Nobelium (No)
actinideSolid
Peso atômico padrão
[259]Configuração eletrônica
[Rn] 7s2 5f14Ponto de fusão
826,85 °CPonto de ebulição
N/DDensidade
9900 kg/m³Estados de oxidação
+2, +3Eletronegatividade (Pauling)
1,3Energia de ionização (1ª)
6,62621 eVAno da descoberta
1957Raio atômico
N/DDetalhes
Nobelium is a synthetic actinide with atomic number 102. It is produced only in particle-accelerator experiments and is studied in atom-at-a-time quantities. Its longest-lived confirmed isotopes have half-lives of only minutes, so no macroscopic sample or ordinary material application exists. Chemically, nobelium is notable because the +2 oxidation state is unusually stable for an actinide, in contrast to the more common +3 state of many neighboring elements.
Nobelium does not occur naturally in the Earth’s crust. It was first synthesized in 1966 by Russian scientists from the Joint Institute for Nuclear Research (JINR) in Dubna, Russia under Georgi Flerov. Earlier claims to have synthesized “nobelium” beginning in 1957 were shown to be erroneous. This element was originally named for Alfred Nobel (Fig. IUPAC.102.1), the inventor of dynamite and founder of the Nobel prizes. The name was later retained because of its widespread use throughout the scientific literature [636], [638]. There are no uses for isotopes of nobelium outside of scientific research.
Nobelium is named after Alfred Nobel.
In 1957, a group of scientists working at the Nobel Institute of Physics in Stockhlom, Sweden, announced the discovery of a new element. They produced this new element, which they named nobelium, by bombarding a target of curium-244 with ions of carbon-13 with a device called a cyclotron. The isotope they created had a half-life of 10 minutes. In 1958, another group of scientists, Albert Ghiorso, Glenn T. Seaborg, Torbørn Sikkeland and John R. Walton, working at the Lawrence Radiation Laboratory in Berkeley, California, attempted to confirm the Nobel Institute's discovery. They were unable to produce any isotope of nobelium with a half-life of 10 minutes, but were able to produce nobelium-254, with a half-life of three seconds, by bombarding curium-246 with carbon-12. A third group, working at the Joint Institute for Nuclear Research in Dubna, Russia, also could not duplicate the Nobel Institute's work but were able to confirm the Berkeley group's work. Credit for discovering nobelium was eventually given to the scientists working at Lawrence Radiation Laboratory, who decided to keep the name nobelium. Today, the Lawrence Radiation Laboratory is known as the Lawrence Berkeley Laboratory. Nobelium's most stable isotope, nobelium-259, has a half-life of about 58 minutes. It decays into fermium-255 through alpha decay, into mendelevium-259 through electron capture or through spontaneous fission.
Named after Alfred Nobel, inventor of dynamite. Nobelium was unambiguously discovered and identified in April 1958 at Berkeley by A. Ghiorso, T. Sikkeland, J.R. Walton, and G.T. Seaborg, who used a new double-recoil technique. A heavy-ion linear accelerator (HILAC) was used to bombard a thin target of curium (95%244Cm and 4.5% 246Cm) with 12C ions to produce 102No according to the 246Cm(12C, 4n) reaction.
In 1957 workers in the United States, Britain, and Sweden announced the discovery of an isotope of element 102 with a 10-minute half-life at 8.5 MeV, as a result of bombarding 244Cm with 13C nuclei. On the basis of this experiment, the name nobelium was assigned and accepted by the Commission on Atomic Weights of the International Union of Pure and Applied Chemistry.
The acceptance of the name was premature because both Russian and American efforts now completely rule out the possibility of any isotope of Element 102 having a half-life of 10 min in the vicinity of 8.5 MeV. Early work in 1957 on the search for this element, in Russia at the Kurchatov Institute, was marred by the assignment of 8.9 +/- 0.4 MeV alpha radiation with a half-life of 2 to 40 sec, which was too indefinite to support discovery claims.
Confirmatory experiments at Berkeley in 1966 have shown the existence of 254102 with a 55-s half-life, 252102 with a 2.3-s half-life, and 257102 with a 23-s half-life.
Following tradition giving the right to name an element to the discoverer(s), the Berkeley group in 1967, suggested that the hastily given name nobelium along with the symbol No , be retained.
The bulk appearance of nobelium is unknown, because it has never been isolated as a visible sample. Metallic nobelium is expected to be a dense, silvery actinide metal by analogy with neighboring elements, but this is a prediction rather than an observed property.
Nobelium has no practical use outside scientific research. Individual atoms are produced to study heavy-element nuclear stability, decay chains, and relativistic effects in actinide chemistry. Its isotopes have also served as links in identifying the decay products of heavier synthetic elements. These uses rely on rapid radiochemical separation and radiation detection, not on bulk nobelium metal or compounds.
Since only tiny amounts of nobelium have ever been produced, there are currently no uses for it outside of basic scientific research.
Nobelium chemistry has been examined mainly in aqueous tracer experiments. The divalent ion No²⁺ is the best-established chemically distinctive form and behaves in some separations more like alkaline earth ions than typical trivalent actinides. The trivalent ion No³⁺ is also known, but it is less favored in reducing aqueous systems. Specific bulk compounds such as nobelium(II) chloride, NoCl₂, or nobelium(III) oxide, No₂O₃, have not been isolated as macroscopic materials; their properties are inferred from trace chemistry and theory.
See more information at the Nobelium compound page.
All known nobelium isotopes are radioactive, and several decay by alpha emission or spontaneous fission. The element is made in quantities far too small to create ordinary chemical toxicity hazards outside specialized laboratories, but radiological precautions are essential during production and detection work. Safety considerations are isotope-specific because half-lives and decay modes vary widely.
Nobelium has no confirmed natural environmental reservoir. Any atoms produced on Earth are artificial and decay rapidly compared with geological or ecological timescales. Because only atom-scale amounts are generated in shielded research facilities, nobelium has no known role in biogeochemical cycles and no observed environmental transport behavior as a bulk contaminant.
Nobelium is not a traded commodity and has no commercial supply chain. It is made by bombarding heavy actinide targets, commonly curium or californium isotopes, with accelerated light ions under conditions optimized for a desired isotope. Production yields are extremely small, and separation must occur quickly because of radioactive decay. The limiting factors are accelerator access, rare target materials, radiochemical expertise, and detector time rather than market demand, recycling, or substitution.
Made by bombarding curium with carbon-13
Nobelium is not expected to have a persistent cosmic abundance. Its known isotopes are too short-lived to survive from stellar nucleosynthesis to the present, and no stable isotope is known. If formed transiently in extreme neutron-rich events or by artificial nuclear reactions, nobelium would decay rapidly into lighter nuclei.
- Nobelium was named for Alfred Nobel, the inventor and industrial chemist associated with the Nobel Prizes.
- The isotope ²⁵⁹No is among the longest-lived known nobelium isotopes, with a half-life of about an hour.
- Nobelium helped show that the +2 state can become strongly stabilized late in the actinide series.
- Most nobelium experiments detect decay events from individual atoms rather than weighing a sample.
Imagens
Propriedades
Física
- Raio de van der Waals
- 246 pm Comparar Raio de van der Waals de todos os elementos →
- Densidade
- 9900 kg/m³ Comparar Densidade de todos os elementos →
- Fase nas CNTP
- Sólido Comparar Fase nas CNTP de todos os elementos →
- Ponto de fusão
- 826,85 °C Comparar Ponto de fusão de todos os elementos →
Química
- Eletronegatividade (Pauling)
- 1,3 Comparar Eletronegatividade (Pauling) de todos os elementos →
- Afinidade eletrônica
- -2,36 eV (valor negativo — prevê-se que o átomo não capte um eletrão adicional)
- Energia de ionização (1ª)
- 6,62621 eV Comparar Energia de ionização (1ª) de todos os elementos →
- Energia de ionização (2ª)
- 12,930045 eV Comparar Energia de ionização (2ª) de todos os elementos →
- Energia de ionização (3ª)
- 25,800089 eV Comparar Energia de ionização (3ª) de todos os elementos →
- Energia de ionização (4ª)
- 41,500143 eV Comparar Energia de ionização (4ª) de todos os elementos →
- Energia de ionização (5ª)
- 60,000207 eV Comparar Energia de ionização (5ª) de todos os elementos →
- Estados de oxidação
- +2, +3 Comparar Estados de oxidação de todos os elementos →
- Elétrons de valência
- 3 Comparar Elétrons de valência de todos os elementos →
- Configuração eletrônica
- [Rn] 7s2 5f14
Termodinâmica
- Calor de sublimação
- 4,042079 eV
- Calor de atomização
- 4,042079 eV
Nuclear
- Prótons
- 102 Comparar Prótons de todos os elementos →
- Nêutrons
- 159 Comparar Nêutrons de todos os elementos →
- Isótopos conhecidos
- 17 Comparar Isótopos conhecidos de todos os elementos →
- Isótopos estáveis
- 0 Comparar Isótopos estáveis de todos os elementos →
- Número de massa (mais estável)
- 259
- Isótopo mais estável
- No-261
- Ano da descoberta
- 1957
Abundância
N/D
Estrutura cristalina
N/D
Estrutura eletrônica
- Elétrons por camada
- 2, 8, 18, 32, 32, 8, 2 Comparar Elétrons por camada de todos os elementos →
Identificadores
- Número CAS
- 10028-14-5 Comparar Número CAS de todos os elementos →
- Símbolo de termo
- 1S0
- InChI
- InChI=1S/No
- Chave InChI
- ORQBXQOJMQIAOY-UHFFFAOYSA-N
Configuração eletrônica Medido
No: 5f¹⁴ 7s²[Rn] 5f¹⁴ 7s²1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d¹⁰ 6s² 6p⁶ 5f¹⁴ 7s²Modelo atômico
Os isótopos alteram o número de nêutrons, a massa e a estabilidade — não a configuração eletrônica de um átomo neutro.
Modelo atômico esquemático, sem escala.
Assinatura atômica
Espectro de emissão / absorção
Distribuição isotópica
Sem isótopos estáveis.
| Número de massa | Massa atômica (u) | Abundância natural | Meia-vida |
|---|---|---|---|
| 251 Radioativo | 251,08894 ± 0,00012 | N/D | 800 ms |
| 260 Radioativo | 260,10264 ± 0,00022 | N/D | 106 ms |
| 259 Radioativo | 259,10103 ± 0,00011 | N/D | 58 minutos |
| 249 Radioativo | 249,0878 ± 0,0003 | N/D | 57 us |
| 254 Radioativo | 254,090956 ± 0,000011 | N/D | 51.2 segundos |
Fase / Estado
Motivo: 801,9 °C abaixo do ponto de sublimação (826,85 °C)
Esquemático, sem escala
Pontos de transição de fase
Energias de transição
Energia necessária para sublimar 1 mol no ponto de sublimação
Densidade
Em condições padrão
Em condições padrão
Espectros atômicos
Mostrando 10 de 102. Ordenado por carga do íon (ordem crescente).
Dados de níveis disponíveis ?
| Íon | Carga | Níveis |
|---|---|---|
| No I | 0 | 2 |
| No II | +1 | 2 |
| No III | +2 | 2 |
| No IV | +3 | 2 |
| No V | +4 | 2 |
| No VI | +5 | 2 |
| No VII | +6 | 2 |
| No VIII | +7 | 2 |
| No IX | +8 | 2 |
| No X | +9 | 2 |
Dados de estrutura cristalina indisponíveis
Raios iônicos
| Carga | Coordenação | Spin | Raio |
|---|---|---|---|
| +2 | 6 | N/D | 110.00000000000001 pm |
| +3 | 9 | N/D | 108.5 pm |
Compostos
Isótopos (5)
Ten isotopes are now recognized, one of which 255102 has a half-life of 3 minutes.
| Número de massa | Massa atômica (u) | Abundância natural | Meia-vida | Modo de decaimento | |
|---|---|---|---|---|---|
| 251 Radioativo | 251,08894 ± 0,00012 | N/D | 800 ms | α =83±1.6%β+ ?SF<0.3% | |
| 260 Radioativo | 260,10264 ± 0,00022 | N/D | 106 ms | SF =100% | |
| 259 Radioativo | 259,10103 ± 0,00011 | N/D | 58 minutos | α =75±0.4%ε =25±0.4%SF<10% | |
| 249 Radioativo | 249,0878 ± 0,0003 | N/D | 57 us | β+ ?α ? | |
| 254 Radioativo | 254,090956 ± 0,000011 | N/D | 51.2 segundos | α =90±0.1%β+ =10±0.1%SF =0.17±0.2% |
Propriedades ampliadas
Raios covalentes (dados ampliados)
- Raio covalente (Pyykkö)
- 176 pm
Raios de van der Waals
- UFF
- 324,8 pm
Escalas de numeração
- Mendeleev
- 40
- Pettifor
- 35
- Glawe
- 46
Escalas de eletronegatividade
- Ghosh
- 0
Polarizabilidade e dispersão
- Polarizabilidade dipolar
- 110 a.u.
- Polarizabilidade dipolar (incerteza)
- 6 a.u.
Transições de fase e alótropos
| Ponto de fusão | 1100,15 K |
Categorias de estados de oxidação
Dados de referência avançados
Detalhes dos raios cristalinos (2)
| Carga | CN | Spin | rcrystal (pm) | Origem |
|---|---|---|---|---|
| 2 | VI | 124 | estimated, | |
| 3 | IX | — | 122,5 |
Modos de decaimento dos isótopos (39)
| Isótopo | Modo | Intensidade |
|---|---|---|
| 248 | SF | — |
| 249 | B+ | — |
| 249 | A | — |
| 250 | SF | 100% |
| 250 | A | — |
| 250 | B+ | — |
| 251 | A | 83% |
| 251 | B+ | — |
| 251 | SF | 0,3% |
| 252 | A | 67,6% |
Dados adicionais
Estimated Crustal Abundance
The estimated element abundance in the earth's crust.
Not Applicable
Referências (1)
- [5] Nobelium https://education.jlab.org/itselemental/ele102.html
Estimated Oceanic Abundance
The estimated element abundance in the earth's oceans.
Not Applicable
Referências (1)
- [5] Nobelium https://education.jlab.org/itselemental/ele102.html
Referências
(9)
Data deposited in or computed by PubChem
The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.
Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.
The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.
Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/
The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.
The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database
This section provides all form of data related to element Nobelium.
The element property data was retrieved from publications.
