Titanium (Ti)
transition-metalSolid
표준 원자량
47.867 u전자 배치
[Ar] 4s2 3d2녹는점
1667.85 °C끓는점
3286.85 °C밀도
4500 kg/m³산화 상태
−2, −1, 0, +1, +2, +3, +4전기 음성도(Pauling)
1.54제1 이온화 에너지
6.82812 eV발견 연도
1791원자 반지름
140 pm상세 정보
Titanium is a light, strong transition metal with a high melting point and exceptional resistance to corrosion in many natural and industrial environments. Its chemistry is dominated by the +4 oxidation state, although +3 and lower states occur in specialized compounds. The metal is abundant in Earth’s crust but is rarely found in concentrated metallic form because it bonds strongly to oxygen and nitrogen. Its combination of low density, strength, and passivation makes it important in aerospace, chemical equipment, pigments, and medical materials.
Titanium, when pure, is a lustrous, white metal. It has a low density, good strength, is easily fabricated, and has excellent corrosion resistance. It is ductile only when it is free of oxygen. The metal, which burns in air, is the only element that burns in nitrogen.
Titanium is resistant to dilute sulfuric and hydrochloric acid, most organic acids, most chlorine gas, and chloride solutions.
Natural titanium is reported to become very radioactive after bombardment with deuterons. The emitted radiations are mostly positrons and hard gamma rays. The metal is dimorphic. The hexagonal alpha form changes to the cubic beta form very slowly at about 880°C. The metal combines with oxygen at red heat, and with chlorine at 550°C.
Titanium metal is considered to be physiologically inert. When pure, titanium dioxide is relatively clear and has an extremely high index of refraction with an optical dispersion higher than diamond.
The name derives from the Latin titans, who were the mythological "first sons of the earth". It was originally discovered by the English clergyman William Gregor in the mineral ilmenite (FeTiO3) in 1791. He called this mineral menachanite and the element menachin, for the Menachan parish where it was found. It was rediscovered in 1795 by the German chemist Martin Heinrich Klaproth, who called it titanium because it had no characteristic properties to use as a name. Titanium metal was first isolated by the Swedish chemists Sven Otto Pettersson and Lars Fredrik Nilson.
Titanium was discovered in 1791 by the Reverend William Gregor, an English pastor. Pure titanium was first produced by Matthew A. Hunter, an American metallurgist, in 1910. Titanium is the ninth most abundant element in the earth's crust and is primarily found in the minerals rutile (TiO2), ilmenite (FeTiO3) and sphene (CaTiSiO5). Titanium makes up about 0.57% of the earth's crust.
From the Latin titans, the first sons of the Earth, Greek mythology.
Discovered by Gregor in 1791; named by Klaproth in 1795. Impure titanium was prepared by Nilson and Pettersson in 1887; however, the pure metal (99.9%) was not made until 1910 when Hunter heated TiCl4 with sodium in a steel bomb.
Pure titanium is a silvery gray metal. It is ductile when sufficiently pure, but interstitial oxygen, nitrogen, carbon, or hydrogen can harden and embrittle it. At ordinary temperatures it is protected by a thin, adherent oxide film that reforms rapidly after scratching in air or water.
Most titanium mined is not converted to metal but to titanium dioxide, TiO₂, a white pigment used in paints, plastics, paper, inks, ceramics, and sunscreens. Metallic titanium and its alloys are used where high strength-to-weight ratio and corrosion resistance justify the cost, including aircraft structures, jet-engine parts, marine hardware, heat exchangers, and chemical-process equipment. Biocompatible titanium alloys are used for dental and orthopedic implants. Titanium is also used in some sporting goods, architecture, and as a getter or alloying addition in metallurgy.
Titanium is a strong, light metal. It is as strong as steel and twice as strong as aluminum, but is 45% lighter than steel and only 60% heavier than aluminum. Titanium is not easily corroded by sea water and is used in propeller shafts, rigging and other parts of boats that are exposed to sea water. Titanium and titanium alloys are used in airplanes, missiles and rockets where strength, low weight and resistance to high temperatures are important. Since titanium does not react within the human body, it is used to create artificial hips, pins for setting bones and for other biological implants. Unfortunately, the high cost of titanium has limited its widespread use.
Titanium oxide (TiO2) is used as a pigment to create white paint and accounts for the largest use of the element. Pure titanium oxide is relatively clear and is used to create titania, an artificial gemstone. Titanium tetrachloride (TiCl4), another titanium compound, has been used to make smoke screens.
A final bit of titanium trivia titanium is one of the few elements that will burn in an atmosphere of pure nitrogen.
Titanium is important as an alloying agent with aluminum, molybdenum, manganese, iron, and other metals. Alloys of titanium are principally used for aircraft and missiles where lightweight strength and ability to withstand extremes of temperature are important.
Titanium is as strong as steel, but 45% lighter. It is 60% heavier than aluminum, but twice as strong.
Titanium has potential use in desalination plants for converting sea water into fresh water. The metal has excellent resistance to sea water and is used for propeller shafts, rigging, and other parts of ships exposed to salt water. A titanium anode coated with platinum has been used to provide cathodic protection from corrosion by salt water.
It is produced artificially for use as a gemstone, but it is relatively soft. Star sapphires and rubies exhibit their asterism as a result of the presence of TiO2.
Titanium dioxide is extensively used for both house paint and artist's paint, because it is permanent and has good covering power. Titanium oxide pigment accounts for the largest use of the element. Titanium paint is an excellent reflector of infrared, and is extensively used in solar observatories where heat causes poor viewing conditions.
Titanium tetrachloride is used to iridize glass. This compound fumes strongly in air and has been used to produce smoke screens.
Isotopes in Earth/Planetary Science
The isotope-amount ratio n(50Ti)/n(46Ti) is used to study the early history of the Solar System. The value of the ratio can help determine whether the Solar System was created from a well-homogenized source [197] I. Leya, M. Schönbächler, U. Krähenbühl, A. N. Halliday. Astrophys. J.702, 1118 (2009)., [198] R. Courtland. Titanium Reveals Explosive Origins of the Solar System, New Scientist (2014), Feb. 25; http://www.newscientist.com/article/dn16969-titanium-reveals-explosive-origins-of-the-solar-system.html.. For example, variations in titanium isotopic compositions of various groups of meteorites can be observed (Fig. IUPAC.22.1) [199] J. Zhang, N. Dauphas, A. M. Davis, A. Pourmand. J. Anal. At. Spectrom.26, 2197 (2011)..
Isotopes in Industry
The isotope-amount ratio n(48Ti)/n(49Ti) has been used in Isotope Ratio Method (IRM) analysis (initial titanium ratio/final titanium ratio) to estimate the energy production of nuclear reactors. This ratio can also be used to confirm that a reactor is being used for non-proliferation purposes (purposes other than to assist in the formation of nuclear weapon grade materials) [201] D. C. Gerlach, C. J. Gesh, D. E. Hurley, M. R. Mitchell, G. H. Meriwether, B. D. Reid. Final Report on Isotope Ratio Techniques for Light Water Reactors, PNNL-18573. U.S. Department of Energy (2009)..
Titanium forms stable oxides, halides, nitrides, carbides, and organometallic compounds. Titanium dioxide, TiO₂, occurs mainly as rutile, anatase, and brookite and is chemically durable and optically important. Titanium tetrachloride, TiCl₄, is a volatile liquid used in metal production and pigment processing; it fumes in moist air by hydrolysis. Titanium nitride, TiN, is a hard, gold-colored ceramic coating. Titanium carbide, TiC, is a very hard refractory material. In aqueous chemistry, Ti⁴⁺ hydrolyzes strongly, while Ti³⁺ compounds are reducing and less stable in air.
See more information at the Titanium compound page.
Massive titanium metal is generally of low toxicity and is widely used in implants, but fine powder, turnings, and dust can burn vigorously and may pose explosion hazards when dispersed. Hot titanium reacts readily with oxygen, nitrogen, and hydrogen. Titanium tetrachloride, TiCl₄, is highly corrosive and releases hydrogen chloride, HCl, on contact with moisture. Titanium dioxide, TiO₂, is chemically inert in many uses, but inhalation of respirable dust is controlled in occupational settings.
Titanium is a common lithophile element in rocks and soils, mostly locked in resistant oxide and silicate minerals. It has low biological availability because Ti⁴⁺ is strongly hydrolyzed and insoluble under many environmental conditions. Weathering can concentrate titanium minerals such as rutile and ilmenite in heavy-mineral sands. Titanium dioxide particles are persistent, and their environmental behavior depends on particle size, surface coating, and light exposure rather than simple dissolution.
Titanium supply is tied mainly to mineral feedstocks used for pigment production, especially ilmenite and rutile, rather than to metallic titanium demand. Metal production is energy- and process-intensive because titanium cannot be reduced easily from its oxide; the Kroll process converts titanium tetrachloride, TiCl₄, with magnesium to produce sponge metal. Alloy fabrication and machining are costly compared with steel or aluminum. Recycling of clean titanium scrap is important in aerospace and medical supply chains, while contaminated scrap is harder to reuse in high-grade alloys.
Titanium is present in meteorites and the sun. Rocks obtained during the Apollo 17 lunar mission showed presence of 12.1% TiO2; rocks obtained during earlier Apollo missions show lower percentages.
Titanium oxide bands are prominent in the spectra of M-type stars. The element is the ninth most abundant in the crust of the earth. Titanium is almost always present in igneous rocks and in the sediments derived from them.
It occurs in the minerals rutile, ilmenite, and sphene, and is present in titanates and in many iron ores. Titanium is present in ash of coal, in plants, and in human body.
The metal was a laboratory curiosity until Kroll, in 1946, showed that titanium could be produced commercially by reducing titanium tetrachloride with magnesium. This method is still largely used for producing the metal. The metal can be purified by decomposing the iodide.
Titanium is produced in massive stars and supernova environments by nuclear burning and related explosive nucleosynthesis. It is a minor but widely detected element in the Sun, meteorites, and many stellar spectra. In rocky planets it behaves as a refractory lithophile element and is incorporated into oxide and silicate minerals rather than metallic cores. Calcium-aluminum-rich inclusions in meteorites can contain titanium-bearing refractory phases.
- Titanium was named after the Titans of Greek mythology, not after the element’s strength.
- The metal’s useful corrosion resistance comes from a nanometer-scale TiO₂ film.
- Titanium can burn in nitrogen at high temperature, forming titanium nitride.
- Commercially pure titanium grades differ largely by controlled oxygen content.
- Titanium tetrachloride produces dense white fumes in humid air.
- Rutile TiO₂ has one of the highest refractive indices of common colorless solids.
이미지
특성
물리적 특성
- 원자 반지름(경험값)
- 140 pm 모든 원소의 원자 반지름(경험값) 비교 →
- 공유 결합 반지름
- 160 pm 모든 원소의 공유 결합 반지름 비교 →
- 반데르발스 반지름
- 187 pm 모든 원소의 반데르발스 반지름 비교 →
- 금속 반지름
- 132 pm 모든 원소의 금속 반지름 비교 →
- 밀도
- 4500 kg/m³ 모든 원소의 밀도 비교 →
- 몰 부피
- 0.0106 L/mol
- STP에서의 상
- 고체 모든 원소의 STP에서의 상 비교 →
- 녹는점
- 1667.85 °C 모든 원소의 녹는점 비교 →
- 끓는점
- 3286.85 °C 모든 원소의 끓는점 비교 →
- 열전도율
- 21.9 W/(m·K) 모든 원소의 열전도율 비교 →
- 비열
- 0.523 J/(g·K) 모든 원소의 비열 비교 →
- 몰 열용량
- 25.06 J/(mol·K) 모든 원소의 몰 열용량 비교 →
- 결정 구조
- 육방 조밀 충전 모든 원소의 결정 구조 비교 →
화학적 특성
- 전기 음성도(Pauling)
- 1.54 모든 원소의 전기 음성도(Pauling) 비교 →
- 전기 음성도(Allen)
- 1.38
- 전자 친화도
- 0.0755 eV
- 제1 이온화 에너지
- 6.82812 eV 모든 원소의 제1 이온화 에너지 비교 →
- 제2 이온화 에너지
- 13.575547 eV 모든 원소의 제2 이온화 에너지 비교 →
- 제3 이온화 에너지
- 27.491805 eV 모든 원소의 제3 이온화 에너지 비교 →
- 제4 이온화 에너지
- 43.267319 eV 모든 원소의 제4 이온화 에너지 비교 →
- 제5 이온화 에너지
- 99.299342 eV 모든 원소의 제5 이온화 에너지 비교 →
- 산화 상태
- −2, −1, 0, +1, +2, +3, +4 모든 원소의 산화 상태 비교 →
- 원자가 전자
- 4 모든 원소의 원자가 전자 비교 →
- 전자 배치
- [Ar] 4s2 3d2
열역학적 특성
- 융해열
- 0.14665492 eV 모든 원소의 융해열 비교 →
- 기화열
- 4.40483 eV 모든 원소의 기화열 비교 →
- 승화열
- 4.851531 eV
- 원자화열
- 4.851531 eV
- 원자화 엔탈피
- 4.902316 eV
핵 특성
- 양성자 수
- 22 모든 원소의 양성자 수 비교 →
- 중성자 수
- 26 모든 원소의 중성자 수 비교 →
- 알려진 동위원소 수
- 29 모든 원소의 알려진 동위원소 수 비교 →
- 안정 동위원소 수
- 5 모든 원소의 안정 동위원소 수 비교 →
- 가장 안정한 동위원소
- Ti-48
- 발견 연도
- 1791
존재비
- 존재비(지각)
- 5650 mg/kg 모든 원소의 존재비(지각) 비교 →
- 존재비(해양)
- 0.001 mg/L 모든 원소의 존재비(해양) 비교 →
결정 구조
- 격자 상수 a
- 295 pm
전자 구조
- 전자껍질별 전자 수
- 2, 8, 10, 2 모든 원소의 전자껍질별 전자 수 비교 →
식별자
- CAS 등록 번호
- 7440-32-6 모든 원소의 CAS 등록 번호 비교 →
- 항 기호
- 3F2
- InChI
- InChI=1S/Ti
- InChI 키
- RTAQQCXQSZGOHL-UHFFFAOYSA-N
전자 배치 측정값
Ti: 3d² 4s²[Ar] 3d² 4s²1s² 2s² 2p⁶ 3s² 3p⁶ 3d² 4s²원자 모형
동위원소에 따라 중성자 수, 질량, 안정성은 달라지지만, 중성 원자의 전자 배치는 달라지지 않습니다.
개략적인 원자 모형이며 실제 비율과 다릅니다.
원자 지문
방출 / 흡수 스펙트럼
동위원소 분포
| 질량수 | 원자 질량(u) | 천연 존재비 | 반감기 |
|---|---|---|---|
| 46 안정 | 45.95262772 ± 0.00000035 | 8.2500% | 안정 |
| 47 안정 | 46.95175879 ± 0.00000038 | 7.4400% | 안정 |
| 48 안정 | 47.94794198 ± 0.00000038 | 73.7200% | 안정 |
| 49 안정 | 48.94786568 ± 0.00000039 | 5.4100% | 안정 |
| 50 안정 | 49.94478689 ± 0.00000039 | 5.1800% | 안정 |
상 / 상태
이유: 녹는점(1667.85 °C)보다 1642.8 °C 낮음
개략도이며 실제 비율과 다름
상전이점
전이 에너지
녹는점에서 1 mol을 녹이는 데 필요한 에너지
끓는점에서 1 mol을 기화시키는 데 필요한 에너지
승화점에서 1 mol을 승화시키는 데 필요한 에너지
밀도
표준 조건에서
표준 조건에서
원자 스펙트럼
전체 22개 중 10개를 표시합니다. 이온 전하순으로 정렬되었습니다(오름차순).
보유 스펙트럼선 데이터 ?
| 이온 | 전하 | 총 스펙트럼선 수 | 전이 확률 | 준위 표기 |
|---|---|---|---|---|
| Ti I | 0 | 4029 | 496 | 4029 |
| Ti II | +1 | 1872 | 470 | 1872 |
| Ti III | +2 | 819 | 297 | 819 |
| Ti IV | +3 | 86 | 39 | 86 |
| Ti V | +4 | 252 | 4 | 252 |
| Ti VI | +5 | 71 | 14 | 71 |
| Ti VII | +6 | 92 | 13 | 92 |
| Ti VIII | +7 | 85 | 37 | 85 |
| Ti IX | +8 | 85 | 50 | 85 |
| Ti X | +9 | 162 | 78 | 162 |
보유 에너지 준위 데이터 ?
| 이온 | 전하 | 준위 |
|---|---|---|
| Ti I | 0 | 559 |
| Ti II | +1 | 253 |
| Ti III | +2 | 200 |
| Ti IV | +3 | 40 |
| Ti V | +4 | 66 |
| Ti VI | +5 | 59 |
| Ti VII | +6 | 62 |
| Ti VIII | +7 | 44 |
| Ti IX | +8 | 32 |
| Ti X | +9 | 83 |
이온 반지름
| 전하 | 배위 | 스핀 | 반지름 |
|---|---|---|---|
| +2 | 6 | 해당 없음 | 86 pm |
| +3 | 6 | 해당 없음 | 67 pm |
| +4 | 4 | 해당 없음 | 42 pm |
| +4 | 5 | 해당 없음 | 51 pm |
| +4 | 6 | 해당 없음 | 60.5 pm |
| +4 | 8 | 해당 없음 | 74 pm |
화합물
동위원소 (5)
Natural titanium consists of five isotopes with atomic masses from 46 to 50. All are stable. Eight other unstable isotopes are known.
| 질량수 | 원자 질량(u) | 천연 존재비 | 반감기 | 붕괴 방식 | |
|---|---|---|---|---|---|
| 46 안정 | 45.95262772 ± 0.00000035 | 8.2500% ± 0.0300% | 안정 | stable | |
| 47 안정 | 46.95175879 ± 0.00000038 | 7.4400% ± 0.0200% | 안정 | stable | |
| 48 안정 | 47.94794198 ± 0.00000038 | 73.7200% ± 0.0300% | 안정 | stable | |
| 49 안정 | 48.94786568 ± 0.00000039 | 5.4100% ± 0.0200% | 안정 | stable | |
| 50 안정 | 49.94478689 ± 0.00000039 | 5.1800% ± 0.0200% | 안정 | stable |
스펙트럼선
전체 1717개 중 50개를 표시합니다. 기본적으로 세기가 측정된 스펙트럼선만 표시됩니다.
| 파장(nm) | 세기 | 이온화 단계 | 유형 | 전이 | 정확도 | 출처 | |
|---|---|---|---|---|---|---|---|
| 521.03843 nm | 21000 | Ti I | emission | 3d2.4s2 a 3F → 3d2.(3F).4s.4p.(3P*) z 3F* | 측정값 | NIST | |
| 506.46526 nm | 17000 | Ti I | emission | 3d2.4s2 a 3F → 3d2.(3F).4s.4p.(3P*) z 3D* | 측정값 | NIST | |
| 519.29686 nm | 17000 | Ti I | emission | 3d2.4s2 a 3F → 3d2.(3F).4s.4p.(3P*) z 3F* | 측정값 | NIST | |
| 517.37431 nm | 15000 | Ti I | emission | 3d2.4s2 a 3F → 3d2.(3F).4s.4p.(3P*) z 3F* | 측정값 | NIST | |
| 498.17305 nm | 14000 | Ti I | emission | 3d3.(4F).4s a 5F → 3d3.(4F).4p y 5G* | 측정값 | NIST | |
| 503.99574 nm | 14000 | Ti I | emission | 3d2.4s2 a 3F → 3d2.(3F).4s.4p.(3P*) z 3D* | 측정값 | NIST | |
| 468.19089 nm | 13000 | Ti I | emission | 3d2.4s2 a 3F → 3d2.(3F).4s.4p.(3P*) z 3G* | 측정값 | NIST | |
| 499.1066 nm | 13000 | Ti I | emission | 3d3.(4F).4s a 5F → 3d3.(4F).4p y 5G* | 측정값 | NIST | |
| 499.9503 nm | 12000 | Ti I | emission | 3d3.(4F).4s a 5F → 3d3.(4F).4p y 5G* | 측정값 | NIST | |
| 501.41861 nm | 11000 | Ti I | emission | 3d2.4s2 a 3F → 3d2.(3F).4s.4p.(3P*) z 3D* | 측정값 | NIST | |
| 399.86363 nm | 10000 | Ti I | emission | 3d2.4s2 a 3F → 3d2.(3F).4s.4p.(1P*) y 3F* | 측정값 | NIST | |
| 466.75845 nm | 10000 | Ti I | emission | 3d2.4s2 a 3F → 3d2.(3F).4s.4p.(3P*) z 3G* | 측정값 | NIST | |
| 500.72093 nm | 10000 | Ti I | emission | 3d3.(4F).4s a 5F → 3d3.(4F).4p y 5G* | 측정값 | NIST | |
| 453.32394 nm | 9200 | Ti I | emission | 3d3.(4F).4s a 5F → 3d3.(4F).4p y 5F* | 측정값 | NIST | |
| 398.17616 nm | 8800 | Ti I | emission | 3d2.4s2 a 3F → 3d2.(3F).4s.4p.(1P*) y 3F* | 측정값 | NIST | |
| 398.97582 nm | 8800 | Ti I | emission | 3d2.4s2 a 3F → 3d2.(3F).4s.4p.(1P*) y 3F* | 측정값 | NIST | |
| 501.42762 nm | 8700 | Ti I | emission | 3d3.(4F).4s a 5F → 3d3.(4F).4p y 5G* | 측정값 | NIST | |
| 395.82055 nm | 8600 | Ti I | emission | 3d2.4s2 a 3F → 3d3.(4F).4p y 3D* | 측정값 | NIST | |
| 465.64693 nm | 8400 | Ti I | emission | 3d2.4s2 a 3F → 3d2.(3F).4s.4p.(3P*) z 3G* | 측정값 | NIST | |
| 395.63338 nm | 8000 | Ti I | emission | 3d2.4s2 a 3F → 3d3.(4F).4p y 3D* | 측정값 | NIST | |
| 453.47761 nm | 7900 | Ti I | emission | 3d3.(4F).4s a 5F → 3d3.(4F).4p y 5F* | 측정값 | NIST | |
| 394.86705 nm | 7000 | Ti I | emission | 3d2.4s2 a 3F → 3d3.(4F).4p y 3D* | 측정값 | NIST | |
| 484.08737 nm | 6600 | Ti I | emission | 3d2.4s2 a 1D → 3d2.(1D).4s.4p.(1P*) y 1D* | 측정값 | NIST | |
| 430.59074 nm | 6400 | Ti I | emission | 3d3.(4F).4s a 5F → 3d3.(4F).4p x 5D* | 측정값 | NIST | |
| 453.55686 nm | 6100 | Ti I | emission | 3d3.(4F).4s a 5F → 3d3.(4F).4p y 5F* | 측정값 | NIST | |
| 394.77683 nm | 5700 | Ti I | emission | 3d2.4s2 a 3F → 3d2.(1D).4s.4p.(3P*) 3P* | 측정값 | NIST | |
| 502.00263 nm | 5100 | Ti I | emission | 3d3.(4F).4s a 5F → 3d3.(4F).4p y 5G* | 측정값 | NIST | |
| 430.10787 nm | 4900 | Ti I | emission | 3d3.(4F).4s a 5F → 3d3.(4F).4p x 5D* | 측정값 | NIST | |
| 503.5903 nm | 4900 | Ti I | emission | 3d3.(4F).4s b 3F → 3d3.(4F).4p w 3G* | 측정값 | NIST | |
| 502.28679 nm | 4800 | Ti I | emission | 3d3.(4F).4s a 5F → 3d3.(4F).4p y 5G* | 측정값 | NIST | |
| 453.59176 nm | 4700 | Ti I | emission | 3d3.(4F).4s a 5F → 3d3.(4F).4p y 5F* | 측정값 | NIST | |
| 430.05538 nm | 4400 | Ti I | emission | 3d3.(4F).4s a 5F → 3d3.(4F).4p x 5D* | 측정값 | NIST | |
| 453.60403 nm | 4000 | Ti I | emission | 3d3.(4F).4s a 5F → 3d3.(4F).4p y 5F* | 측정값 | NIST | |
| 503.64639 nm | 4000 | Ti I | emission | 3d3.(4F).4s b 3F → 3d3.(4F).4p w 3G* | 측정값 | NIST | |
| 501.61609 nm | 3800 | Ti I | emission | 3d3.(4F).4s a 5F → 3d3.(4F).4p y 5G* | 측정값 | NIST | |
| 451.8022 nm | 3700 | Ti I | emission | 3d3.(4F).4s a 5F → 3d3.(4F).4p y 5F* | 측정값 | NIST | |
| 488.50794 nm | 3700 | Ti I | emission | 3d3.(2G).4s a 3G → 3d3.(2G).4p y 3H* | 측정값 | NIST | |
| 392.45264 nm | 3600 | Ti I | emission | 3d2.4s2 a 3F → 3d3.(4F).4p y 3D* | 측정값 | NIST | |
| 402.45711 nm | 3600 | Ti I | emission | 3d2.4s2 a 3F → 3d2.(3F).4s.4p.(1P*) y 3F* | 측정값 | NIST | |
| 390.47826 nm | 3500 | Ti I | emission | 3d2.4s2 a 1D → 3d2.(1D).4s.4p.(1P*) y 1F* | 측정값 | NIST | |
| 452.2797 nm | 3500 | Ti I | emission | 3d3.(4F).4s a 5F → 3d3.(4F).4p y 5F* | 측정값 | NIST | |
| 502.48444 nm | 3500 | Ti I | emission | 3d3.(4F).4s a 5F → 3d3.(4F).4p y 5G* | 측정값 | NIST | |
| 398.24811 nm | 3400 | Ti I | emission | 3d2.4s2 a 3F → 3d2.(3P).4s.4p.(3P*) z 5S* | 측정값 | NIST | |
| 454.87635 nm | 3400 | Ti I | emission | 3d3.(4F).4s a 5F → 3d3.(4F).4p y 5F* | 측정값 | NIST | |
| 455.24533 nm | 3400 | Ti I | emission | 3d3.(4F).4s a 5F → 3d3.(4F).4p y 5F* | 측정값 | NIST | |
| 400.89274 nm | 3300 | Ti I | emission | 3d2.4s2 a 3F → 3d2.(3F).4s.4p.(1P*) y 3F* | 측정값 | NIST | |
| 503.83979 nm | 3300 | Ti I | emission | 3d3.(4F).4s b 3F → 3d3.(4F).4p w 3G* | 측정값 | NIST | |
| 392.98737 nm | 3200 | Ti I | emission | 3d2.4s2 a 3F → 3d3.(4F).4p y 3D* | 측정값 | NIST | |
| 429.86657 nm | 3200 | Ti I | emission | 3d3.(4F).4s a 5F → 3d3.(4F).4p x 5D* | 측정값 | NIST | |
| 489.99088 nm | 3200 | Ti I | emission | 3d3.(2G).4s a 3G → 3d3.(2G).4p y 3H* | 측정값 | NIST |
확장 특성
공유 결합 반지름(확장)
- 공유 결합 반지름(Pyykkö)
- 136 pm
- 공유 결합 반지름(Pyykkö, 이중 결합)
- 117 pm
- 공유 결합 반지름(Pyykkö, 삼중 결합)
- 108 pm
- 공유 결합 반지름(Bragg)
- 140 pm
반데르발스 반지름
- Batsanov
- 215 pm
- Alvarez
- 246 pm
- UFF
- 317.5 pm
- MM3
- 239 pm
원자 및 금속 반지름
- 원자 반지름(Rahm)
- 257 pm
- 금속 반지름(C12)
- 147 pm
번호 척도
- Mendeleev
- 43
- Pettifor
- 51
- Glawe
- 51
전기 음성도 척도
- Ghosh
- 0
- Miedema
- 4
- Gunnarsson–Lundqvist
- 5
- Robles–Bartolotti
- 4
분극률 및 분산
- 쌍극자 분극률
- 100 a.u.
- 쌍극자 분극률(불확도)
- 10 a.u.
- C₆
- 1044 Ha·Bohr6
- C₆ (Gould–Bučko)
- 1200 Ha·Bohr6
화학 친화력
- 양성자 친화도
- 876 kJ/mol
- 기체상 염기성
- 853.7 kJ/mol
미데마 매개변수
- 미데마 몰 부피
- 10.58 cm3/mol
- 미데마 전자 밀도
- 4
공급 위험 및 경제성
- 생산 집중도
- 21
- 상대적 공급 위험
- 5
- 매장량 분포
- 29
- 정치적 안정성(최대 생산국)
- 81
- 정치적 안정성(최대 매장국)
- 24
상전이 및 동소체
| 녹는점 | 1943.15 K |
| 끓는점 | 3560.15 K |
산화 상태 분류
심화 참고 데이터
차폐 상수 (7)
| n | 오비탈 | σ |
|---|---|---|
| 1 | s | 0.5591 |
| 2 | p | 3.9352 |
| 2 | s | 6.6234 |
| 3 | d | 13.8586 |
| 3 | p | 11.8963 |
| 3 | s | 10.9669 |
| 4 | s | 17.1832 |
결정 반지름 상세 정보 (6)
| 전하 | CN | 스핀 | rcrystal (pm) | 기원 |
|---|---|---|---|---|
| 2 | VI | 100 | estimated, | |
| 3 | VI | 81 | from r^3 vs V plots, | |
| 4 | IV | 56 | calculated, | |
| 4 | V | 65 | calculated, | |
| 4 | VI | 74.5 | from r^3 vs V plots, | |
| 4 | VIII | 88 | calculated, |
동위원소 붕괴 방식 (47)
| 동위원소 | 모드 | 세기 |
|---|---|---|
| 37 | p | — |
| 38 | 2p | — |
| 39 | B+ | 100% |
| 39 | B+p | 93.7% |
| 39 | 2p | — |
| 40 | B+ | 100% |
| 40 | B+p | 95.8% |
| 41 | B+ | 100% |
| 41 | B+p | 91.1% |
| 42 | B+ | 100% |
X선 산란 인자 (530)
| 에너지 (eV) | f₁ | f₂ |
|---|---|---|
| 10 | — | 1.51668 |
| 10.1428 | — | 1.54246 |
| 10.3068 | — | 1.57217 |
| 10.4735 | — | 1.60245 |
| 10.6429 | — | 1.63331 |
| 10.8151 | — | 1.66477 |
| 10.99 | — | 1.70636 |
| 11.1677 | — | 1.75257 |
| 11.3484 | — | 1.80003 |
| 11.5319 | — | 1.84878 |
추가 데이터
Estimated Crustal Abundance
The estimated element abundance in the earth's crust.
5.65×103 milligrams per kilogram
참고 문헌 (1)
- [5] Titanium https://education.jlab.org/itselemental/ele022.html
Estimated Oceanic Abundance
The estimated element abundance in the earth's oceans.
1×10-3 milligrams per liter
참고 문헌 (1)
- [5] Titanium https://education.jlab.org/itselemental/ele022.html
Sources
Sources of this element.
Titanium is present in meteorites and the sun. Rocks obtained during the Apollo 17 lunar mission showed presence of 12.1% TiO2; rocks obtained during earlier Apollo missions show lower percentages.
Titanium oxide bands are prominent in the spectra of M-type stars. The element is the ninth most abundant in the crust of the earth. Titanium is almost always present in igneous rocks and in the sediments derived from them.
It occurs in the minerals rutile, ilmenite, and sphene, and is present in titanates and in many iron ores. Titanium is present in ash of coal, in plants, and in human body.
The metal was a laboratory curiosity until Kroll, in 1946, showed that titanium could be produced commercially by reducing titanium tetrachloride with magnesium. This method is still largely used for producing the metal. The metal can be purified by decomposing the iodide.
참고 문헌 (1)
- [6] Titanium https://periodic.lanl.gov/22.shtml
참고 문헌
(9)
Data deposited in or computed by PubChem
The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.
Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.
The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.
Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/
The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.
The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database
This section provides all form of data related to element Titanium.
The element property data was retrieved from publications.