Rhenium (Re)
transition-metalSolid
표준 원자량
186.207 u전자 배치
[Xe] 6s2 4f14 5d5녹는점
3185.85 °C끓는점
5595.85 °C밀도
2.08e+4 kg/m³산화 상태
−3, −1, 0, +1, +2, +3, +4, +5, +6, +7전기 음성도(Pauling)
1.9제1 이온화 에너지
7.83352 eV발견 연도
1925원자 반지름
135 pm상세 정보
Rhenium is a very dense, high-melting transition metal in group 7, chemically related to manganese and technetium but far less abundant in the crust. It is notable for retaining strength at extreme temperature and for forming stable high oxidation states, especially +7. Natural rhenium occurs mainly as a trace substitute in molybdenite rather than as separate ores, making it a by-product metal of copper-molybdenum processing.
The element is silvery white with a metallic luster; its density is exceeded only by that of platinum, iridium, and osmium, and its melting point is exceeded only by that of tungsten and carbon.
The usual commercial form of the element is powder, but it can be consolidated by pressing and resistance-sintering in a vacuum or hydrogen atmosphere. This process produces a compact shape in excess of 90 percent of the density of the metal.
Annealed rhenium is very ductile, and can be bent, coiled, or rolled. Rhenium is used as an additive to tungsten and molybdenum -based alloys to impart useful properties.
The name derives from the Latin rhenus for the Rhine river in Germany. Rhenium was discovered by x-ray spectroscopy in 1925 by German chemists Walter Noddack, Ida Tacke, and Otto Berg.
Rhenium was discovered by the German chemists Ida Tacke-Noddack, Walter Noddack and Otto Carl Berg in 1925. They detected rhenium spectroscopically in platinum ores and in the minerals columbite ((Fe, Mn, Mg)(Nb, Ta)2O6), gadolinite ((Ce, La, Nd, Y)2FeBe2Si2O10) and molybdenite (MoS2). Rhenium is present in these materials only in trace amounts. In 1928, Noddack and Berg were able to extract 1 gram of rhenium from 660 kilograms of molybdenite. Today, rhenium is obtained as a byproduct of refining molybdenum and copper.
Discovery of rhenium is generally attributed to Noddack, Tacke, and Berg, who announced in 1925 they had detected the element in platinum ore and columbite. They also found the element in gadolinite and molybdenite. By working up 660 kg of molybdenite in 1928 they were able to extract 1 g of rhenium.
Pure rhenium is a silvery-white to gray metallic solid with a bright luster when freshly prepared. It is hard, dense, and refractory, with one of the highest melting points among the elements. Powdered rhenium can be darker gray because of surface condition and particle size.
The largest use of rhenium is in nickel-based superalloys for turbine blades and other hot-section components, where small additions improve high-temperature strength and creep resistance. Rhenium is also used with platinum in reforming catalysts for petroleum refining. Tungsten-rhenium and molybdenum-rhenium alloys serve in high-temperature thermocouples, filaments, electrical contacts, and specialized X-ray tube targets. Its radioisotopes ¹⁸⁶Re and ¹⁸⁸Re have been studied and used in limited nuclear-medicine applications.
Rhenium is used in flash lamps for photography and for filaments in mass spectrographs and ion gages, but is most frequently used as an alloying agent in tungsten and molybdenum and as a catalyst for performing certain reactions to a type of hydrocarbon known as an olefin.
It is widely used as filaments for mass spectrographs and ion gauges. Rhenium-molybdenum alloys are superconductive at 10 K.
Rhenium is also used as an electrical contact material because it has good wear resistance and withstands arc corrosion. Thermocouples made of Re-W are used for measuring temperatures up to 2200C, and rhenium wire is used in photoflash lamps for photography.
Rhenium catalysts are exceptionally resistant to poisoning from nitrogen, sulfur, and phosphorus, and are used for hydrogenation of fine chemicals.
Isotopes in Geochronology
The rhenium-osmium dating method is of special interest for the dating of rhenium-bearing ores, gold deposits, copper-nickel deposits, and meteorites. This method is based on the beta-decay of 187Re (having a half-life of 41.6×109 years) to 187Os, an example of which appears in Fig. IUPAC.75.1 [515] H. M. Baioumy, L. B. Eglinton, B. Peucker-Ehrenbrink. Chem. Geol.285, 70 (2011)..
Isotopes in Medicine
186Re (with a half-life of 89 h) is a beta-emitting radioisotope that is used for cancer treatment, in particular for pain relief in bone cancer and in rheumatoid arthritis (see radiosynovectomy). It is produced from the stable isotope 185Re via the 185Re (n, γ) 186Re reaction [188] S. J. Adelstein, F. J. Manning. Isotopes for Medicine and the Life Sciences, pp. 20–25, National Academy Press, Washington DC (1995).. 186Re is also used for radiolabeling of cancer therapeutic agents [188] S. J. Adelstein, F. J. Manning. Isotopes for Medicine and the Life Sciences, pp. 20–25, National Academy Press, Washington DC (1995).. 188Re (with a half-life of 17 h) is used to irradiate coronary arteries with beta particles during insertion of an angioplasty balloon (a tiny balloon that is inserted into an artery and inflated to flatten plaque build-up and improve blood flow) and in palliative therapy, particularly for bone metastases. The beta irradiation can decrease scar tissue formation after the overstretching of arteries by angioplasty.
Rhenium chemistry spans oxidation states from negative values in carbonyl complexes to +7 in oxo compounds, with +4, +5, and +7 especially important. Perrhenic acid, HReO₄, and perrhenate salts containing ReO₄⁻ resemble perchlorates in charge and geometry but are less oxidizing under many conditions. Rhenium(VII) oxide, Re₂O₇, is the volatile anhydride of perrhenic acid. Rhenium disulfide, ReS₂, is a layered dichalcogenide with lower symmetry than many related sulfides. Dirhenium decacarbonyl, Re₂(CO)₁₀, is a common starting material in organorhenium chemistry.
See more information at the Rhenium compound page.
Massive rhenium metal is generally of low chemical reactivity, but dusts and fine powders present inhalation and fire-control concerns typical of refractory metals. Soluble perrhenate compounds can be absorbed and should be handled as toxicologically insufficiently characterized heavy-metal salts. Radioactive rhenium isotopes pose isotope-specific radiation hazards; their risk depends on half-life, emissions, chemical form, and administered or handled activity.
Rhenium is a trace element with no known essential biological role. In rocks it is commonly associated with sulfide minerals, especially molybdenite, and can be mobilized during weathering as the soluble perrhenate ion, ReO₄⁻. Seawater contains very low concentrations of dissolved rhenium, and marine sediments can record rhenium enrichment under reducing conditions. Industrial releases are mainly linked to mining, smelting, and catalyst handling.
Rhenium is obtained almost entirely as a by-product, principally from molybdenite concentrates generated in porphyry copper-molybdenum mining. During roasting, volatile rhenium oxides are captured from flue dusts and converted to ammonium perrhenate, NH₄ReO₄, or to metal powder. Supply is constrained because production depends on the output and processing choices of other metals rather than on primary rhenium mines. Demand is concentrated in aerospace superalloys and platinum-rhenium catalysts, so recycling from spent catalysts and high-value alloy scrap is important. Substitution is limited in some turbine applications, but alloy design can reduce rhenium content when supply or cost pressures are high.
Rhenium does not occur free in nature or as a compound in a distinct mineral species. It is, however, widely spread throughout the earth's crust to the extent of about 0.001 ppm. Commercial rhenium in the U.S. today is obtained from molybdenum roaster-flue dusts obtained from copper-sulfide ores mined in the vicinity of Miami, Arizona and elsewhere in Arizona and in Utah.
Some molybdenum contains from 0.002% to 0.2% rhenium. More than 150,000 troy ounces of rhenium are now being produced yearly in the United States. The total estimated Free World reserve of rhenium metal is 3500 tons. Rhenium metal is prepared by reducing ammonium perrhentate with hydrogen at elevated temperatures.
Rhenium is cosmically rare. Its stable and very long-lived isotopes are produced mainly by neutron-capture processes in earlier generations of stars, followed by dispersal into interstellar material. In planetary bodies it behaves as a siderophile and chalcophile trace element, so it partitions into metal and sulfide phases rather than forming abundant silicate minerals.
- Rhenium was one of the last stable elements to be discovered.
- Natural rhenium is dominated by ¹⁸⁷Re, which is radioactive with an extremely long half-life.
- The ¹⁸⁷Re-¹⁸⁷Os decay system is used for dating some sulfide ores and meteorites.
- Rhenium has a higher boiling point than any other element under standard tabulations.
- Perrhenate, ReO₄⁻, is often used as a nonradioactive chemical analogue for pertechnetate, TcO₄⁻.
이미지
특성
물리적 특성
- 원자 반지름(경험값)
- 135 pm 모든 원소의 원자 반지름(경험값) 비교 →
- 공유 결합 반지름
- 151 pm 모든 원소의 공유 결합 반지름 비교 →
- 반데르발스 반지름
- 217 pm 모든 원소의 반데르발스 반지름 비교 →
- 금속 반지름
- 128 pm 모든 원소의 금속 반지름 비교 →
- 밀도
- 2.08 × 104 kg/m³ 모든 원소의 밀도 비교 →
- 몰 부피
- 0.00885 L/mol
- STP에서의 상
- 고체 모든 원소의 STP에서의 상 비교 →
- 녹는점
- 3185.85 °C 모든 원소의 녹는점 비교 →
- 끓는점
- 5595.85 °C 모든 원소의 끓는점 비교 →
- 열전도율
- 48 W/(m·K) 모든 원소의 열전도율 비교 →
- 비열
- 0.137 J/(g·K) 모든 원소의 비열 비교 →
- 몰 열용량
- 25.48 J/(mol·K) 모든 원소의 몰 열용량 비교 →
- 결정 구조
- 육방 조밀 충전 모든 원소의 결정 구조 비교 →
화학적 특성
- 전기 음성도(Pauling)
- 1.9 모든 원소의 전기 음성도(Pauling) 비교 →
- 전기 음성도(Allen)
- 1.6
- 전자 친화도
- 0.15 eV
- 제1 이온화 에너지
- 7.83352 eV 모든 원소의 제1 이온화 에너지 비교 →
- 제2 이온화 에너지
- 16.600057 eV 모든 원소의 제2 이온화 에너지 비교 →
- 제3 이온화 에너지
- 27.000093 eV 모든 원소의 제3 이온화 에너지 비교 →
- 제4 이온화 에너지
- 39.100135 eV 모든 원소의 제4 이온화 에너지 비교 →
- 제5 이온화 에너지
- 51.900179 eV 모든 원소의 제5 이온화 에너지 비교 →
- 산화 상태
- −3, −1, 0, +1, +2, +3, +4, +5, +6, +7 모든 원소의 산화 상태 비교 →
- 원자가 전자
- 7 모든 원소의 원자가 전자 비교 →
- 전자 배치
- [Xe] 6s2 4f14 5d5
열역학적 특성
- 융해열
- 0.34927709 eV 모든 원소의 융해열 비교 →
- 기화열
- 7.358657 eV 모든 원소의 기화열 비교 →
- 승화열
- 8.032337 eV
- 원자화열
- 8.032337 eV
- 원자화 엔탈피
- 8.021972 eV
핵 특성
- 양성자 수
- 75 모든 원소의 양성자 수 비교 →
- 중성자 수
- 110 모든 원소의 중성자 수 비교 →
- 알려진 동위원소 수
- 41 모든 원소의 알려진 동위원소 수 비교 →
- 안정 동위원소 수
- 1 모든 원소의 안정 동위원소 수 비교 →
- 가장 안정한 동위원소
- Re-185
- 발견 연도
- 1925
존재비
- 존재비(지각)
- 7e-4 mg/kg 모든 원소의 존재비(지각) 비교 →
- 존재비(해양)
- 4 × 10−6 mg/L 모든 원소의 존재비(해양) 비교 →
결정 구조
- 격자 상수 a
- 276 pm
전자 구조
- 전자껍질별 전자 수
- 2, 8, 18, 32, 13, 2 모든 원소의 전자껍질별 전자 수 비교 →
식별자
- CAS 등록 번호
- 7440-15-5 모든 원소의 CAS 등록 번호 비교 →
- 항 기호
- 6S5/2
- InChI
- InChI=1S/Re
- InChI 키
- WUAPFZMCVAUBPE-UHFFFAOYSA-N
전자 배치 측정값
Re: 4f¹⁴ 5d⁵ 6s²[Xe] 4f¹⁴ 5d⁵ 6s²1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d⁵ 6s²원자 모형
동위원소에 따라 중성자 수, 질량, 안정성은 달라지지만, 중성 원자의 전자 배치는 달라지지 않습니다.
개략적인 원자 모형이며 실제 비율과 다릅니다.
원자 지문
방출 / 흡수 스펙트럼
동위원소 분포
| 질량수 | 원자 질량(u) | 천연 존재비 | 반감기 |
|---|---|---|---|
| 185 안정 | 184.9529545 ± 0.0000013 | 37.4000% | 안정 |
상 / 상태
이유: 녹는점(3185.85 °C)보다 3160.8 °C 낮음
개략도이며 실제 비율과 다름
상전이점
전이 에너지
녹는점에서 1 mol을 녹이는 데 필요한 에너지
끓는점에서 1 mol을 기화시키는 데 필요한 에너지
승화점에서 1 mol을 승화시키는 데 필요한 에너지
밀도
표준 조건에서
표준 조건에서
원자 스펙트럼
전체 75개 중 10개를 표시합니다. 이온 전하순으로 정렬되었습니다(오름차순).
보유 스펙트럼선 데이터 ?
| 이온 | 전하 | 총 스펙트럼선 수 | 전이 확률 | 준위 표기 |
|---|---|---|---|---|
| Re I | 0 | 432 | 0 | 0 |
| Re II | +1 | 56 | 0 | 0 |
| Re III | +2 | 1381 | 1381 | 1381 |
| Re IV | +3 | 982 | 982 | 982 |
| Re V | +4 | 401 | 401 | 401 |
보유 에너지 준위 데이터 ?
| 이온 | 전하 | 준위 |
|---|---|---|
| Re I | 0 | 291 |
| Re II | +1 | 140 |
| Re III | +2 | 232 |
| Re IV | +3 | 162 |
| Re V | +4 | 80 |
| Re VI | +5 | 2 |
| Re VII | +6 | 2 |
| Re VIII | +7 | 2 |
| Re IX | +8 | 2 |
| Re X | +9 | 2 |
이온 반지름
| 전하 | 배위 | 스핀 | 반지름 |
|---|---|---|---|
| +4 | 6 | 해당 없음 | 63 pm |
| +5 | 6 | 해당 없음 | 57.99999999999999 pm |
| +6 | 6 | 해당 없음 | 55.00000000000001 pm |
| +7 | 4 | 해당 없음 | 38 pm |
| +7 | 6 | 해당 없음 | 53 pm |
화합물
동위원소 (1)
Natural rhenium is a mixture of two stable isotopes. Twenty six other unstable isotopes are recognized.
| 질량수 | 원자 질량(u) | 천연 존재비 | 반감기 | 붕괴 방식 | |
|---|---|---|---|---|---|
| 185 안정 | 184.9529545 ± 0.0000013 | 37.4000% ± 0.0200% | 안정 | stable |
확장 특성
공유 결합 반지름(확장)
- 공유 결합 반지름(Pyykkö)
- 131 pm
- 공유 결합 반지름(Pyykkö, 이중 결합)
- 119 pm
- 공유 결합 반지름(Pyykkö, 삼중 결합)
- 110 pm
반데르발스 반지름
- Batsanov
- 205 pm
- Alvarez
- 249 pm
- UFF
- 295.4 pm
- MM3
- 237 pm
원자 및 금속 반지름
- 원자 반지름(Rahm)
- 249 pm
- 금속 반지름(C12)
- 137 pm
번호 척도
- Mendeleev
- 57
- Pettifor
- 59
- Glawe
- 58
전기 음성도 척도
- Ghosh
- 0
- Miedema
- 5
- Gunnarsson–Lundqvist
- 5
- Robles–Bartolotti
- 4
분극률 및 분산
- 쌍극자 분극률
- 62 a.u.
- 쌍극자 분극률(불확도)
- 3 a.u.
- C₆ (Gould–Bučko)
- 663 Ha·Bohr6
미데마 매개변수
- 미데마 몰 부피
- 8.85 cm3/mol
- 미데마 전자 밀도
- 6
공급 위험 및 경제성
- 생산 집중도
- 51
- 상대적 공급 위험
- 6
- 매장량 분포
- 52
- 정치적 안정성(최대 생산국)
- 68
- 정치적 안정성(최대 매장국)
- 68
상전이 및 동소체
| 녹는점 | 3458.15 K |
| 끓는점 | 5863.15 K |
산화 상태 분류
심화 참고 데이터
차폐 상수 (14)
| n | 오비탈 | σ |
|---|---|---|
| 1 | s | 1.4522 |
| 2 | p | 4.438 |
| 2 | s | 19.5902 |
| 3 | d | 13.5453 |
| 3 | p | 21.5655 |
| 3 | s | 22.3515 |
| 4 | d | 36.9456 |
| 4 | f | 39.0752 |
| 4 | p | 34.6268 |
| 4 | s | 33.6436 |
결정 반지름 상세 정보 (5)
| 전하 | CN | 스핀 | rcrystal (pm) | 기원 |
|---|---|---|---|---|
| 4 | VI | 77 | from r^3 vs V plots, from metallic oxides, | |
| 5 | VI | 72 | estimated, | |
| 6 | VI | 69 | estimated, | |
| 7 | IV | 52 | ||
| 7 | VI | 67 |
동위원소 붕괴 방식 (54)
| 동위원소 | 모드 | 세기 |
|---|---|---|
| 159 | p | — |
| 159 | A | — |
| 160 | p | 89% |
| 160 | A | 11% |
| 161 | p | 100% |
| 161 | A | — |
| 162 | A | 94% |
| 162 | B+ | — |
| 163 | B+ | — |
| 163 | A | 32% |
X선 산란 인자 (516)
| 에너지 (eV) | f₁ | f₂ |
|---|---|---|
| 10 | — | 1.8209 |
| 10.1617 | — | 1.91145 |
| 10.3261 | — | 2.0065 |
| 10.4931 | — | 2.10629 |
| 10.6628 | — | 2.21103 |
| 10.8353 | — | 2.28753 |
| 11.0106 | — | 2.3602 |
| 11.1886 | — | 2.43518 |
| 11.3696 | — | 2.51255 |
| 11.5535 | — | 2.59237 |
추가 데이터
Estimated Crustal Abundance
The estimated element abundance in the earth's crust.
7×10-4 milligrams per kilogram
참고 문헌 (1)
Estimated Oceanic Abundance
The estimated element abundance in the earth's oceans.
4×10-6 milligrams per liter
참고 문헌 (1)
Sources
Sources of this element.
Rhenium does not occur free in nature or as a compound in a distinct mineral species. It is, however, widely spread throughout the earth's crust to the extent of about 0.001 ppm. Commercial rhenium in the U.S. today is obtained from molybdenum roaster-flue dusts obtained from copper-sulfide ores mined in the vicinity of Miami, Arizona and elsewhere in Arizona and in Utah.
Some molybdenum contains from 0.002% to 0.2% rhenium. More than 150,000 troy ounces of rhenium are now being produced yearly in the United States. The total estimated Free World reserve of rhenium metal is 3500 tons. Rhenium metal is prepared by reducing ammonium perrhentate with hydrogen at elevated temperatures.
참고 문헌 (1)
- [6] Rhenium https://periodic.lanl.gov/75.shtml
참고 문헌
(9)
Data deposited in or computed by PubChem
The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.
Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.
The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.
Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/
The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.
The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database
This section provides all form of data related to element Rhenium.
The element property data was retrieved from publications.