Cesium (Cs)
alkali-metalSolid
प्रमाणित अणुभार
132.905452 uइलेक्ट्रॉन संरूपण
[Xe] 6s1द्रवणांक
28.44 °Cउत्कलनांक
670.85 °Cघनता
1930 kg/m³ऑक्सिडीकरण अवस्था
−1, +1विद्युतऋणता (पॉलिंग)
0.79आयनीकरण ऊर्जा (पहिली)
3.893906 eVशोधाचे वर्ष
1860अणुत्रिज्या
260 pmतपशील
Cesium is a soft alkali metal with very low ionization energy and an unusually low melting point for a metal. It occurs naturally as the single stable isotope ¹³³Cs, chiefly in rare granitic pegmatite minerals. Chemically it is the heaviest stable group 1 element and forms almost exclusively Cs⁺ salts. Its best-known technological role is in the definition of the second, based on the microwave transition of the ¹³³Cs atom.
The metal is characterized by a spectrum containing two bright lines in the blue along with several others in the red, yellow, and green wavelengths. It is silvery white, soft, and ductile. It is the most electropositive and most alkaline element.
Cesium, gallium, and mercury are the only three metals that are liquid at room temperature. Cesium reacts explosively with cold water, and reacts with ice at temperatures above -116C. Cesium hydroxide, the strongest base known, attacks glass.
The name derives from the Latin caesius for "sky blue", which was the colour of the caesium line in the spectroscope. Caesium was discovered by the German chemist Robert Wilhelm Bunsen and the German physicist Gustav Robert Kirchhoff in 1860. It was first isolated by the German chemist Carl Setterberg in 1882.
Cesium was discovered by Robert Wilhelm Bunsen and Gustav Robert Kirchhoff, German chemists, in 1860 through the spectroscopic analysis of Durkheim mineral water. They named cesium after the blue lines they observed in its spectrum. Today, cesium is primarily obtained from the mineral pollucite (CsAlSi2O6). Obtaining pure cesium is difficult since cesium ores are frequently contaminated with rubidium, an element that is chemically similar to cesium. To obtain pure cesium, cesium and rubidium ores are crushed and heated with sodium metal to 650°C, forming an alloy that can then be separated with a process known as fractional distillation. Metallic cesium is too reactive to easily handle and is usually sold in the form of cesium azide (CsN3). Cesium is recovered from cesium azide by heating it.
From the Latin word caesius, sky blue. Cesium was discovered spectroscopically in 1860 by Bunsen and Kirchhoff in mineral water from Durkheim.
Pure cesium is a pale gold, silvery metal that is solid near ordinary room temperature but melts at about 28.5 °C. It is extremely soft and must be kept under dry inert gas, vacuum, or mineral oil because fresh surfaces tarnish and react rapidly with air or moisture.
Cesium vapor is used in atomic clocks and frequency standards, where ¹³³Cs provides a reproducible microwave reference. Cesium compounds are used in specialty photoemissive and scintillation materials, in some radiation detectors, and in high-density cesium formate brines for demanding oil and gas drilling operations. Radioactive ¹³⁷Cs has been used in industrial gauges, calibration sources, and radiotherapy, although many applications now use alternatives where security or disposal is difficult.
Cesium has the second lowest melting point of all metallic elements, which limits its uses. Cesium readily combines with oxygen and is used as a getter, a material that combines with and removes trace gases from vacuum tubes. Cesium is also used in atomic clocks, in photoelectric cells and as a catalyst in the hydrogenation of certain organic compounds. Since it is easily ionized and has a high mass, cesium ions may one day be used as a propellant in ion engines on spacecraft.
Cesium reacts violently with water and ice, forming cesium hydroxide (CsOH). Cesium hydroxide is the strongest base known and will attack glass. Cesium chloride (CsCl) and cesium nitrate (CsNO3) are cesium's most common compounds and are primarily used in the production of other chemicals.
Because of it has great affinity for oxygen, the metal is used as a "getter" in electron tubes. It is also used in photoelectric cells, as well as a catalyst in the hydrogenation of certain organic compounds.
The metal has recently found application in ion propulsion systems. Cesium is used in atomic clocks, which are accurate to 5 s in 300 years. Its chief compounds are the chloride and the nitrate.
Isotopes in Biology
137Cs (with a half-life of 30 years) can be used as a tracer in fungal mycelia (an extensive matrix of underground hyphae (stems of growth from a fungus)) to monitor the immobilization of this radioactive caesium isotope. After the nuclear reactor accident at Chernobyl, large quantities of 137Cs were released as fission products into the environment. Areas with large fungal populations and fungal mycelia seemed to immobilize the 137Cs isotope, which limited the spread of the radioactive isotope [399] S. N. Gray, J. Dighton, S. Olsson, D. H. Jennings. New Phytol.129, 449 (1995)., [400] J. Dighton, G. M. Clint, J. Poskitt. Mycol. Res.95, 1052 (1991)..
Isotopes in Earth/Planetary Science
River floodplains are an important site for storing suspended sediments and contaminants transferred from upstream catchments. 137Cs measurements of floodplain sediments provide a technique for estimating overbank sediment deposition, and it can provide information on spatial patterns of sediment deposition (Fig. IUPAC.55.1) [401] R. H. Gardner, W. W. Hargrove, D. A. Levine, S. M. Pearson, K. A. Rose. Spatial Analysis of Cesium in Sediments of Watts Bar Reservoir, Oak Ridge National Laboratory (2014), Feb. 27; http://research.esd.ornl.gov/CRERP/WATTSBAR/INDEX.HTM., [402] C. R. Olsen, I. L. Larson, P. D. Lowry, C. R. Moriones, C. J. Ford, K. C. Dearstone, R. R. Turner, B. L. Kimmel, C. C. Brandt. Transport and Accumulation of Cesium-137 and Mercury in the Clinch River and Watts Bar Reservoir system, ORNL/ER-7, Oak Ridge National Laboratory, Oak Ridge, TN (1992)., [403] D. E. Walling, Q. He. Catena29, 263 (1997)..
Isotopes in Geochronology
Nuclear fission of 235U (or other fissionable materials) yields 137Cs as a product. Although 137Cs is not naturally present in the environment, it can be collected from nuclear reactor processing and then used as an environmental tracer. 137Cs adheres tightly to porous sediments and will follow the movement of the sediment. By exposing sediments to 137Cs and allowing this combination to move dynamically, gamma ray spectrometry can then be used to measure the activity of 137Cs and monitor the movement of the radioactive sediments [404] W. G. Winn. J. Radioanal. Nucl. Chem.195, 345 (1995)., [405] A. V. Chesnokov, A. P. Govorun, F. V. N., O. P. Ivanov, V. I. Liksonov, V. N. Potapov, S. B. Shcherbak, S. V. Smirnov, L. I. Urutskoev. Nucl. Instrm. Methods Phys. Res. Section A: Accelerators, Spectrometers, Detectors and Associated Equipment.420, 336 (1999)., [406] A. Albrecht, R. Reiser, A. Lück, J. M. A. Stoll, W. Giger. Environ. Sci. Technol.32, 1882 (1998)..
137Cs dating of sediments not older than 60 years is useful in natural and artificial lakes and other environments because of its widespread production and release during atmospheric nuclear weapons testing, which began in the late 1940s, plus subsequent releases, such as during the accident at the Chernobyl nuclear reactor in April 1986. The 137Cs concentration profile in a sediment core can be matched with the historical record of 137Cs release to determine the approximate age profile of the sediment [406] A. Albrecht, R. Reiser, A. Lück, J. M. A. Stoll, W. Giger. Environ. Sci. Technol.32, 1882 (1998)., [407] M. S. Humphries, A. Kindness, W. N. Ellery, J. C. Hughes, C. R. Benitez-Nelson. Geomorphology119, 88 (2010)..
Isotopes in Industry
High-energy gamma rays from 137Cs serve as food irradiation devices to remove bacteria and other harmful microorganisms (living single celled organisms such as virus, algae and fungus) from food. Although 137Cs is not used commercially for large-scale food irradiation, it has been proposed that it can be used this way. Gamma rays from the radioactive 137Cs destroy the DNA of organisms to enable foods to last longer (i.e. irradiation of fruits and vegetables stops the ripening process) and be contamination free [408] D. W. Hayer. J. Food Quality13, 147 (1990)., [409] United States General Accounting Office. Food Irradiation: Available Research Indicates that Benefits Outweigh the Risks, GAO/RCED-00-217, GAO (2000)..
Cesium chemistry is dominated by the +1 oxidation state and by large, highly soluble salts. Cesium chloride (CsCl), cesium nitrate (CsNO₃), cesium carbonate (Cs₂CO₃), and cesium sulfate (Cs₂SO₄) are common laboratory compounds. Cesium hydroxide (CsOH) is a very strong base, and cesium fluoride (CsF) is valued as a fluoride source in some syntheses. The element forms oxides and superoxides, including cesium superoxide (CsO₂), when exposed to oxygen under suitable conditions.
See more information at the Cesium compound page.
Metallic cesium is highly reactive and can ignite or explode on contact with water, forming cesium hydroxide (CsOH) and hydrogen (H₂). Soluble cesium salts can be taken up by the body in ways broadly similar to potassium, so toxic or radioactive isotopes require strict control. ¹³⁷Cs is a significant gamma-emitting contamination hazard because it is mobile in many environments and has a half-life of about 30 years.
Natural cesium is a trace constituent of crustal rocks and is enriched in some pegmatites. In soils and sediments, Cs⁺ can be strongly fixed by clay minerals, especially at selective exchange sites, but mobility increases in low-clay or organic-rich settings. Fallout-derived ¹³⁷Cs is useful as an environmental tracer, while accidental releases can contaminate food chains through uptake by plants and animals.
Cesium is produced in small quantities compared with major industrial metals. The principal ore mineral is pollucite, a hydrated cesium aluminosilicate found in rare pegmatite deposits. Processing commonly converts ore to soluble cesium salts, from which metal or specialty compounds can be prepared. Demand is concentrated in specialized uses, so supply is shaped more by a few deposits, inventory management, and technical purity than by broad commodity trading. Recycling is limited, except for controlled recovery of sealed radioactive sources and some specialty materials.
Cesium, an alkali metal, occurs in lepidolite, pollucte (a hydrated silicate of aluminum and cesium), and in other sources. One of the world's richest sources of cesium is located at Bernic Lake, Manitoba. The deposits are estimated to contain 300,000 tons of pollucite, averaging 20% cesium.
It can be isolated by elecytrolysis of the fused cyanide and by a number of other methods. Very pure, gas-free cesium can be prepared by thermal decomposition of cesium azide.
Cesium is a rare element in cosmic terms. Its stable isotope ¹³³Cs is produced mainly by slow neutron-capture processes in evolved stars, with contributions from other neutron-rich nucleosynthesis pathways. In planetary materials it behaves as an incompatible, lithophile alkali element, tending to concentrate in late-stage melts rather than in common rock-forming minerals.
- Cesium is one of the few metals that can melt in a warm hand, though handling it that way would be dangerous.
- The official SI second is defined using a hyperfine transition of neutral ¹³³Cs.
- Pollucite is important because cesium has few concentrated ore minerals.
- Cesium salts often make dense solutions because the Cs⁺ ion is very heavy.
- The name comes from the blue spectral lines observed when the element was discovered.
प्रतिमा
गुणधर्म
भौतिक
- अणुत्रिज्या (अनुभवाधारित)
- 260 pm सर्व घटकांच्या अणुत्रिज्या (अनुभवाधारित) ची तुलना करा →
- सहसंयुजी त्रिज्या
- 244 pm सर्व घटकांच्या सहसंयुजी त्रिज्या ची तुलना करा →
- व्हॅन डर वाल्स त्रिज्या
- 343 pm सर्व घटकांच्या व्हॅन डर वाल्स त्रिज्या ची तुलना करा →
- धात्विक त्रिज्या
- 235 pm सर्व घटकांच्या धात्विक त्रिज्या ची तुलना करा →
- घनता
- 1930 kg/m³ सर्व घटकांच्या घनता ची तुलना करा →
- मोलर आयतन
- 0.07 L/mol
- STP येथे अवस्था
- घन सर्व घटकांच्या STP येथे अवस्था ची तुलना करा →
- द्रवणांक
- 28.44 °C सर्व घटकांच्या द्रवणांक ची तुलना करा →
- उत्कलनांक
- 670.85 °C सर्व घटकांच्या उत्कलनांक ची तुलना करा →
- उष्णता चालकता
- 35.9 W/(m·K) सर्व घटकांच्या उष्णता चालकता ची तुलना करा →
- विशिष्ट उष्माधारकता
- 0.242 J/(g·K) सर्व घटकांच्या विशिष्ट उष्माधारकता ची तुलना करा →
- मोलर उष्माधारकता
- 32.21 J/(mol·K) सर्व घटकांच्या मोलर उष्माधारकता ची तुलना करा →
- स्फटिक संरचना
- पिंडकेंद्रित घनीय सर्व घटकांच्या स्फटिक संरचना ची तुलना करा →
रासायनिक
- विद्युतऋणता (पॉलिंग)
- 0.79 सर्व घटकांच्या विद्युतऋणता (पॉलिंग) ची तुलना करा →
- विद्युतऋणता (ॲलन)
- 0.659
- इलेक्ट्रॉन आसक्ती
- 0.4716 eV
- आयनीकरण ऊर्जा (पहिली)
- 3.893906 eV सर्व घटकांच्या आयनीकरण ऊर्जा (पहिली) ची तुलना करा →
- आयनीकरण ऊर्जा (दुसरी)
- 23.15753 eV सर्व घटकांच्या आयनीकरण ऊर्जा (दुसरी) ची तुलना करा →
- आयनीकरण ऊर्जा (तिसरी)
- 33.195114 eV सर्व घटकांच्या आयनीकरण ऊर्जा (तिसरी) ची तुलना करा →
- आयनीकरण ऊर्जा (चौथी)
- 43.000148 eV सर्व घटकांच्या आयनीकरण ऊर्जा (चौथी) ची तुलना करा →
- आयनीकरण ऊर्जा (पाचवी)
- 56.000193 eV सर्व घटकांच्या आयनीकरण ऊर्जा (पाचवी) ची तुलना करा →
- ऑक्सिडीकरण अवस्था
- −1, +1 सर्व घटकांच्या ऑक्सिडीकरण अवस्था ची तुलना करा →
- संयुजा इलेक्ट्रॉन
- 1 सर्व घटकांच्या संयुजा इलेक्ट्रॉन ची तुलना करा →
- इलेक्ट्रॉन संरूपण
- [Xe] 6s1
उष्मागतिक
- क्रांतिक बिंदू (तापमान)
- 1665 °C
- क्रांतिक बिंदू (दाब)
- 9.4e+6 Pa
- द्रवण उष्मा
- 0.0216614 eV सर्व घटकांच्या द्रवण उष्मा ची तुलना करा →
- बाष्पीभवन उष्मा
- 0.67367985 eV सर्व घटकांच्या बाष्पीभवन उष्मा ची तुलना करा →
- संप्लवन उष्मा
- 0.79286936 eV
- अणूकरण उष्मा
- 0.79286936 eV
- अणूकरण एन्थाल्पी
- 0.79286936 eV
केंद्रकीय
- प्रोटॉन
- 55 सर्व घटकांच्या प्रोटॉन ची तुलना करा →
- न्यूट्रॉन
- 78 सर्व घटकांच्या न्यूट्रॉन ची तुलना करा →
- ज्ञात समस्थानिके
- 42 सर्व घटकांच्या ज्ञात समस्थानिके ची तुलना करा →
- स्थिर समस्थानिके
- 1 सर्व घटकांच्या स्थिर समस्थानिके ची तुलना करा →
- सर्वाधिक स्थिर समस्थानिक
- Cs-133
- शोधाचे वर्ष
- 1860
विपुलता
- विपुलता (पृथ्वीचे कवच)
- 3 mg/kg सर्व घटकांच्या विपुलता (पृथ्वीचे कवच) ची तुलना करा →
- विपुलता (महासागर)
- 3 × 10−4 mg/L सर्व घटकांच्या विपुलता (महासागर) ची तुलना करा →
स्फटिक संरचना
- जालक स्थिरांक a
- 605 pm
इलेक्ट्रॉन संरचना
- प्रत्येक कवचातील इलेक्ट्रॉन
- 2, 8, 18, 18, 8, 1 सर्व घटकांच्या प्रत्येक कवचातील इलेक्ट्रॉन ची तुलना करा →
ओळखचिन्हे
- CAS क्रमांक
- 7440-46-2 सर्व घटकांच्या CAS क्रमांक ची तुलना करा →
- टर्म चिन्ह
- 2S1/2
- InChI
- InChI=1S/Cs
- InChI की
- TVFDJXOCXUVLDH-UHFFFAOYSA-N
इलेक्ट्रॉन संरूपण मोजलेले
Cs: 6s¹[Xe] 6s¹1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 6s¹अणुप्रतिमान
समस्थानिकांमुळे न्यूट्रॉन संख्या, वस्तुमान आणि स्थैर्य बदलते — विद्युतदृष्ट्या उदासीन अणूचे इलेक्ट्रॉन संरूपण बदलत नाही.
योजनात्मक अणुप्रतिमान, प्रमाणानुसार नाही.
अणूची विशिष्ट ओळख
उत्सर्जन / शोषण वर्णपट
समस्थानिक वितरण
| वस्तुमानांक | अणुवस्तुमान (u) | नैसर्गिक विपुलता | अर्धायुष्य |
|---|---|---|---|
| 133 स्थिर | १३२.९०५४५१९६१ ± ०.००००००००८ | 100.0000% | स्थिर |
अवस्था / स्थिती
कारण: द्रवणांकापेक्षा (28.44 °C) 3.4 °C कमी
योजनात्मक, प्रमाणानुसार नाही
अवस्थांतर बिंदू
अवस्थांतर ऊर्जा
द्रवणांकावर 1 mol वितळवण्यासाठी आवश्यक ऊर्जा
उत्कलनांकावर 1 mol चे बाष्पीभवन करण्यासाठी आवश्यक ऊर्जा
संप्लवनांकावर 1 mol चे संप्लवन करण्यासाठी आवश्यक ऊर्जा
घनता
प्रमाणित परिस्थितीत
प्रमाणित परिस्थितीत
प्रगत
अणुवर्णपट
55 पैकी 10 दाखवले आहेत. आयनाच्या विद्युतभारानुसार चढत्या क्रमाने मांडलेले.
वर्णरेषांचा संग्रह ?
| आयन | विद्युतभार | एकूण वर्णरेषा | संक्रमण संभाव्यता | पातळ्यांची नामांकने |
|---|---|---|---|---|
| Cs I | 0 | 230 | 42 | 228 |
| Cs II | +1 | 1757 | 2 | 1737 |
| Cs III | +2 | 1010 | 1010 | 1010 |
| Cs IV | +3 | 207 | 0 | 207 |
| Cs V | +4 | 143 | 0 | 143 |
| Cs VI | +5 | 67 | 0 | 67 |
| Cs VII | +6 | 185 | 0 | 185 |
| Cs VIII | +7 | 111 | 13 | 111 |
| Cs IX | +8 | 50 | 16 | 50 |
| Cs X | +9 | 86 | 86 | 86 |
ऊर्जा पातळ्यांचा संग्रह ?
| आयन | विद्युतभार | पातळ्या |
|---|---|---|
| Cs I | 0 | 179 |
| Cs II | +1 | 316 |
| Cs III | +2 | 174 |
| Cs IV | +3 | 116 |
| Cs V | +4 | 50 |
| Cs VI | +5 | 32 |
| Cs VII | +6 | 79 |
| Cs VIII | +7 | 55 |
| Cs IX | +8 | 69 |
| Cs X | +9 | 79 |
आयनिक त्रिज्या
| विद्युतभार | समन्वय | प्रचक्रण | त्रिज्या |
|---|---|---|---|
| +1 | 6 | उपलब्ध नाही | 167 pm |
| +1 | 8 | उपलब्ध नाही | 174 pm |
| +1 | 9 | उपलब्ध नाही | 178 pm |
| +1 | 10 | उपलब्ध नाही | 181 pm |
| +1 | 11 | उपलब्ध नाही | 185 pm |
| +1 | 12 | उपलब्ध नाही | 188 pm |
संयुगे
समस्थानिके (1)
Cesium has more isotopes than any element32with masses ranging from 114 to 145.
| वस्तुमानांक | अणुवस्तुमान (u) | नैसर्गिक विपुलता | अर्धायुष्य | क्षय प्रकार | |
|---|---|---|---|---|---|
| 133 स्थिर | १३२.९०५४५१९६१ ± ०.००००००००८ | 100.0000% | स्थिर | stable |
वर्णरेषा
728 पैकी 50 दाखवले आहेत. मूलभूत सेटिंगनुसार केवळ मोजलेली तीव्रता असलेल्या वर्णरेषा दाखवल्या जातात.
| तरंगलांबी (nm) | तीव्रता | आयनीकरण टप्पा | प्रकार | संक्रमण | अचूकता | स्रोत | |
|---|---|---|---|---|---|---|---|
| 460.37908 nm | 10000000 | Cs II | emission | 5p5.(2P*<3/2>).6s 2[3/2]* → 5p5.(2P*<3/2>).6p 2[5/2] | मोजलेले | NIST | |
| 522.70372 nm | 7500000 | Cs II | emission | 5p5.(2P*<3/2>).6s 2[3/2]* → 5p5.(2P*<3/2>).6p 2[1/2] | मोजलेले | NIST | |
| 592.56312 nm | 5100000 | Cs II | emission | 5p5.(2P*<3/2>).5d 2[7/2]* → 5p5.(2P*<3/2>).6p 2[5/2] | मोजलेले | NIST | |
| 556.3024 nm | 3900000 | Cs II | emission | 5p5.(2P*<3/2>).5d 2[3/2]* → 5p5.(2P*<3/2>).6p 2[3/2] | मोजलेले | NIST | |
| 495.28523 nm | 3700000 | Cs II | emission | 5p5.(2P*<3/2>).5d 2[1/2]* → 5p5.(2P*<3/2>).6p 2[5/2] | मोजलेले | NIST | |
| 695.54998 nm | 3700000 | Cs II | emission | 5p5.(2P*<3/2>).5d 2[7/2]* → 5p5.(2P*<3/2>).6p 2[5/2] | मोजलेले | NIST | |
| 524.93849 nm | 2900000 | Cs II | emission | 5p5.(2P*<3/2>).6s 2[3/2]* → 5p5.(2P*<3/2>).6p 2[3/2] | मोजलेले | NIST | |
| 504.38026 nm | 2700000 | Cs II | emission | 5p5.(2P*<3/2>).6s 2[3/2]* → 5p5.(2P*<3/2>).6p 2[3/2] | मोजलेले | NIST | |
| 483.01864 nm | 2500000 | Cs II | emission | 5p5.(2P*<3/2>).6s 2[3/2]* → 5p5.(2P*<3/2>).6p 2[5/2] | मोजलेले | NIST | |
| 583.11404 nm | 2400000 | Cs II | emission | 5p5.(2P*<3/2>).6s 2[3/2]* → 5p5.(2P*<3/2>).6p 2[5/2] | मोजलेले | NIST | |
| 537.09876 nm | 2200000 | Cs II | emission | 5p5.(2P*<3/2>).5d 2[1/2]* → 5p5.(2P*<3/2>).6p 2[1/2] | मोजलेले | NIST | |
| 452.67416 nm | 2000000 | Cs II | emission | 5p5.(2P*<3/2>).5d 2[1/2]* → 5p5.(2P*<3/2>).6p 2[3/2] | मोजलेले | NIST | |
| 487.00392 nm | 1900000 | Cs II | emission | 5p5.(2P*<1/2>).6s 2[1/2]* → 5p5.(2P*<1/2>).6p 2[3/2] | मोजलेले | NIST | |
| 427.71303 nm | 1800000 | Cs II | emission | 5p5.(2P*<3/2>).6s 2[3/2]* → 5p5.(2P*<3/2>).6p 2[3/2] | मोजलेले | NIST | |
| 697.96684 nm | 1600000 | Cs II | emission | 5p5.(2P*<3/2>).5d 2[5/2]* → 5p5.(2P*<3/2>).6p 2[3/2] | मोजलेले | NIST | |
| 426.470255 nm | 1400000 | Cs II | emission | 5p5.(2P*<3/2>).6p 2[5/2] → 5p5.(2P*<3/2>).6d 2[7/2]* | मोजलेले | NIST | |
| 721.9603 nm | 1400000 | Cs III | emission | 5s2.5p5 2P* → 5s2.5p5 2P* | मोजलेले | NIST | |
| 714.95415 nm | 1300000 | Cs II | emission | 5p5.(2P*<1/2>).5d 2[5/2]* → 5p5.(2P*<1/2>).6p 2[3/2] | मोजलेले | NIST | |
| 450.15517 nm | 1200000 | Cs II | emission | 5p5.(2P*<3/2>).6s 2[3/2]* → 5p5.(2P*<3/2>).6p 2[1/2] | मोजलेले | NIST | |
| 527.40539 nm | 1100000 | Cs II | emission | 5p5.(2P*<3/2>).5d 2[1/2]* → 5p5.(2P*<3/2>).6p 2[1/2] | मोजलेले | NIST | |
| 534.91319 nm | 1000000 | Cs II | emission | 5p5.(2P*<1/2>).6s 2[1/2]* → 5p5.(2P*<1/2>).6p 2[3/2] | मोजलेले | NIST | |
| 653.6445 nm | 1000000 | Cs II | emission | 5p5.(2P*<3/2>).5d 2[3/2]* → 5p5.(2P*<3/2>).6p 2[5/2] | मोजलेले | NIST | |
| 612.86072 nm | 980000 | Cs II | emission | 5p5.(2P*<3/2>).5d 2[3/2]* → 5p5.(2P*<3/2>).6p 2[5/2] | मोजलेले | NIST | |
| 672.44659 nm | 960000 | Cs II | emission | 5p5.(2P*<1/2>).5d 2[5/2]* → 5p5.(2P*<1/2>).6p 2[3/2] | मोजलेले | NIST | |
| 664.65663 nm | 880000 | Cs II | emission | 5p5.(2P*<1/2>).5d 2[3/2]* → 5p5.(2P*<1/2>).6p 2[1/2] | मोजलेले | NIST | |
| 400.65447 nm | 860000 | Cs III | emission | 5s2.5p4.(3P<2>).6s 2[2] → 5s2.5p4.(3P<2>).6p 2[3]* | मोजलेले | NIST | |
| 649.55329 nm | 830000 | Cs II | emission | 5p5.(2P*<3/2>).5d 2[7/2]* → 5p5.(2P*<3/2>).6p 2[5/2] | मोजलेले | NIST | |
| 497.25963 nm | 820000 | Cs II | emission | 5p5.(2P*<3/2>).6p 2[5/2] → 5p5.(2P*<3/2>).7s 2[3/2]* | मोजलेले | NIST | |
| 403.985602 nm | 800000 | Cs II | emission | 5p5.(2P*<3/2>).6p 2[5/2] → 5p5.(2P*<3/2>).6d 2[7/2]* | मोजलेले | NIST | |
| 436.329875 nm | 760000 | Cs II | emission | 5p5.(2P*<3/2>).6p 2[3/2] → 5p5.(2P*<3/2>).6d 2[5/2]* | मोजलेले | NIST | |
| 388.83763 nm | 740000 | Cs III | emission | 5s2.5p4.(3P<1>).5d 2[3] → 5s2.5p4.(3P<2>).6p 2[3]* | मोजलेले | NIST | |
| 441.02226 nm | 720000 | Cs III | emission | 5s2.5p4.(3P<2>).5d 2[3] → 5s2.5p4.(3P<2>).6p 2[2]* | मोजलेले | NIST | |
| 450.67197 nm | 720000 | Cs III | emission | 5s2.5p4.(3P<2>).5d 2[3] → 5s2.5p4.(3P<2>).6p 2[2]* | मोजलेले | NIST | |
| 476.36362 nm | 700000 | Cs II | emission | 5p5.(2P*<1/2>).6s 2[1/2]* → 5p5.(2P*<1/2>).6p 2[1/2] | मोजलेले | NIST | |
| 520.95813 nm | 650000 | Cs II | emission | 5p5.(2P*<1/2>).6s 2[1/2]* → 5p5.(2P*<1/2>).6p 2[3/2] | मोजलेले | NIST | |
| 392.55957 nm | 620000 | Cs III | emission | 5s2.5p4.(3P<2>).5d 2[3] → 5s2.5p4.(3P<2>).6p 2[3]* | मोजलेले | NIST | |
| 442.56759 nm | 560000 | Cs III | emission | 5s2.5p4.(3P<2>).6s 2[2] → 5s2.5p4.(3P<2>).6p 2[2]* | मोजलेले | NIST | |
| 428.837507 nm | 510000 | Cs II | emission | 5p5.(2P*<3/2>).6p 2[3/2] → 5p5.(2P*<3/2>).6d 2[5/2]* | मोजलेले | NIST | |
| 488.00516 nm | 490000 | Cs II | emission | 5p5.(2P*<1/2>).6s 2[1/2]* → 5p5.(2P*<1/2>).6p 2[1/2] | मोजलेले | NIST | |
| 581.41641 nm | 450000 | Cs II | emission | 5p5.(2P*<3/2>).5d 2[3/2]* → 5p5.(2P*<3/2>).6p 2[3/2] | मोजलेले | NIST | |
| 395.95055 nm | 420000 | Cs II | emission | 5p5.(2P*<3/2>).5d 2[1/2]* → 5p5.(2P*<3/2>).6p 2[1/2] | मोजलेले | NIST | |
| 461.61693 nm | 420000 | Cs II | emission | 5p5.(2P*<1/2>).6s 2[1/2]* → 5p5.(2P*<1/2>).6p 2[1/2] | मोजलेले | NIST | |
| 453.896566 nm | 410000 | Cs II | emission | 5p5.(2P*<3/2>).6p 2[3/2] → 5p5.(2P*<3/2>).6d 2[3/2]* | मोजलेले | NIST | |
| 440.525568 nm | 390000 | Cs II | emission | 5p5.(2P*<3/2>).6p 2[1/2] → 5p5.(2P*<3/2>).7s 2[3/2]* | मोजलेले | NIST | |
| 437.30356 nm | 370000 | Cs II | emission | 5p5.(2P*<3/2>).5d 2[1/2]* → 5p5.(2P*<3/2>).6p 2[3/2] | मोजलेले | NIST | |
| 452.28578 nm | 350000 | Cs III | emission | 5s2.5p4.(3P<2>).6s 2[2] → 5s2.5p4.(3P<2>).6p 2[2]* | मोजलेले | NIST | |
| 389.698641 nm | 340000 | Cs II | emission | 5p5.(2P*<3/2>).6p 2[1/2] → 5p5.(2P*<3/2>).6d 2[1/2]* | मोजलेले | NIST | |
| 404.34262 nm | 310000 | Cs III | emission | 5s2.5p4.(1D<2>).6s 2[2] → 5s2.5p4.(1D<2>).6p 2[3]* | मोजलेले | NIST | |
| 645.6318 nm | 310000 | Cs III | emission | 5s2.5p4.(3P<2>).7p 2[3]* → 5s2.5p4.(3P<2>).7d 2[4] | मोजलेले | NIST | |
| 607.9854 nm | 300000 | Cs III | emission | 5s2.5p4.(3P<2>).5f 2[2]* → 5s2.5p4.(3P<2>).5g 2[3] | मोजलेले | NIST |
विस्तारित गुणधर्म
सहसंयुजी त्रिज्या (विस्तारित)
- सहसंयुजी त्रिज्या (प्युक्को)
- 232 pm
- सहसंयुजी त्रिज्या (प्युक्को, दुहेरी बंध)
- 209 pm
- सहसंयुजी त्रिज्या (ब्रॅग)
- 237 pm
व्हॅन डर वाल्स त्रिज्या
- Truhlar
- 343 pm
- Batsanov
- 300 pm
- Alvarez
- 348 pm
- UFF
- 451.7 pm
- MM3
- 344 pm
अणुत्रिज्या आणि धात्विक त्रिज्या
- अणुत्रिज्या (राह्म)
- 249 pm
- धात्विक त्रिज्या (C12)
- 267 pm
क्रमांकन मापनपट्ट्या
- Mendeleev
- 5
- Pettifor
- 8
- Glawe
- 8
विद्युतऋणता मापनपट्ट्या
- Ghosh
- 0
- Miedema
- 2
- Gunnarsson–Lundqvist
- 2
- Robles–Bartolotti
- 1
ध्रुवणक्षमता आणि अपस्करण
- द्विध्रुव ध्रुवणक्षमता
- 400.9 a.u.
- द्विध्रुव ध्रुवणक्षमता (अनिश्चितता)
- 0.7 a.u.
- C₆ (Gould–Bučko)
- 6660 Ha·Bohr6
मिडेमा प्राचल
- मिडेमा मोलर आयतन
- 69.23 cm3/mol
- मिडेमा इलेक्ट्रॉन घनता
- 0
अवस्थांतरे आणि अपरूपे
| द्रवणांक | 301.65 K |
| उत्कलनांक | 944.15 K |
| क्रांतिक बिंदू (तापमान) | 1938.15 K |
| क्रांतिक बिंदू (दाब) | 9.4 MPa |
ऑक्सिडीकरण अवस्थांचे वर्ग
प्रगत संदर्भ माहिती
परिरक्षण स्थिरांक (12)
| n | कक्षिका | σ |
|---|---|---|
| 1 | s | 1.0957 |
| 2 | p | 4.1804 |
| 2 | s | 14.4884 |
| 3 | d | 14.0194 |
| 3 | p | 18.4222 |
| 3 | s | 18.6226 |
| 4 | d | 32.1616 |
| 4 | p | 29.1424 |
| 4 | s | 27.9576 |
| 5 | p | 41.349 |
स्फटिक त्रिज्यांचा तपशील (6)
| विद्युतभार | CN | प्रचक्रण | rcrystal (pm) | उत्पत्ती |
|---|---|---|---|---|
| 1 | VI | 181 | ||
| 1 | VIII | 188 | ||
| 1 | IX | 192 | ||
| 1 | X | 195 | ||
| 1 | XI | 199 | ||
| 1 | XII | 202 |
समस्थानिक क्षय प्रकार (74)
| समस्थानिक | मोड | तीव्रता |
|---|---|---|
| 111 | p | — |
| 112 | p | 100% |
| 112 | A | 0.3% |
| 113 | p | 100% |
| 114 | B+ | 100% |
| 114 | A | 0% |
| 114 | B+p | 8.7% |
| 114 | B+A | 0.2% |
| 115 | B+ | 100% |
| 115 | B+p | 0.1% |
क्ष-किरण प्रकीर्णन गुणक (508)
| ऊर्जा (eV) | f₁ | f₂ |
|---|---|---|
| 10 | — | 0.04294 |
| 10.1617 | — | 0.04199 |
| 10.3261 | — | 0.04106 |
| 10.4931 | — | 0.04015 |
| 10.6628 | — | 0.03925 |
| 10.8353 | — | 0.03838 |
| 11.0106 | — | 0.04186 |
| 11.1886 | — | 0.04987 |
| 11.3696 | — | 0.06291 |
| 11.5535 | — | 0.06823 |
अतिरिक्त माहिती
Estimated Crustal Abundance
The estimated element abundance in the earth's crust.
3 milligrams per kilogram
संदर्भ (1)
Estimated Oceanic Abundance
The estimated element abundance in the earth's oceans.
3×10-4 milligrams per liter
संदर्भ (1)
Sources
Sources of this element.
Cesium, an alkali metal, occurs in lepidolite, pollucte (a hydrated silicate of aluminum and cesium), and in other sources. One of the world's richest sources of cesium is located at Bernic Lake, Manitoba. The deposits are estimated to contain 300,000 tons of pollucite, averaging 20% cesium.
It can be isolated by elecytrolysis of the fused cyanide and by a number of other methods. Very pure, gas-free cesium can be prepared by thermal decomposition of cesium azide.
संदर्भ (1)
- [6] Cesium https://periodic.lanl.gov/55.shtml
संदर्भ
(9)
Data deposited in or computed by PubChem
The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.
Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.
The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.
Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/
The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.
The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database
This section provides all form of data related to element Cesium.
The element property data was retrieved from publications.