Oxygen (O)
nonmetalGas
표준 원자량
15.999 u [15.99903, 15.99977]전자 배치
[He] 2s2 2p4녹는점
-218.79 °C끓는점
-182.95 °C밀도
1.429 kg/m³산화 상태
−2, −1, 0, +1, +2전기 음성도(Pauling)
3.44제1 이온화 에너지
13.618055 eV발견 연도
1771원자 반지름
60 pm상세 정보
Oxygen is a reactive nonmetal and chalcogen that occurs mainly as the diatomic gas O₂ and, less commonly, as ozone O₃. It is essential to aerobic respiration and is a major constituent of water, silicate minerals, carbonates, and many biological molecules. Its high electronegativity and ability to form strong bonds make oxidation chemistry central to combustion, corrosion, metabolism, and industrial processing.
The gas is colorless, odorless, and tasteless. The liquid and solid forms are a pale blue color and are strongly paramagnetic.
The name derives from the Greek oxys for "acid" and genes for "forming" because the French chemist Antoine-Laurent Lavoisier once thought that oxygen was integral to all acids.
Oxygen was discovered independently by the Swedish pharmacist and chemist Carl-Wilhelm Scheele in 1771, and the English clergyman and chemist Joseph Priestley in 1774. Scheele's Chemical Treatise on Air and Fire was delayed in publication until 1777, so Priestley is credited with the discovery because he published first.
Oxygen had been produced by several chemists prior to its discovery in 1774, but they failed to recognize it as a distinct element. Joseph Priestley and Carl Wilhelm Scheele both independently discovered oxygen, but Priestly is usually given credit for the discovery. They were both able to produce oxygen by heating mercuric oxide (HgO). Priestley called the gas produced in his experiments 'dephlogisticated air' and Scheele called his 'fire air'. The name oxygen was created by Antoine Lavoisier who incorrectly believed that oxygen was necessary to form all acids. Oxygen is the third most abundant element in the universe and makes up nearly 21% of the earth's atmosphere. Oxygen accounts for nearly half of the mass of the earth's crust, two thirds of the mass of the human body and nine tenths of the mass of water. Large amounts of oxygen can be extracted from liquefied air through a process known as fractional distillation. Oxygen can also be produced through the electrolysis of water or by heating potassium chlorate (KClO3).
From the Greek word oxys, acid, and genes, forming. The behavior of oxygen and nitrogen as components of air led to the advancement of the phlogiston theory of combustion, which captured the minds of chemists for a century.
Joseph Priestley is generally credited with its discovery, although Scheele also discovered it independently.
Its atomic weight was used as a standard of comparison for each of the other elements until 1961 when the International Union of Pure and Applied Chemistry adopted carbon 12 as the new basis.
At ordinary temperature and pressure, pure O₂ is a colorless, odorless gas. Liquid oxygen is pale blue and strongly paramagnetic. Solid oxygen is also blue at low temperature and has several pressure- and temperature-dependent phases.
Elemental O₂ is used in steelmaking, nonferrous metal refining, welding and cutting, chemical oxidation, wastewater treatment, pulp bleaching, and medical and emergency breathing systems. Liquid oxygen is a major oxidizer in rocketry. Enriched oxygen improves combustion efficiency in some furnaces. Ozone O₃ is used as a strong oxidant for water treatment, odor control, and selected chemical processes, but it must be generated near the point of use because it decomposes readily.
Oxygen is a highly reactive element and is capable of combining with most other elements. It is required by most living organisms and for most forms of combustion. Impurities in molten pig iron are burned away with streams of high pressure oxygen to produce steel. Oxygen can also be combined with acetylene (C2H2) to produce an extremely hot flame used for welding. Liquid oxygen, when combined with liquid hydrogen, makes an excellent rocket fuel. Ozone (O3) forms a thin, protective layer around the earth that shields the surface from the sun's ultraviolet radiation. Oxygen is also a component of hundreds of thousands of organic compounds.
Plants and animals rely on oxygen for respiration. Hospitals frequently prescribe oxygen for patients with respiratory ailments.
Isotopes in Earth/Planetary Science
Molecules, atoms, and ions of the stable isotopes of oxygen possess slightly different physical and chemical properties, and they commonly will be fractionated during physical, chemical, and biological processes, giving rise to variations in isotopic abundances and in atomic weights. There are substantial variations in the isotopic abundances of oxygen in natural terrestrial materials (Fig. IUPAC.8.1). These variations are useful in investigating the origin of substances and studying environmental, hydrological, and geological processes [13] M. W. Wieser, T. B. Coplen. Pure Appl Chem.83, 359 (2011)..
A primary use of stable oxygen isotopes is in isotope hydrology. Although the evolution of the stable hydrogen and oxygen isotopic composition of precipitation begins with the evaporation of water from the oceans, their local and global relationship arises primarily from equilibrium isotopic fractionation of heavier (2H and 18O) and lighter isotopes (1H and 16O) of hydrogen and oxygen during condensation as a tropospheric vapor mass follows a trajectory to higher latitudes and over continents [14] W. Dansgaard. Tellus16, 436 (1964)., [15] I. D. Clark, P. Fritz. Environmental Isotopes in Hydrogeology, p. 328, Lewis Publishers, New York (1997).. As a consequence, the isotopic composition and atomic weight of oxygen in precipitation, rivers, and tap waters varies with elevation, season, and distance from the ocean-continent boundary. Figure 4.8.2 shows the variation in stable oxygen isotopic composition of water from rivers across the United States. These variations in oxygen isotopic composition of environmental water are often combined with hydrogen isotopic compositions and have been used to identify the origin of water and to investigate the interaction between groundwater and surface water (e.g. lakes, streams, and rivers) [16] C. Kendall, T. B. Coplen. Hydrol. Processes.15, 1363 (2011)..
Isotopes in Forensic Science and Anthropology
Measurements of relative 18O abundances have been used to determine the breeding grounds of many species of migrant songbirds. These species of songbirds only grow their feathers before migration, and they grow them on or close to their breeding grounds. Therefore, the isotopic composition of a bird’s feathers correlates to the isotopic signature of the growing season’s precipitation [19] K. A. Hobson. Oecologia120, 314 (1999)., [20] K. A. Hobson, L. I. Wassenaar. Oecologia.109, 142 (1996)..
Measurements of relative 18O abundances of human hair or nail samples collected at archeological sites have been used to determine the geographic region in which a subject lived based on the oxygen isotopic composition of the water they drank (Fig. IUPAC.8.3). This is possible because hair stores a daily record of oxygen isotopic composition of intake water, which correlates to local meteoric water [92] D. M. O’Brien, M. J. Woller. Rapid Commun. Mass Spectrom.21, 2422 (2007)..
Isotopes in Medicine
16O is used to produce radioactive 13N via the 16O (p, 4He) 13N reaction for imaging in positron emission tomography (PET) and to study blood flow through the heart (myocardial perfusion) [94] International Atomic Energy Agency. Cyclotron Produced Radionuclides: Physical Characteristics and Production Methods, Technical Reports Series No. 468. International Atomic Energy Agency Vienna (2009)., [95] M. Sajjad, R. M. Lambrecht, A. P. Wolf. Radiochim. Acta39, 165 (1986)..
17O has been used as a tracer to study cerebral oxygen utilization [96] T. Arai, S. Nakao, K. Mori, K. Ishimori, I. Morishima, T. Miyazawa, B. Fritz-Zieroth. Rapid Commun. Mass Spectrom.169, 153 (1990).. Variations in stable oxygen and hydrogen isotopes are used in energy expenditure studies in animals and humans. The subject is administered a dose of doubly labeled water (water enriched in both 2H and 18O). Measurements of the elimination rates of 2H and 18O in the subject over time through regular sampling of body water (by sampling saliva, urine, or blood) provide information on energy expenditure because the hydrogen isotopic composition of body water is affected primarily by water loss (mainly urination), but the oxygen isotopic composition is affected by both respiration and water loss [97] J. R. Speakman. Theory and Practice, Doubly Labelled Water. Springer Scientific, London (1997)..
Oxygen commonly has oxidation state −2 in oxides and silicates, −1 in peroxides such as hydrogen peroxide H₂O₂, and −1/2 in superoxides such as potassium superoxide KO₂. In water H₂O it forms extensive hydrogen-bonded networks. Oxygen also forms carbon dioxide CO₂, sulfur dioxide SO₂, nitrates, phosphates, carbonates, and many organic functional groups. Positive oxidation states occur only with more electronegative fluorine, as in oxygen difluoride OF₂.
Ozone (O3), a highly active compound, is formed by the action of an electrical discharge or ultraviolet light on oxygen.
Ozone's presence in the atmosphere (amounting to the equivalent of a layer 3 mm thick under ordinary pressures and temperatures) helps prevent harmful ultraviolet rays of the sun from reaching the earth's surface. Pollutants in the atmosphere may have a detrimental effect on this ozone layer. Ozone is toxic and exposure should not exceed 0.2 mg/m# (8-hour time-weighted average - 40-hour work week). Undiluted ozone has a bluish color. Liquid ozone is bluish black and solid ozone is violet-black.
Oxygen, which is very reactive, is a component of hundreds of thousands of organic compounds and combines with most elements.
See more information at the Oxygen compound page.
O₂ is not flammable, but oxygen enrichment greatly increases the speed and severity of fires and can cause materials that normally burn slowly to ignite violently. Liquid oxygen can cause severe cold burns and can make porous materials dangerously oxygen-rich. Ozone O₃ is toxic by inhalation and irritates the respiratory tract. High partial pressures of oxygen can be harmful, especially in diving, hyperbaric, and intensive-care settings.
Oxygen cycles through photosynthesis, respiration, weathering, combustion, and exchange between the atmosphere and oceans. Most atmospheric O₂ is maintained by oxygenic photosynthesis, while much of Earth’s oxygen inventory is locked in rocks as oxides, silicates, and carbonates. Dissolved oxygen controls the habitability of waters for many organisms and is depleted by decay of organic matter and some pollution events.
Industrial oxygen is produced mainly by cryogenic fractional distillation of air where large volumes and high purity are required. Pressure-swing adsorption and membrane systems supply smaller or on-site needs at lower purities. Demand is tied to steel, chemicals, refining, healthcare, water treatment, and aerospace. Because air is the feedstock, cost is dominated by energy, plant scale, purity, transport, and storage rather than geological scarcity. Oxygen itself is not recycled as a commodity, although efficient process design reduces consumption.
Oxygen is the third most abundant element found in the sun, and it plays a part in the carbon-nitrogen cycle, the process once thought to give the sun and stars their energy. Oxygen under excited conditions is responsible for the bright red and yellow-green colors of the Aurora Borealis.
A gaseous element, oxygen forms 21% of the atmosphere by volume and is obtained by liquefaction and fractional distillation. The atmosphere of Mars contains about 0.15% oxygen. The element and its compounds make up 49.2%, by weight, of the earth's crust. About two thirds of the human body and nine tenths of water is oxygen.
In the laboratory it can be prepared by the electrolysis of water or by heating potassium chlorate with manganese dioxide as a catalyst.
Oxygen is one of the most abundant elements in the universe and is made chiefly by helium and carbon burning in massive stars, then dispersed by stellar winds and supernovae. It is common in planets, dust, ices, and rocky minerals. In the Solar System it is a major component of water ice, silicate rock, carbon dioxide ice or gas, and many metal oxides.
- Liquid oxygen is attracted to a magnet strongly enough to be visibly held between magnet poles.
- Ozone in the stratosphere absorbs much biologically damaging ultraviolet radiation.
- Most oxygen atoms on Earth are in minerals, not in the atmosphere.
- The name oxygen originally reflected the mistaken idea that it was required to make all acids.
- Singlet oxygen is an electronically excited form important in photochemistry and some biological damage.
- Hemoglobin binds O₂ reversibly through iron centers rather than by oxidizing iron completely.
이미지
특성
물리적 특성
- 원자 반지름(경험값)
- 60 pm 모든 원소의 원자 반지름(경험값) 비교 →
- 공유 결합 반지름
- 66 pm 모든 원소의 공유 결합 반지름 비교 →
- 반데르발스 반지름
- 152 pm 모든 원소의 반데르발스 반지름 비교 →
- 밀도
- 1.429 kg/m³ 모든 원소의 밀도 비교 →
- 몰 부피
- 0.014 L/mol
- STP에서의 상
- 기체 모든 원소의 STP에서의 상 비교 →
- 녹는점
- -218.79 °C 모든 원소의 녹는점 비교 →
- 끓는점
- -182.95 °C 모든 원소의 끓는점 비교 →
- 열전도율
- 0.027 W/(m·K) 모든 원소의 열전도율 비교 →
- 비열
- 0.918 J/(g·K) 모든 원소의 비열 비교 →
- 몰 열용량
- 29.378 J/(mol·K) 모든 원소의 몰 열용량 비교 →
- 결정 구조
- 입방 모든 원소의 결정 구조 비교 →
화학적 특성
- 전기 음성도(Pauling)
- 3.44 모든 원소의 전기 음성도(Pauling) 비교 →
- 전기 음성도(Allen)
- 3.61
- 전자 친화도
- 1.4611 eV
- 제1 이온화 에너지
- 13.618055 eV 모든 원소의 제1 이온화 에너지 비교 →
- 제2 이온화 에너지
- 35.121241 eV 모든 원소의 제2 이온화 에너지 비교 →
- 제3 이온화 에너지
- 54.935729 eV 모든 원소의 제3 이온화 에너지 비교 →
- 제4 이온화 에너지
- 77.413766 eV 모든 원소의 제4 이온화 에너지 비교 →
- 제5 이온화 에너지
- 113.899392 eV 모든 원소의 제5 이온화 에너지 비교 →
- 산화 상태
- −2, −1, 0, +1, +2 모든 원소의 산화 상태 비교 →
- 원자가 전자
- 6 모든 원소의 원자가 전자 비교 →
- 전자 배치
- [He] 2s2 2p4
열역학적 특성
- 삼중점(온도)
- -218.7916 °C
- 삼중점(압력)
- 146.3 Pa
- 임계점(온도)
- -118.569 °C
- 임계점(압력)
- 5.043e+6 Pa
- 융해열
- 0.00460175 eV 모든 원소의 융해열 비교 →
- 기화열
- 0.07068456 eV 모든 원소의 기화열 비교 →
- 원자화열
- 2.582474 eV
- 원자화 엔탈피
- 2.583085 eV
핵 특성
- 양성자 수
- 8 모든 원소의 양성자 수 비교 →
- 중성자 수
- 8 모든 원소의 중성자 수 비교 →
- 알려진 동위원소 수
- 18 모든 원소의 알려진 동위원소 수 비교 →
- 안정 동위원소 수
- 3 모든 원소의 안정 동위원소 수 비교 →
- 가장 안정한 동위원소
- O-16
- 발견 연도
- 1771
존재비
- 존재비(지각)
- 4.61e+5 mg/kg 모든 원소의 존재비(지각) 비교 →
- 존재비(해양)
- 8.57 × 105 mg/L 모든 원소의 존재비(해양) 비교 →
결정 구조
- 격자 상수 a
- 683 pm
전자 구조
- 전자껍질별 전자 수
- 2, 6 모든 원소의 전자껍질별 전자 수 비교 →
식별자
- CAS 등록 번호
- 7782-44-7 모든 원소의 CAS 등록 번호 비교 →
- 항 기호
- 3P2
- InChI
- InChI=1S/O
- InChI 키
- QVGXLLKOCUKJST-UHFFFAOYSA-N
전자 배치 측정값
O: 2s² 2p⁴[He] 2s² 2p⁴1s² 2s² 2p⁴원자 모형
동위원소에 따라 중성자 수, 질량, 안정성은 달라지지만, 중성 원자의 전자 배치는 달라지지 않습니다.
개략적인 원자 모형이며 실제 비율과 다릅니다.
원자 지문
방출 / 흡수 스펙트럼
동위원소 분포
| 질량수 | 원자 질량(u) | 천연 존재비 | 반감기 |
|---|---|---|---|
| 16 안정 | 15.99491461957 ± 0.00000000017 | 99.7570% | 안정 |
| 17 안정 | 16.9991317565 ± 0.00000000069 | 0.0380% | 안정 |
| 18 안정 | 17.99915961286 ± 0.00000000076 | 0.2050% | 안정 |
상 / 상태
이유: 끓는점(-182.95 °C)보다 207.9 °C 높음
개략도이며 실제 비율과 다름
상전이점
전이 에너지
녹는점에서 1 mol을 녹이는 데 필요한 에너지
끓는점에서 1 mol을 기화시키는 데 필요한 에너지
밀도
표준 조건에서
현재 온도 T에서 이상 기체 법칙으로 추정
심화
원자 스펙트럼
보유 스펙트럼선 데이터 ?
| 이온 | 전하 | 총 스펙트럼선 수 | 전이 확률 | 준위 표기 |
|---|---|---|---|---|
| O I | 0 | 910 | 854 | 907 |
| O II | +1 | 1630 | 876 | 1630 |
| O III | +2 | 1005 | 974 | 974 |
| O IV | +3 | 1525 | 1521 | 1523 |
| O V | +4 | 391 | 385 | 385 |
| O VI | +5 | 157 | 126 | 157 |
| O VII | +6 | 189 | 188 | 189 |
| O VIII | +7 | 137 | 137 | 137 |
보유 에너지 준위 데이터 ?
| 이온 | 전하 | 준위 |
|---|---|---|
| O I | 0 | 614 |
| O II | +1 | 287 |
| O III | +2 | 188 |
| O IV | +3 | 219 |
| O V | +4 | 172 |
| O VI | +5 | 148 |
| O VII | +6 | 149 |
| O VIII | +7 | 149 |
이온 반지름
| 전하 | 배위 | 스핀 | 반지름 |
|---|---|---|---|
| -2 | 2 | 해당 없음 | 135 pm |
| -2 | 3 | 해당 없음 | 136 pm |
| -2 | 4 | 해당 없음 | 138 pm |
| -2 | 6 | 해당 없음 | 140 pm |
| -2 | 8 | 해당 없음 | 142 pm |
화합물
동위원소 (3)
Oxygen has nine isotopes. Natural oxygen is a mixture of three isotopes.
| 질량수 | 원자 질량(u) | 천연 존재비 | 반감기 | 붕괴 방식 | |
|---|---|---|---|---|---|
| 16 안정 | 15.99491461957 ± 0.00000000017 | 99.7570% ± 0.0160% | 안정 | stable | |
| 17 안정 | 16.9991317565 ± 0.00000000069 | 0.0380% ± 0.0010% | 안정 | stable | |
| 18 안정 | 17.99915961286 ± 0.00000000076 | 0.2050% ± 0.0140% | 안정 | stable |
스펙트럼선
전체 1013개 중 50개를 표시합니다. 기본적으로 세기가 측정된 스펙트럼선만 표시됩니다.
| 파장(nm) | 세기 | 이온화 단계 | 유형 | 전이 | 정확도 | 출처 | |
|---|---|---|---|---|---|---|---|
| 615.8187 nm | 490 | O I | emission | 2s2.2p3.(4S*).3p 5P → 2s2.2p3.(4S*).4d 5D* | 측정값 | NIST | |
| 615.6778 nm | 450 | O I | emission | 2s2.2p3.(4S*).3p 5P → 2s2.2p3.(4S*).4d 5D* | 측정값 | NIST | |
| 700.223 nm | 450 | O I | emission | 2s2.2p3.(4S*).3p 3P → 2s2.2p3.(4S*).4d 3D* | 측정값 | NIST | |
| 725.4448 nm | 450 | O I | emission | 2s2.2p3.(4S*).3p 3P → 2s2.2p3.(4S*).5s 3S* | 측정값 | NIST | |
| 615.5971 nm | 400 | O I | emission | 2s2.2p3.(4S*).3p 5P → 2s2.2p3.(4S*).4d 5D* | 측정값 | NIST | |
| 645.5977 nm | 400 | O I | emission | 2s2.2p3.(4S*).3p 5P → 2s2.2p3.(4S*).5s 5S* | 측정값 | NIST | |
| 725.4154 nm | 400 | O I | emission | 2s2.2p3.(4S*).3p 3P → 2s2.2p3.(4S*).5s 3S* | 측정값 | NIST | |
| 645.4444 nm | 360 | O I | emission | 2s2.2p3.(4S*).3p 5P → 2s2.2p3.(4S*).5s 5S* | 측정값 | NIST | |
| 700.1922 nm | 360 | O I | emission | 2s2.2p3.(4S*).3p 3P → 2s2.2p3.(4S*).4d 3D* | 측정값 | NIST | |
| 645.3602 nm | 320 | O I | emission | 2s2.2p3.(4S*).3p 5P → 2s2.2p3.(4S*).5s 5S* | 측정값 | NIST | |
| 725.4531 nm | 320 | O I | emission | 2s2.2p3.(4S*).3p 3P → 2s2.2p3.(4S*).5s 3S* | 측정값 | NIST | |
| 715.6701 nm | 210 | O I | emission | 2s2.2p3.(2D*).3s 1D* → 2s2.2p3.(2D*).3p 1D | 측정값 | NIST | |
| 396.1573 nm | 200 | O III | emission | 2s2.2p.(2P*).3p 1D → 2s2.2p.(2P*).3d 1F* | 측정값 | NIST | |
| 533.0741 nm | 190 | O I | emission | 2s2.2p3.(4S*).3p 5P → 2s2.2p3.(4S*).5d 5D* | 측정값 | NIST | |
| 604.6438 nm | 190 | O I | emission | 2s2.2p3.(4S*).3p 3P → 2s2.2p3.(4S*).6s 3S* | 측정값 | NIST | |
| 394.72949 nm | 185 | O I | emission | 2s2.2p3.(4S*).3s 5S* → 2s2.2p3.(4S*).4p 5P | 측정값 | NIST | |
| 394.74813 nm | 160 | O I | emission | 2s2.2p3.(4S*).3s 5S* → 2s2.2p3.(4S*).4p 5P | 측정값 | NIST | |
| 532.9681 nm | 160 | O I | emission | 2s2.2p3.(4S*).3p 5P → 2s2.2p3.(4S*).5d 5D* | 측정값 | NIST | |
| 604.6233 nm | 160 | O I | emission | 2s2.2p3.(4S*).3p 3P → 2s2.2p3.(4S*).6s 3S* | 측정값 | NIST | |
| 394.75862 nm | 140 | O I | emission | 2s2.2p3.(4S*).3s 5S* → 2s2.2p3.(4S*).4p 5P | 측정값 | NIST | |
| 543.6862 nm | 135 | O I | emission | 2s2.2p3.(4S*).3p 5P → 2s2.2p3.(4S*).6s 5S* | 측정값 | NIST | |
| 559.789 nm | 130 | O V | emission | 1s2.2s.3p 3P* → 1s2.2s.3d 3D | 측정값 | NIST | |
| 650.024 nm | 130 | O V | emission | 1s2.2p.(2P*<3/2>).3p 3D → 1s2.2p.(2P*<3/2>).3d 3F* | 측정값 | NIST | |
| 382.34136 nm | 120 | O I | emission | 2s2.2p3.(2D*).3s 3D* → 2s2.2p3.(2P*).3p 3D | 측정값 | NIST | |
| 557.7339 nm | 120 | O I | emission | 2s2.2p4 1D → 2s2.2p4 1S | 측정값 | NIST | |
| 543.5775 nm | 110 | O I | emission | 2s2.2p3.(4S*).3p 5P → 2s2.2p3.(4S*).6s 5S* | 측정값 | NIST | |
| 559.2252 nm | 110 | O III | emission | 2s2.2p.(2P*).3s 1P* → 2s2.2p.(2P*).3p 1P | 측정값 | NIST | |
| 604.6495 nm | 110 | O I | emission | 2s2.2p3.(4S*).3p 3P → 2s2.2p3.(4S*).6s 3S* | 측정값 | NIST | |
| 395.46067 nm | 100 | O I | emission | 2s2.2p3.(4S*).3p 3P → 2s2.2p3.(2P*).3s 3P* | 측정값 | NIST | |
| 412.396 nm | 100 | O V | emission | 1s2.2p.(2P*<3/2>).3s 3P* → 1s2.2p.(2P*<3/2>).3p 3D | 측정값 | NIST | |
| 436.8258 nm | 100 | O I | emission | 2s2.2p3.(4S*).3s 3S* → 2s2.2p3.(4S*).4p 3P | 측정값 | NIST | |
| 543.5178 nm | 90 | O I | emission | 2s2.2p3.(4S*).3p 5P → 2s2.2p3.(4S*).6s 5S* | 측정값 | NIST | |
| 423.3274 nm | 80 | O I | emission | 2s2.2p3.(4S*).4p 3P → 2s2.2p3.(2D*<3/2>).3d 3P* | 측정값 | NIST | |
| 441.4899 nm | 27 | O II | emission | 2s2.2p2.(3P).3s 2P → 2s2.2p2.(3P).3p 2D* | 측정값 | NIST | |
| 672.1388 nm | 26 | O II | emission | 2s2.2p2.(3P).3s 2P → 2s2.2p2.(3P).3p 2S* | 측정값 | NIST | |
| 441.6975 nm | 25 | O II | emission | 2s2.2p2.(3P).3s 2P → 2s2.2p2.(3P).3p 2D* | 측정값 | NIST | |
| 397.3256 nm | 24 | O II | emission | 2s2.2p2.(3P).3s 2P → 2s2.2p2.(3P).3p 2P* | 측정값 | NIST | |
| 407.58617 nm | 24 | O II | emission | 2s2.2p2.(3P).3p 4D* → 2s2.2p2.(3P).3d 4F | 측정값 | NIST | |
| 464.91347 nm | 24 | O II | emission | 2s2.2p2.(3P).3s 4P → 2s2.2p2.(3P).3p 4D* | 측정값 | NIST | |
| 664.1031 nm | 24 | O II | emission | 2s2.2p2.(3P).3s 2P → 2s2.2p2.(3P).3p 2S* | 측정값 | NIST | |
| 407.21525 nm | 23 | O II | emission | 2s2.2p2.(3P).3p 4D* → 2s2.2p2.(3P).3d 4F | 측정값 | NIST | |
| 434.9426 nm | 23 | O II | emission | 2s2.2p2.(3P).3s 4P → 2s2.2p2.(3P).3p 4P* | 측정값 | NIST | |
| 411.92165 nm | 22 | O II | emission | 2s2.2p2.(3P).3p 4P* → 2s2.2p2.(3P).3d 4D | 측정값 | NIST | |
| 459.0974 nm | 22 | O II | emission | 2s2.2p2.(1D).3s 2D → 2s2.2p2.(1D).3p 2F* | 측정값 | NIST | |
| 464.18103 nm | 22 | O II | emission | 2s2.2p2.(3P).3s 4P → 2s2.2p2.(3P).3p 4D* | 측정값 | NIST | |
| 689.5102 nm | 22 | O II | emission | 2s2.2p2.(3P).3d 4F → 2s2.2p2.(3P).4p 4D* | 측정값 | NIST | |
| 406.98819 nm | 21 | O II | emission | 2s2.2p2.(3P).3p 4D* → 2s2.2p2.(3P).3d 4F | 측정값 | NIST | |
| 435.126 nm | 21 | O II | emission | 2s2.2p2.(1D).3s 2D → 2s2.2p2.(1D).3p 2D* | 측정값 | NIST | |
| 466.16324 nm | 21 | O II | emission | 2s2.2p2.(3P).3s 4P → 2s2.2p2.(3P).3p 4D* | 측정값 | NIST | |
| 470.5346 nm | 21 | O II | emission | 2s2.2p2.(3P).3p 2D* → 2s2.2p2.(3P).3d 2F | 측정값 | NIST |
확장 특성
공유 결합 반지름(확장)
- 공유 결합 반지름(Pyykkö)
- 63 pm
- 공유 결합 반지름(Pyykkö, 이중 결합)
- 57 pm
- 공유 결합 반지름(Pyykkö, 삼중 결합)
- 53 pm
- 공유 결합 반지름(Bragg)
- 65 pm
반데르발스 반지름
- Bondi
- 152 pm
- Batsanov
- 155 pm
- Alvarez
- 150 pm
- UFF
- 350 pm
- MM3
- 182 pm
- Dreiding
- 340.46 pm
- Rowland–Taylor
- 158 pm
원자 및 금속 반지름
- 원자 반지름(Rahm)
- 171 pm
번호 척도
- Mendeleev
- 99
- Pettifor
- 101
- Glawe
- 97
전기 음성도 척도
- Ghosh
- 0
- Gunnarsson–Lundqvist
- 8
- Robles–Bartolotti
- 6
분극률 및 분산
- 쌍극자 분극률
- 5.3 a.u.
- 쌍극자 분극률(불확도)
- 0.2 a.u.
- C₆
- 15.6 Ha·Bohr6
- C₆ (Gould–Bučko)
- 16.7 Ha·Bohr6
화학 친화력
- 양성자 친화도
- 485.2 kJ/mol
- 기체상 염기성
- 459.6 kJ/mol
상전이 및 동소체
| 녹는점 | 54.36 K |
| 끓는점 | 90.19 K |
| 임계점(온도) | 154.58 K |
| 임계점(압력) | 5.04 MPa |
| 삼중점(온도) | 54.36 K |
| 삼중점(압력) | 0.15 kPa |
산화 상태 분류
심화 참고 데이터
차폐 상수 (3)
| n | 오비탈 | σ |
|---|---|---|
| 1 | s | 0.3421 |
| 2 | p | 3.5468 |
| 2 | s | 3.5084 |
결정 반지름 상세 정보 (5)
| 전하 | CN | 스핀 | rcrystal (pm) | 기원 |
|---|---|---|---|---|
| -2 | II | 121 | ||
| -2 | III | 122 | ||
| -2 | IV | 124 | ||
| -2 | VI | 126 | ||
| -2 | VIII | 128 |
동위원소 붕괴 방식 (22)
| 동위원소 | 모드 | 세기 |
|---|---|---|
| 11 | 2p | 100% |
| 12 | 2p | 100% |
| 13 | B+ | 100% |
| 13 | B+p | 10.9% |
| 14 | B+ | 100% |
| 15 | B+ | 100% |
| 19 | B- | 100% |
| 20 | B- | 100% |
| 21 | B- | 100% |
| 21 | B-n | — |
X선 산란 인자 (502)
| 에너지 (eV) | f₁ | f₂ |
|---|---|---|
| 10 | — | 0.70328 |
| 10.1617 | — | 0.70723 |
| 10.3261 | — | 0.70738 |
| 10.4931 | — | 0.70753 |
| 10.6628 | — | 0.70768 |
| 10.8353 | — | 0.70783 |
| 11.0106 | — | 0.70798 |
| 11.1886 | — | 0.70813 |
| 11.3696 | — | 0.70828 |
| 11.5535 | — | 0.70843 |
추가 데이터
Estimated Crustal Abundance
The estimated element abundance in the earth's crust.
4.61×105 milligrams per kilogram
참고 문헌 (1)
Estimated Oceanic Abundance
The estimated element abundance in the earth's oceans.
8.57×105 milligrams per liter
참고 문헌 (1)
Sources
Sources of this element.
Oxygen is the third most abundant element found in the sun, and it plays a part in the carbon-nitrogen cycle, the process once thought to give the sun and stars their energy. Oxygen under excited conditions is responsible for the bright red and yellow-green colors of the Aurora Borealis.
A gaseous element, oxygen forms 21% of the atmosphere by volume and is obtained by liquefaction and fractional distillation. The atmosphere of Mars contains about 0.15% oxygen. The element and its compounds make up 49.2%, by weight, of the earth's crust. About two thirds of the human body and nine tenths of water is oxygen.
In the laboratory it can be prepared by the electrolysis of water or by heating potassium chlorate with manganese dioxide as a catalyst.
참고 문헌 (1)
- [6] Oxygen https://periodic.lanl.gov/8.shtml
Isotopes in Forensic Science and Anthropology
Information on the use of this element's isotopes in forensic science and anthropology.
Measurements of relative 18O abundances have been used to determine the breeding grounds of many species of migrant songbirds. These species of songbirds only grow their feathers before migration, and they grow them on or close to their breeding grounds. Therefore, the isotopic composition of a bird’s feathers correlates to the isotopic signature of the growing season’s precipitation [19] K. A. Hobson. Oecologia120, 314 (1999)., [20] K. A. Hobson, L. I. Wassenaar. Oecologia.109, 142 (1996)..
Measurements of relative 18O abundances of human hair or nail samples collected at archeological sites have been used to determine the geographic region in which a subject lived based on the oxygen isotopic composition of the water they drank (Fig. IUPAC.8.3). This is possible because hair stores a daily record of oxygen isotopic composition of intake water, which correlates to local meteoric water [92] D. M. O’Brien, M. J. Woller. Rapid Commun. Mass Spectrom.21, 2422 (2007)..
참고 문헌 (7)
- [14] W. Dansgaard. Tellus16, 436 (1964).
- [15] I. D. Clark, P. Fritz. Environmental Isotopes in Hydrogeology, p. 328, Lewis Publishers, New York (1997).
- [19] K. A. Hobson. Oecologia120, 314 (1999).
- [20] K. A. Hobson, L. I. Wassenaar. Oecologia.109, 142 (1996).
- [92] D. M. O’Brien, M. J. Woller. Rapid Commun. Mass Spectrom.21, 2422 (2007).
- [93] I. Fraser, W. Meier-Augenstein, R. M. Kalin. Rapid Commun. Mass Spectrom.20, 1109 (2006).
- [4] IUPAC Periodic Table of the Elements and Isotopes (IPTEI) https://doi.org/10.1515/pac-2015-0703
참고 문헌
(9)
Data deposited in or computed by PubChem
The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.
Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.
The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.
Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/
The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.
The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database
This section provides all form of data related to element Oxygen.
The element property data was retrieved from publications.