No 102

Nobelium (No)

actinide
周期: 7 区: f

Solid

标准原子量

[259]

电子排布

[Rn] 7s2 5f14

熔点

826.85 °C

沸点

暂无

密度

9900 kg/m³

氧化态

+2, +3

电负性(鲍林)

1.3

第一电离能

6.62621 eV

发现年份

1957

原子半径

暂无

详细信息

名称来源 Named in honor of Alfred Nobel, who invented dynamite and founded Nobel prize.
发现国家 Sweden
发现者 Nobel Institute for Physics

Nobelium is a synthetic actinide with atomic number 102. It is produced only in particle-accelerator experiments and is studied in atom-at-a-time quantities. Its longest-lived confirmed isotopes have half-lives of only minutes, so no macroscopic sample or ordinary material application exists. Chemically, nobelium is notable because the +2 oxidation state is unusually stable for an actinide, in contrast to the more common +3 state of many neighboring elements.

Nobelium does not occur naturally in the Earth’s crust. It was first synthesized in 1966 by Russian scientists from the Joint Institute for Nuclear Research (JINR) in Dubna, Russia under Georgi Flerov. Earlier claims to have synthesized “nobelium” beginning in 1957 were shown to be erroneous. This element was originally named for Alfred Nobel (Fig. IUPAC.102.1), the inventor of dynamite and founder of the Nobel prizes. The name was later retained because of its widespread use throughout the scientific literature [636], [638]. There are no uses for isotopes of nobelium outside of scientific research.

Nobelium is named after Alfred Nobel.

In 1957, a group of scientists working at the Nobel Institute of Physics in Stockhlom, Sweden, announced the discovery of a new element. They produced this new element, which they named nobelium, by bombarding a target of curium-244 with ions of carbon-13 with a device called a cyclotron. The isotope they created had a half-life of 10 minutes. In 1958, another group of scientists, Albert Ghiorso, Glenn T. Seaborg, Torbørn Sikkeland and John R. Walton, working at the Lawrence Radiation Laboratory in Berkeley, California, attempted to confirm the Nobel Institute's discovery. They were unable to produce any isotope of nobelium with a half-life of 10 minutes, but were able to produce nobelium-254, with a half-life of three seconds, by bombarding curium-246 with carbon-12. A third group, working at the Joint Institute for Nuclear Research in Dubna, Russia, also could not duplicate the Nobel Institute's work but were able to confirm the Berkeley group's work. Credit for discovering nobelium was eventually given to the scientists working at Lawrence Radiation Laboratory, who decided to keep the name nobelium. Today, the Lawrence Radiation Laboratory is known as the Lawrence Berkeley Laboratory. Nobelium's most stable isotope, nobelium-259, has a half-life of about 58 minutes. It decays into fermium-255 through alpha decay, into mendelevium-259 through electron capture or through spontaneous fission.

Named after Alfred Nobel, inventor of dynamite. Nobelium was unambiguously discovered and identified in April 1958 at Berkeley by A. Ghiorso, T. Sikkeland, J.R. Walton, and G.T. Seaborg, who used a new double-recoil technique. A heavy-ion linear accelerator (HILAC) was used to bombard a thin target of curium (95%244Cm and 4.5% 246Cm) with 12C ions to produce 102No according to the 246Cm(12C, 4n) reaction.

In 1957 workers in the United States, Britain, and Sweden announced the discovery of an isotope of element 102 with a 10-minute half-life at 8.5 MeV, as a result of bombarding 244Cm with 13C nuclei. On the basis of this experiment, the name nobelium was assigned and accepted by the Commission on Atomic Weights of the International Union of Pure and Applied Chemistry.

The acceptance of the name was premature because both Russian and American efforts now completely rule out the possibility of any isotope of Element 102 having a half-life of 10 min in the vicinity of 8.5 MeV. Early work in 1957 on the search for this element, in Russia at the Kurchatov Institute, was marred by the assignment of 8.9 +/- 0.4 MeV alpha radiation with a half-life of 2 to 40 sec, which was too indefinite to support discovery claims.

Confirmatory experiments at Berkeley in 1966 have shown the existence of 254102 with a 55-s half-life, 252102 with a 2.3-s half-life, and 257102 with a 23-s half-life.

Following tradition giving the right to name an element to the discoverer(s), the Berkeley group in 1967, suggested that the hastily given name nobelium along with the symbol No , be retained.

图片

性质

物理性质

范德华半径
246 pm 比较所有元素的范德华半径 →
密度
9900 kg/m³ 比较所有元素的密度 →
标准温度和压力下的物相
固态 比较所有元素的标准温度和压力下的物相 →
熔点
826.85 °C 比较所有元素的熔点 →

化学性质

电负性(鲍林)
1.3 比较所有元素的电负性(鲍林) →
电子亲和能
-2.36 eV (负值——预计该原子不结合额外电子)
第一电离能
6.62621 eV 比较所有元素的第一电离能 →
第二电离能
12.930045 eV 比较所有元素的第二电离能 →
第三电离能
25.800089 eV 比较所有元素的第三电离能 →
第四电离能
41.500143 eV 比较所有元素的第四电离能 →
第五电离能
60.000207 eV 比较所有元素的第五电离能 →
氧化态
+2, +3 比较所有元素的氧化态 →
价电子
3 比较所有元素的价电子 →
电子排布
[Rn] 7s2 5f14

热力学性质

升华热
4.042079 eV
原子化热
4.042079 eV

核性质

质子
102 比较所有元素的质子 →
中子
159 比较所有元素的中子 →
已知同位素
17 比较所有元素的已知同位素 →
稳定同位素
0 比较所有元素的稳定同位素 →
质量数(最稳定同位素)
259
最稳定同位素
No-261
发现年份
1957

丰度

暂无

晶体结构

暂无

电子结构

各电子层电子数
2, 8, 18, 32, 32, 8, 2 比较所有元素的各电子层电子数 →

标识符

CAS登记号
10028-14-5 比较所有元素的CAS登记号 →
谱项符号
1S0
InChI
InChI=1S/No
InChI Key
ORQBXQOJMQIAOY-UHFFFAOYSA-N

电子排布 实测值

离子电荷
质子 102
电子 102
电荷 中性
电子排布 No: 5f¹⁴ 7s²
电子排布
实测值
[Rn] 5f¹⁴ 7s²
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d¹⁰ 6s² 6p⁶ 5f¹⁴ 7s²
轨道图
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
2/2
4d
10/10
5p
6/6
6s
2/2
4f
14/14
5d
10/10
6p
6/6
7s
2/2
5f
14/14
电子总数: 102 未配对: 0

原子模型

质子 102
中子 152
电子 102
质量数 254
稳定性 放射性

不同同位素的中子数、质量和稳定性不同,但中性原子的电子排布不变。

原子模型示意图,未按比例绘制。

原子指纹

发射 / 吸收光谱

0 / 0 (0 0条具有强度数据)
实测值
发射 可见光:380–750 nm

同位素分布

无稳定同位素。

质量数原子质量(u)天然丰度半衰期
251 放射性251.08894 ± 0.00012暂无800 ms
260 放射性260.10264 ± 0.00022暂无106 ms
259 放射性259.10103 ± 0.00011暂无58 分钟
249 放射性249.0878 ± 0.0003暂无57 us
254 放射性254.090956 ± 0.000011暂无51.2 秒
实测值

物相 / 状态

1 atm / 101.325 kPa
固态 25 °C (298.15 K)

原因: 低于升华点(826.85 °C)801.9 °C

升华点 826.85 °C
0 K 当前温度: 25 °C 6000 K
物相变化轴

示意图,未按比例绘制

固态
气态
升华
25°C
固态
液态
气态
当前

相变点

升华点 文献值
826.85 °C
当前物相 计算值
固态

相变能

升华热 文献值
4.042079 eV

在升华点升华1 mol物质所需的能量

密度

参考密度 文献值
9900 kg/m³

标准条件下

当前密度 计算值
9900 kg/m³

标准条件下

原子光谱

已显示10项,共102项。 按离子电荷升序排列。

收录能级 ?

离子电荷能级
No I 02
No II +12
No III +22
No IV +32
No V +42
No VI +52
No VII +62
No VIII +72
No IX +82
No X +92
NIST收录能级 →
102 No 259

Nobelium — 原子轨道可视化工具

[Rn]7s25f14
能级 2 8 18 32 32 8 2
氧化态 +2, +3
HOMO 7s n=7 · l=0 · m=0
Nobelium — 原子轨道可视化预览
Three.js仅在需要时加载
102 No 259

Nobelium — 晶体结构可视化工具

暂无晶体结构数据

离子半径

电荷配位自旋半径
+26暂无110.00000000000001 pm
+39暂无108.5 pm

化合物

No
259.101 u

同位素 (5)

Ten isotopes are now recognized, one of which 255102 has a half-life of 3 minutes.

质量数原子质量(u)天然丰度半衰期衰变方式
251 放射性251.08894 ± 0.00012暂无800 ms
α =83±1.6%β+ ?SF<0.3%
260 放射性260.10264 ± 0.00022暂无106 ms
SF =100%
259 放射性259.10103 ± 0.00011暂无58 分钟
α =75±0.4%ε =25±0.4%SF<10%
249 放射性249.0878 ± 0.0003暂无57 us
β+ ?α ?
254 放射性254.090956 ± 0.000011暂无51.2 秒
α =90±0.1%β+ =10±0.1%SF =0.17±0.2%
251 放射性
原子质量(u) 251.08894 ± 0.00012
天然丰度 暂无
半衰期 800 ms
衰变方式
α =83±1.6%β+ ? +1
260 放射性
原子质量(u) 260.10264 ± 0.00022
天然丰度 暂无
半衰期 106 ms
衰变方式
SF =100%
259 放射性
原子质量(u) 259.10103 ± 0.00011
天然丰度 暂无
半衰期 58 分钟
衰变方式
α =75±0.4%ε =25±0.4% +1
249 放射性
原子质量(u) 249.0878 ± 0.0003
天然丰度 暂无
半衰期 57 us
衰变方式
β+ ?α ?
254 放射性
原子质量(u) 254.090956 ± 0.000011
天然丰度 暂无
半衰期 51.2 秒
衰变方式
α =90±0.1%β+ =10±0.1% +1

扩展性质

共价半径(扩展)

共价半径(Pyykkö)
176 pm

范德华半径

UFF
324.8 pm

编号标度

Mendeleev
40
Pettifor
35
Glawe
46

电负性标度

Ghosh
0

极化率与色散

偶极极化率
110 a.u.
偶极极化率(不确定度)
6 a.u.

相变与同素异形体

熔点1100.15 K

氧化态分类

+2 extended
+3 main

高级参考数据

晶体半径详情 (2)
电荷CN自旋rcrystal (pm)来源
2VI124estimated,
3IX—122.5
同位素衰变方式 (39)
同位素模式强度
248SF—
249B+—
249A—
250SF100%
250A—
250B+—
251A83%
251B+—
251SF0.3%
252A67.6%

补充数据

参考文献

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
No

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Nobelium

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

许可证说明: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Nobelium

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

许可证说明: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Nobelium

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Nobelium

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Nobelium

This section provides all form of data related to element Nobelium.

9 PubChem Elements
Nobelium

The element property data was retrieved from publications.

最后更新:

数据已核实:

内容已依据最新科学数据进行审核。