W 74

Tungsten (W)

transition-metal
周期: 6 族: 6 区: d

Solid

标准原子量

183.84 u

电子排布

[Xe] 6s2 4f14 5d4

熔点

3421.85 °C

沸点

5554.85 °C

密度

1.93e+4 kg/m³

氧化态

−4, −2, −1, 0, +1, +2, +3, +4, +5, +6

电负性(鲍林)

2.36

第一电离能

7.86403 eV

发现年份

1781

原子半径

135 pm

详细信息

名称来源 Swedish: tung sten (heavy stone): symbol from its German name wolfram.
发现国家 Spain
发现者 Fausto and Juan José de Elhuyar

Tungsten is a dense, refractory transition metal in group 6. It has the highest melting point of any element and retains strength at temperatures where most engineering metals soften. Chemically it is best known for stable high oxidation states, especially +6, and for forming hard carbides and complex oxoanions. Natural tungsten occurs mainly in tungstate minerals rather than as the native metal.

Pure tungsten is a steel-gray to tin-white metal. Very pure tungsten can be cut with a hacksaw, forged, spun, drawn, and extruded. The impure metal is brittle and can be worked only with difficulty. Tungsten has the highest melting point of all metals, and at temperatures over 1650°C has the highest tensile strength. The metal oxidizes in air and must be protected at elevated temperatures. It has excellent corrosion resistance and is attacked only slightly by most mineral acids. The thermal expansion is about the same as borosilicate glass, which makes the metal useful for glass-to-metal seals.

The name derives from the Swedish tungsten for "heavy stone". The symbol W derives from the German wolfram, which was found with tin and interfered with the smelting of tin. It was said to eat up tin like a wolf eats up sheep. The element was discovered by the Swedish pharmacist and chemist Carl-Wilhelm Scheele in 1781. Tungsten metal was first isolated by the Spanish chemists Fausto Elhuyar and his brother Juan José in 1783.

Tungsten was discovered by Juan José and Fausto Elhuyar, Spanish chemists and brothers, in 1783 in samples of the mineral wolframite ((Fe, Mn)WO4). Today, tungsten is primarily obtained from wolframite and scheelite (CaWO4) using the same basic method developed by José and Elhuyar. Tungsten ores are crushed, cleaned and treated with alkalis to form tungsten trioxide (WO3). Tungsten trioxide is then heated with carbon or hydrogen gas (H2), forming tungsten metal and carbon dioxide (CO2) or tungsten metal and water vapor (H2O).

From Swedish, tung sten meanig heavy stone. In 1779 Peter Woulfe examined the mineral now known as wolframite and concluded it must contain a new substance. Scheele, in 1781, found that a new acid could be made from tungsten (a name first applied about 1758 to a mineral now known as scheelite). Scheele and Berman suggested the possibility of obtaining a new metal by reducing this acid. The de Elhuyar brothers found acid in wolframite in 1783 that was identical to the acid of tungsten (tungstic acid) of Scheele, and in that year they succeeded in obtaining the element by reduction of this acid with charcoal. Tungsten occurs in wolframite, scheelite, huebnertie, and ferberite. Important deposits of tungsten occur in California, Colorado, South Korea, Bolivia, Russia, and Portugal. China is reported to have about 75% of the world's tungsten resources. Natural tungsten contains five stable isotopes. Twenty one other unstable isotopes are recognized. The metal is obtained commercially be reducing tungsten oxide with hydrogen or carbon.

图片

性质

物理性质

原子半径(经验值)
135 pm 比较所有元素的原子半径(经验值) →
共价半径
162 pm 比较所有元素的共价半径 →
范德华半径
210 pm 比较所有元素的范德华半径 →
金属半径
130 pm 比较所有元素的金属半径 →
密度
1.93 × 104 kg/m³ 比较所有元素的密度 →
摩尔体积
0.00953 L/mol
标准温度和压力下的物相
固态 比较所有元素的标准温度和压力下的物相 →
熔点
3421.85 °C 比较所有元素的熔点 →
沸点
5554.85 °C 比较所有元素的沸点 →
热导率
173 W/(m·K) 比较所有元素的热导率 →
比热容
0.132 J/(g·K) 比较所有元素的比热容 →
摩尔热容
24.27 J/(mol·K) 比较所有元素的摩尔热容 →
晶体结构
体心立方 比较所有元素的晶体结构 →

化学性质

电负性(鲍林)
2.36 比较所有元素的电负性(鲍林) →
电负性(Allen)
1.47
电子亲和能
0.815 eV
第一电离能
7.86403 eV 比较所有元素的第一电离能 →
第二电离能
16.370056 eV 比较所有元素的第二电离能 →
第三电离能
26.000089 eV 比较所有元素的第三电离能 →
第四电离能
38.200131 eV 比较所有元素的第四电离能 →
第五电离能
51.600178 eV 比较所有元素的第五电离能 →
氧化态
−4, −2, −1, 0, +1, +2, +3, +4, +5, +6 比较所有元素的氧化态 →
价电子
6 比较所有元素的价电子 →
电子排布
[Xe] 6s2 4f14 5d4

热力学性质

熔化热
0.36482355 eV 比较所有元素的熔化热 →
汽化热
8.360885 eV 比较所有元素的汽化热 →
升华热
8.803441 eV
原子化热
8.803441 eV
原子化焓
8.820024 eV

核性质

质子
74 比较所有元素的质子 →
中子
110 比较所有元素的中子 →
已知同位素
41 比较所有元素的已知同位素 →
稳定同位素
0 比较所有元素的稳定同位素 →
最稳定同位素
W-184
发现年份
1781

丰度

丰度(地壳)
1.25 mg/kg 比较所有元素的丰度(地壳) →
丰度(海洋)
1 × 10−4 mg/L 比较所有元素的丰度(海洋) →

晶体结构

晶格常数a
316 pm

电子结构

各电子层电子数
2, 8, 18, 32, 12, 2 比较所有元素的各电子层电子数 →

标识符

CAS登记号
7440-33-7 比较所有元素的CAS登记号 →
谱项符号
5D0
InChI
InChI=1S/W
InChI Key
WFKWXMTUELFFGS-UHFFFAOYSA-N

电子排布 实测值

离子电荷
质子 74
电子 74
电荷 中性
电子排布 W: 4f¹⁴ 5d⁴ 6s²
电子排布
实测值
[Xe] 4f¹⁴ 5d⁴ 6s²
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d⁴ 6s²
轨道图
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
2/2
4d
10/10
5p
6/6
6s
2/2
4f
14/14
5d
4/10 4↑
电子总数: 74 未配对: 4 ?

原子模型

质子 74
中子 103
电子 74
质量数 177
稳定性 放射性

不同同位素的中子数、质量和稳定性不同,但中性原子的电子排布不变。

原子模型示意图,未按比例绘制。

原子指纹

发射 / 吸收光谱

25 / 50 (50 50条具有强度数据)
实测值
发射 可见光:380–750 nm

同位素分布

无稳定同位素。

质量数原子质量(u)天然丰度半衰期
183 放射性182.95022275 ± 0.000000914.3100%670 Ey
161 放射性160.9672 ± 0.00021暂无409 ms
157 放射性156.97884 ± 0.00043暂无275 ms
177 放射性176.946643 ± 0.00003暂无132.4 分钟
181 放射性180.9481978 ± 0.0000051暂无120.956 天
实测值

物相 / 状态

1 atm / 101.325 kPa
固态 25 °C (298.15 K)

原因: 低于熔点(3421.85 °C)3396.8 °C

熔点 3421.85 °C
沸点 5554.85 °C
低于熔点的温差 3396.8 °C
0 K 当前温度: 25 °C 6000 K
物相变化轴

示意图,未按比例绘制

固态
液态
气态
熔化
沸腾
25°C
固态
液态
气态
当前

相变点

熔点 文献值
3421.85 °C
沸点 文献值
5554.85 °C
当前物相 计算值
固态

相变能

熔化热 文献值
0.36482355 eV

在熔点熔化1 mol物质所需的能量

汽化热 文献值
8.360885 eV

在沸点汽化1 mol物质所需的能量

升华热 文献值
8.803441 eV

在升华点升华1 mol物质所需的能量

密度

参考密度 文献值
1.93e+4 kg/m³

标准条件下

当前密度 计算值
1.93e+4 kg/m³

标准条件下

原子光谱

已显示10项,共74项。 按离子电荷升序排列。

收录谱线 ?

离子电荷谱线总数跃迁概率能级标记
W I 070495225852
W II +128382112838
W III +22644372644
W IV +37910791
W V +41930193
W VI +517017
W VII +63970397
W VIII +7193187193
NIST收录谱线 →

收录能级 ?

离子电荷能级
W I 0509
W II +1264
W III +2236
W IV +3106
W V +460
W VI +515
W VII +6113
W VIII +7103
W IX +83
W X +92
NIST收录能级 →
74 W 183.84

Tungsten — 原子轨道可视化工具

[Xe]6s24f145d4
能级 2 8 18 32 12 2
氧化态 -4, -2, -1, 0, +1, +2, +3, +4, +5, +6
HOMO 5d n=5 · l=2 · m=-2
Tungsten — 原子轨道可视化预览
Three.js仅在需要时加载
74 W 183.84

Tungsten — 晶体结构可视化工具

体心立方 · 皮尔逊符号 cI2
实验数据
皮尔逊符号 cI2
配位数 8
堆积系数 68.000%
Tungsten — 晶体结构可视化预览
Three.js仅在需要时加载

离子半径

电荷配位自旋半径
+46暂无66 pm
+56暂无62 pm
+64暂无42 pm
+65暂无51 pm
+66暂无60 pm

化合物

W
183.840 u
W
184.953 u
W
180.948 u
W
187.958 u
W
177.946 u
W
179.947 u
W
181.948 u
W
182.950 u
W
186.957 u
W
178.947 u
W
175.946 u
W
176.947 u
W
185.954 u
W
183.951 u
W+2
183.840 u

同位素 (5)

质量数原子质量(u)天然丰度半衰期衰变方式
183 放射性182.95022275 ± 0.000000914.3100% ± 0.0400%670 Ey
IS =14.31±0.4%α ?
161 放射性160.9672 ± 0.00021暂无409 ms
α =73±0.3%β+ =27±0.3%
157 放射性156.97884 ± 0.00043暂无275 ms
β+ =100%α =0%
177 放射性176.946643 ± 0.00003暂无132.4 分钟
β+ =100%
181 放射性180.9481978 ± 0.0000051暂无120.956 天
ε =100%
183 放射性
原子质量(u) 182.95022275 ± 0.0000009
天然丰度 14.3100% ± 0.0400%
半衰期 670 Ey
衰变方式
IS =14.31±0.4%α ?
161 放射性
原子质量(u) 160.9672 ± 0.00021
天然丰度 暂无
半衰期 409 ms
衰变方式
α =73±0.3%β+ =27±0.3%
157 放射性
原子质量(u) 156.97884 ± 0.00043
天然丰度 暂无
半衰期 275 ms
衰变方式
β+ =100%α =0%
177 放射性
原子质量(u) 176.946643 ± 0.00003
天然丰度 暂无
半衰期 132.4 分钟
衰变方式
β+ =100%
181 放射性
原子质量(u) 180.9481978 ± 0.0000051
天然丰度 暂无
半衰期 120.956 天
衰变方式
ε =100%

谱线

已显示50项,共2460项。 默认仅显示具有实测强度的谱线。

波长(nm)强度电离级类型跃迁准确度来源
400.8749 nm1000W Iemission5d5.(6S).6s 7S → 5d5.(6S).6p 7P*实测值NIST
429.4605 nm800W Iemission5d5.(6S).6s 7S → 5d5.(6S).6p 7P*实测值NIST
386.7982 nm600W Iemission5d5.(6S).6s 7S → 5d4.6s.(6D).6p 7D*实测值NIST
407.4357 nm600W Iemission5d5.(6S).6s 7S → 5d5.(6S).6p 7P*实测值NIST
381.7484 nm400W Iemission5d5.(6S).6s 7S → 5d4.6s.(6D).6p 5F*实测值NIST
484.381 nm400W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 7D*实测值NIST
505.328 nm400W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 7D*实测值NIST
384.6213 nm300W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 5F*实测值NIST
525.9338 nm300W Iemission5d5.(6S).6p 7P* → 5d4.6s.(6D).7s 7D实测值NIST
551.4684 nm300W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 7D*实测值NIST
383.5052 nm250W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 5P*实测值NIST
388.1394 nm250W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 5P*实测值NIST
522.4661 nm250W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 7D*实测值NIST
524.2973 nm250W Iemission5d4.6s2 3G → *实测值NIST
424.4367 nm200W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 7D*实测值NIST
426.9384 nm200W Iemission5d5.(6S).6s 7S → *实测值NIST
430.2103 nm200W Iemission5d5.(6S).6s 7S → 5d4.6s.(6D).6p 7D*实测值NIST
488.6902 nm200W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 7F*实测值NIST
498.2586 nm200W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 7F*实测值NIST
380.9234 nm150W Iemission5d5.(6S).6s 7S → 5d4.6s.(6D).6p 5D*实测值NIST
384.749 nm150W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 5F*实测值NIST
505.4594 nm150W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 7F*实测值NIST
507.1736 nm150W Iemission5d4.6s.(6D).6p 7F* → 5d4.6s.(6D).7s 7D实测值NIST
523.352 nm150W Iemission5d4.6s2 3P2 → *实测值NIST
527.5538 nm150W Iemission5d5.(4G).6s 5G → *实测值NIST
549.2315 nm150W Iemission5d4.6s.(6D).6p 7D* → 5d4.6s.(6D).7s 7D实测值NIST
381.0796 nm120W Iemission5d4.6s2 3F2 → *实测值NIST
506.9123 nm120W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 7F*实测值NIST
525.5401 nm120W Iemission5d5.(4D).6s 5D → *实测值NIST
434.811303 nm109W IIemission5d4.(5D).6s 4D实测值NIST
381.0385 nm100W Iemission5d5.(4G).6s 5G → *实测值NIST
401.5216 nm100W Iemission5d5.(4G).6s 5G → *实测值NIST
404.56 nm100W Iemission5d5.(6S).6s 7S → 5d4.6s.(6D).6p 5F*实测值NIST
410.2701 nm100W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 5P*实测值NIST
424.1444 nm100W Iemission5d4.6s2 3D → *实测值NIST
427.4553 nm100W Iemission5d4.6s.(6D).6p 7F* → 5d4.6s.(6D).7s 7D实测值NIST
525.4544 nm100W Iemission5d4.6s2 3D → *实测值NIST
526.3195 nm100W Iemission5d5.(4D).6s 5D → *实测值NIST
526.9315 nm100W Iemission5d4.6s2 3F2 → *实测值NIST
543.5042 nm100W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 7F*实测值NIST
395.105951 nm91W IIemission5d4.(5D).6s 4D → 5d3.(4F).6s.(5F).6p 6G*实测值NIST
406.9948 nm80W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 5P*实测值NIST
413.7464 nm80W Iemission5d4.6s2 5D → 5d5.(6S).6p 7P*实测值NIST
421.9375 nm80W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 5D*实测值NIST
425.9363 nm80W Iemission5d4.6s.(6D).6p 7F* → 5d4.6s.(6D).7s 7D实测值NIST
468.0513 nm80W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 7D*实测值NIST
498.6924 nm80W Iemission5d4.6s2 3H → *实测值NIST
526.8545 nm80W Iemission5d4.6s2 3F2 → *实测值NIST
547.7798 nm80W Iemission5d4.6s2 3P2 → 5d4.6s.(6D).6p 5D*实测值NIST
667.838 nm80W Iemission5d5.(4G).6s 5G → *实测值NIST

扩展性质

共价半径(扩展)

共价半径(Pyykkö)
137 pm
共价半径(Pyykkö,双键)
120 pm
共价半径(Pyykkö,三键)
115 pm

范德华半径

Batsanov
210 pm
Alvarez
257 pm
UFF
309.6 pm
MM3
239 pm

原子半径与金属半径

原子半径(Rahm)
253 pm
金属半径(C12)
139 pm

编号标度

Mendeleev
53
Pettifor
56
Glawe
57

电负性标度

Ghosh
0
Miedema
5
Gunnarsson–Lundqvist
6
Robles–Bartolotti
5

极化率与色散

偶极极化率
68 a.u.
偶极极化率(不确定度)
15 a.u.
C₆ (Gould–Bučko)
757 Ha·Bohr6

Miedema参数

Miedema摩尔体积
9.55 cm3/mol
Miedema电子密度
6

供应风险与经济性

生产集中度
84
相对供应风险
10
储量分布
61
政治稳定性(最大生产国)
24
政治稳定性(最大储量国)
24

相变与同素异形体

熔点3687.15 K
沸点5828.15 K

氧化态分类

+2 extended
+4 main
−4 extended
+5 extended
0 extended
+6 main
+3 extended
−1 extended
−2 extended
+1 extended

高级参考数据

屏蔽常数 (14)
n轨道σ
1s1.4343
2p4.4258
2s19.3302
3d13.5476
3p21.3824
3s22.13
4d36.8268
4f39.2892
4p34.4516
4s33.4412
晶体半径详情 (5)
电荷CN自旋rcrystal (pm)来源
4VI80from r^3 vs V plots, from metallic oxides,
5VI76from r^3 vs V plots,
6IV56
6V65
6VI74
同位素衰变方式 (54)
同位素模式强度
157B+100%
157A0%
158A100%
159A100%
159B+—
160A87%
160B+—
161A73%
161B+27%
162B+—
X射线散射因子 (541)
能量 (eV)f₁f₂
10—1.92551
10.1617—2.00949
10.3261—2.09714
10.4931—2.18428
10.6628—2.26758
10.8353—2.35405
11.0105—2.44381
11.1886—2.537
11.3696—2.63375
11.5535—2.73418

补充数据

参考文献

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
W

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Tungsten

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

许可证说明: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Tungsten

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

许可证说明: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Tungsten

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Tungsten

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Tungsten

This section provides all form of data related to element Tungsten.

9 PubChem Elements
Tungsten

The element property data was retrieved from publications.

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