabe, N. S. Ishioka, Y. Iida, H. Hanaoka, K. Endo, S. Matsuhashi. J. Radioanal. Nucl. Chem.277, 467 (2008).. Irradiation of 64Zn with a deuteron (the nucleus of 2H, consisting of a proton and a neutron) in a cyclotron will produce the radioisotope 64Cu (with a half-life of 12.7 h), which can be used for therapeutic applications and diagnosis with positron emission tomography (PET) via the 64Zn (d, 2p) 64Cu reaction [255] K. Abbas, J. Kozempel, M. Bonardi, F. Groppi, A. Alfarano, U. Holzwarth, F. Simonelli, H. Hofman, W. Horstmann, E. Menapace, L. Leseticky, N. Gibson. Appl. Radiat. Isot.64, 1001 (2006)..
Zinc chemistry is mainly Zn²⁺, with little stable redox chemistry in water because the d¹⁰ ion is not easily oxidized or reduced under ordinary conditions. Important compounds include zinc oxide, ZnO, a white amphoteric oxide; zinc sulfide, ZnS, a major ore mineral and phosphor host; zinc sulfate, ZnSO₄, used in industry and agriculture; and zinc chloride, ZnCl₂, a hygroscopic Lewis-acidic salt. Zinc also forms many coordination complexes, and organozinc reagents are useful in synthetic chemistry.
See more information at the Zinc compound page.
Zinc is nutritionally essential, but excessive intake of soluble zinc salts can cause toxicity and can interfere with copper metabolism. Fumes from freshly formed zinc oxide, ZnO, produced during welding or cutting galvanized metal, can cause metal fume fever. Zinc dust is combustible under suitable conditions, and some soluble or strongly acidic zinc compounds are irritants or environmentally hazardous at elevated concentrations. The stable isotopes are not radioactive hazards.
Zinc is not considered to be toxic, but when freshly formed ZnO is inhaled a disorder known as oxide shakes or zinc chills sometimes occurs. Where zinc oxide is encountered, recommendations include providing good ventilation to avoid concentration exceeding 5 mg/m3, (time-weighted over an 8-hour exposure, 40-hour work week).
Zinc is naturally released by rock weathering, volcanic emissions, and biological cycling, and it is also mobilized by mining, smelting, tire wear, galvanized materials, and waste streams. In soils and waters it partitions among dissolved Zn²⁺, mineral surfaces, organic matter, sulfides, and carbonates, so pH and redox conditions strongly affect mobility. It is an essential micronutrient, but elevated bioavailable zinc can harm aquatic organisms and soil microbiota.
Zinc is a major base metal produced primarily from sphalerite-rich ores, commonly after concentration by flotation. Roasted concentrates are processed by electrolytic or pyrometallurgical routes, with sulfur captured largely as sulfuric acid, H₂SO₄, in modern plants. Demand is closely tied to steel galvanizing, construction, transport, die casting, brass, and batteries. Recycling is significant from brass scrap, galvanized steel dusts, and die-cast alloys, although dispersed coatings are harder to recover efficiently than bulk metal scrap.
The principal ores of zinc are sphalerite (sulfide), smithsonite (carbonate), calamine (silicate), and franklinite (zinc, manganese, iron oxide). One method of zinc extraction involves roasting its ores to form the oxide and reducing the oxide with coal or carbon, with subsequent distillation of the metal.
Zinc is less cosmically abundant than iron-group elements such as iron and nickel, but it is a normal constituent of the solar system and of many stellar spectra. Its stable isotopes are produced by several nucleosynthetic pathways in massive stars and supernova environments. In planetary materials zinc is moderately volatile, so its abundance can record thermal processing during planet formation and impact history.
- Zinc coatings can protect exposed scratches because zinc corrodes preferentially to iron.
- Brass, a copper-zinc alloy, was made long before zinc was isolated as a pure metal in Europe.
- Zinc oxide is white, but it turns yellow when hot and becomes white again on cooling.
- Many enzymes use Zn²⁺ as a structural or catalytic center without changing its oxidation state.
- Sphalerite, the main zinc ore, can contain economically important cadmium, indium, or germanium impurities.
Imagens
Propriedades
Física
- Raio atômico (empírico)
- 135 pm Comparar Raio atômico (empírico) de todos os elementos →
- Raio covalente
- 122 pm Comparar Raio covalente de todos os elementos →
- Raio de van der Waals
- 139 pm Comparar Raio de van der Waals de todos os elementos →
- Raio metálico
- 121 pm Comparar Raio metálico de todos os elementos →
- Densidade
- 7134 kg/m³ Comparar Densidade de todos os elementos →
- Volume molar
- 0,0092 L/mol
- Fase nas CNTP
- Sólido Comparar Fase nas CNTP de todos os elementos →
- Ponto de fusão
- 419,53 °C Comparar Ponto de fusão de todos os elementos →
- Ponto de ebulição
- 906,85 °C Comparar Ponto de ebulição de todos os elementos →
- Condutividade térmica
- 116 W/(m·K) Comparar Condutividade térmica de todos os elementos →
- Capacidade calorífica específica
- 0,388 J/(g·K) Comparar Capacidade calorífica específica de todos os elementos →
- Capacidade calorífica molar
- 25,39 J/(mol·K) Comparar Capacidade calorífica molar de todos os elementos →
- Estrutura cristalina
- Hexagonal compacta Comparar Estrutura cristalina de todos os elementos →
Química
- Eletronegatividade (Pauling)
- 1,65 Comparar Eletronegatividade (Pauling) de todos os elementos →
- Eletronegatividade (Allen)
- 1,59
- Afinidade eletrônica
- -0,6 eV (valor negativo — prevê-se que o átomo não capte um eletrão adicional)
- Energia de ionização (1ª)
- 9,394197 eV Comparar Energia de ionização (1ª) de todos os elementos →
- Energia de ionização (2ª)
- 17,964452 eV Comparar Energia de ionização (2ª) de todos os elementos →
- Energia de ionização (3ª)
- 39,723437 eV Comparar Energia de ionização (3ª) de todos os elementos →
- Energia de ionização (4ª)
- 59,573205 eV Comparar Energia de ionização (4ª) de todos os elementos →
- Energia de ionização (5ª)
- 82,600284 eV Comparar Energia de ionização (5ª) de todos os elementos →
- Estados de oxidação
- −2, 0, +1, +2 Comparar Estados de oxidação de todos os elementos →
- Elétrons de valência
- 12 Comparar Elétrons de valência de todos os elementos →
- Configuração eletrônica
- [Ar] 4s2 3d10
Termodinâmica
- Calor de fusão
- 0,07617764 eV Comparar Calor de fusão de todos os elementos →
- Calor de vaporização
- 1,195004 eV Comparar Calor de vaporização de todos os elementos →
- Calor de sublimação
- 1,351505 eV
- Calor de atomização
- 1,351505 eV
- Entalpia de atomização
- 1,351505 eV
Nuclear
- Prótons
- 30 Comparar Prótons de todos os elementos →
- Nêutrons
- 36 Comparar Nêutrons de todos os elementos →
- Isótopos conhecidos
- 33 Comparar Isótopos conhecidos de todos os elementos →
- Isótopos estáveis
- 3 Comparar Isótopos estáveis de todos os elementos →
- Isótopo mais estável
- Zn-66
- Ano da descoberta
- 1746
Abundância
- Abundância (crosta terrestre)
- 70 mg/kg Comparar Abundância (crosta terrestre) de todos os elementos →
- Abundância (oceano)
- 0,005 mg/L Comparar Abundância (oceano) de todos os elementos →
Estrutura cristalina
- Constante de rede a
- 266 pm
Estrutura eletrônica
- Elétrons por camada
- 2, 8, 18, 2 Comparar Elétrons por camada de todos os elementos →
Identificadores
- Número CAS
- 7440-66-6 Comparar Número CAS de todos os elementos →
- Símbolo de termo
- 1S0
- InChI
- InChI=1S/Zn
- Chave InChI
- HCHKCACWOHOZIP-UHFFFAOYSA-N
Configuração eletrônica Medido
Zn: 3d¹⁰ 4s²[Ar] 3d¹⁰ 4s²1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s²Modelo atômico
Os isótopos alteram o número de nêutrons, a massa e a estabilidade — não a configuração eletrônica de um átomo neutro.
Modelo atômico esquemático, sem escala.
Assinatura atômica
Espectro de emissão / absorção
Distribuição isotópica
| Número de massa | Massa atômica (u) | Abundância natural | Meia-vida |
|---|---|---|---|
| 66 Estável | 65,92603381 ± 0,00000094 | 27,7300% | Estável |
| 67 Estável | 66,92712775 ± 0,00000096 | 4,0400% | Estável |
| 68 Estável | 67,92484455 ± 0,00000098 | 18,4500% | Estável |
Fase / Estado
Motivo: 394,5 °C abaixo do ponto de fusão (419,53 °C)
Esquemático, sem escala
Pontos de transição de fase
Energias de transição
Energia necessária para fundir 1 mol no ponto de fusão
Energia necessária para vaporizar 1 mol no ponto de ebulição
Energia necessária para sublimar 1 mol no ponto de sublimação
Densidade
Em condições padrão
Em condições padrão
Espectros atômicos
Mostrando 10 de 30. Ordenado por carga do íon (ordem crescente).
Dados de linhas disponíveis ?
| Íon | Carga | Total de linhas | Probabilidades de transição | Designações dos níveis |
|---|---|---|---|---|
| Zn I | 0 | 570 | 16 | 564 |
| Zn II | +1 | 96 | 22 | 90 |
| Zn III | +2 | 39 | 0 | 0 |
| Zn IV | +3 | 119 | 0 | 0 |
Dados de níveis disponíveis ?
| Íon | Carga | Níveis |
|---|---|---|
| Zn I | 0 | 380 |
| Zn II | +1 | 94 |
| Zn III | +2 | 316 |
| Zn IV | +3 | 245 |
| Zn V | +4 | 158 |
| Zn VI | +5 | 193 |
| Zn VII | +6 | 134 |
| Zn VIII | +7 | 5 |
| Zn IX | +8 | 2 |
| Zn X | +9 | 2 |
Raios iônicos
| Carga | Coordenação | Spin | Raio |
|---|---|---|---|
| +2 | 4 | N/D | 60 pm |
| +2 | 5 | N/D | 68 pm |
| +2 | 6 | N/D | 74 pm |
| +2 | 8 | N/D | 90 pm |
Compostos
Isótopos (3)
Naturally occurring zinc contains five stable isotopes. Sixteen other unstable isotopes are recognized.
| Número de massa | Massa atômica (u) | Abundância natural | Meia-vida | Modo de decaimento | |
|---|---|---|---|---|---|
| 66 Estável | 65,92603381 ± 0,00000094 | 27,7300% ± 0,9800% | Estável | stable | |
| 67 Estável | 66,92712775 ± 0,00000096 | 4,0400% ± 0,1600% | Estável | stable | |
| 68 Estável | 67,92484455 ± 0,00000098 | 18,4500% ± 0,6300% | Estável | stable |
Linhas espectrais
| Comprimento de onda (nm) | Intensidade | Estágio de ionização | Tipo | Transição | Exatidão | Fonte | |
|---|---|---|---|---|---|---|---|
| 387.9141 nm | N/D | Zn I | emission | 3d10.4s.4p 1P* → 3d10.4s.7d 1D | Medida | NIST | |
| 396.543 nm | 78000 | Zn I | emission | 3d10.4s.4p 1P* → 3d10.4s.8s 1S | Medida | NIST | |
| 411.31114 nm | 81000 | Zn I | emission | 3d10.4s.4p 1P* → 3d10.4s.6d 1D | Medida | NIST | |
| 429.2883 nm | 32000 | Zn I | emission | 3d10.4s.4p 3P* → 3d10.4s.5s 1S | Medida | NIST | |
| 429.8325 nm | 49000 | Zn I | emission | 3d10.4s.4p 1P* → 3d10.4s.7s 1S | Medida | NIST | |
| 455.326 nm | N/D | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.30p 1P* | Medida | NIST | |
| 455.548 nm | N/D | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.29p 1P* | Medida | NIST | |
| 455.795 nm | N/D | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.28p 1P* | Medida | NIST | |
| 456.073 nm | N/D | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.27p 1P* | Medida | NIST | |
| 456.388 nm | N/D | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.26p 1P* | Medida | NIST | |
| 456.745 nm | N/D | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.25p 1P* | Medida | NIST | |
| 457.155 nm | N/D | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.24p 1P* | Medida | NIST | |
| 457.623 nm | N/D | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.23p 1P* | Medida | NIST | |
| 458.167 nm | N/D | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.22p 1P* | Medida | NIST | |
| 458.796 nm | N/D | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.21p 1P* | Medida | NIST | |
| 459.541 nm | N/D | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.20p 1P* | Medida | NIST | |
| 460.423 nm | N/D | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.19p 1P* | Medida | NIST | |
| 461.482 nm | N/D | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.18p 1P* | Medida | NIST | |
| 462.768 nm | N/D | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.17p 1P* | Medida | NIST | |
| 462.980809 nm | 390000 | Zn I | emission | 3d10.4s.4p 1P* → 3d10.4s.5d 1D | Medida | NIST | |
| 464.351 nm | N/D | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.16p 1P* | Medida | NIST | |
| 466.559 nm | N/D | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.15p 3P* | Medida | NIST | |
| 468.013589 nm | 540000 | Zn I | emission | 3d10.4s.4p 3P* → 3d10.4s.5s 3S | Medida | NIST | |
| 469.143 nm | N/D | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.14p 3P* | Medida | NIST | |
| 472.215691 nm | 1000000 | Zn I | emission | 3d10.4s.4p 3P* → 3d10.4s.5s 3S | Medida | NIST | |
| 472.527 nm | N/D | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.13p 3P* | Medida | NIST | |
| 477.071 nm | N/D | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.12p 3P* | Medida | NIST | |
| 481.053206 nm | 1100000 | Zn I | emission | 3d10.4s.4p 3P* → 3d10.4s.5s 3S | Medida | NIST | |
| 506.866 nm | 77000 | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.9p 3P* | Medida | NIST | |
| 506.943 nm | 21000 | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.9p 3P* | Medida | NIST | |
| 506.998 nm | 3300 | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.9p 3P* | Medida | NIST | |
| 518.19819 nm | 120000 | Zn I | emission | 3d10.4s.4p 1P* → 3d10.4s.6s 1S | Medida | NIST | |
| 530.866 nm | 380000 | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.8p 3P* | Medida | NIST | |
| 531.017 nm | 160000 | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.8p 3P* | Medida | NIST | |
| 531.101 nm | 56000 | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.8p 3P* | Medida | NIST | |
| 577.205 nm | 490000 | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.7p 3P* | Medida | NIST | |
| 577.5452 nm | 210000 | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.7p 3P* | Medida | NIST | |
| 577.7033 nm | 85000 | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.7p 3P* | Medida | NIST | |
| 623.78967 nm | 93000 | Zn I | emission | 3d10.4s.4p 1P* → 3d10.4s.4d 3D | Medida | NIST | |
| 623.9169 nm | 38000 | Zn I | emission | 3d10.4s.4p 1P* → 3d10.4s.4d 3D | Medida | NIST | |
| 636.23458 nm | 240000 | Zn I | emission | 3d10.4s.4p 1P* → 3d10.4s.4d 1D | Medida | NIST | |
| 647.9184 nm | 55000 | Zn I | emission | 3d10.4s.5s 1S → 3d10.4s.7p 1P* | Medida | NIST | |
| 692.8295 nm | 40000 | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.6p 3P* | Medida | NIST | |
| 693.8449 nm | 20000 | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.6p 3P* | Medida | NIST | |
| 694.3184 nm | 7000 | Zn I | emission | 3d10.4s.5s 3S → 3d10.4s.6p 3P* | Medida | NIST |
Propriedades ampliadas
Raios covalentes (dados ampliados)
- Raio covalente (Pyykkö)
- 118 pm
- Raio covalente (Pyykkö, ligação dupla)
- 120 pm
- Raio covalente (Bragg)
- 132 pm
Raios de van der Waals
- Batsanov
- 210 pm
- Alvarez
- 239 pm
- UFF
- 276,3 pm
- MM3
- 229 pm
Raios atômicos e metálicos
- Raio atômico (Rahm)
- 222 pm
- Raio metálico (C12)
- 134 pm
Escalas de numeração
- Mendeleev
- 77
- Pettifor
- 76
- Glawe
- 74
Escalas de eletronegatividade
- Ghosh
- 0
- Miedema
- 4
- Gunnarsson–Lundqvist
- 4
- Robles–Bartolotti
- 3
Polarizabilidade e dispersão
- Polarizabilidade dipolar
- 38,67 a.u.
- Polarizabilidade dipolar (incerteza)
- 0,3 a.u.
- C₆
- 284 Ha·Bohr6
- C₆ (Gould–Bučko)
- 276 Ha·Bohr6
Afinidade química
- Afinidade protônica
- 608,6 kJ/mol
- Basicidade em fase gasosa
- 586 kJ/mol
Parâmetros de Miedema
- Volume molar de Miedema
- 9,17 cm3/mol
- Densidade eletrônica de Miedema
- 2
Risco de abastecimento e economia
- Concentração da produção
- 30
- Risco relativo de abastecimento
- 5
- Distribuição das reservas
- 22
- Estabilidade política (maior produtor)
- 24
- Estabilidade política (detentor das maiores reservas)
- 75
Transições de fase e alótropos
| Ponto de fusão | 692,68 K |
| Ponto de ebulição | 1180,15 K |
Categorias de estados de oxidação
Dados de referência avançados
Constantes de blindagem (7)
| n | Orbital | σ |
|---|---|---|
| 1 | s | 0,6755 |
| 2 | p | 3,902 |
| 2 | s | 8,172 |
| 3 | d | 16,1217 |
| 3 | p | 14,6307 |
| 3 | s | 13,7808 |
| 4 | s | 24,0348 |
Detalhes dos raios cristalinos (4)
| Carga | CN | Spin | rcrystal (pm) | Origem |
|---|---|---|---|---|
| 2 | IV | 74 | ||
| 2 | V | 82 | ||
| 2 | VI | 88 | from r^3 vs V plots, | |
| 2 | VIII | 104 | calculated, |
Modos de decaimento dos isótopos (49)
| Isótopo | Modo | Intensidade |
|---|---|---|
| 54 | 2p | 87% |
| 55 | B+ | 100% |
| 55 | B+p | 91% |
| 56 | B+ | 100% |
| 56 | B+p | 88% |
| 57 | B+ | 100% |
| 57 | B+p | 87% |
| 58 | B+ | 100% |
| 58 | B+p | 0,7% |
| 59 | B+ | 100% |
Fatores de espalhamento de raios X (504)
| Energia (eV) | f₁ | f₂ |
|---|---|---|
| 10 | — | 2,21675 |
| 10,1617 | — | 2,11915 |
| 10,3261 | — | 2,02585 |
| 10,4931 | — | 1,93665 |
| 10,6628 | — | 1,85138 |
| 10,8353 | — | 1,76986 |
| 11,0106 | — | 1,69194 |
| 11,1886 | — | 1,63293 |
| 11,3696 | — | 1,57784 |
| 11,5535 | — | 1,5246 |
Dados adicionais
Estimated Crustal Abundance
The estimated element abundance in the earth's crust.
7.0×101 milligrams per kilogram
Referências (1)
Estimated Oceanic Abundance
The estimated element abundance in the earth's oceans.
4.9×10-3 milligrams per liter
Referências (1)
Sources
Sources of this element.
The principal ores of zinc are sphalerite (sulfide), smithsonite (carbonate), calamine (silicate), and franklinite (zinc, manganese, iron oxide). One method of zinc extraction involves roasting its ores to form the oxide and reducing the oxide with coal or carbon, with subsequent distillation of the metal.
Referências (1)
- [6] Zinc https://periodic.lanl.gov/30.shtml
Referências
(9)
Data deposited in or computed by PubChem
The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.
Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.
The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.
Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/
The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.
The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database
This section provides all form of data related to element Zinc.
The element property data was retrieved from publications.