Chromium (Cr)
transition-metalSolid
标准原子量
51.9961 u电子排布
[Ar] 3d5 4s1熔点
1906.85 °C沸点
2670.85 °C密度
7150 kg/m³氧化态
−4, −2, −1, 0, +1, +2, +3, +4, +5, +6电负性（鲍林）
1.66第一电离能
6.76651 eV发现年份
1797原子半径
140 pm详细信息
Chromium is a hard transition metal best known for forming adherent, protective oxide films and for giving many minerals and compounds strong colors. It occurs mainly in chromite ores and is an important alloying element in stainless and heat-resisting steels. Its chemistry spans several oxidation states, especially +3 and +6, with a sharp contrast between relatively stable Cr(III) compounds and strongly oxidizing, often toxic Cr(VI) species.
Chromium is used extensively in automobile trim as chromium metal because of its shiny finish and corrosion resistance.
The name derives from the Greek chroma for "colour", from the many coloured compounds of chromium. It was discovered in 1797 by the French chemist and pharmacist Nicolas-Louis Vauquelin, who also isolated chromium in 1798.
Chromium was discovered by Louis-Nicholas Vauquelin while experimenting with a material known as Siberian red lead, also known as the mineral crocoite (PbCrO4), in 1797. He produced chromium oxide (CrO3) by mixing crocoite with hydrochloric acid (HCl). Although he believed a method for isolating chromium didn't yet exist, Vauquelin was pleasantly surprised in 1798 to discover that he was able to obtain metallic chromium by simply heating chromium oxide in a charcoal oven. Today, chromium is primarily obtained by heating the mineral chromite (FeCr2O4) in the presence of aluminum or silicon.
From the Greek word chroma, color. Chromium is a steel-gray, lustrous, hard metal that takes a high polish. Discovered in 1797 by the Frenchman Louis Nicolas Vauquelin.
Pure chromium is a lustrous, silvery-gray metal with a high polish and a relatively high melting point. It is hard and brittle at room temperature, and its surface is rapidly passivated by a very thin oxide layer that resists further corrosion under many conditions.
The largest use of chromium is in ferrochrome for stainless steel, where chromium provides corrosion resistance by forming a passive surface film. It is also used in tool steels, superalloys, wear-resistant coatings, and hard chromium electroplating. Chromium compounds have been used in pigments, leather tanning, wood preservation, catalysts, and refractory materials, although several Cr(VI)-based uses have been restricted or replaced because of toxicity and environmental persistence.
Chromium is a blue-white metal that is hard, brittle and very corrosion resistant. Chromium can be polished to form a very shiny surface and is often plated to other metals to form a protective and attractive covering. Chromium is added to steel to harden it and to form stainless steel, a steel alloy that contains at least 10% chromium. Other chromium-steel alloys are used to make armor plate, safes, ball bearings and cutting tools.
Chromium forms many colorful compounds that have industrial uses. Lead chromate (PbCrO4), also known as chrome yellow, has been used as a yellow pigment in paints. Chromic oxide (Cr2O3), also known as chrome green, is the ninth most abundant compound in the earth's crust and is a widely used green pigment. Rubies and emeralds also owe their colors to chromium compounds. Potassium dichromate (K2Cr2O7) is used in the tanning of leather while other chromium compounds are used as mordants, materials which permanently fix dyes to fabrics. Chromium compounds are also used to anodize aluminum, a process which coats aluminum with a thick, protective layer of oxide. Chromite, chromium's primary ore, is used to make molds for the firing of bricks because of its high melting point, moderate thermal expansion and stable crystal structure.
Chromium is used to harden steel, manufacture stainless steel, and form many useful alloys. It is mostly used in plating to produce a hard, beautiful surface and to prevent corrosion. Chromium gives glass an emerald green color and is widely used as a catalyst.
The refractory industry uses chromite for forming bricks and shapes, as it has a high melting point, moderate thermal expansion, and stability of crystalline structure.
Isotopes in Earth/Planetary Science
Molecules, atoms, and ions of the stable isotopes of chromium possess slightly different physical and chemical properties, and they commonly will be fractionated during physical, chemical, and biological processes, giving rise to variations in isotopic abundances and in atomic weights. There are measureable variations in the isotopic abundances of chromium in natural terrestrial materials (Fig. IUPAC.24.1).
SiC grains are formed in very high-temperature events that occurred before the formation of the Solar System. The chemical and isotopic composition of certain elements in these grains, such as chromium, provides insights into the origin of the Solar System. The 54Cr nucleus is only produced by supernovae. Excess amounts of this isotope in the SiC grains (relative to terrestrial isotopic composition) in primitive meteorites suggest a heterogeneous distribution of 54Cr in the early Solar System and different sources of material to our Solar System [206] L. Qin, L. R. Nittler, C. M. O. D. Alexander, J. Wang, F. J. Stadermann, R. W. Carlson. Geochim. Cosmochim. Acta.75, 629 (2010).. The early solar nebula was divided into two components. One contained chromium depleted in the lighter isotopes and the other contained heavier chromium isotopes. Isotopic studies indicate these components formed a homogeneous mixture in the early Earth, but they separated during partitioning of the Earth’s core (Fig. IUPAC.24.1) [207] F. Moynier, Q. Z. Yin, E. Schauble. Science331, 1417 (2011)., [208] W. F. McDonough. Science331, 1397 (2011)..
Mobility and toxicity of chromium metal depend largely on the oxidation state of the element. Isotopes of chromium are fractionated by reduction-oxidation (redox) chemical reactions. The isotopic composition has been used to trace the origin of the element in the environment and provide information on reduction-oxidation chemical processes [209] A. S. Ellis, T. M. Johnson, T. D. Bullen. Science295, 2060 (2002)..
Isotopes in Medicine
Stable isotopes of chromium are used to investigate the metabolism of chromium (III), which is an essential nutrient. Chromium stable isotopes (53Cr and 54Cr) have been administered to patients and the relative metabolic activity of each isotope is measured to study insulin function in patients suffering from diabetes (a disease in which the body is unable to produce any or enough insulin, and/or is not able to properly use the insulin that it does produce, resulting in elevated levels of glucose in the blood) [210] H. M. Silver, M. A. Seebeck, R. M. Cowett, K. Y. Patterson, C. Veillon. J. Soc. Gynecol. Investig.4, 254 (1997).. 51Cr and 53Cr have been used to label red blood cells to determine blood volume and life-time of red blood cells in the body [210] H. M. Silver, M. A. Seebeck, R. M. Cowett, K. Y. Patterson, C. Veillon. J. Soc. Gynecol. Investig.4, 254 (1997)..
Chromium forms compounds in oxidation states from negative values in organometallic chemistry to +6, but +3 and +6 dominate common inorganic chemistry. Chromium(III) oxide, Cr₂O₃, is a stable green solid and an important pigment and refractory material. Chromium(VI) oxide, CrO₃, chromates such as potassium chromate, K₂CrO₄, and dichromates such as potassium dichromate, K₂Cr₂O₇, are strong oxidants. Chromium(II) chloride, CrCl₂, is a reducing Cr(II) salt used in specialized synthesis.
All compounds of chromium are colored. The most important chromates are those of sodium and potassium, the dichromates, and the potassium and ammonium chrome alums. The dichromates are used as oxidizing agents in quantitative analysis, also in tanning leather.
Other compounds are of industrial value; lead chromate is chrome yellow, a valued pigment. Chromium compounds are used in the textile industry as mordants, and by the aircraft and other industries for anodizing aluminum.
See more information at the Chromium compound page.
Metallic chromium is not highly reactive in bulk form, but dusts and fumes from welding, grinding, or plating operations can be hazardous. Soluble Cr(VI) compounds are toxic, corrosive, sensitizing, and carcinogenic by inhalation, and they require strict exposure control. Cr(III) compounds are generally less mobile and less toxic, although concentrated salts and fine powders still present chemical and occupational hazards.
Chromium compounds are toxic and should be handled with proper safeguards.
Chromium is a natural trace constituent of rocks, soils, and sediments, commonly associated with ultramafic rocks and chromite minerals. In the environment, Cr(III) tends to form insoluble hydroxides and complexes with organic matter, while Cr(VI) oxyanions are more mobile in oxygenated waters. Industrial releases from plating, tanning, pigment manufacture, and waste disposal have produced localized contamination where redox conditions control persistence and transport.
Chromium is produced chiefly by mining chromite ore and reducing it to ferrochrome for steelmaking. South Africa, Kazakhstan, India, Turkey, and several other countries are important sources of chromite, so supply is tied to ore quality, energy costs, and metallurgical capacity. Demand is dominated by stainless steel production, with smaller markets for chemicals, refractories, and plating. Recycling occurs mainly through stainless steel and alloy scrap, which returns chromium to steel production and reduces dependence on primary ore.
The principal ore is chromite, which is found in Zimbabwe, Russia, New Zealand, Turkey, Iran, Albania, Finland, Democratic Republic of Madagascar, and the Phillippines. The metal is usually produced by reducing the oxide with aluminum.
Chromium is a minor but widespread element in the cosmos, made mainly in massive stars and supernova nucleosynthesis near the iron peak. It is present in the Sun, meteorites, and rocky planetary materials. Isotopic ratios of chromium in meteorites are used in cosmochemistry to trace early Solar System reservoirs and nucleosynthetic contributions.
- The name chromium comes from the Greek word for color, reflecting its vividly colored compounds.
- Ruby owes its red color to trace Cr³⁺ substituting for aluminum in corundum.
- Chrome plating can be decorative, but engineering hard chrome is used mainly for wear resistance.
- Passivation by chromium oxide is the key reason stainless steel does not behave like ordinary carbon steel.
- Lead chromate, PbCrO₄, was once a major yellow pigment but is now restricted in many applications.
- Chromium metal is usually traded through ferrochrome rather than as pure metal.
图片
性质
物理性质
- 原子半径（经验值）
- 140 pm 比较所有元素的原子半径（经验值） →
- 共价半径
- 139 pm 比较所有元素的共价半径 →
- 范德华半径
- 189 pm 比较所有元素的范德华半径 →
- 金属半径
- 119 pm 比较所有元素的金属半径 →
- 密度
- 7150 kg/m³ 比较所有元素的密度 →
- 摩尔体积
- 0.00723 L/mol
- 标准温度和压力下的物相
- 固态 比较所有元素的标准温度和压力下的物相 →
- 熔点
- 1906.85 °C 比较所有元素的熔点 →
- 沸点
- 2670.85 °C 比较所有元素的沸点 →
- 热导率
- 93.9 W/(m·K) 比较所有元素的热导率 →
- 比热容
- 0.449 J/(g·K) 比较所有元素的比热容 →
- 摩尔热容
- 23.35 J/(mol·K) 比较所有元素的摩尔热容 →
- 晶体结构
- 体心立方 比较所有元素的晶体结构 →
化学性质
- 电负性（鲍林）
- 1.66 比较所有元素的电负性（鲍林） →
- 电负性（Allen）
- 1.65
- 电子亲和能
- 0.675 eV
- 第一电离能
- 6.76651 eV 比较所有元素的第一电离能 →
- 第二电离能
- 16.486362 eV 比较所有元素的第二电离能 →
- 第三电离能
- 30.959107 eV 比较所有元素的第三电离能 →
- 第四电离能
- 49.160169 eV 比较所有元素的第四电离能 →
- 第五电离能
- 69.460239 eV 比较所有元素的第五电离能 →
- 氧化态
- −4, −2, −1, 0, +1, +2, +3, +4, +5, +6 比较所有元素的氧化态 →
- 价电子
- 6 比较所有元素的价电子 →
- 电子排布
- [Ar] 3d5 4s1
热力学性质
- 熔化热
- 0.21246826 eV 比较所有元素的熔化热 →
- 汽化热
- 3.518682 eV 比较所有元素的汽化热 →
- 升华热
- 4.119811 eV
- 原子化热
- 4.119811 eV
- 原子化焓
- 4.119604 eV
核性质
- 质子
- 24 比较所有元素的质子 →
- 中子
- 28 比较所有元素的中子 →
- 已知同位素
- 30 比较所有元素的已知同位素 →
- 稳定同位素
- 3 比较所有元素的稳定同位素 →
- 最稳定同位素
- Cr-52
- 发现年份
- 1797
丰度
- 丰度（地壳）
- 102 mg/kg 比较所有元素的丰度（地壳） →
- 丰度（海洋）
- 3 × 10−4 mg/L 比较所有元素的丰度（海洋） →
晶体结构
- 晶格常数a
- 288 pm
电子结构
- 各电子层电子数
- 2, 8, 13, 1 比较所有元素的各电子层电子数 →
标识符
- CAS登记号
- 7440-47-3 比较所有元素的CAS登记号 →
- 谱项符号
- 7S3
- InChI
- InChI=1S/Cr
- InChI Key
- VYZAMTAEIAYCRO-UHFFFAOYSA-N
电子排布 实测值
Cr: 3d⁵ 4s¹[Ar] 3d⁵ 4s¹1s² 2s² 2p⁶ 3s² 3p⁶ 3d⁵ 4s¹原子模型
不同同位素的中子数、质量和稳定性不同，但中性原子的电子排布不变。
原子模型示意图，未按比例绘制。
原子指纹
发射 / 吸收光谱
同位素分布
| 质量数 | 原子质量（u） | 天然丰度 | 半衰期 |
|---|---|---|---|
| 52 稳定 | 51.94050623 ± 0.00000063 | 83.7890% | 稳定 |
| 53 稳定 | 52.94064815 ± 0.00000062 | 9.5010% | 稳定 |
| 54 稳定 | 53.93887916 ± 0.00000061 | 2.3650% | 稳定 |
物相 / 状态
原因: 低于熔点（1906.85 °C）1881.8 °C
示意图，未按比例绘制
相变点
相变能
在熔点熔化1 mol物质所需的能量
在沸点汽化1 mol物质所需的能量
在升华点升华1 mol物质所需的能量
密度
标准条件下
标准条件下
原子光谱
已显示10项，共24项。 按离子电荷升序排列。
收录谱线 ?
| 离子 | 电荷 | 谱线总数 | 跃迁概率 | 能级标记 |
|---|---|---|---|---|
| Cr I | 0 | 4369 | 527 | 4369 |
| Cr II | +1 | 5370 | 92 | 5370 |
| Cr III | +2 | 136 | 0 | 0 |
| Cr IV | +3 | 188 | 102 | 102 |
| Cr V | +4 | 193 | 104 | 193 |
| Cr VI | +5 | 102 | 26 | 102 |
| Cr VII | +6 | 143 | 4 | 143 |
| Cr VIII | +7 | 36 | 9 | 36 |
| Cr IX | +8 | 58 | 18 | 58 |
| Cr X | +9 | 75 | 46 | 75 |
收录能级 ?
| 离子 | 电荷 | 能级 |
|---|---|---|
| Cr I | 0 | 659 |
| Cr II | +1 | 914 |
| Cr III | +2 | 215 |
| Cr IV | +3 | 155 |
| Cr V | +4 | 47 |
| Cr VI | +5 | 63 |
| Cr VII | +6 | 66 |
| Cr VIII | +7 | 34 |
| Cr IX | +8 | 49 |
| Cr X | +9 | 39 |
离子半径
| 电荷 | 配位 | 自旋 | 半径 |
|---|---|---|---|
| +2 | 6 | low | 73 pm |
| +2 | 6 | high | 80 pm |
| +3 | 6 | 暂无 | 61.5 pm |
| +4 | 4 | 暂无 | 41 pm |
| +4 | 6 | 暂无 | 55.00000000000001 pm |
| +5 | 4 | 暂无 | 34.5 pm |
| +5 | 6 | 暂无 | 49 pm |
| +5 | 8 | 暂无 | 56.99999999999999 pm |
| +6 | 4 | 暂无 | 26 pm |
| +6 | 6 | 暂无 | 44 pm |
化合物
同位素 (3)
| 质量数 | 原子质量（u） | 天然丰度 | 半衰期 | 衰变方式 | |
|---|---|---|---|---|---|
| 52 稳定 | 51.94050623 ± 0.00000063 | 83.7890% ± 0.0180% | 稳定 | stable | |
| 53 稳定 | 52.94064815 ± 0.00000062 | 9.5010% ± 0.0170% | 稳定 | stable | |
| 54 稳定 | 53.93887916 ± 0.00000061 | 2.3650% ± 0.0070% | 稳定 | stable |
谱线
已显示50项，共2531项。 默认仅显示具有实测强度的谱线。
| 波长（nm） | 强度 | 电离级 | 类型 | 跃迁 | 准确度 | 来源 | |
|---|---|---|---|---|---|---|---|
| 540.978408 nm | 8500 | Cr I | emission | 3d4.4s2 a 5D → 3d5.(6S).4p z 5P* | 实测值 | NIST | |
| 534.57965 nm | 5100 | Cr I | emission | 3d4.4s2 a 5D → 3d5.(6S).4p z 5P* | 实测值 | NIST | |
| 529.827202 nm | 3540 | Cr I | emission | 3d4.4s2 a 5D → 3d5.(6S).4p z 5P* | 实测值 | NIST | |
| 435.17622 nm | 3500 | Cr I | emission | 3d4.4s2 a 5D → 3d4.(5D).4s.4p.(3P*) z 5F* | 实测值 | NIST | |
| 534.83147 nm | 3200 | Cr I | emission | 3d4.4s2 a 5D → 3d5.(6S).4p z 5P* | 实测值 | NIST | |
| 434.450128 nm | 3100 | Cr I | emission | 3d4.4s2 a 5D → 3d4.(5D).4s.4p.(3P*) z 5F* | 实测值 | NIST | |
| 433.944609 nm | 2600 | Cr I | emission | 3d4.4s2 a 5D → 3d4.(5D).4s.4p.(3P*) z 5F* | 实测值 | NIST | |
| 526.415341 nm | 2600 | Cr I | emission | 3d4.4s2 a 5D → 3d5.(6S).4p z 5P* | 实测值 | NIST | |
| 464.616212 nm | 2400 | Cr I | emission | 3d4.4s2 a 5D → 3d4.(5D).4s.4p.(3P*) y 5P* | 实测值 | NIST | |
| 529.669109 nm | 2100 | Cr I | emission | 3d4.4s2 a 5D → 3d5.(6S).4p z 5P* | 实测值 | NIST | |
| 391.915844 nm | 2030 | Cr I | emission | 3d4.4s2 a 5D → 3d4.(5D).4s.4p.(3P*) z 5D* | 实测值 | NIST | |
| 433.755701 nm | 1900 | Cr I | emission | 3d4.4s2 a 5D → 3d4.(5D).4s.4p.(3P*) z 5F* | 实测值 | NIST | |
| 740.01798 nm | 1900 | Cr I | emission | 3d5.(6S).4p z 7P* → 3d5.(6S).5s e 7S | 实测值 | NIST | |
| 465.215743 nm | 1750 | Cr I | emission | 3d4.4s2 a 5D → 3d4.(5D).4s.4p.(3P*) y 5P* | 实测值 | NIST | |
| 435.962444 nm | 1420 | Cr I | emission | 3d4.4s2 a 5D → 3d4.(5D).4s.4p.(3P*) z 5F* | 实测值 | NIST | |
| 437.127465 nm | 1400 | Cr I | emission | 3d4.4s2 a 5D → 3d4.(5D).4s.4p.(3P*) z 5F* | 实测值 | NIST | |
| 735.58903 nm | 1400 | Cr I | emission | 3d5.(6S).4p z 7P* → 3d5.(6S).5s e 7S | 实测值 | NIST | |
| 461.612404 nm | 1360 | Cr I | emission | 3d4.4s2 a 5D → 3d4.(5D).4s.4p.(3P*) y 5P* | 实测值 | NIST | |
| 390.875593 nm | 1310 | Cr I | emission | 3d4.4s2 a 5D → 3d4.(5D).4s.4p.(3P*) z 5D* | 实测值 | NIST | |
| 449.685195 nm | 1300 | Cr I | emission | 3d5.(6S).4s a 5S → 3d4.(5D).4s.4p.(3P*) y 5P* | 实测值 | NIST | |
| 524.756509 nm | 1250 | Cr I | emission | 3d4.4s2 a 5D → 3d5.(6S).4p z 5P* | 实测值 | NIST | |
| 460.074835 nm | 1190 | Cr I | emission | 3d4.4s2 a 5D → 3d4.(5D).4s.4p.(3P*) y 5P* | 实测值 | NIST | |
| 433.971051 nm | 1120 | Cr I | emission | 3d4.4s2 a 5D → 3d4.(5D).4s.4p.(3P*) z 5F* | 实测值 | NIST | |
| 462.617342 nm | 1100 | Cr I | emission | 3d4.4s2 a 5D → 3d4.(5D).4s.4p.(3P*) y 5P* | 实测值 | NIST | |
| 435.104951 nm | 1080 | Cr I | emission | 3d4.4s2 a 5D → 3d4.(5D).4s.4p.(3P*) z 5F* | 实测值 | NIST | |
| 438.4975 nm | 1060 | Cr I | emission | 3d4.4s2 a 5D → 3d4.(5D).4s.4p.(3P*) z 5F* | 实测值 | NIST | |
| 526.571497 nm | 1050 | Cr I | emission | 3d4.4s2 a 5D → 3d5.(6S).4p z 5P* | 实测值 | NIST | |
| 452.64538 nm | 960 | Cr I | emission | 3d5.(4G).4s a 5G → 3d5.(4G).4p z 5G* | 实测值 | NIST | |
| 454.595302 nm | 930 | Cr I | emission | 3d5.(6S).4s a 5S → 3d4.(5D).4s.4p.(3P*) y 5P* | 实测值 | NIST | |
| 532.832346 nm | 930 | Cr I | emission | 3d5.(6S).4p z 7P* → 3d5.(6S).4d e 7D | 实测值 | NIST | |
| 388.32867 nm | 910 | Cr I | emission | 3d4.4s2 a 5D → 3d4.(5D).4s.4p.(3P*) z 5D* | 实测值 | NIST | |
| 392.86372 nm | 880 | Cr I | emission | 3d4.4s2 a 5D → 3d4.(5D).4s.4p.(3P*) z 5D* | 实测值 | NIST | |
| 388.521354 nm | 810 | Cr I | emission | 3d4.4s2 a 5D → 3d4.(5D).4s.4p.(3P*) z 5D* | 实测值 | NIST | |
| 746.23079 nm | 800 | Cr I | emission | 3d5.(6S).4p z 7P* → 3d5.(6S).5s e 7S | 实测值 | NIST | |
| 453.073802 nm | 770 | Cr I | emission | 3d5.(4G).4s a 5G → 3d5.(4G).4p z 5G* | 实测值 | NIST | |
| 388.679508 nm | 740 | Cr I | emission | 3d4.4s2 a 5D → 3d4.(5D).4s.4p.(3P*) z 5D* | 实测值 | NIST | |
| 392.102067 nm | 740 | Cr I | emission | 3d4.4s2 a 5D → 3d4.(5D).4s.4p.(3P*) z 5D* | 实测值 | NIST | |
| 394.148757 nm | 720 | Cr I | emission | 3d4.4s2 a 5D → 3d4.(5D).4s.4p.(3P*) z 5D* | 实测值 | NIST | |
| 697.83983 nm | 640 | Cr I | emission | 3d4.(5D).4s.4p.(3P*) y 7P* → 3d5.(6S).4d e 7D | 实测值 | NIST | |
| 396.3684 nm | 620 | Cr I | emission | 3d5.(4G).4s a 5G → 3d5.(4G).4p y 5H* | 实测值 | NIST | |
| 453.569676 nm | 600 | Cr I | emission | 3d5.(4G).4s a 5G → 3d5.(4G).4p z 5G* | 实测值 | NIST | |
| 390.290908 nm | 590 | Cr I | emission | 3d4.4s2 a 5D → 3d4.(5D).4s.4p.(3P*) z 5D* | 实测值 | NIST | |
| 455.864413 nm | 590 | Cr II | emission | 3d5 b 4F → 3d4.(5D).4p z 4D* | 实测值 | NIST | |
| 461.335727 nm | 590 | Cr I | emission | 3d4.4s2 a 5D → 3d4.(5D).4s.4p.(3P*) y 5P* | 实测值 | NIST | |
| 396.974253 nm | 570 | Cr I | emission | 3d5.(4G).4s a 5G → 3d5.(4G).4p y 5H* | 实测值 | NIST | |
| 458.004789 nm | 560 | Cr I | emission | 3d5.(6S).4s a 5S → 3d4.(5D).4s.4p.(3P*) y 5P* | 实测值 | NIST | |
| 530.074563 nm | 530 | Cr I | emission | 3d4.4s2 a 5D → 3d5.(6S).4p z 5P* | 实测值 | NIST | |
| 397.665859 nm | 520 | Cr I | emission | 3d5.(4G).4s a 5G → 3d5.(4G).4p y 5H* | 实测值 | NIST | |
| 454.04987 nm | 500 | Cr I | emission | 3d5.(4G).4s a 5G → 3d5.(4G).4p z 5G* | 实测值 | NIST | |
| 459.139098 nm | 490 | Cr I | emission | 3d4.4s2 a 5D → 3d4.(5D).4s.4p.(3P*) y 5P* | 实测值 | NIST |
扩展性质
共价半径（扩展）
- 共价半径（Pyykkö）
- 122 pm
- 共价半径（Pyykkö，双键）
- 111 pm
- 共价半径（Pyykkö，三键）
- 103 pm
- 共价半径（Bragg）
- 140 pm
范德华半径
- Batsanov
- 205 pm
- Alvarez
- 245 pm
- UFF
- 302.3 pm
- MM3
- 225 pm
原子半径与金属半径
- 原子半径（Rahm）
- 233 pm
- 金属半径（C12）
- 128 pm
编号标度
- Mendeleev
- 51
- Pettifor
- 57
- Glawe
- 55
电负性标度
- Ghosh
- 0
- Miedema
- 5
- Gunnarsson–Lundqvist
- 4
- Robles–Bartolotti
- 2
极化率与色散
- 偶极极化率
- 83 a.u.
- 偶极极化率（不确定度）
- 12 a.u.
- C₆
- 602 Ha·Bohr6
- C₆ (Gould–Bučko)
- 709 Ha·Bohr6
化学亲和力
- 质子亲和能
- 791.3 kJ/mol
- 气相碱性
- 768.4 kJ/mol
Miedema参数
- Miedema摩尔体积
- 7.23 cm3/mol
- Miedema电子密度
- 5
供应风险与经济性
- 生产集中度
- 37
- 相对供应风险
- 6
- 储量分布
- 46
- 政治稳定性（最大生产国）
- 44
- 政治稳定性（最大储量国）
- 62
相变与同素异形体
| 熔点 | 2180.15 K |
| 沸点 | 2944.15 K |
氧化态分类
高级参考数据
屏蔽常数 (7)
| n | 轨道 | σ |
|---|---|---|
| 1 | s | 0.5862 |
| 2 | p | 3.9248 |
| 2 | s | 7.0162 |
| 3 | d | 14.2434 |
| 3 | p | 12.534 |
| 3 | s | 11.6322 |
| 4 | s | 18.8668 |
晶体半径详情 (10)
| 电荷 | CN | 自旋 | rcrystal (pm) | 来源 |
|---|---|---|---|---|
| 2 | VI | LS | 87 | estimated, |
| 2 | VI | HS | 94 | from r^3 vs V plots, |
| 3 | VI | 75.5 | from r^3 vs V plots, | |
| 4 | IV | 55 | ||
| 4 | VI | 69 | from r^3 vs V plots, | |
| 5 | IV | 48.5 | from r^3 vs V plots, | |
| 5 | VI | 63 | estimated, from r^3 vs V plots, | |
| 5 | VIII | 71 | ||
| 6 | IV | 40 | ||
| 6 | VI | 58 | calculated, |
同位素衰变方式 (52)
| 同位素 | 模式 | 强度 |
|---|---|---|
| 41 | p | — |
| 42 | B+ | 100% |
| 42 | B+p | 94.4% |
| 42 | 2p | — |
| 43 | B+ | 100% |
| 43 | B+p | 79.3% |
| 43 | 2p | 11.6% |
| 43 | 3p | 0.1% |
| 43 | B+A | — |
| 44 | B+ | 100% |
X射线散射因子 (751)
| 能量 (eV) | f₁ | f₂ |
|---|---|---|
| 0.42 | -0.0076 | 0.02756 |
| 0.46 | -0.01 | 0.03022 |
| 0.5 | -0.0123 | 0.03301 |
| 0.54 | -0.0148 | 0.03586 |
| 0.58 | -0.0176 | 0.03897 |
| 0.62 | -0.0202 | 0.04225 |
| 0.66 | -0.0225 | 0.04515 |
| 0.7 | -0.0257 | 0.04771 |
| 0.74 | -0.0292 | 0.05056 |
| 0.78 | -0.0332 | 0.05331 |
补充数据
Estimated Crustal Abundance
The estimated element abundance in the earth's crust.
1.02×102 milligrams per kilogram
参考文献 (1)
- [5] Chromium https://education.jlab.org/itselemental/ele024.html
Estimated Oceanic Abundance
The estimated element abundance in the earth's oceans.
3×10-4 milligrams per liter
参考文献 (1)
- [5] Chromium https://education.jlab.org/itselemental/ele024.html
Sources
Sources of this element.
The principal ore is chromite, which is found in Zimbabwe, Russia, New Zealand, Turkey, Iran, Albania, Finland, Democratic Republic of Madagascar, and the Phillippines. The metal is usually produced by reducing the oxide with aluminum.
参考文献 (1)
- [6] Chromium https://periodic.lanl.gov/24.shtml
参考文献
(9)
Data deposited in or computed by PubChem
The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.
Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.
The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.
Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/
The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.
The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database
This section provides all form of data related to element Chromium.
The element property data was retrieved from publications.