Praseodymium (Pr)
lanthanideSolid
标准原子量
140.90766 u电子排布
[Xe] 6s2 4f3熔点
930.85 °C沸点
3519.85 °C密度
6770 kg/m³氧化态
0, +1, +2, +3, +4, +5电负性（鲍林）
1.13第一电离能
5.4702 eV发现年份
1885原子半径
185 pm详细信息
Praseodymium is a light lanthanide and one of the rare-earth elements. In nature it occurs with other lanthanides, chiefly in minerals such as monazite and bastnäsite, and only in the +3 oxidation state under normal geochemical conditions. Its chemistry is dominated by Pr³⁺ salts and oxides, but the element is more readily oxidized to Pr⁴⁺ than most neighboring lanthanides. Praseodymium is technologically important in permanent magnets, optical materials, ceramics, and specialized alloys.
Praseodymium is soft, silvery, malleable, and ductile. It is somewhat more resistant to corrosion in air than europium, lanthanum, cerium, or neodymium, but it does develop a green oxide coating that falls off when exposed to air. As with other rare-earth metals, it should be kept under a light mineral oil or sealed in plastic.
The name derives from the Greek prasios for "green" and didymos for "twin" because of the pale green salts it forms. Praseodymium was discovered by the Austrian chemist Carl Auer (Baron von Welsbach) in 1885, who separated it and the element neodymium from a didymium sample (didymium had previously been thought to be a separate element).
Praseodymium was discovered by Carl F. Auer von Welsbach, an Austrian chemist, in 1885. He separated praseodymium, as well as the element neodymium, from a material known as didymium. Today, praseodymium is primarily obtained through an ion exchange process from monazite sand ((Ce, La, Th, Nd, Y)PO4), a material rich in rare earth elements.
From the Greek word prasios, green, and didymos, twin. In 1841 Mosander extracted the rare earth didymia from lanthana; in 1879, Lecoq de Boisbaudran isolated a new earth, samaria, from didymia obtained from the mineral samarskite. Six years later, in 1885, von Welsbach separated didymia into two others, praseodymia and neodymia, which gave salts of different colors. As with other rare earths, compounds of these elements in solution have distinctive sharp spectral absorption bands or lines, some of which are only a few Angstroms wide.
Pure praseodymium is a soft, silvery metal with a pale yellow cast when freshly cut. It tarnishes readily in air, forming oxide layers that can spall, so metal is usually stored under mineral oil, inert gas, or vacuum. It is malleable and reacts slowly with water, faster with dilute acids.
The largest use of praseodymium is in neodymium-iron-boron magnet alloys, where it can partly replace neodymium and help adjust magnetic and processing properties. Praseodymium compounds color glasses and ceramic glazes yellow to green, and mixed praseodymium-neodymium glass is used in didymium filters for glassworking eye protection. Praseodymium is also used in some mischmetal alloys, polishing and catalytic materials, and doped optical crystals or fibers for specialized lasers and signal devices.
Praseodymium's primary use is as an alloying agent with magnesium to create high-strength metals that are used in aircraft engines. Praseodymium also makes up about 5% of Misch metal, a material that is used to make flints for lighters. Praseodymium forms the core of carbon arc lights which are used in the motion picture industry for studio lighting and projector lights. Praseodymium is added to fiber optic cables as a doping agent where it is used as a signal amplifier. Praseodymium salts are used to give glasses and enamels a yellow color. Praseodymium is also a component of didymium glass, which is used to make certain types of welder's and glass blower's goggles.
Misch metal, used in making cigarette lighters, contains about 5% praseodymium metal. The rare-earth oxides, including Pr2O3 are among the most refractory substances known. Along with other rare earths, it is widely used as a core material for carbon arcs used by the motion picture industry for studio lighting and projection. Salts of praseodymium are used to color glasses and enamels; when mixed with certain other materials, praseodymium produces an intense and unusually clean yellow color in glass. Didymium glass, of which praseodymium is a component, is a colorant for welders goggles.
Isotopes in Medicine
Because of its relatively short half-life (19.12 h) and decay primarily by beta decay (96.3 percent beta decay and 3.7 percent alpha decay), 142Pr has been proposed for two main innovative applications in medicine, namely in microsphere brachytherapy and in eye plaque brachytherapy [425] M. C. Ferreira. Dosimetric Study of Beta-Minus Emitter Praseodymium-142: Applications in Microsphere Brachytherapy for Hepatocellular Carcinoma and Brachytherapy for Ocular Squamous Cell Carcinoma, East Carolina University Greenville, North Carolina, USA (2013).. 142Pr is advantageous because penetration of the beta fraction of the radiation is limited to a few millimeters in tissue, therefore limiting the dose of radiation to the treated site. 142Pr may be produced either by fast neutron activation or thermal neutron activation of stable 141Pr.
Research in metal-bearing radiopharmaceuticals is being conducted to determine the most efficient way to produce and process radioactive metals for in vivo tracing. This research has led to the development of a potential radionuclide generator that administers radioactive metal complexes to be observed during positron emission tomography (PET) imaging. A n(140Nd)/n(140Pr) amount-ratio radionuclide generator has been designed to administer 140Pr complexes, such as 140Pr-DTPA, to be used as a tracer during a PET scan [426] K. P. Zhernosekov. Radiochemical Aspects of Production and Processing of Radiometals for Preparation of Metalloradiopharmaceuticals, Johannes Gutenberg-Universität Mainz: Department of Chemistry, Pharmacy and Earth Sciences (2017), Feb. 27; https://publications.ub.uni-mainz.de/theses/volltexte/2006/1043/pdf/1043.pdf.. The half-life of 140Pr is 3.4 min. The n(140Nd)/n(140Pr) ratio radionuclide generators can also be used for administering 140Pr-phosphonate complexes to identify the development of skeletal metastases. Once the skeletal metastases are found, 153Sm-EDTMP can be administered as a radiotherapeutic agent to treat bone cancer (Fig. IUPAC.59.1) [426] K. P. Zhernosekov. Radiochemical Aspects of Production and Processing of Radiometals for Preparation of Metalloradiopharmaceuticals, Johannes Gutenberg-Universität Mainz: Department of Chemistry, Pharmacy and Earth Sciences (2017), Feb. 27; https://publications.ub.uni-mainz.de/theses/volltexte/2006/1043/pdf/1043.pdf.. The half-life of 153Sm is 1.9 days.
Praseodymium forms mainly trivalent compounds containing Pr³⁺, including praseodymium(III) chloride, PrCl₃, praseodymium(III) fluoride, PrF₃, and praseodymium(III) oxide, Pr₂O₃. Mixed-valence and tetravalent oxide chemistry is important: praseodymium(IV) oxide, PrO₂, and the nonstoichiometric oxide often written Pr₆O₁₁ are useful oxidizing and ceramic materials. Praseodymium salts are commonly green, and their optical absorption bands are sharp because 4f electrons are partly shielded from the ligand environment.
See more information at the Praseodymium compound page.
Praseodymium metal dust and filings can burn, and freshly divided material should be treated as a fire risk. Soluble praseodymium salts have low to moderate acute toxicity compared with many heavy metals, but they are not nutrients and should not be inhaled or ingested. Industrial hazards mainly involve dust exposure, reactive metal handling, hot processing, and co-exposure to acids, fluorides, or other chemicals used in separation and alloy production.
Praseodymium is dispersed in the crust with other light rare-earth elements and is concentrated by geological processes in phosphate and carbonate minerals. It is generally immobile in neutral soils and waters because Pr³⁺ strongly adsorbs to clays, oxides, and organic matter or precipitates with phosphate and carbonate. Mining and processing can release rare-earth-bearing dusts and tailings, but praseodymium is not known to have a specific biological role.
Praseodymium is produced as part of rare-earth mining and separation rather than from ores mined solely for Pr. Bastnäsite, monazite, and related concentrates are chemically cracked, and solvent extraction or ion-exchange methods separate the closely similar lanthanides. Demand is strongly linked to high-performance permanent magnets, where praseodymium and neodymium are often managed together as a didymium-rich stream. Supply is constrained by rare-earth separation capacity, environmental controls, and the need to balance production of many co-occurring lanthanides. Recycling from magnets and manufacturing scrap is technically possible and increasingly important, but separation from complex products remains difficult.
The element occurs along with other rare-earth elements in a variety of minerals. Monazite and bastnasite are the two principal commercial sources of the rare-earth metals. It was prepared in relatively pure form in 1931.
Praseodymium is much less abundant in the cosmos than iron-group elements but is a normal product of neutron-capture nucleosynthesis. Its stable isotope, ¹⁴¹Pr, is formed through s-process and r-process pathways in evolved stars and explosive events. In planetary materials it follows other refractory lithophile rare-earth elements and is enriched in differentiated crustal rocks relative to primitive mantle materials.
- Natural praseodymium is essentially monoisotopic, consisting of stable ¹⁴¹Pr.
- The name comes from Greek words meaning “green twin,” referring to the color of its salts and its separation from didymr
- Pr₆O₁₁ is often called praseodymium oxide, although it is not a simple single-valence oxide.
- Praseodymium can replace part of neodymium in many commercial magnet compositions.
- Pr³⁺ absorption lines can give praseodymium glass a distinctive yellow-green filter behavior.
图片
性质
物理性质
- 原子半径（经验值）
- 185 pm 比较所有元素的原子半径（经验值） →
- 共价半径
- 203 pm 比较所有元素的共价半径 →
- 范德华半径
- 239 pm 比较所有元素的范德华半径 →
- 密度
- 6770 kg/m³ 比较所有元素的密度 →
- 摩尔体积
- 0.0208 L/mol
- 标准温度和压力下的物相
- 固态 比较所有元素的标准温度和压力下的物相 →
- 熔点
- 930.85 °C 比较所有元素的熔点 →
- 沸点
- 3519.85 °C 比较所有元素的沸点 →
- 热导率
- 12.5 W/(m·K) 比较所有元素的热导率 →
- 比热容
- 0.193 J/(g·K) 比较所有元素的比热容 →
- 摩尔热容
- 27.2 J/(mol·K) 比较所有元素的摩尔热容 →
- 晶体结构
- 六方密堆积 比较所有元素的晶体结构 →
化学性质
- 电负性（鲍林）
- 1.13 比较所有元素的电负性（鲍林） →
- 电子亲和能
- 0.962 eV
- 第一电离能
- 5.4702 eV 比较所有元素的第一电离能 →
- 第二电离能
- 10.631037 eV 比较所有元素的第二电离能 →
- 第三电离能
- 21.623774 eV 比较所有元素的第三电离能 →
- 第四电离能
- 38.981134 eV 比较所有元素的第四电离能 →
- 第五电离能
- 57.530198 eV 比较所有元素的第五电离能 →
- 氧化态
- 0, +1, +2, +3, +4, +5 比较所有元素的氧化态 →
- 价电子
- 3 比较所有元素的价电子 →
- 电子排布
- [Xe] 6s2 4f3
热力学性质
- 熔化热
- 0.07141006 eV 比较所有元素的熔化热 →
- 汽化热
- 3.078199 eV 比较所有元素的汽化热 →
- 升华热
- 3.430585 eV
- 原子化热
- 3.430585 eV
- 原子化焓
- 3.699021 eV
核性质
- 质子
- 59 比较所有元素的质子 →
- 中子
- 82 比较所有元素的中子 →
- 已知同位素
- 41 比较所有元素的已知同位素 →
- 稳定同位素
- 1 比较所有元素的稳定同位素 →
- 最稳定同位素
- Pr-141
- 发现年份
- 1885
丰度
- 丰度（地壳）
- 9.2 mg/kg 比较所有元素的丰度（地壳） →
- 丰度（海洋）
- 6.4 × 10−7 mg/L 比较所有元素的丰度（海洋） →
晶体结构
- 晶格常数a
- 367 pm
电子结构
- 各电子层电子数
- 2, 8, 18, 21, 8, 2 比较所有元素的各电子层电子数 →
标识符
- CAS登记号
- 7440-10-0 比较所有元素的CAS登记号 →
- 谱项符号
- 4I°9/2
- InChI
- InChI=1S/Pr
- InChI Key
- PUDIUYLPXJFUGB-UHFFFAOYSA-N
电子排布 实测值
Pr: 4f³ 6s²[Xe] 4f³ 6s²1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f³ 6s²原子模型
不同同位素的中子数、质量和稳定性不同，但中性原子的电子排布不变。
原子模型示意图，未按比例绘制。
原子指纹
发射 / 吸收光谱
同位素分布
| 质量数 | 原子质量（u） | 天然丰度 | 半衰期 |
|---|---|---|---|
| 141 稳定 | 140.9076576 ± 0.0000023 | 100.0000% | 稳定 |
物相 / 状态
原因: 低于熔点（930.85 °C）905.9 °C
示意图，未按比例绘制
相变点
相变能
在熔点熔化1 mol物质所需的能量
在沸点汽化1 mol物质所需的能量
在升华点升华1 mol物质所需的能量
密度
标准条件下
标准条件下
原子光谱
已显示10项，共59项。 按离子电荷升序排列。
收录谱线 ?
| 离子 | 电荷 | 谱线总数 | 跃迁概率 | 能级标记 |
|---|---|---|---|---|
| Pr I | 0 | 182 | 0 | 0 |
| Pr II | +1 | 548 | 172 | 356 |
| Pr III | +2 | 372 | 0 | 0 |
| Pr IV | +3 | 135 | 0 | 0 |
| Pr V | +4 | 12 | 0 | 0 |
收录能级 ?
| 离子 | 电荷 | 能级 |
|---|---|---|
| Pr I | 0 | 430 |
| Pr II | +1 | 201 |
| Pr III | +2 | 430 |
| Pr IV | +3 | 104 |
| Pr V | +4 | 9 |
| Pr VI | +5 | 2 |
| Pr VII | +6 | 2 |
| Pr VIII | +7 | 2 |
| Pr IX | +8 | 2 |
| Pr X | +9 | 2 |
离子半径
| 电荷 | 配位 | 自旋 | 半径 |
|---|---|---|---|
| +3 | 6 | 暂无 | 99 pm |
| +3 | 8 | 暂无 | 112.6 pm |
| +3 | 9 | 暂无 | 117.9 pm |
| +4 | 6 | 暂无 | 85 pm |
| +4 | 8 | 暂无 | 96 pm |
化合物
同位素 (1)
| 质量数 | 原子质量（u） | 天然丰度 | 半衰期 | 衰变方式 | |
|---|---|---|---|---|---|
| 141 稳定 | 140.9076576 ± 0.0000023 | 100.0000% | 稳定 | stable |
扩展性质
共价半径（扩展）
- 共价半径（Pyykkö）
- 176 pm
- 共价半径（Pyykkö，双键）
- 138 pm
- 共价半径（Pyykkö，三键）
- 128 pm
范德华半径
- Alvarez
- 292 pm
- UFF
- 360.6 pm
- MM3
- 273 pm
原子半径与金属半径
- 原子半径（Rahm）
- 286 pm
编号标度
- Mendeleev
- 17
- Pettifor
- 31
- Glawe
- 30
电负性标度
- Ghosh
- 0
- Miedema
- 3
- Gunnarsson–Lundqvist
- 4
- Robles–Bartolotti
- 4
极化率与色散
- 偶极极化率
- 216 a.u.
- 偶极极化率（不确定度）
- 20 a.u.
- C₆ (Gould–Bučko)
- 3760 Ha·Bohr6
Miedema参数
- Miedema摩尔体积
- 20.79 cm3/mol
- Miedema电子密度
- 2
供应风险与经济性
- 生产集中度
- 97
- 相对供应风险
- 10
- 储量分布
- 50
- 政治稳定性（最大生产国）
- 24
- 政治稳定性（最大储量国）
- 24
相变与同素异形体
| 熔点 | 1204.15 K |
| 沸点 | 3793.15 K |
氧化态分类
高级参考数据
屏蔽常数 (13)
| n | 轨道 | σ |
|---|---|---|
| 1 | s | 1.1694 |
| 2 | p | 4.2306 |
| 2 | s | 15.538 |
| 3 | d | 13.8476 |
| 3 | p | 19.1756 |
| 3 | s | 19.499 |
| 4 | d | 32.7028 |
| 4 | f | 37.8992 |
| 4 | p | 29.9432 |
| 4 | s | 28.6668 |
晶体半径详情 (5)
| 电荷 | CN | 自旋 | rcrystal (pm) | 来源 |
|---|---|---|---|---|
| 3 | VI | 113 | from r^3 vs V plots, | |
| 3 | VIII | 126.6 | from r^3 vs V plots, | |
| 3 | IX | 131.9 | from r^3 vs V plots, | |
| 4 | VI | 99 | from r^3 vs V plots, | |
| 4 | VIII | 110 | from r^3 vs V plots, |
同位素衰变方式 (58)
| 同位素 | 模式 | 强度 |
|---|---|---|
| 121 | p | 100% |
| 122 | B+ | — |
| 122 | B+p | — |
| 123 | B+ | — |
| 123 | B+p | — |
| 124 | B+ | 100% |
| 124 | B+p | — |
| 125 | B+ | 100% |
| 125 | B+p | — |
| 126 | B+ | 100% |
X射线散射因子 (508)
| 能量 (eV) | f₁ | f₂ |
|---|---|---|
| 10 | — | 1.26325 |
| 10.1617 | — | 1.25455 |
| 10.3261 | — | 1.24591 |
| 10.4931 | — | 1.23732 |
| 10.6628 | — | 1.22879 |
| 10.8353 | — | 1.22033 |
| 11.0106 | — | 1.21192 |
| 11.1886 | — | 1.20357 |
| 11.3696 | — | 1.19528 |
| 11.5535 | — | 1.18704 |
补充数据
Estimated Crustal Abundance
The estimated element abundance in the earth's crust.
9.2 milligrams per kilogram
参考文献 (1)
- [5] Praseodymium https://education.jlab.org/itselemental/ele059.html
Estimated Oceanic Abundance
The estimated element abundance in the earth's oceans.
6.4×10-7 milligrams per liter
参考文献 (1)
- [5] Praseodymium https://education.jlab.org/itselemental/ele059.html
Sources
Sources of this element.
The element occurs along with other rare-earth elements in a variety of minerals. Monazite and bastnasite are the two principal commercial sources of the rare-earth metals. It was prepared in relatively pure form in 1931.
参考文献 (1)
- [6] Praseodymium https://periodic.lanl.gov/59.shtml
Production
Production of this element (from raw materials or other compounds containing the element).
Ion-exchange and solvent extraction techniques have led to much easier isolation of the rare earths and the cost has dropped greatly in the past few years. Praseodymium can be prepared by several methods, such as by calcium reduction of the anhydrous chloride of fluoride.
参考文献 (1)
- [6] Praseodymium https://periodic.lanl.gov/59.shtml
参考文献
(9)
Data deposited in or computed by PubChem
The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.
Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.
The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.
Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/
The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.
The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database
This section provides all form of data related to element Praseodymium.
The element property data was retrieved from publications.