Mercury (Hg)
transition-metalLiquid
標準原子量
200.592 u電子配置
[Xe] 6s2 4f14 5d10融点
-38.83 °C沸点
356.73 °C密度
1.35336e+4 kg/m³酸化数
−2, +1, +2電気陰性度(Pauling)
2第1イオン化エネルギー
10.437504 eV発見年
データなし原子半径
150 pm詳細
Mercury is a heavy, silvery transition metal with the distinctive feature of being liquid near ordinary room temperature. It has a filled 5d shell and commonly forms +1 and +2 compounds, with covalent character more prominent than in many lighter metals. Mercury has been used in instruments, electrical devices, and gold extraction, but many uses have declined because its vapor and several compounds are highly toxic.
It is a heavy, silvery-white metal; a rather poor conductor of heat, as compared with other metals, and a fair conductor of electricity. It easily forms alloys with many metals, such as gold, silver, and tin, which are called amalgams. Its ease in amalgamating with gold is made use of in the recovery of gold from its ores. The most important salts are mercury chloride (corrosive sublimate - a violent poison), mercurous chloride (calomel, occasionally still used in medicine), mercury fulminate, a detonator widely used in explosives, and mercuric sulfide (vermilion, a high-grade paint pigment). Organic mercury compounds are important. It has been found that an electrical discharge causes mercury vapor to combine with neon, argon, krypton, and xenon. These products, held together with van der Waals' forces, correspond to HgNe, HgAr, HgKr, and HgXe. Mercury is a virulent poison and is readily absorbed through the respiratory tract, the gastrointestinal tract, or through unbroken skin. It acts as a cumulative poison and dangerous levels are readily attained in air. Air saturated with mercury vapor at 20°C contains a concentration that exceeds the toxicity limits. The danger increases at higher temperatures. It is important therefore that mercury be handled with care. Containers of mercury should be securely covered and spillage should be avoided. If it is necessary to heat mercury or mercury compounds, it should be done in a well-ventilated hood. Methyl mercury is a dangerous pollutant and is now widely found in water and streams. The triple point of mercury, -38.8344C, is a fixed point on the International Temperature Scale (ITS-90).
The name derives from the Roman god Mercury, the nimble messenger of the gods, because the ancients used that name for the element known from prehistoric times. The symbol Hg derives from the Greek hydrargyrum for "liquid silver" or "quick silver".
Mercury was known to the ancient Chinese and Hindus and has been found in 3500 year old Egyptian tombs. Mercury is not usually found free in nature and is primarily obtained from the mineral cinnabar (HgS). Spain and Italy produce about half of the world's supply of Mercury.
From Greek hydoor. Known to ancient Chinese and Hindus; found in Egyptian tombs of 1500 B.C. Mercury is the only common metal liquid at ordinary temperatures. It only rarely occurs free in nature. The chief ore is cinnabar; Spain and Italy produce about 50% of the world's supply of the metal. The commercial unit for handling mercury is the "flask," which weighs 76 lb. The metal is obtained by heating cinnabar in a current of air and by condensing the vapor.
Pure mercury is a dense, mirror-bright liquid at room temperature, forming rounded droplets with high surface tension. It freezes to a soft, silvery solid below −38.83 °C and boils at 356.73 °C. Clean mercury wets few common surfaces but readily forms amalgams with many metals.
Mercury was historically important in thermometers, barometers, manometers, tilt switches, fluorescent lamps, dental amalgam, and laboratory electrodes. Some of these uses persist under restrictions or in specialized settings. Mercury vapor remains useful in certain discharge lamps, and mercury compounds have had roles as catalysts, reagents, and preservatives, though many have been replaced. Elemental mercury is still used in some artisanal and small-scale gold mining, a practice associated with substantial emissions.
Mercury can be used to make thermometers, barometers and other scientific instruments. Mercury conducts electricity and is used to make silent, position dependent switches. Mercury vapor is used in streetlights, fluorescent lamps and advertising signs.
Mercury easily forms alloys with other metals, such as gold, silver, zinc and cadmium. These alloys are called amalgams. Amalgams are used to help extract gold from its ores, create dental fillings (in the case of silver) and help extend the life of dry cell batteries (in the case of zinc and cadmium).
Mercury forms useful compounds with other elements. Mercuric chloride (HgCl2) is a very poisonous salt and was once used to disinfect wounds. Mercurous chloride (Hg2Cl2), also called calomel, is an antiseptic used to kill bacteria. Mercuric sulfide (HgS) is used to make a red paint pigment called vermilion. Mercuric oxide (HgO) is used to make mercury batteries.
Mercury is poisonous and can enter the body through the respiratory tract, the digestive tract or directly through the skin. It accumulates in the body, eventually causing severe illness or death.
The metal is widely used in laboratory work for making thermometers, barometers, diffusion pumps, and many other instruments. It is used in making mercury-vapor lamps and advertising signs, etc. and is used in mercury switches and other electronic apparatus. Other uses are in making pesticides, Mercury cells for caustic soda and chlorine production, dental preparations, anti-fouling paint, batteries, and catalysts.
Isotopes in Earth/Planetary Science
198Hg, 200Hg, and 202Hg are stable isotopes of mercury that can be used to study environmental sources and environmental sinks of this element in aquatic and terrestrial ecosystems. For example, in an ecosystem, different stable isotopes of mercury can be added to an upland region for run-off evaluation, to a lake for direct deposition analysis, and to a wetland region for outflow contribution analysis (Fig. IUPAC.80.1). As a result, it is possible to determine the entry points of mercury into an ecosystem and determine how the inputs of mercury affect the accumulation of this element in local fish populations. An international consortium of scientists is conducting an experiment called METAALICUS (Mercury Experiment To Assess Atmospheric Loading In Canada and the U.S.). This experiment includes determination of whether mercury contamination in fish is old or new mercury. Tracer studies were performed in northwestern Ontario at the Experimental Lakes Area of the Department of Fisheries and Oceans Canada [537] Toxic Substances Hydrology Program. Mercury-Contaminated Fish-Is it Old or New Mercury? U.S. Geological Survey (2014), Feb. 26; http://toxics.usgs.gov/highlights/mercury_contaminated_fish.html..
Isotopes Used as a Source of Radioactive Isotope(s)
202Hg is used to produce radioactive 203Hg (with a half-life of 46.6 days) via the 202Hg (n, γ) 203Hg reaction, which is used in gamma radiation calibration and medical tests.
Mercury chemistry is dominated by mercury(I) and mercury(II). Mercury(I) usually exists as the dimeric cation Hg₂²⁺, represented in mercury(I) chloride, Hg₂Cl₂. Mercury(II) chloride, HgCl₂, is more soluble and highly toxic. Mercury(II) sulfide, HgS, occurs as cinnabar and is very insoluble. Organomercury compounds such as methylmercury, CH₃Hg⁺, are environmentally important because they are readily bioaccumulated. Mercury forms amalgams with metals such as silver, gold, and tin.
See more information at the Mercury compound page.
Elemental mercury is hazardous mainly through inhalation of vapor, which is produced even at room temperature and can accumulate in poorly ventilated spaces. Soluble mercury(II) salts are corrosive and systemically toxic, while methylmercury, CH₃Hg⁺, is a potent neurotoxin that concentrates in food webs. Spills are treated as chemical contamination because droplets are persistent and difficult to remove. Heating mercury greatly increases vapor exposure.
Mercury is naturally released by volcanic activity, weathering, geothermal emissions, and ocean-atmosphere exchange, but human activities have greatly redistributed it. Coal combustion, metal smelting, waste burning, and gold mining are major anthropogenic sources. In aquatic sediments, microbes can convert inorganic mercury to methylmercury, CH₃Hg⁺, which biomagnifies in predatory fish and wildlife. Mercury can travel long distances in the atmosphere before deposition.
Mercury is produced mainly from cinnabar ore, HgS, and in some regions as a by-product of nonferrous metal processing or from recycling. Demand has fallen in many industrialized markets because of regulation and substitution in instruments, batteries, switches, and chlor-alkali technology. Supply is affected by restrictions on trade and storage as well as recovery from obsolete equipment. Significant consumption persists where alternatives are costly or poorly enforced, especially in small-scale gold extraction.
Virtually all mercury comes from cinnabar or mercury sulfide (HgS). Some sources of red cinnabar are so rich in mercury that droplets of elemental mercury can be found in random samples.
Mercury is a rare heavy element in cosmic terms. Its stable isotopes were formed chiefly by neutron-capture processes in earlier generations of stars, with later redistribution into the solar nebula. In the Solar System it is present in trace amounts in rocky bodies and meteorites, but it is volatile enough that planetary abundance depends strongly on condensation, heating, and loss processes.
- The chemical symbol Hg comes from hydrargyrum, meaning liquid silver.
- Mercury expands fairly uniformly with temperature, which made it valuable in older thermometers.
- Cinnabar, HgS, was used historically as the red pigment vermilion.
- Mercury droplets can divide into many beads, increasing surface area and vapor release.
- Aluminum structures can be damaged by mercury because amalgamation disrupts protective oxide behavior.
- Most dental amalgam is an alloy phase mixture rather than pure mercury.
画像
性質
物理的性質
- 原子半径(経験値)
- 150 pm 全元素の原子半径(経験値)を比較 →
- 共有結合半径
- 132 pm 全元素の共有結合半径を比較 →
- ファンデルワールス半径
- 209 pm 全元素のファンデルワールス半径を比較 →
- 金属半径
- 139 pm 全元素の金属半径を比較 →
- 密度
- 1.35336 × 104 kg/m³ 全元素の密度を比較 →
- モル体積
- 0.0148 L/mol
- 標準温度・圧力(STP)での相
- 液体 全元素の標準温度・圧力(STP)での相を比較 →
- 融点
- -38.83 °C 全元素の融点を比較 →
- 沸点
- 356.73 °C 全元素の沸点を比較 →
- 熱伝導率
- 8.3 W/(m·K) 全元素の熱伝導率を比較 →
- 比熱容量
- 0.14 J/(g·K) 全元素の比熱容量を比較 →
- モル熱容量
- 27.983 J/(mol·K) 全元素のモル熱容量を比較 →
- 結晶構造
- 菱面体構造 全元素の結晶構造を比較 →
化学的性質
- 電気陰性度(Pauling)
- 2 全元素の電気陰性度(Pauling)を比較 →
- 電気陰性度(Allen)
- 1.76
- 電子親和力
- -0.5 eV (負の値—この原子は電子を取り込まないと予測される)
- 第1イオン化エネルギー
- 10.437504 eV 全元素の第1イオン化エネルギーを比較 →
- 第2イオン化エネルギー
- 18.756945 eV 全元素の第2イオン化エネルギーを比較 →
- 第3イオン化エネルギー
- 34.490119 eV 全元素の第3イオン化エネルギーを比較 →
- 第4イオン化エネルギー
- 48.550167 eV 全元素の第4イオン化エネルギーを比較 →
- 第5イオン化エネルギー
- 61.200211 eV 全元素の第5イオン化エネルギーを比較 →
- 酸化数
- −2, +1, +2 全元素の酸化数を比較 →
- 価電子
- 12 全元素の価電子を比較 →
- 電子配置
- [Xe] 6s2 4f14 5d10
熱力学的性質
- 三重点(温度)
- -38.8344 °C
- 臨界点(温度)
- 1491 °C
- 臨界点(圧力)
- 1.67e+8 Pa
- 融解熱
- 0.02373426 eV 全元素の融解熱を比較 →
- 蒸発熱
- 0.61263409 eV 全元素の蒸発熱を比較 →
- 昇華熱
- 0.63636835 eV
- 原子化熱
- 0.63636835 eV
- 原子化エンタルピー
- 0.63616106 eV
原子核
- 陽子数
- 80 全元素の陽子数を比較 →
- 中性子数
- 122 全元素の中性子数を比較 →
- 既知の同位体
- 47 全元素の既知の同位体を比較 →
- 安定同位体
- 6 全元素の安定同位体を比較 →
- 最も安定な同位体
- Hg-202
存在度
- 存在度(地殻)
- 0.085 mg/kg 全元素の存在度(地殻)を比較 →
- 存在度(海洋)
- 3 × 10−5 mg/L 全元素の存在度(海洋)を比較 →
結晶構造
- 格子定数a
- 299 pm
電子構造
- 各電子殻の電子数
- 2, 8, 18, 32, 18, 2 全元素の各電子殻の電子数を比較 →
識別子
- CAS登録番号
- 7439-97-6 全元素のCAS登録番号を比較 →
- 項記号
- 1S0
- InChI
- InChI=1S/Hg
- InChI Key
- QSHDDOUJBYECFT-UHFFFAOYSA-N
電子配置 測定値
Hg: 4f¹⁴ 5d¹⁰ 6s²[Xe] 4f¹⁴ 5d¹⁰ 6s²1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d¹⁰ 6s²原子モデル
同位体によって中性子数、質量、安定性は変わりますが、中性原子の電子配置は変わりません。
模式的な原子モデルです。実際の縮尺とは異なります。
原子の指紋
発光/吸収スペクトル
同位体分布
| 質量数 | 原子質量(u) | 天然存在比 | 半減期 |
|---|---|---|---|
| 198 安定 | 197.9667686 ± 0.00000052 | 9.9700% | 安定 |
| 199 安定 | 198.96828064 ± 0.00000046 | 16.8700% | 安定 |
| 200 安定 | 199.96832659 ± 0.00000047 | 23.1000% | 安定 |
| 201 安定 | 200.97030284 ± 0.00000069 | 13.1800% | 安定 |
| 202 安定 | 201.9706434 ± 0.00000069 | 29.8600% | 安定 |
| 204 安定 | 203.97349398 ± 0.00000053 | 6.8700% | 安定 |
相/状態
理由: 融点(-38.83 °C)と沸点(356.73 °C)の間
模式図、実際の縮尺とは異なります
相転移点
相転移エネルギー
融点で1 molを融解させるのに必要なエネルギー
沸点で1 molを蒸発させるのに必要なエネルギー
昇華点で1 molを昇華させるのに必要なエネルギー
密度
標準条件下
液相のデータはありません
詳細
原子スペクトル
全81件中10件を表示しています。 イオンの電荷の昇順で並べています。
スペクトル線データの収録状況 ?
| イオン | 電荷 | スペクトル線の総数 | 遷移確率 | 準位の表記 |
|---|---|---|---|---|
| Hg I | 0 | 754 | 53 | 708 |
| 198Hg I 同位体 | 0 | 210 | 0 | 210 |
| Hg II | +1 | 554 | 446 | 463 |
| Hg III | +2 | 52 | 0 | 0 |
準位データの収録状況 ?
| イオン | 電荷 | 準位 |
|---|---|---|
| Hg I | 0 | 299 |
| 198Hg I 同位体 | 0 | 61 |
| Hg II | +1 | 115 |
| Hg III | +2 | 94 |
| Hg IV | +3 | 61 |
| Hg V | +4 | 2 |
| Hg VI | +5 | 2 |
| Hg VII | +6 | 2 |
| Hg VIII | +7 | 2 |
| Hg IX | +8 | 2 |
固相の結晶構造データはありません
結晶構造: rhombohedral
イオン半径
| 電荷 | 配位 | スピン | 半径 |
|---|---|---|---|
| +1 | 3 | データなし | 97 pm |
| +1 | 6 | データなし | 119 pm |
| +2 | 2 | データなし | 69 pm |
| +2 | 4 | データなし | 96 pm |
| +2 | 6 | データなし | 102 pm |
| +2 | 8 | データなし | 113.99999999999999 pm |
化合物
同位体 (6)
| 質量数 | 原子質量(u) | 天然存在比 | 半減期 | 崩壊形式 | |
|---|---|---|---|---|---|
| 198 安定 | 197.9667686 ± 0.00000052 | 9.9700% ± 0.2000% | 安定 | stable | |
| 199 安定 | 198.96828064 ± 0.00000046 | 16.8700% ± 0.2200% | 安定 | stable | |
| 200 安定 | 199.96832659 ± 0.00000047 | 23.1000% ± 0.1900% | 安定 | stable | |
| 201 安定 | 200.97030284 ± 0.00000069 | 13.1800% ± 0.0900% | 安定 | stable | |
| 202 安定 | 201.9706434 ± 0.00000069 | 29.8600% ± 0.2600% | 安定 | stable | |
| 204 安定 | 203.97349398 ± 0.00000053 | 6.8700% ± 0.1500% | 安定 | stable |
スペクトル線
全218件中50件を表示しています。 初期設定では、強度の測定値があるスペクトル線のみを表示します。
| 波長(nm) | 強度 | 電離段階 | 種類 | 遷移 | 精度 | 出典 | |
|---|---|---|---|---|---|---|---|
| 542.5249 nm | 8000000 | Hg II | emission | 5d10.6d 2D → 5d10.5f 2F* | 測定値 | NIST | |
| 587.12779 nm | 1200000 | Hg II | emission | 5d10.7p 2P* → 5d10.7d 2D | 測定値 | NIST | |
| 559.526 nm | 200000 | Hg II | emission | 5d10.6d 2D → 5d10.5f 2F* | 測定値 | NIST | |
| 520.4768 nm | 150000 | Hg II | emission | 5d9.6s.6d [(2D<5/2>,1/2)<3>,5/2] → 5d9.6s.5f [(2D<5/2>,1/2)<3>,7/2]* | 測定値 | NIST | |
| 629.123 nm | 65000 | Hg II | emission | 5d10.5f 2F* → 5d10.6g 2G | 測定値 | NIST | |
| 639.4888 nm | 55000 | Hg II | emission | 5d10.5f 2F* → 5d10.6g 2G | 測定値 | NIST | |
| 380.63154 nm | 50000 | Hg II | emission | 5d10.7p 2P* → 5d10.8d 2D | 測定値 | NIST | |
| 439.8623 nm | 40000 | Hg II | emission | 5d10.7p 2P* → 5d10.8d 2D | 測定値 | NIST | |
| 521.6379 nm | 40000 | Hg II | emission | 5d9.6s.6d [(2D<5/2>,1/2)<3>,5/2] → 5d9.6s.5f [(2D<5/2>,1/2)<3>,5/2]* | 測定値 | NIST | |
| 466.0216 nm | 30000 | Hg II | emission | 5d9.6s.6p (2D<3/2>,3P<1>)* → 5d10.7d 2D | 測定値 | NIST | |
| 527.7593 nm | 18000 | Hg II | emission | 5d9.6s.6d [(2D<5/2>,1/2)<3>,5/2] → 5d9.6s.5f [(2D<5/2>,1/2)<3>,5/2]* | 測定値 | NIST | |
| 482.5564 nm | 17000 | Hg II | emission | 5d9.6s.6d [(2D<5/2>,1/2)<3>,3/2] → 5d9.6s.5f [(2D<5/2>,1/2)<3>,5/2]* | 測定値 | NIST | |
| 514.6293 nm | 15000 | Hg II | emission | 5d9.6s.6d [(2D<5/2>,1/2)<3>,5/2] → 5d9.6s.5f [(2D<5/2>,1/2)<3>,5/2]* | 測定値 | NIST | |
| 404.65643 nm | 12000 | Hg I | emission | 5d10.6s.6p 3P* → 5d10.6s.7s 3S | 測定値 | NIST | |
| 435.83363 nm | 12000 | Hg I | emission | 5d10.6s.6p 3P* → 5d10.6s.7s 3S | 測定値 | NIST | |
| 383.9255 nm | 10000 | Hg II | emission | 5d10.7s 2S → 5d9.6s.6p (2D<3/2>,1P<1>)* | 測定値 | NIST | |
| 546.07498 nm | 6000 | Hg I | emission | 5d10.6s.6p 3P* → 5d10.6s.7s 3S | 測定値 | NIST | |
| 391.43142 nm | 5000 | Hg II | emission | 5d9.6s.6p (2D<3/2>,3P<2>)* → 5d9.6s.7s [(2D<5/2>,1/2)<3>,1/2] | 測定値 | NIST | |
| 412.0447 nm | 4000 | Hg II | emission | 5d10.7p 2P* → 5d10.9s 2S | 測定値 | NIST | |
| 449.28309 nm | 2800 | Hg II | emission | 5d10.6d 2D → 5d10.8p 2P* | 測定値 | NIST | |
| 664.66839 nm | 1300 | Hg II | emission | 5d9.6s2 2D → 5d9.6s2 2D | 測定値 | NIST | |
| 506.6497 nm | 1200 | Hg II | emission | 5d9.6s.6d [(2D<5/2>,1/2)<3>,3/2] → 5d9.6s.5f [(2D<5/2>,1/2)<3>,7/2]* | 測定値 | NIST | |
| 382.89121 nm | 1000 | Hg II | emission | 5d9.6s.6p (2D<3/2>,3P<2>)* → 5d9.6s.7s [(2D<5/2>,1/2)<3>,1/2] | 測定値 | NIST | |
| 407.7837 nm | 1000 | Hg I | emission | 5d10.6s.6p 3P* → 5d10.6s.7s 1S | 測定値 | NIST | |
| 576.96095 nm | 1000 | Hg I | emission | 5d10.6s.6p 1P* → 5d10.6s.6d 3D | 測定値 | NIST | |
| 690.746 nm | 1000 | Hg I | emission | 5d10.6s.7s 3S → 5d10.6s.8p 3P* | 測定値 | NIST | |
| 708.1901 nm | 1000 | Hg I | emission | 5d10.6s.7s 3S → 5d10.6s.8p 3P* | 測定値 | NIST | |
| 579.06705 nm | 900 | Hg I | emission | 5d10.6s.6p 1P* → 5d10.6s.6d 1D | 測定値 | NIST | |
| 709.186 nm | 800 | Hg I | emission | 5d10.6s.7s 3S → 5d10.6s.8p 3P* | 測定値 | NIST | |
| 567.588 nm | 600 | Hg I | emission | 5d10.6s.7s 3S → 5d10.6s.9p 1P* | 測定値 | NIST | |
| 671.636 nm | 600 | Hg I | emission | 5d10.6s.7s 1S → 5d9.6s2.(2D<5/2>).6p 2[3/2]* | 測定値 | NIST | |
| 580.3783 nm | 400 | Hg I | emission | 5d10.6s.7s 1S → 5d10.6s.10p 1P* | 測定値 | NIST | |
| 474.2296 nm | 300 | Hg II | emission | 5d9.6s.6d [(2D<5/2>,1/2)<3>,3/2] → 5d9.6s.5f [(2D<5/2>,1/2)<3>,7/2]* | 測定値 | NIST | |
| 434.74951 nm | 150 | Hg I | emission | 5d10.6s.6p 1P* → 5d10.6s.7d 1D | 測定値 | NIST | |
| 594.7682 nm | 150 | Hg II | emission | 5d10.7d 2D → 5d10.8f 2F* | 測定値 | NIST | |
| 535.4036 nm | 130 | Hg I | emission | 5d10.6s.7s 3S → 5d10.6s.10p 3P* | 測定値 | NIST | |
| 585.9254 nm | 130 | Hg I | emission | 5d10.6s.7s 3S → 5d10.6s.9p 3P* | 測定値 | NIST | |
| 496.017 nm | 100 | Hg I | emission | 5d9.6s2.(2D<5/2>).6p 2[7/2]* → 5d9.6s2.(2D<5/2>).7s 2[5/2] | 測定値 | NIST | |
| 510.0945 nm | 100 | Hg II | emission | 5d9.6s.6d [(2D<5/2>,1/2)<3>,5/2] → 5d9.6s.5f [(2D<5/2>,1/2)<3>,7/2]* | 測定値 | NIST | |
| 410.8054 nm | 70 | Hg I | emission | 5d10.6s.6p 1P* → 5d10.6s.9s 1S | 測定値 | NIST | |
| 512.0637 nm | 70 | Hg I | emission | 5d10.6s.7s 3S → 5d10.6s.11p 3P* | 測定値 | NIST | |
| 509.8561 nm | 60 | Hg II | emission | 5d9.6s.6d [(2D<5/2>,1/2)<3>,5/2] → 5d9.6s.5f [(2D<5/2>,1/2)<3>,5/2]* | 測定値 | NIST | |
| 380.16582 nm | 50 | Hg I | emission | 5d10.6s.6p 1P* → 5d10.6s.10s 1S | 測定値 | NIST | |
| 382.037 nm | 50 | Hg I | emission | 5d9.6s2.(2D<5/2>).6p 2[7/2]* → 5d9.6s2.(2D<5/2>).7s 2[5/2] | 測定値 | NIST | |
| 404.7742 nm | 50 | Hg II | emission | 5d9.6s.6p (2D<3/2>,3P<2>)* → 5d9.6s.7s [(2D<5/2>,1/2)<3>,1/2] | 測定値 | NIST | |
| 433.92228 nm | 50 | Hg I | emission | 5d10.6s.6p 1P* → 5d10.6s.7d 3D | 測定値 | NIST | |
| 538.4627 nm | 50 | Hg I | emission | 5d10.6s.7s 3S → 5d10.6s.10p 3P* | 測定値 | NIST | |
| 554.9636 nm | 50 | Hg I | emission | 5d10.6s.7s 1S → 5d10.6s.11p 1P* | 測定値 | NIST | |
| 623.435 nm | 50 | Hg I | emission | 5d10.6s.7s 1S → 5d10.6s.9p 1P* | 測定値 | NIST | |
| 390.6383 nm | 40 | Hg I | emission | 5d10.6s.6p 1P* → 5d10.6s.8d 1D | 測定値 | NIST |
詳細な性質
共有結合半径(詳細)
- 共有結合半径(Pyykkö)
- 133 pm
- 共有結合半径(Pyykkö、二重結合)
- 142 pm
ファンデルワールス半径
- Batsanov
- 205 pm
- Alvarez
- 245 pm
- UFF
- 270.5 pm
- MM3
- 253 pm
原子半径と金属半径
- 原子半径(Rahm)
- 229 pm
- 金属半径(C12)
- 151 pm
番号付けの尺度
- Mendeleev
- 79
- Pettifor
- 74
- Glawe
- 76
電気陰性度の尺度
- Ghosh
- 0
- Miedema
- 4
- Gunnarsson–Lundqvist
- 4
- Robles–Bartolotti
- 3
分極率と分散
- 双極子分極率
- 33.91 a.u.
- 双極子分極率(不確かさ)
- 0.34 a.u.
- C₆ (Gould–Bučko)
- 268 Ha·Bohr6
ミーデマパラメータ
- ミーデマモル体積
- 14.08 cm3/mol
- ミーデマ電子密度
- 2
供給リスクと経済性
- 生産集中度
- 74
- 相対供給リスク
- 9
- 埋蔵量の分布
- 29
- 政治的安定性(最大生産国)
- 24
- 政治的安定性(最大埋蔵国)
- 23
相転移と同素体
| 融点 | 234.32 K |
| 沸点 | 629.77 K |
| 臨界点(温度) | 1764.15 K |
| 臨界点(圧力) | 167 MPa |
| 三重点(温度) | 234.32 K |
酸化数の分類
専門参考データ
遮蔽定数 (14)
| n | 軌道 | σ |
|---|---|---|
| 1 | s | 1.5419 |
| 2 | p | 4.499 |
| 2 | s | 20.8906 |
| 3 | d | 13.4804 |
| 3 | p | 22.4798 |
| 3 | s | 23.4587 |
| 4 | d | 37.532 |
| 4 | f | 38.2392 |
| 4 | p | 35.594 |
| 4 | s | 34.7552 |
結晶半径の詳細 (6)
| 電荷 | CN | スピン | rcrystal (pm) | 由来 |
|---|---|---|---|---|
| 1 | III | 111 | ||
| 1 | VI | 133 | ||
| 2 | II | 83 | ||
| 2 | IV | 110 | ||
| 2 | VI | 116 | ||
| 2 | VIII | 128 | from r^3 vs V plots, |
同位体の崩壊形式 (76)
| 同位体 | モード | 強度 |
|---|---|---|
| 170 | A | 100% |
| 171 | A | 100% |
| 171 | B+ | — |
| 172 | A | 100% |
| 172 | B+ | — |
| 173 | A | 100% |
| 174 | A | 100% |
| 174 | B+ | — |
| 175 | A | 100% |
| 175 | B+ | — |
X線散乱因子 (516)
| エネルギー (eV) | f₁ | f₂ |
|---|---|---|
| 10 | — | 3.07253 |
| 10.1617 | — | 3.05926 |
| 10.3261 | — | 3.04605 |
| 10.4931 | — | 3.0329 |
| 10.6628 | — | 3.0198 |
| 10.8353 | — | 3.00676 |
| 11.0106 | — | 3.02448 |
| 11.1886 | — | 3.04517 |
| 11.3696 | — | 3.066 |
| 11.5535 | — | 3.08698 |
追加データ
Estimated Crustal Abundance
The estimated element abundance in the earth's crust.
8.5×10-2 milligrams per kilogram
参考文献 (1)
Estimated Oceanic Abundance
The estimated element abundance in the earth's oceans.
3×10-5 milligrams per liter
参考文献 (1)
参考文献
(9)
Data deposited in or computed by PubChem
The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.
Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.
The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.
Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/
The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.
The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database
This section provides all form of data related to element Mercury.
The element property data was retrieved from publications.
