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No 102

Nobelium (No)

actinide
周期: 7 ブロック: f

Solid

標準原子量

[259]

電子配置

[Rn] 7s2 5f14

融点

826.85 °C

沸点

データなし

密度

9900 kg/m³

酸化数

+2, +3

電気陰性度(Pauling)

1.3

第1イオン化エネルギー

6.62621 eV

発見年

1957

原子半径

データなし

詳細

名称の由来 Named in honor of Alfred Nobel, who invented dynamite and founded Nobel prize.
発見国 Sweden
発見者 Nobel Institute for Physics

Nobelium is a synthetic actinide with atomic number 102. It is produced only in particle-accelerator experiments and is studied in atom-at-a-time quantities. Its longest-lived confirmed isotopes have half-lives of only minutes, so no macroscopic sample or ordinary material application exists. Chemically, nobelium is notable because the +2 oxidation state is unusually stable for an actinide, in contrast to the more common +3 state of many neighboring elements.

Nobelium does not occur naturally in the Earth’s crust. It was first synthesized in 1966 by Russian scientists from the Joint Institute for Nuclear Research (JINR) in Dubna, Russia under Georgi Flerov. Earlier claims to have synthesized “nobelium” beginning in 1957 were shown to be erroneous. This element was originally named for Alfred Nobel (Fig. IUPAC.102.1), the inventor of dynamite and founder of the Nobel prizes. The name was later retained because of its widespread use throughout the scientific literature [636], [638]. There are no uses for isotopes of nobelium outside of scientific research.

Nobelium is named after Alfred Nobel.

In 1957, a group of scientists working at the Nobel Institute of Physics in Stockhlom, Sweden, announced the discovery of a new element. They produced this new element, which they named nobelium, by bombarding a target of curium-244 with ions of carbon-13 with a device called a cyclotron. The isotope they created had a half-life of 10 minutes. In 1958, another group of scientists, Albert Ghiorso, Glenn T. Seaborg, Torbørn Sikkeland and John R. Walton, working at the Lawrence Radiation Laboratory in Berkeley, California, attempted to confirm the Nobel Institute's discovery. They were unable to produce any isotope of nobelium with a half-life of 10 minutes, but were able to produce nobelium-254, with a half-life of three seconds, by bombarding curium-246 with carbon-12. A third group, working at the Joint Institute for Nuclear Research in Dubna, Russia, also could not duplicate the Nobel Institute's work but were able to confirm the Berkeley group's work. Credit for discovering nobelium was eventually given to the scientists working at Lawrence Radiation Laboratory, who decided to keep the name nobelium. Today, the Lawrence Radiation Laboratory is known as the Lawrence Berkeley Laboratory. Nobelium's most stable isotope, nobelium-259, has a half-life of about 58 minutes. It decays into fermium-255 through alpha decay, into mendelevium-259 through electron capture or through spontaneous fission.

Named after Alfred Nobel, inventor of dynamite. Nobelium was unambiguously discovered and identified in April 1958 at Berkeley by A. Ghiorso, T. Sikkeland, J.R. Walton, and G.T. Seaborg, who used a new double-recoil technique. A heavy-ion linear accelerator (HILAC) was used to bombard a thin target of curium (95%244Cm and 4.5% 246Cm) with 12C ions to produce 102No according to the 246Cm(12C, 4n) reaction.

In 1957 workers in the United States, Britain, and Sweden announced the discovery of an isotope of element 102 with a 10-minute half-life at 8.5 MeV, as a result of bombarding 244Cm with 13C nuclei. On the basis of this experiment, the name nobelium was assigned and accepted by the Commission on Atomic Weights of the International Union of Pure and Applied Chemistry.

The acceptance of the name was premature because both Russian and American efforts now completely rule out the possibility of any isotope of Element 102 having a half-life of 10 min in the vicinity of 8.5 MeV. Early work in 1957 on the search for this element, in Russia at the Kurchatov Institute, was marred by the assignment of 8.9 +/- 0.4 MeV alpha radiation with a half-life of 2 to 40 sec, which was too indefinite to support discovery claims.

Confirmatory experiments at Berkeley in 1966 have shown the existence of 254102 with a 55-s half-life, 252102 with a 2.3-s half-life, and 257102 with a 23-s half-life.

Following tradition giving the right to name an element to the discoverer(s), the Berkeley group in 1967, suggested that the hastily given name nobelium along with the symbol No , be retained.

画像

性質

物理的性質

ファンデルワールス半径
246 pm 全元素のファンデルワールス半径を比較 →
密度
9900 kg/m³ 全元素の密度を比較 →
標準温度・圧力(STP)での相
固体 全元素の標準温度・圧力(STP)での相を比較 →
融点
826.85 °C 全元素の融点を比較 →

化学的性質

電気陰性度(Pauling)
1.3 全元素の電気陰性度(Pauling)を比較 →
電子親和力
-2.36 eV (負の値—この原子は電子を取り込まないと予測される)
第1イオン化エネルギー
6.62621 eV 全元素の第1イオン化エネルギーを比較 →
第2イオン化エネルギー
12.930045 eV 全元素の第2イオン化エネルギーを比較 →
第3イオン化エネルギー
25.800089 eV 全元素の第3イオン化エネルギーを比較 →
第4イオン化エネルギー
41.500143 eV 全元素の第4イオン化エネルギーを比較 →
第5イオン化エネルギー
60.000207 eV 全元素の第5イオン化エネルギーを比較 →
酸化数
+2, +3 全元素の酸化数を比較 →
価電子
3 全元素の価電子を比較 →
電子配置
[Rn] 7s2 5f14

熱力学的性質

昇華熱
4.042079 eV
原子化熱
4.042079 eV

原子核

陽子数
102 全元素の陽子数を比較 →
中性子数
159 全元素の中性子数を比較 →
既知の同位体
17 全元素の既知の同位体を比較 →
安定同位体
0 全元素の安定同位体を比較 →
質量数(最も安定な同位体)
259
最も安定な同位体
No-261
発見年
1957

存在度

データなし

結晶構造

データなし

電子構造

各電子殻の電子数
2, 8, 18, 32, 32, 8, 2 全元素の各電子殻の電子数を比較 →

識別子

CAS登録番号
10028-14-5 全元素のCAS登録番号を比較 →
項記号
1S0
InChI
InChI=1S/No
InChI Key
ORQBXQOJMQIAOY-UHFFFAOYSA-N

電子配置 測定値

イオンの電荷
陽子 102
電子 102
電荷 中性
電子配置 No: 5f¹⁴ 7s²
電子配置
測定値
[Rn] 5f¹⁴ 7s²
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d¹⁰ 6s² 6p⁶ 5f¹⁴ 7s²
軌道図
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
2/2
4d
10/10
5p
6/6
6s
2/2
4f
14/14
5d
10/10
6p
6/6
7s
2/2
5f
14/14
総電子数: 102 不対電子: 0

原子モデル

陽子 102
中性子 152
電子 102
質量数 254
安定性 放射性

同位体によって中性子数、質量、安定性は変わりますが、中性原子の電子配置は変わりません。

模式的な原子モデルです。実際の縮尺とは異なります。

原子の指紋

発光/吸収スペクトル

0 / 0 (0 強度データあり:0本)
測定値
発光 可視光:380–750 nm

同位体分布

安定同位体はありません。

質量数原子質量(u)天然存在比半減期
251 放射性251.08894 ± 0.00012データなし800 ms
260 放射性260.10264 ± 0.00022データなし106 ms
259 放射性259.10103 ± 0.00011データなし58 分
249 放射性249.0878 ± 0.0003データなし57 us
254 放射性254.090956 ± 0.000011データなし51.2 秒
測定値

相/状態

1 atm / 101.325 kPa
固体 25 °C (298.15 K)

理由: 昇華点(826.85 °C)より801.9 °C低い

昇華点 826.85 °C
0 K 現在の温度: 25 °C 6000 K
相変化図

模式図、実際の縮尺とは異なります

固体
気体
昇華
25°C
固体
液体
気体
現在

相転移点

昇華点 文献値
826.85 °C
現在の相 計算値
固体

相転移エネルギー

昇華熱 文献値
4.042079 eV

昇華点で1 molを昇華させるのに必要なエネルギー

密度

基準密度 文献値
9900 kg/m³

標準条件下

現在の密度 計算値
9900 kg/m³

標準条件下

原子スペクトル

全102件中10件を表示しています。 イオンの電荷の昇順で並べています。

準位データの収録状況 ?

イオン電荷準位
No I 02
No II +12
No III +22
No IV +32
No V +42
No VI +52
No VII +62
No VIII +72
No IX +82
No X +92
NIST準位データの収録状況 →
102 No 259

Nobelium — 原子軌道可視化ツール

[Rn]7s25f14
エネルギー準位 2 8 18 32 32 8 2
酸化数 +2, +3
HOMO 7s n=7 · l=0 · m=0
Nobelium — 原子軌道可視化ツールのプレビュー
Three.jsは必要な場合にのみ読み込まれます
102 No 259

Nobelium — 結晶構造可視化ツール

結晶構造のデータはありません

イオン半径

電荷配位スピン半径
+26データなし110.00000000000001 pm
+39データなし108.5 pm

化合物

No
259.101 u

同位体 (5)

Ten isotopes are now recognized, one of which 255102 has a half-life of 3 minutes.

質量数原子質量(u)天然存在比半減期崩壊形式
251 放射性251.08894 ± 0.00012データなし800 ms
α =83±1.6%β+ ?SF<0.3%
260 放射性260.10264 ± 0.00022データなし106 ms
SF =100%
259 放射性259.10103 ± 0.00011データなし58 分
α =75±0.4%ε =25±0.4%SF<10%
249 放射性249.0878 ± 0.0003データなし57 us
β+ ?α ?
254 放射性254.090956 ± 0.000011データなし51.2 秒
α =90±0.1%β+ =10±0.1%SF =0.17±0.2%
251 放射性
原子質量(u) 251.08894 ± 0.00012
天然存在比 データなし
半減期 800 ms
崩壊形式
α =83±1.6%β+ ? +1
260 放射性
原子質量(u) 260.10264 ± 0.00022
天然存在比 データなし
半減期 106 ms
崩壊形式
SF =100%
259 放射性
原子質量(u) 259.10103 ± 0.00011
天然存在比 データなし
半減期 58 分
崩壊形式
α =75±0.4%ε =25±0.4% +1
249 放射性
原子質量(u) 249.0878 ± 0.0003
天然存在比 データなし
半減期 57 us
崩壊形式
β+ ?α ?
254 放射性
原子質量(u) 254.090956 ± 0.000011
天然存在比 データなし
半減期 51.2 秒
崩壊形式
α =90±0.1%β+ =10±0.1% +1

詳細な性質

共有結合半径(詳細)

共有結合半径(Pyykkö)
176 pm

ファンデルワールス半径

UFF
324.8 pm

番号付けの尺度

Mendeleev
40
Pettifor
35
Glawe
46

電気陰性度の尺度

Ghosh
0

分極率と分散

双極子分極率
110 a.u.
双極子分極率(不確かさ)
6 a.u.

相転移と同素体

融点1100.15 K

酸化数の分類

+2 extended
+3 main

専門参考データ

結晶半径の詳細 (2)
電荷CNスピンrcrystal (pm)由来
2VI124estimated,
3IX—122.5
同位体の崩壊形式 (39)
同位体モード強度
248SF—
249B+—
249A—
250SF100%
250A—
250B+—
251A83%
251B+—
251SF0.3%
252A67.6%

追加データ

参考文献

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
No

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Nobelium

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

ライセンスに関する注記: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Nobelium

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

ライセンスに関する注記: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Nobelium

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Nobelium

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Nobelium

This section provides all form of data related to element Nobelium.

9 PubChem Elements
Nobelium

The element property data was retrieved from publications.

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