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Cd 48

Cadmium (Cd)

transition-metal
Periode: 5 Golongan: 12 Blok: d

Solid

Bobot Atom Standar

112,414 u

Konfigurasi elektron

[Kr] 5s2 4d10

Titik lebur

321,07 °C

Titik didih

766,85 °C

Massa jenis

8690 kg/m³

Bilangan oksidasi

−2, +1, +2

Keelektronegatifan (Pauling)

1,69

Energi ionisasi (ke-1)

8,99382 eV

Tahun penemuan

1817

Jari-jari atom

155 pm

Detail

Asal nama Greek: kadmeia (ancient name for calamine (zinc oxide)).
Negara penemuan Germany
Penemu Fredrich Stromeyer

Cadmium is a soft, bluish-white post-transition metal in group 12. It occurs mainly as a minor constituent of zinc ores and is usually recovered as a by-product of zinc refining. Chemically it is dominated by the +2 oxidation state and forms many salts with ionic character. Its technological importance has declined in some applications because cadmium and many cadmium compounds are highly toxic, but it remains useful where particular electrochemical, pigment, or semiconductor properties are required.

Soft bluish metal belonging to group 12 of the periodic table. Extremely toxic even in low concentrations. Chemically similar to zinc, but lends itself to more complex compounds. Discovered in 1817 by F. Stromeyer.

The name derives from Greek kadmeia for "calamine" (zinc carbonate), with which it was found as an impurity in nature. It may have been found in furnace flue dust in Thebes, a city in the Boeottia region of central Greece. The mythological king of Phoenicia, Cadmus, founded Thebes and would be a source for the name of the ore. The element was discovered and first isolated by German physician Friedrich Stromeyer in 1817.

Cadmium was discovered by Friedrich Strohmeyer, a German chemist, in 1817 while studying samples of calamine (ZnCO3). When heated, Strohmeyer noticed that some samples of calamine glowed with a yellow color while other samples did not. After further examination, he determined that the calamine that changed color when heated contained trace amounts of a new element. There is only one mineral that contains significant amounts of cadmium, greenockite (CdS), but it is not common enough to mine profitably. Fortunately, small amounts of cadmium are found in zinc ores and most of the cadmium produced today is obtained as a byproduct of mining and refining zinc.

From the Latin word cadmia, Greek kadmeia - the ancient name for calamine, zinc carbonate. Discovered by Stromeyer in 1817 from an impurity in zinc carbonate. Cadmium most often occurs in small quantities associated with zinc ores, such as sphalerite (ZnS). Greenockite (CdS) is the only mineral of any consequence bearing cadmium. Almost all cadmium is obtained as a by-product in the treatment of zinc, copper, and lead ores. It is a soft, bluish-white metal which is easily cut with a knife. It is similar in many respects to zinc. In 1927 the International Conference on Weights and Measures redefined the meter in terms of the wavelength of the red cadmium spectral line (i.e. 1m = 1.553,164.13 wavelengths). This definition has been changed (see Krypton).

Gambar

Sifat

Fisika

Jari-jari atom (empiris)
155 pm Bandingkan Jari-jari atom (empiris) semua unsur →
Jari-jari kovalen
144 pm Bandingkan Jari-jari kovalen semua unsur →
Jari-jari van der Waals
158 pm Bandingkan Jari-jari van der Waals semua unsur →
Jari-jari logam
138 pm Bandingkan Jari-jari logam semua unsur →
Massa jenis
8690 kg/m³ Bandingkan Massa jenis semua unsur →
Volume molar
0,0131 L/mol
Fase pada STP
Padat Bandingkan Fase pada STP semua unsur →
Titik lebur
321,07 °C Bandingkan Titik lebur semua unsur →
Titik didih
766,85 °C Bandingkan Titik didih semua unsur →
Konduktivitas termal
96,9 W/(m·K) Bandingkan Konduktivitas termal semua unsur →
Kapasitas kalor spesifik
0,232 J/(g·K) Bandingkan Kapasitas kalor spesifik semua unsur →
Kapasitas kalor molar
26,02 J/(mol·K) Bandingkan Kapasitas kalor molar semua unsur →
Struktur kristal
Heksagonal susunan rapat Bandingkan Struktur kristal semua unsur →

Kimia

Keelektronegatifan (Pauling)
1,69 Bandingkan Keelektronegatifan (Pauling) semua unsur →
Keelektronegatifan (Allen)
1,52
Afinitas elektron
-0,7 eV (nilai negatif — atom tidak diprediksi mengikat elektron tambahan)
Energi ionisasi (ke-1)
8,99382 eV Bandingkan Energi ionisasi (ke-1) semua unsur →
Energi ionisasi (ke-2)
16,908371 eV Bandingkan Energi ionisasi (ke-2) semua unsur →
Energi ionisasi (ke-3)
37,468129 eV Bandingkan Energi ionisasi (ke-3) semua unsur →
Energi ionisasi (ke-4)
51,000176 eV Bandingkan Energi ionisasi (ke-4) semua unsur →
Energi ionisasi (ke-5)
67,900234 eV Bandingkan Energi ionisasi (ke-5) semua unsur →
Bilangan oksidasi
−2, +1, +2 Bandingkan Bilangan oksidasi semua unsur →
Elektron valensi
12 Bandingkan Elektron valensi semua unsur →
Konfigurasi elektron
[Kr] 5s2 4d10

Termodinamika

Kalor peleburan
0,06436234 eV Bandingkan Kalor peleburan semua unsur →
Kalor penguapan
1,036431 eV Bandingkan Kalor penguapan semua unsur →
Kalor sublimasi
1,160802 eV
Kalor atomisasi
1,160802 eV
Entalpi atomisasi
1,158729 eV

Nuklir

Proton
48 Bandingkan Proton semua unsur →
Neutron
64 Bandingkan Neutron semua unsur →
Isotop yang diketahui
42 Bandingkan Isotop yang diketahui semua unsur →
Isotop stabil
3 Bandingkan Isotop stabil semua unsur →
Isotop paling stabil
Cd-112
Tahun penemuan
1817

Kelimpahan

Kelimpahan (kerak Bumi)
0,15 mg/kg Bandingkan Kelimpahan (kerak Bumi) semua unsur →
Kelimpahan (samudra)
1,1 × 10−4 mg/L Bandingkan Kelimpahan (samudra) semua unsur →

Struktur Kristal

Konstanta kisi a
298 pm

Struktur Elektronik

Elektron per kulit
2, 8, 18, 18, 2 Bandingkan Elektron per kulit semua unsur →

Pengenal

Nomor CAS
7440-43-9 Bandingkan Nomor CAS semua unsur →
Simbol term
1S0
InChI
InChI=1S/Cd
Kunci InChI
BDOSMKKIYDKNTQ-UHFFFAOYSA-N

Konfigurasi Elektron Diukur

Muatan ion
Proton 48
Elektron 48
Muatan Netral
Konfigurasi Cd: 4d¹⁰ 5s²
Konfigurasi elektron
Diukur
[Kr] 4d¹⁰ 5s²
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s²
Diagram orbital
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
2/2
4d
10/10
Total elektron: 48 Tidak berpasangan: 0

Model atom

Proton 48
Neutron 64
Elektron 48
Nomor massa 112
Kestabilan Stabil

Isotop mengubah jumlah neutron, massa, dan kestabilan — bukan konfigurasi elektron atom netral.

Model atom skematis, tidak sesuai skala.

Sidik Jari Atom

Spektrum Emisi / Absorpsi

16 / 16 (14 14 dengan intensitas)
Diukur
Emisi Tampak: 380–750 nm

Distribusi Isotop

11224,1300%11112,8000%11012,4900%Nomor massaKelimpahan alami (%)
Nomor massaMassa atom (u)Kelimpahan alamiWaktu paruh
110 Stabil109,90300661 ± 0,0000006112,4900%Stabil
111 Stabil110,90418287 ± 0,0000006112,8000%Stabil
112 Stabil111,90276287 ± 0,000000624,1300%Stabil
Diukur

Fase / Wujud

1 atm / 101.325 kPa
Padat 25 °C (298,15 K)

Alasan: 296,1 °C di bawah titik lebur (321,07 °C)

Titik lebur 321,07 °C
Titik didih 766,85 °C
Di bawah titik lebur sebesar 296,1 °C
0 K Suhu saat ini: 25 °C 6000 K
Linimasa fase

Skematis, tidak sesuai skala

Padat
Cair
Gas
Peleburan
Pendidihan
25°C
Padat
Cair
Gas
Saat ini

Titik transisi fase

Titik lebur Literatur
321,07 °C
Titik didih Literatur
766,85 °C
Fase saat ini Dihitung
Padat

Energi transisi

Kalor peleburan Literatur
0,06436234 eV

Energi yang diperlukan untuk meleburkan 1 mol pada titik lebur

Kalor penguapan Literatur
1,036431 eV

Energi yang diperlukan untuk menguapkan 1 mol pada titik didih

Kalor sublimasi Literatur
1,160802 eV

Energi yang diperlukan untuk menyublimkan 1 mol pada titik sublimasi

Massa jenis

Massa jenis referensi Literatur
8690 kg/m³

Pada kondisi standar

Massa jenis saat ini Dihitung
8690 kg/m³

Pada kondisi standar

Spektrum Atom

Menampilkan 10 dari 48. Diurutkan berdasarkan muatan ion (menaik).

Data Garis Spektrum ?

IonMuatanTotal garisProbabilitas transisiPenamaan tingkat energi
Cd I 0691869
Cd II +117387173
Cd III +29500
Cd IV +310200
Data Garis Spektrum NIST →

Data Tingkat Energi ?

IonMuatanTingkat energi
Cd I 0128
Cd II +1101
Cd III +248
Cd IV +352
Cd V +42
Cd VI +52
Cd VII +62
Cd VIII +72
Cd IX +82
Cd X +92
Data Tingkat Energi NIST →
48 Cd 112.414

Cadmium — Visualisasi Orbital Atom

[Kr]5s24d10
Tingkat energi 2 8 18 18 2
Bilangan oksidasi -2, +1, +2
HOMO 5s n=5 · l=0 · m=0
Cadmium — Pratinjau Visualisasi Orbital Atom
Three.js hanya dimuat saat diminta
48 Cd 112.414

Cadmium — Visualisasi Struktur Kristal

Heksagonal Primitif · Pearson hP2
Eksperimental
Pearson hP2
No. Koord. 12
Pengemasan 61.221%
Cadmium — Pratinjau Visualisasi Struktur Kristal
Three.js hanya dimuat saat diminta

Jari-jari Ion

MuatanKoordinasiSpinJari-jari
+24Tidak tersedia78 pm
+25Tidak tersedia87 pm
+26Tidak tersedia95 pm
+27Tidak tersedia103 pm
+28Tidak tersedia110.00000000000001 pm
+212Tidak tersedia131 pm

Senyawa

Cd
112,410 u
Cd+2
112,410 u
Cd
108,905 u
Cd
114,905 u
Cd
112,904 u
Cd
106,907 u
Cd
113,903 u
Cd
110,904 u
Cd
103,910 u
Cd
116,907 u
Cd+2
110,904 u
Cd
102,913 u
Cd
111,903 u
Cd
109,903 u
Cd+2
108,905 u
Cd
105,906 u
Cd
107,904 u
Cd
115,905 u

Isotop (3)

Nomor massaMassa atom (u)Kelimpahan alamiWaktu paruhMode peluruhan
110 Stabil109,90300661 ± 0,0000006112,4900% ± 0,1800%Stabil
stable
111 Stabil110,90418287 ± 0,0000006112,8000% ± 0,1200%Stabil
stable
112 Stabil111,90276287 ± 0,000000624,1300% ± 0,2100%Stabil
stable
110 Stabil
Massa atom (u) 109,90300661 ± 0,00000061
Kelimpahan alami 12,4900% ± 0,1800%
Waktu paruh Stabil
Mode peluruhan
stable
111 Stabil
Massa atom (u) 110,90418287 ± 0,00000061
Kelimpahan alami 12,8000% ± 0,1200%
Waktu paruh Stabil
Mode peluruhan
stable
112 Stabil
Massa atom (u) 111,90276287 ± 0,0000006
Kelimpahan alami 24,1300% ± 0,2100%
Waktu paruh Stabil
Mode peluruhan
stable

Garis Spektrum

Panjang gelombang (nm)IntensitasTahap ionisasiJenisTransisiAkurasiSumber
398.19257 nm10Cd Iemission4d10.5s.5p 1P* → 4d10.5s.9s 1SDiukurNIST
414.03021 nmTidak tersediaCd Iemission4d10.5s.5p 1P* → 4d10.5s.7d 1DDiukurNIST
430.66718 nm8Cd Iemission4d10.5s.5p 1P* → 4d10.5s.8s 1SDiukurNIST
441.29894 nm3Cd Iemission4d10.5s.5p 3P* → 4d10.5s.6s 1SDiukurNIST
466.2352 nm8Cd Iemission4d10.5s.5p 1P* → 4d10.5s.6d 1DDiukurNIST
467.815 nm200Cd Iemission4d10.5s.5p 3P* → 4d10.5s.6s 3SDiukurNIST
479.99121 nm300Cd Iemission4d10.5s.5p 3P* → 4d10.5s.6s 3SDiukurNIST
508.58214 nmTidak tersediaCd Iemission4d10.5s.5p 3P* → 4d10.5s.6s 3SDiukurNIST
515.46618 nm6Cd Iemission4d10.5s.5p 1P* → 4d10.5s.7s 1SDiukurNIST
609.9142 nm300Cd Iemission4d10.5s.6s 3S → 4d10.5s.8p 3P*DiukurNIST
611.1495 nm100Cd Iemission4d10.5s.6s 3S → 4d10.5s.8p 3P*DiukurNIST
632.51689 nm100Cd Iemission4d10.5s.5p 1P* → 4d10.5s.5d 3DDiukurNIST
633.00149 nm30Cd Iemission4d10.5s.5p 1P* → 4d10.5s.5d 3DDiukurNIST
643.84695 nm2000Cd Iemission4d10.5s.5p 1P* → 4d10.5s.5d 1DDiukurNIST
677.8116 nm30Cd Iemission4d10.5s.6s 1S → 4d10.5s.8p 1P*DiukurNIST
734.5665 nm1000Cd Iemission4d10.5s.6s 3S → 4d10.5s.7p 3P*DiukurNIST

Sifat Lanjutan

Jari-jari Kovalen (Lanjutan)

Jari-jari kovalen (Pyykkö)
136 pm
Jari-jari kovalen (Pyykkö, ikatan rangkap dua)
144 pm
Jari-jari kovalen (Bragg)
160 pm

Jari-jari van der Waals

Batsanov
220 pm
Alvarez
249 pm
UFF
284,8 pm
MM3
250 pm

Jari-jari Atom & Logam

Jari-jari atom (Rahm)
238 pm
Jari-jari logam (C12)
151 pm

Skala Penomoran

Mendeleev
78
Pettifor
75
Glawe
75

Skala Keelektronegatifan

Ghosh
0
Miedema
4
Gunnarsson–Lundqvist
4
Robles–Bartolotti
3

Polarizabilitas & Dispersi

Polarizabilitas dipol
46 a.u.
Polarizabilitas dipol (ketidakpastian)
2 a.u.
C₆ (Gould–Bučko)
405 Ha·Bohr6

Parameter Miedema

Volume molar Miedema
13 cm3/mol
Kerapatan elektron Miedema
2

Risiko Pasokan & Ekonomi

Konsentrasi produksi
32
Risiko pasokan relatif
7
Distribusi cadangan
20
Stabilitas politik (produsen terbesar)
24
Stabilitas politik (pemilik cadangan terbesar)
11

Transisi Fase & Alotrop

Titik lebur594,22 K
Titik didih1040,15 K

Kategori Bilangan Oksidasi

−2 extended
+2 main
+1 extended

Data Referensi Lanjutan

Konstanta Pemerisaian (10)
nOrbitalσ
1s0,9744
2p4,091
2s12,6142
3d14,3931
3p17,3085
3s17,1588
4d32,1232
4p28,5888
4s27,1308
5s39,808
Detail Jari-jari Kristal (6)
MuatanCNSpinrcrystal (pm)Asal
2IV92
2V101
2VI109
2VII117calculated,
2VIII124calculated,
2XII145
Mode Peluruhan Isotop (59)
IsotopModeIntensitas
94B+—
94B+p—
95B+100%
95B+p4,6%
96B+100%
96B+p1,6%
97B+100%
97B+p7,4%
98B+100%
98B+p0%
Faktor Hamburan Sinar-X (510)
Energi (eV)f₁f₂
10—0,40004
10,1617—0,41842
10,3261—0,43764
10,4931—0,45775
10,6628—0,49362
10,8353—0,53685
11,0106—0,59258
11,1886—0,66328
11,3696—0,74242
11,5535—0,86125

Data Tambahan

Referensi

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
Cd

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Cadmium

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

Catatan lisensi: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Cadmium

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

Catatan lisensi: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Cadmium

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Cadmium

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Cadmium

This section provides all form of data related to element Cadmium.

9 PubChem Elements
Cadmium

The element property data was retrieved from publications.

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