Palladium (Pd)
transition-metalSolid
Standart Atom Ağırlığı
106,42 uElektron dizilimi
[Kr] 4d10Erime noktası
1554,9 °CKaynama noktası
2962,85 °CYoğunluk
1,2e+4 kg/m³Yükseltgenme basamakları
+1, +2, +3, +4, +5Elektronegatiflik (Pauling)
2,2İyonlaşma enerjisi (1.)
8,336839 eVKeşif yılı
1803Atom yarıçapı
140 pmAyrıntılar
Palladium is a silvery platinum-group metal with high catalytic activity and an unusual ability to absorb large amounts of hydrogen into its lattice. It is chemically noble in air at ordinary temperatures, but it forms many complexes and is readily used in surface chemistry. Its technological importance is dominated by vehicle emission control, fine-chemical catalysis, electronics, and hydrogen-related applications.
The element is a silvery-white metal, it does not tarnish in air, and it is the least dense and lowest melting of the platinum group of metals. When annealed, it is soft and ductile; cold-working greatly increases its strength and hardness. Palladium is attacked by nitric and sulfuric acid.
At room temperatures, the metal has the unusual property of absorbing up to 900 times its own volume of hydrogen, possibly forming Pd2H. It is not yet clear if this is a true compound. Hydrogen readily diffuses through heated palladium, providing a means of purifying the gas.
The name derives from the second largest asteroid of the solar system Pallas (named after the goddess of wisdom and arts—Pallas Athene). The element was discovered by the English chemist and physicist William Hyde Wollaston in 1803, one year after the discovery of Pallas by the German astronomer Wilhelm Olbers in 1802. The discovery was originally published anonymously by Wollaston to obtain priority, while not disclosing any details about his preparation.
Palladium was discovered by William Hyde Wollaston, an English chemist, in 1803 while analyzing samples of platinum ore that were obtained from South America. Although it is a rare element, palladium tends to occur along with deposits of platinum, nickel, copper, silver and gold and is recovered as a byproduct of mining these other metals.
Palladium was named after the asteroid Pallas, which was discovered at about the same time. Pallas was the Greek goddess of wisdom.
Pure palladium is a lustrous, silver-white metal. It is soft and ductile when annealed, can be rolled into thin foil, and does not tarnish rapidly in clean air. Finely divided palladium is gray to black and has much higher surface reactivity than the compact metal.
The largest use of palladium is in catalytic converters, especially for oxidation of carbon monoxide and hydrocarbons and reduction reactions in exhaust systems. Palladium catalysts are also central to hydrogenation and carbon–carbon coupling reactions in chemical manufacture. The metal is used in multilayer ceramic capacitors, electrical contacts, dental alloys, some jewelry alloys, hydrogen purification membranes, and laboratory catalysts such as palladium on carbon.
Palladium is used to make springs for watches, surgical instruments, electrical contacts and dental fillings and crowns. Finely divided palladium acts as a catalyst and is used in hydrogenation and dehydrogenation processes. Palladium at room temperature can absorb up to 900 times its own volume of hydrogen. Hydrogen will easily pass through heated palladium, a property that allows for the easy purification of hydrogen. Palladium alloys are used to make jewelry and, when alloyed with gold, forms a material known as white gold.
Palladium dichloride (PdCl2), a palladium compound, can absorb large amounts of carbon monoxide (CO) gas and is used in carbon monoxide detectors.
Finely divided palladium is a good catalyst and is used for hydrogenation and dehydrogenation reactions. It is alloyed and used in jewelry trades.
White gold is an alloy of gold decolorized by the addition of palladium. Like gold, palladium can be beaten into leaf as thin as 1/250,000 in. The metal is used in dentistry, watch making, and in making surgical instruments and electrical contacts.
Isotopes in Earth/Planetary Science
Small palladium nucleosynthetic anomalies in isotopic composition (related to s-process variability) were identified in type IVB iron meteorites [340] B. Mayer, N. Wittig, M. Humayun, I. Leya. Astrophys. J.809, 180 (2015).. These nucleosynthetic isotope anomalies may represent spatial and/or temporal heterogeneity in the early solar nebula or may be due to chemical processing within the solar nebula [327] N. Dauphas, A. M. Davis, B. Marty, L. Reisberg. Earth Planet. Sci. Lett.226, 465 (2004)., [341] A. Trinquier, T. Elliott, D. Ulfbeck, C. Coath, A. N. Krot, M. Bizzarro. Science324, 374 (2009).. Palladium and molybdenum isotopic compositions on selected iron meteorites are correlated (Fig. IUPAC.46.1). One possible conclusion is that “a common presolar carrier must have been thermally processed on which the more volatile (a measure of the tendency of a substance to vaporize) Pd was lost and homogenized in the solar nebula, resulting in the deviation from the s-process” variability [342] B. Mayer, K. R. Bermingham, E. A. Worsham, M. Humayun, R. J. Walker. “Correlated nucleosynthetic anomalies in Mo, Ru, and Pd from iron meteorites”, in 47th Lunar and Planetary Science Conference.. Because these palladium (and other element) anomalies are persistent throughout the measured iron meteorites, the thermal processing must have occurred prior to the formation of the parent body that produced iron meteorites [342] B. Mayer, K. R. Bermingham, E. A. Worsham, M. Humayun, R. J. Walker. “Correlated nucleosynthetic anomalies in Mo, Ru, and Pd from iron meteorites”, in 47th Lunar and Planetary Science Conference..
Isotopes in Geochronology
The isotope-amount ratio n(107Pd)/n(107Ag) is used in geochronology to help date major thermal events in the Solar System. Although 107Ag is naturally occurring, 107Ag is also the daughter product of the beta decay of 107Pd. If both excess 107Ag and 107Pd (with a half-life of 6.5×106 years) are present in a sample of extraterrestrial origin, then the material would have formed sometime after 107Pd decayed. The n(107Pd)/n(107Ag) amount ratio can be measured to help determine when the 107Pd decay process began and how much time has elapsed since the material was formed [344] W. R. Kelly, G. J. Wasserburg. Geophys. Res. Lett.5 1079 (1978)., [345] G. J. Wasserburg, D. A. Papanastassiou. Some Short-Lived Nuclides in the Early Solar-System – A Connection with the Placental ISM, in Essays in Nuclear Astrophysics, C. A. Barnes, D. D. Clayton, and D. N. Schramm. Cambridge University Press, Cambridge, UK (1982)., [346] J. H. Chen, G. J. Wasserburg. Live 107Pd in the Early Solar System and Implications on Planetary Evolution, in Earth Processes: Reading the Isotopic Code, Geophysical Monograph 95, A. Basu and S. Hart. Amer. Geophys. U., Washington (1996)., [347] J. H. Chen, G. J. Wasserburg. Geochim. Cosmochim. Acta54, 1729 (1990)., [348] A. P. Dicken. Radiogenic Isotope Geology, Cambridge University Press, New York (1995)..
Isotopes in Medicine
Seeds of the radioactive isotope 103Pd are internally placed in the body to fight prostate and other cancers locally. 103Pd has a half-life of 16.99 days and releases energy at about 80 X-rays and 186 Auger electrons per 100 decays of 103Pd. Therefore, this makes this isotope an ideal candidate for internal radiotherapy for the treatment of cancers [349] M. Hussain, S. Sudar, M. N. Aslam, H. A. Shah, R. Ahmad, A. A. Malik, S. M. Qaim. Appl. Radiat. Isot.67, 1842 (2009)..
The radioisotope 109Pd (with a half-life of 13.5 h) can be used as a form of cancer therapy. For example, 109Pd-labeled porphyrins or porphyrin-like substances are used as diagnostic and therapeutic techniques to help locate and address areas of tumorous growth. Porphyrins accumulate in tumors of the body and when radiolabeled porphyrins are introduced to the body, the X-rays and energy released can help determine the location and even treat the cancerous tumors [350] T. Das, S. Chakraborty, H. D. Sarma, S. Banerjee. Radiochim. Acta96, 427 (2008)..
Isotopes Used as a Source of Radioactive Isotope(s)
104Pd is the major target used for cyclotron production of the medically important radioactive isotope 103Pd via the reaction 104Pd (p, p n) 103Pd [349] M. Hussain, S. Sudar, M. N. Aslam, H. A. Shah, R. Ahmad, A. A. Malik, S. M. Qaim. Appl. Radiat. Isot.67, 1842 (2009)..
Palladium most often shows oxidation states +2 and 0, with +4 important in some fluorides and complex salts. Palladium(II) chloride, PdCl₂, is a common starting material for coordination compounds and catalysts. Tetrakis(triphenylphosphine)palladium(0), Pd[P(C₆H₅)₃]₄, is a widely used homogeneous catalyst precursor. Palladium(II) acetate, Pd(CH₃COO)₂, and palladium on carbon are frequent sources of active palladium species in organic synthesis.
See more information at the Palladium compound page.
Compact palladium metal is not highly reactive and presents low acute toxicity, but dusts and finely divided catalysts can be irritating and may ignite adsorbed hydrogen or organic material under unfavorable conditions. Soluble palladium salts and organopalladium compounds can cause skin sensitization and other toxic effects. Spent catalysts may contain hazardous residues from the processes in which they were used.
Palladium occurs naturally at low concentrations, mainly with other platinum-group elements in sulfide and chromite-associated ores. Environmental releases are increased by abrasion and loss from automotive catalysts, creating fine particles in road dust and nearby soils. Palladium is generally sparingly soluble in many natural waters, but complexing ligands such as chloride and organic matter can increase mobility.
Palladium is obtained chiefly as a by-product of nickel, copper, and platinum-group metal mining and refining, so supply cannot respond as independently as demand for a primary metal. Major demand comes from emission-control catalysts, with electronics, chemical catalysts, dentistry, and jewelry making smaller contributions. Recycling from spent automotive catalysts is an important secondary source. Substitution with platinum or rhodium is possible in some catalyst systems but depends on performance, regulation, and relative availability.
Discovered in 1803 by Wollaston, Palladium is found with platinum and other metals of the platinum group in placer deposits of Russia, South America, North America, Ethiopia, and Australia. It is also found associated with the nickel-copper deposits of South Africa and Ontario. Palladium's separation from the platinum metals depends upon the type of ore in which it is found.
Palladium is a heavy element produced mainly by neutron-capture processes in earlier generations of stars. It is much less abundant cosmically than iron or nickel but is present in meteorites and planetary materials with other siderophile and chalcophile elements. On Earth it was partly concentrated into the core during differentiation, leaving crustal concentrations low.
- Palladium can absorb hydrogen to form non-stoichiometric palladium hydride without becoming a simple fixed-ratio salt.
- The element was named after the asteroid Pallas, which had been discovered shortly before palladium.
- Palladium-gold alloys are used to make white gold in some jewelry.
- Carbon monoxide binds strongly to palladium surfaces, a key feature of exhaust catalysis.
- Palladium leaf can be made, but it is less familiar than gold leaf because the metal is far rarer and costlier.
Görseller
Özellikler
Fiziksel
- Atom yarıçapı (ampirik)
- 140 pm Tüm elementlerin Atom yarıçapı (ampirik) değerlerini karşılaştır →
- Kovalent yarıçap
- 139 pm Tüm elementlerin Kovalent yarıçap değerlerini karşılaştır →
- Van der Waals yarıçapı
- 202 pm Tüm elementlerin Van der Waals yarıçapı değerlerini karşılaştır →
- Metalik yarıçap
- 128 pm Tüm elementlerin Metalik yarıçap değerlerini karşılaştır →
- Yoğunluk
- 1,2 × 104 kg/m³ Tüm elementlerin Yoğunluk değerlerini karşılaştır →
- Molar hacim
- 0,0089 L/mol
- STP'deki faz
- Katı Tüm elementlerin STP'deki faz değerlerini karşılaştır →
- Erime noktası
- 1554,9 °C Tüm elementlerin Erime noktası değerlerini karşılaştır →
- Kaynama noktası
- 2962,85 °C Tüm elementlerin Kaynama noktası değerlerini karşılaştır →
- Isıl iletkenlik
- 71,8 W/(m·K) Tüm elementlerin Isıl iletkenlik değerlerini karşılaştır →
- Özgül ısı kapasitesi
- 0,246 J/(g·K) Tüm elementlerin Özgül ısı kapasitesi değerlerini karşılaştır →
- Molar ısı kapasitesi
- 25,98 J/(mol·K) Tüm elementlerin Molar ısı kapasitesi değerlerini karşılaştır →
- Kristal yapı
- Yüzey merkezli kübik Tüm elementlerin Kristal yapı değerlerini karşılaştır →
Kimyasal
- Elektronegatiflik (Pauling)
- 2,2 Tüm elementlerin Elektronegatiflik (Pauling) değerlerini karşılaştır →
- Elektronegatiflik (Allen)
- 1,58
- Elektron ilgisi
- 0,557 eV
- İyonlaşma enerjisi (1.)
- 8,336839 eV Tüm elementlerin İyonlaşma enerjisi (1.) değerlerini karşılaştır →
- İyonlaşma enerjisi (2.)
- 19,430067 eV Tüm elementlerin İyonlaşma enerjisi (2.) değerlerini karşılaştır →
- İyonlaşma enerjisi (3.)
- 32,930113 eV Tüm elementlerin İyonlaşma enerjisi (3.) değerlerini karşılaştır →
- İyonlaşma enerjisi (4.)
- 46,000158 eV Tüm elementlerin İyonlaşma enerjisi (4.) değerlerini karşılaştır →
- İyonlaşma enerjisi (5.)
- 61,00021 eV Tüm elementlerin İyonlaşma enerjisi (5.) değerlerini karşılaştır →
- Yükseltgenme basamakları
- +1, +2, +3, +4, +5 Tüm elementlerin Yükseltgenme basamakları değerlerini karşılaştır →
- Değerlik elektronları
- 10 Tüm elementlerin Değerlik elektronları değerlerini karşılaştır →
- Elektron dizilimi
- [Kr] 4d10
Termodinamik
- Erime ısısı
- 0,17349847 eV Tüm elementlerin Erime ısısı değerlerini karşılaştır →
- Buharlaşma ısısı
- 3,700057 eV Tüm elementlerin Buharlaşma ısısı değerlerini karşılaştır →
- Süblimleşme ısısı
- 3,907343 eV
- Atomlaşma ısısı
- 3,907343 eV
- Atomlaşma entalpisi
- 3,903197 eV
Nükleer
- Protonlar
- 46 Tüm elementlerin Protonlar değerlerini karşılaştır →
- Nötronlar
- 60 Tüm elementlerin Nötronlar değerlerini karşılaştır →
- Bilinen izotoplar
- 42 Tüm elementlerin Bilinen izotoplar değerlerini karşılaştır →
- Kararlı izotoplar
- 4 Tüm elementlerin Kararlı izotoplar değerlerini karşılaştır →
- En kararlı izotop
- Pd-106
- Keşif yılı
- 1803
Bolluk
- Bolluk (yer kabuğu)
- 0,015 mg/kg Tüm elementlerin Bolluk (yer kabuğu) değerlerini karşılaştır →
Kristal Yapı
- Örgü sabiti a
- 389 pm
Elektronik Yapı
- Kabuk başına elektron sayısı
- 2, 8, 18, 18 Tüm elementlerin Kabuk başına elektron sayısı değerlerini karşılaştır →
Tanımlayıcılar
- CAS numarası
- 7440-05-3 Tüm elementlerin CAS numarası değerlerini karşılaştır →
- Terim simgesi
- 1S0
- InChI
- InChI=1S/Pd
- InChI Anahtarı
- KDLHZDBZIXYQEI-UHFFFAOYSA-N
Elektron Dizilimi Ölçülmüş
Pd: 4d¹⁰[Kr] 4d¹⁰1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰Atom modeli
İzotoplar nötron sayısını, kütleyi ve kararlılığı değiştirir; nötr bir atomun elektron dizilimini değiştirmez.
Şematik atom modeli, ölçekli değildir.
Atomik Parmak İzi
Emisyon / Soğurma Spektrumu
İzotop Dağılımı
| Kütle numarası | Atom kütlesi (u) | Doğal bolluk | Yarı ömür |
|---|---|---|---|
| 104 Kararlı | 103,9040305 ± 0,0000014 | 11,1400% | Kararlı |
| 105 Kararlı | 104,9050796 ± 0,0000012 | 22,3300% | Kararlı |
| 106 Kararlı | 105,9034804 ± 0,0000012 | 27,3300% | Kararlı |
| 108 Kararlı | 107,9038916 ± 0,0000012 | 26,4600% | Kararlı |
Faz / Hâl
Neden: erime noktasının (1554,9 °C) 1529,9 °C altında
Şematik, ölçekli değil
Faz geçiş noktaları
Geçiş enerjileri
Erime noktasında 1 mol maddeyi eritmek için gereken enerji
Kaynama noktasında 1 mol maddeyi buharlaştırmak için gereken enerji
Süblimleşme noktasında 1 mol maddeyi süblimleştirmek için gereken enerji
Yoğunluk
Standart koşullarda
Standart koşullarda
Atomik Spektrumlar
46 kayıttan 10 tanesi gösteriliyor. İyon yüküne göre sıralandı (artan).
Spektral Çizgi Kayıtları ?
| İyon | Yük | Toplam çizgi sayısı | Geçiş olasılıkları | Düzey gösterimleri |
|---|---|---|---|---|
| Pd I | 0 | 76 | 8 | 75 |
| Pd II | +1 | 62 | 10 | 62 |
| Pd III | +2 | 75 | 0 | 0 |
Enerji Düzeyi Kayıtları ?
| İyon | Yük | Düzeyler |
|---|---|---|
| Pd I | 0 | 145 |
| Pd II | +1 | 186 |
| Pd III | +2 | 177 |
| Pd IV | +3 | 2 |
| Pd V | +4 | 2 |
| Pd VI | +5 | 2 |
| Pd VII | +6 | 2 |
| Pd VIII | +7 | 2 |
| Pd IX | +8 | 2 |
| Pd X | +9 | 2 |
İyon Yarıçapları
| Yük | Koordinasyon | Spin | Yarıçap |
|---|---|---|---|
| +1 | 2 | Mevcut değil | 59 pm |
| +2 | 4 | Mevcut değil | 64 pm |
| +2 | 6 | Mevcut değil | 86 pm |
| +3 | 6 | Mevcut değil | 76 pm |
| +4 | 6 | Mevcut değil | 61.5 pm |
Bileşikler
İzotoplar (4)
| Kütle numarası | Atom kütlesi (u) | Doğal bolluk | Yarı ömür | Bozunma türü | |
|---|---|---|---|---|---|
| 104 Kararlı | 103,9040305 ± 0,0000014 | 11,1400% ± 0,0800% | Kararlı | stable | |
| 105 Kararlı | 104,9050796 ± 0,0000012 | 22,3300% ± 0,0800% | Kararlı | stable | |
| 106 Kararlı | 105,9034804 ± 0,0000012 | 27,3300% ± 0,0300% | Kararlı | stable | |
| 108 Kararlı | 107,9038916 ± 0,0000012 | 26,4600% ± 0,0900% | Kararlı | stable |
Spektral Çizgiler
| Dalga boyu (nm) | Şiddet | İyonlaşma aşaması | Tür | Geçiş | Doğruluk | Kaynak | |
|---|---|---|---|---|---|---|---|
| 383.2286 nm | 1500 | Pd I | emission | 4d9.(2D<3/2>).5s 2[3/2] → 4d9.(2D<5/2>).5p 2[3/2]* | Ölçülmüş | NIST | |
| 389.41982 nm | 2200 | Pd I | emission | 4d9.(2D<3/2>).5s 2[3/2] → 4d9.(2D<5/2>).5p 2[5/2]* | Ölçülmüş | NIST | |
| 395.86229 nm | 1500 | Pd I | emission | 4d9.(2D<3/2>).5s 2[3/2] → 4d9.(2D<5/2>).5p 2[5/2]* | Ölçülmüş | NIST | |
| 408.73428 nm | 290 | Pd I | emission | 4d9.(2D<3/2>).5s 2[3/2] → 4d9.(2D<5/2>).5p 2[3/2]* | Ölçülmüş | NIST | |
| 416.98387 nm | 90 | Pd I | emission | 4d9.(2D<3/2>).5s 2[3/2] → 4d9.(2D<5/2>).5p 2[3/2]* | Ölçülmüş | NIST | |
| 421.29533 nm | 2500 | Pd I | emission | 4d9.(2D<3/2>).5s 2[3/2] → 4d9.(2D<5/2>).5p 2[7/2]* | Ölçülmüş | NIST | |
| 447.35846 nm | 180 | Pd I | emission | 4d9.(2D<3/2>).5s 2[3/2] → 4d9.(2D<5/2>).5p 2[3/2]* | Ölçülmüş | NIST | |
| 478.81874 nm | Mevcut değil | Pd I | emission | 4d9.(2D<5/2>).5p 2[3/2]* → 4d9.(2D<5/2>).5d 2[5/2] | Ölçülmüş | NIST | |
| 481.75067 nm | Mevcut değil | Pd I | emission | 4d9.(2D<5/2>).5p 2[3/2]* → 4d9.(2D<5/2>).5d 2[3/2] | Ölçülmüş | NIST | |
| 487.54251 nm | 35 | Pd I | emission | 4d9.(2D<5/2>).5p 2[3/2]* → 4d9.(2D<5/2>).5d 2[1/2] | Ölçülmüş | NIST | |
| 511.08092 nm | 55 | Pd I | emission | 4d9.(2D<5/2>).5p 2[7/2]* → 4d9.(2D<5/2>).5d 2[7/2] | Ölçülmüş | NIST | |
| 511.70072 nm | 75 | Pd I | emission | 4d9.(2D<3/2>).5p 2[5/2]* → 4d9.(2D<3/2>).5d 2[7/2] | Ölçülmüş | NIST | |
| 516.38405 nm | 160 | Pd I | emission | 4d9.(2D<5/2>).5p 2[7/2]* → 4d9.(2D<5/2>).5d 2[9/2] | Ölçülmüş | NIST | |
| 523.48612 nm | 55 | Pd I | emission | 4d9.(2D<5/2>).5p 2[7/2]* → 4d9.(2D<5/2>).5d 2[7/2] | Ölçülmüş | NIST | |
| 529.56266 nm | 120 | Pd I | emission | 4d9.(2D<5/2>).5p 2[7/2]* → 4d9.(2D<5/2>).5d 2[9/2] | Ölçülmüş | NIST | |
| 531.25867 nm | 18 | Pd I | emission | 4d9.(2D<5/2>).5p 2[3/2]* → 4d9.(2D<5/2>).5d 2[5/2] | Ölçülmüş | NIST | |
| 534.51048 nm | 15 | Pd I | emission | 4d9.(2D<3/2>).5p 2[5/2]* → 4d9.(2D<3/2>).5d 2[5/2] | Ölçülmüş | NIST | |
| 539.52204 nm | 35 | Pd I | emission | 4d9.(2D<3/2>).5p 2[5/2]* → 4d9.(2D<3/2>).5d 2[7/2] | Ölçülmüş | NIST | |
| 554.28067 nm | 55 | Pd I | emission | 4d9.(2D<5/2>).5p 2[5/2]* → 4d9.(2D<5/2>).5d 2[7/2] | Ölçülmüş | NIST | |
| 554.70204 nm | 35 | Pd I | emission | 4d9.(2D<5/2>).5p 2[5/2]* → 4d9.(2D<5/2>).5d 2[5/2] | Ölçülmüş | NIST | |
| 561.94631 nm | 27 | Pd I | emission | 4d9.(2D<3/2>).5p 2[3/2]* → 4d9.(2D<3/2>).5d 2[5/2] | Ölçülmüş | NIST | |
| 564.27039 nm | 15 | Pd I | emission | 4d9.(2D<3/2>).5p 2[1/2]* → 4d9.(2D<3/2>).5d 2[3/2] | Ölçülmüş | NIST | |
| 565.54366 nm | 14 | Pd I | emission | 4d9.(2D<3/2>).5p 2[3/2]* → 4d9.(2D<3/2>).5d 2[5/2] | Ölçülmüş | NIST | |
| 567.00702 nm | 75 | Pd I | emission | 4d9.(2D<5/2>).5p 2[5/2]* → 4d9.(2D<5/2>).5d 2[7/2] | Ölçülmüş | NIST | |
| 569.0128 nm | 11 | Pd I | emission | 4d9.(2D<3/2>).5p 2[1/2]* → 4d9.(2D<3/2>).5d 2[3/2] | Ölçülmüş | NIST | |
| 569.50921 nm | Mevcut değil | Pd I | emission | 4d9.(2D<5/2>).5p 2[5/2]* → 4d9.(2D<5/2>).5d 2[5/2] | Ölçülmüş | NIST | |
| 573.66175 nm | 18 | Pd I | emission | 4d9.(2D<5/2>).5p 2[5/2]* → 4d9.(2D<5/2>).5d 2[3/2] | Ölçülmüş | NIST | |
| 677.45174 nm | 23 | Pd I | emission | 4d8.5s2 3F → 4d9.(2D<3/2>).5p 2[5/2]* | Ölçülmüş | NIST | |
| 678.44893 nm | 65 | Pd I | emission | 4d9.(2D<5/2>).5p 2[3/2]* → 4d9.(2D<5/2>).6s 2[5/2] | Ölçülmüş | NIST | |
| 683.3446 nm | Mevcut değil | Pd I | emission | 4d9.(2D<3/2>).5p 2[3/2]* → 4d9.(2D<5/2>).5d 2[5/2] | Ölçülmüş | NIST | |
| 701.6446 nm | 11 | Pd I | emission | 4d9.(2D<3/2>).5p 2[1/2]* → 4d9.(2D<3/2>).6s 2[3/2] | Ölçülmüş | NIST | |
| 731.0053 nm | Mevcut değil | Pd I | emission | 4d9.(2D<3/2>).5p 2[5/2]* → 4d9.(2D<3/2>).6s 2[3/2] | Ölçülmüş | NIST | |
| 736.8096 nm | 75 | Pd I | emission | 4d9.(2D<5/2>).5p 2[7/2]* → 4d9.(2D<5/2>).6s 2[5/2] | Ölçülmüş | NIST | |
| 739.19 nm | 27 | Pd I | emission | 4d9.(2D<3/2>).5p 2[5/2]* → 4d9.(2D<3/2>).6s 2[3/2] | Ölçülmüş | NIST | |
| 748.6909 nm | 16 | Pd I | emission | 4d9.(2D<5/2>).5p 2[7/2]* → 4d9.(2D<5/2>).6s 2[5/2] | Ölçülmüş | NIST |
Genişletilmiş Özellikler
Kovalent Yarıçaplar (Genişletilmiş)
- Kovalent yarıçap (Pyykkö)
- 120 pm
- Kovalent yarıçap (Pyykkö, çift bağ)
- 117 pm
- Kovalent yarıçap (Pyykkö, üçlü bağ)
- 112 pm
Van der Waals Yarıçapları
- Batsanov
- 205 pm
- Alvarez
- 215 pm
- UFF
- 289,9 pm
- MM3
- 237 pm
Atom ve Metalik Yarıçaplar
- Atom yarıçapı (Rahm)
- 215 pm
- Metalik yarıçap (C12)
- 137 pm
Numaralandırma Ölçekleri
- Mendeleev
- 68
- Pettifor
- 69
- Glawe
- 65
Elektronegatiflik Ölçekleri
- Ghosh
- 0
- Miedema
- 5
- Gunnarsson–Lundqvist
- 3
- Robles–Bartolotti
- 2
Kutuplanabilirlik ve Dispersiyon
- Dipol kutuplanabilirliği
- 26,14 a.u.
- Dipol kutuplanabilirliği (belirsizlik)
- 0,1 a.u.
- C₆ (Gould–Bučko)
- 628 Ha·Bohr6
Kimyasal İlgi
- Proton ilgisi
- 696 kJ/mol
- Gaz fazı bazlığı
- 673,4 kJ/mol
Miedema Parametreleri
- Miedema molar hacmi
- 8,9 cm3/mol
- Miedema elektron yoğunluğu
- 5
Tedarik Riski ve Ekonomi
- Üretim yoğunlaşması
- 60
- Göreli tedarik riski
- 8
- Rezerv dağılımı
- 95
- Siyasi istikrar (en büyük üretici)
- 44
- Siyasi istikrar (en büyük rezerv sahibi)
- 44
Faz Geçişleri ve Allotroplar
| Erime noktası | 1827,95 K |
| Kaynama noktası | 3236,15 K |
Yükseltgenme Basamağı Kategorileri
İleri Düzey Referans Verileri
Perdeleme Sabitleri (9)
| n | Orbital | σ |
|---|---|---|
| 1 | s | 0,9411 |
| 2 | p | 4,07 |
| 2 | s | 12,1172 |
| 3 | d | 14,5489 |
| 3 | p | 16,9804 |
| 3 | s | 16,7788 |
| 4 | d | 32,3824 |
| 4 | p | 28,2768 |
| 4 | s | 27,014 |
Kristal Yarıçaplarının Ayrıntıları (5)
| Yük | CN | Spin | rcrystal (pm) | Köken |
|---|---|---|---|---|
| 1 | II | 73 | ||
| 2 | IVSQ | 78 | ||
| 2 | VI | 100 | ||
| 3 | VI | 90 | ||
| 4 | VI | 75,5 | from r^3 vs V plots, |
İzotop Bozunma Türleri (62)
| İzotop | Mod | Şiddet |
|---|---|---|
| 90 | B+ | — |
| 90 | B+p | — |
| 90 | 2p | — |
| 91 | B+ | 100% |
| 91 | B+p | 3,1% |
| 92 | B+ | 100% |
| 92 | B+p | 1,6% |
| 93 | B+ | 100% |
| 93 | B+p | 7,4% |
| 94 | B+ | 100% |
X Işını Saçılma Faktörleri (507)
| Enerji (eV) | f₁ | f₂ |
|---|---|---|
| 10 | — | 1,15058 |
| 10,1617 | — | 1,2095 |
| 10,3261 | — | 1,27144 |
| 10,4931 | — | 1,33655 |
| 10,6628 | — | 1,40499 |
| 10,8353 | — | 1,47694 |
| 11,0106 | — | 1,54695 |
| 11,1886 | — | 1,61473 |
| 11,3696 | — | 1,68548 |
| 11,5535 | — | 1,75934 |
Ek Veriler
Estimated Crustal Abundance
The estimated element abundance in the earth's crust.
1.5×10-2 milligrams per kilogram
Kaynaklar (1)
- [5] Palladium https://education.jlab.org/itselemental/ele046.html
Estimated Oceanic Abundance
The estimated element abundance in the earth's oceans.
Not Applicable
Kaynaklar (1)
- [5] Palladium https://education.jlab.org/itselemental/ele046.html
Sources
Sources of this element.
Discovered in 1803 by Wollaston, Palladium is found with platinum and other metals of the platinum group in placer deposits of Russia, South America, North America, Ethiopia, and Australia. It is also found associated with the nickel-copper deposits of South Africa and Ontario. Palladium's separation from the platinum metals depends upon the type of ore in which it is found.
Kaynaklar (1)
- [6] Palladium https://periodic.lanl.gov/46.shtml
Kaynaklar
(9)
Data deposited in or computed by PubChem
The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.
Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.
The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.
Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/
The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.
The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database
This section provides all form of data related to element Palladium.
The element property data was retrieved from publications.