Copernicium (Cn)
transition-metalExpected to be a Solid
Peso atômico padrão
[285]Configuração eletrônica
[Rn] 7s2 5f14 6d10 (Previsto)Ponto de fusão
N/DPonto de ebulição
-165,15 °CDensidade
1,4e+4 kg/m³Estados de oxidação
+2, +4Eletronegatividade (Pauling)
N/DEnergia de ionização (1ª)
N/DAno da descoberta
1996Raio atômico
147 pmDetalhes
Copernicium is a synthetic transactinide element in group 12, below zinc, cadmium, and mercury. It is known only from accelerator experiments that create individual atoms of short-lived isotopes. Relativistic effects are expected to make its chemistry unusually noble for a group 12 element, with weak metallic bonding and a comparatively volatile elemental state. Its confirmed properties are therefore mainly nuclear, while its chemical behavior remains partly experimental and partly theoretical.
Copernicium does not occur naturally in the Earth’s crust. Copernicium was synthesized by scientists at the GSI Helmholtz Center for Heavy Ion Research in Darmstadt, Germany in 1996 (Fig. IUPAC.112.1). Sigurd Hofmann and an international team of scientists used the nuclear reaction 208Pb (70Zn, n) 277Cn. The observed alpha decays led to the known nuclide, 269Sg. The name, copernicium, was given to element 112 to honor astronomer Nicholas Copernicus, who is known for his heliocentric theory of how the planets orbit the Sun [663], [664]. Copernicium has no known isotopic applications aside from scientific research.
Copernicium is named after the astronomer Nicolaus Copernicus.
Copernicium was first produced by Peter Armbruster, Gottfried Münzenber and their team working at the Gesellschaft für Schwerionenforschung in Darmstadt, Germany on February 9, 1996. They bombarded atoms of lead with ions of zinc with a device known as a linear accelerator. This produced atoms of copernicium-277, an isotope with a half-life of about 0.24 milliseconds (0.00024 seconds). Copernicium's most stable isotope, copernicium-285, has a half-life of about 30 seconds. It decays into darmstadtium-281 through alpha decay.
On February 9, 1996, element 277Cn was created at the Gesellschaft fur Schwerionenforschung in Darmstadt, Germany by using the reaction 208Pb + 70Zn. Unlike element 110, Copernicium has properties more similar to radon than mercury, but due to its short half-life, it is difficult to study. As of 2011, Copernicum's most stable isotope has an atomic weight of 285.
No macroscopic sample of copernicium has been made, so its visible appearance is unknown. Calculations suggest a very volatile, weakly bound metal, possibly more gas-like in atom-at-a-time conditions than mercury, but this is not a directly observed bulk property.
Copernicium has no practical use outside scientific research. Its isotopes are produced one atom at a time to study superheavy nuclei, decay chains, and the influence of strong relativistic effects on chemical behavior. Experimental work with copernicium also helps test models used to predict the stability and chemistry of still heavier elements. No commercial, medical, structural, or electronic application is known or feasible with present production methods and isotope lifetimes.
Since only a few atoms of copernicium have ever been produced, it currently has no uses outside of basic scientific research.
Originally, the symbol Cp was recommended for Copernicium. That symbol was rejected because Cp had previously been used for the element lutetium which, prior to 1949, had cassiopeium as an alternative allowed name. Please see this file for additional details.
Copernicium chemistry has been investigated only in atom-at-a-time experiments and by theory. The element is expected to favor the +2 oxidation state in compounds, by analogy with group 12 elements, but strong relativistic stabilization of the 7s electrons may make neutral copernicium especially inert. Studies of adsorption behavior suggest that elemental Cn interacts weakly with gold surfaces compared with mercury. Predicted species include copernicium(II) fluoride, CnF₂, and copernicium(II) chloride, CnCl₂, but well-characterized bulk compounds do not exist.
See more information at the Copernicium compound page.
The hazards of copernicium are dominated by radioactivity rather than ordinary chemical toxicity. All known isotopes are short-lived and decay mainly by alpha emission, with some decay chains involving spontaneous fission. The element is produced in quantities far too small for conventional handling or environmental exposure. In laboratories, risk control concerns the accelerator target, recoil products, and radioactive decay products, not bulk copernicium material.
Copernicium has no confirmed natural occurrence and no environmental cycle. Any atoms formed naturally, if at all, would decay rapidly and would not accumulate. Laboratory production yields isolated atoms that decay within controlled experimental systems. Consequently, environmental behavior such as solubility, transport in soils or waters, bioaccumulation, and ecological effects has not been observed for copernicium.
Copernicium has no commodity market, industrial supply chain, or recoverable source. It is made in heavy-ion fusion experiments, commonly by bombarding heavy actinide targets with accelerated ions, followed by separation and detection of a few decay events. Production depends on specialized accelerators, rare target materials, long beam times, and highly sensitive detectors. The limiting factors are nuclear reaction cross sections and isotope half-lives, not ore availability or refining capacity. Recycling and substitution have no practical meaning for this element outside research planning.
Made by bombarding lead-208 with zinc-70.
Copernicium is not expected to be a primordial or cosmically abundant element because its known isotopes decay far too quickly to survive since nucleosynthesis. Superheavy nuclei may be formed fleetingly in extreme astrophysical neutron-rich events, but no stable or long-lived copernicium isotope is known. It has no established role in planetary chemistry or extraterrestrial materials.
- Copernicium was named for Nicolaus Copernicus.
- Its chemistry is strongly affected by relativistic stabilization of the 7s electrons.
- Only individual atoms have been studied experimentally.
- The most useful evidence for its chemistry comes from rapid gas-phase adsorption experiments.
- Copernicium sits below mercury but may be even more volatile.
- Its discovery was credited to work at GSI in Darmstadt, Germany.
Imagens
Propriedades
Física
- Raio atômico (empírico)
- 147 pm Comparar Raio atômico (empírico) de todos os elementos →
- Densidade
- 1,4 × 104 kg/m³ Comparar Densidade de todos os elementos →
- Fase nas CNTP
- Gás Comparar Fase nas CNTP de todos os elementos →
- Ponto de ebulição
- -165,15 °C Comparar Ponto de ebulição de todos os elementos →
Química
- Afinidade eletrônica
- -0,8 eV (valor negativo — prevê-se que o átomo não capte um eletrão adicional)
- Estados de oxidação
- +2, +4 Comparar Estados de oxidação de todos os elementos →
- Elétrons de valência
- 2 Comparar Elétrons de valência de todos os elementos →
- Configuração eletrônica
- [Rn] 7s2 5f14 6d10 (Previsto)
Termodinâmica
N/D
Nuclear
- Prótons
- 112 Comparar Prótons de todos os elementos →
- Nêutrons
- 173 Comparar Nêutrons de todos os elementos →
- Isótopos conhecidos
- 13 Comparar Isótopos conhecidos de todos os elementos →
- Isótopos estáveis
- 0 Comparar Isótopos estáveis de todos os elementos →
- Número de massa (mais estável)
- 285
- Isótopo mais estável
- Cn-285
- Ano da descoberta
- 1996
Abundância
N/D
Estrutura cristalina
N/D
Estrutura eletrônica
- Elétrons por camada
- 14, 10, 2 Comparar Elétrons por camada de todos os elementos →
Identificadores
- Número CAS
- 54084-26-3 Comparar Número CAS de todos os elementos →
- InChI
- InChI=1S/Cn
- Chave InChI
- NOTIIDSZELDPOP-UHFFFAOYSA-N
Configuração eletrônica Previsto
——Dados de configuração eletrônica indisponíveis para este íon.
Modelo atômico
Os isótopos alteram o número de nêutrons, a massa e a estabilidade — não a configuração eletrônica de um átomo neutro.
N/D
Modelo atômico esquemático, sem escala.
Assinatura atômica
Espectro de emissão / absorção
Distribuição isotópica
Sem isótopos estáveis.
| Número de massa | Massa atômica (u) | Abundância natural | Meia-vida |
|---|---|---|---|
| 277 Radioativo | 277,16364 ± 0,00015 | N/D | 790 us |
| 281 Radioativo | 281,16975 ± 0,00042 | N/D | 180 ms |
| 284 Radioativo | 284,17416 ± 0,00091 | N/D | 102 ms |
| 276 Radioativo | 276,16141 ± 0,00064 | N/D | 100 us |
| 279 Radioativo | 279,16654 ± 0,0005 | N/D | 60 us |
Fase / Estado
Motivo: 190,1 °C acima do ponto de ebulição (-165,15 °C)
Esquemático, sem escala
Pontos de transição de fase
Densidade
Em condições padrão
Estimada pela lei dos gases ideais à T atual
Dados de estrutura cristalina indisponíveis para a fase sólida
Isótopos (5)
| Número de massa | Massa atômica (u) | Abundância natural | Meia-vida | Modo de decaimento | |
|---|---|---|---|---|---|
| 277 Radioativo | 277,16364 ± 0,00015 | N/D | 790 us | α =100% | |
| 281 Radioativo | 281,16975 ± 0,00042 | N/D | 180 ms | α ≈100%SF ? | |
| 284 Radioativo | 284,17416 ± 0,00091 | N/D | 102 ms | SF =100% | |
| 276 Radioativo | 276,16141 ± 0,00064 | N/D | 100 us | α ?SF ? | |
| 279 Radioativo | 279,16654 ± 0,0005 | N/D | 60 us | α ?SF ? |
Propriedades ampliadas
Raios covalentes (dados ampliados)
- Raio covalente (Pyykkö)
- 122 pm
- Raio covalente (Pyykkö, ligação dupla)
- 137 pm
- Raio covalente (Pyykkö, ligação tripla)
- 130 pm
Escalas de numeração
- Mendeleev
- 80
Polarizabilidade e dispersão
- Polarizabilidade dipolar
- 28 a.u.
- Polarizabilidade dipolar (incerteza)
- 2 a.u.
Categorias de estados de oxidação
Dados de referência avançados
Modos de decaimento dos isótopos (23)
| Isótopo | Modo | Intensidade |
|---|---|---|
| 276 | A | — |
| 276 | SF | — |
| 277 | A | 100% |
| 278 | A | — |
| 278 | SF | — |
| 279 | A | — |
| 279 | SF | — |
| 280 | A | — |
| 280 | SF | — |
| 281 | A | 100% |
Dados adicionais
Estimated Crustal Abundance
The estimated element abundance in the earth's crust.
Not Applicable
Referências (1)
- [5] Copernicium https://education.jlab.org/itselemental/ele112.html
Estimated Oceanic Abundance
The estimated element abundance in the earth's oceans.
Not Applicable
Referências (1)
- [5] Copernicium https://education.jlab.org/itselemental/ele112.html
Referências
(8)
Data deposited in or computed by PubChem
The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.
Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.
The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.
Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/
The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.
The periodic table contains NIST's critically-evaluated data on atomic properties of the elements.
This section provides all form of data related to element Copernicium.