Nobelium (No)
actinideSolid
標準原子量
[259]電子配置
[Rn] 7s2 5f14融点
826.85 °C沸点
データなし密度
9900 kg/m³酸化数
+2, +3電気陰性度(Pauling)
1.3第1イオン化エネルギー
6.62621 eV発見年
1957原子半径
データなし詳細
Nobelium is a synthetic actinide with atomic number 102. It is produced only in particle-accelerator experiments and is studied in atom-at-a-time quantities. Its longest-lived confirmed isotopes have half-lives of only minutes, so no macroscopic sample or ordinary material application exists. Chemically, nobelium is notable because the +2 oxidation state is unusually stable for an actinide, in contrast to the more common +3 state of many neighboring elements.
Nobelium does not occur naturally in the Earth’s crust. It was first synthesized in 1966 by Russian scientists from the Joint Institute for Nuclear Research (JINR) in Dubna, Russia under Georgi Flerov. Earlier claims to have synthesized “nobelium” beginning in 1957 were shown to be erroneous. This element was originally named for Alfred Nobel (Fig. IUPAC.102.1), the inventor of dynamite and founder of the Nobel prizes. The name was later retained because of its widespread use throughout the scientific literature [636], [638]. There are no uses for isotopes of nobelium outside of scientific research.
Nobelium is named after Alfred Nobel.
In 1957, a group of scientists working at the Nobel Institute of Physics in Stockhlom, Sweden, announced the discovery of a new element. They produced this new element, which they named nobelium, by bombarding a target of curium-244 with ions of carbon-13 with a device called a cyclotron. The isotope they created had a half-life of 10 minutes. In 1958, another group of scientists, Albert Ghiorso, Glenn T. Seaborg, Torbørn Sikkeland and John R. Walton, working at the Lawrence Radiation Laboratory in Berkeley, California, attempted to confirm the Nobel Institute's discovery. They were unable to produce any isotope of nobelium with a half-life of 10 minutes, but were able to produce nobelium-254, with a half-life of three seconds, by bombarding curium-246 with carbon-12. A third group, working at the Joint Institute for Nuclear Research in Dubna, Russia, also could not duplicate the Nobel Institute's work but were able to confirm the Berkeley group's work. Credit for discovering nobelium was eventually given to the scientists working at Lawrence Radiation Laboratory, who decided to keep the name nobelium. Today, the Lawrence Radiation Laboratory is known as the Lawrence Berkeley Laboratory. Nobelium's most stable isotope, nobelium-259, has a half-life of about 58 minutes. It decays into fermium-255 through alpha decay, into mendelevium-259 through electron capture or through spontaneous fission.
Named after Alfred Nobel, inventor of dynamite. Nobelium was unambiguously discovered and identified in April 1958 at Berkeley by A. Ghiorso, T. Sikkeland, J.R. Walton, and G.T. Seaborg, who used a new double-recoil technique. A heavy-ion linear accelerator (HILAC) was used to bombard a thin target of curium (95%244Cm and 4.5% 246Cm) with 12C ions to produce 102No according to the 246Cm(12C, 4n) reaction.
In 1957 workers in the United States, Britain, and Sweden announced the discovery of an isotope of element 102 with a 10-minute half-life at 8.5 MeV, as a result of bombarding 244Cm with 13C nuclei. On the basis of this experiment, the name nobelium was assigned and accepted by the Commission on Atomic Weights of the International Union of Pure and Applied Chemistry.
The acceptance of the name was premature because both Russian and American efforts now completely rule out the possibility of any isotope of Element 102 having a half-life of 10 min in the vicinity of 8.5 MeV. Early work in 1957 on the search for this element, in Russia at the Kurchatov Institute, was marred by the assignment of 8.9 +/- 0.4 MeV alpha radiation with a half-life of 2 to 40 sec, which was too indefinite to support discovery claims.
Confirmatory experiments at Berkeley in 1966 have shown the existence of 254102 with a 55-s half-life, 252102 with a 2.3-s half-life, and 257102 with a 23-s half-life.
Following tradition giving the right to name an element to the discoverer(s), the Berkeley group in 1967, suggested that the hastily given name nobelium along with the symbol No , be retained.
The bulk appearance of nobelium is unknown, because it has never been isolated as a visible sample. Metallic nobelium is expected to be a dense, silvery actinide metal by analogy with neighboring elements, but this is a prediction rather than an observed property.
Nobelium has no practical use outside scientific research. Individual atoms are produced to study heavy-element nuclear stability, decay chains, and relativistic effects in actinide chemistry. Its isotopes have also served as links in identifying the decay products of heavier synthetic elements. These uses rely on rapid radiochemical separation and radiation detection, not on bulk nobelium metal or compounds.
Since only tiny amounts of nobelium have ever been produced, there are currently no uses for it outside of basic scientific research.
Nobelium chemistry has been examined mainly in aqueous tracer experiments. The divalent ion No²⁺ is the best-established chemically distinctive form and behaves in some separations more like alkaline earth ions than typical trivalent actinides. The trivalent ion No³⁺ is also known, but it is less favored in reducing aqueous systems. Specific bulk compounds such as nobelium(II) chloride, NoCl₂, or nobelium(III) oxide, No₂O₃, have not been isolated as macroscopic materials; their properties are inferred from trace chemistry and theory.
See more information at the Nobelium compound page.
All known nobelium isotopes are radioactive, and several decay by alpha emission or spontaneous fission. The element is made in quantities far too small to create ordinary chemical toxicity hazards outside specialized laboratories, but radiological precautions are essential during production and detection work. Safety considerations are isotope-specific because half-lives and decay modes vary widely.
Nobelium has no confirmed natural environmental reservoir. Any atoms produced on Earth are artificial and decay rapidly compared with geological or ecological timescales. Because only atom-scale amounts are generated in shielded research facilities, nobelium has no known role in biogeochemical cycles and no observed environmental transport behavior as a bulk contaminant.
Nobelium is not a traded commodity and has no commercial supply chain. It is made by bombarding heavy actinide targets, commonly curium or californium isotopes, with accelerated light ions under conditions optimized for a desired isotope. Production yields are extremely small, and separation must occur quickly because of radioactive decay. The limiting factors are accelerator access, rare target materials, radiochemical expertise, and detector time rather than market demand, recycling, or substitution.
Made by bombarding curium with carbon-13
Nobelium is not expected to have a persistent cosmic abundance. Its known isotopes are too short-lived to survive from stellar nucleosynthesis to the present, and no stable isotope is known. If formed transiently in extreme neutron-rich events or by artificial nuclear reactions, nobelium would decay rapidly into lighter nuclei.
- Nobelium was named for Alfred Nobel, the inventor and industrial chemist associated with the Nobel Prizes.
- The isotope ²⁵⁹No is among the longest-lived known nobelium isotopes, with a half-life of about an hour.
- Nobelium helped show that the +2 state can become strongly stabilized late in the actinide series.
- Most nobelium experiments detect decay events from individual atoms rather than weighing a sample.
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性質
物理的性質
- ファンデルワールス半径
- 246 pm 全元素のファンデルワールス半径を比較 →
- 密度
- 9900 kg/m³ 全元素の密度を比較 →
- 標準温度・圧力(STP)での相
- 固体 全元素の標準温度・圧力(STP)での相を比較 →
- 融点
- 826.85 °C 全元素の融点を比較 →
化学的性質
- 電気陰性度(Pauling)
- 1.3 全元素の電気陰性度(Pauling)を比較 →
- 電子親和力
- -2.36 eV (負の値—この原子は電子を取り込まないと予測される)
- 第1イオン化エネルギー
- 6.62621 eV 全元素の第1イオン化エネルギーを比較 →
- 第2イオン化エネルギー
- 12.930045 eV 全元素の第2イオン化エネルギーを比較 →
- 第3イオン化エネルギー
- 25.800089 eV 全元素の第3イオン化エネルギーを比較 →
- 第4イオン化エネルギー
- 41.500143 eV 全元素の第4イオン化エネルギーを比較 →
- 第5イオン化エネルギー
- 60.000207 eV 全元素の第5イオン化エネルギーを比較 →
- 酸化数
- +2, +3 全元素の酸化数を比較 →
- 価電子
- 3 全元素の価電子を比較 →
- 電子配置
- [Rn] 7s2 5f14
熱力学的性質
- 昇華熱
- 4.042079 eV
- 原子化熱
- 4.042079 eV
原子核
- 陽子数
- 102 全元素の陽子数を比較 →
- 中性子数
- 159 全元素の中性子数を比較 →
- 既知の同位体
- 17 全元素の既知の同位体を比較 →
- 安定同位体
- 0 全元素の安定同位体を比較 →
- 質量数(最も安定な同位体)
- 259
- 最も安定な同位体
- No-261
- 発見年
- 1957
存在度
データなし
結晶構造
データなし
電子構造
- 各電子殻の電子数
- 2, 8, 18, 32, 32, 8, 2 全元素の各電子殻の電子数を比較 →
識別子
- CAS登録番号
- 10028-14-5 全元素のCAS登録番号を比較 →
- 項記号
- 1S0
- InChI
- InChI=1S/No
- InChI Key
- ORQBXQOJMQIAOY-UHFFFAOYSA-N
電子配置 測定値
No: 5f¹⁴ 7s²[Rn] 5f¹⁴ 7s²1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d¹⁰ 6s² 6p⁶ 5f¹⁴ 7s²原子モデル
同位体によって中性子数、質量、安定性は変わりますが、中性原子の電子配置は変わりません。
模式的な原子モデルです。実際の縮尺とは異なります。
原子の指紋
発光/吸収スペクトル
同位体分布
安定同位体はありません。
| 質量数 | 原子質量(u) | 天然存在比 | 半減期 |
|---|---|---|---|
| 251 放射性 | 251.08894 ± 0.00012 | データなし | 800 ms |
| 260 放射性 | 260.10264 ± 0.00022 | データなし | 106 ms |
| 259 放射性 | 259.10103 ± 0.00011 | データなし | 58 分 |
| 249 放射性 | 249.0878 ± 0.0003 | データなし | 57 us |
| 254 放射性 | 254.090956 ± 0.000011 | データなし | 51.2 秒 |
相/状態
理由: 昇華点(826.85 °C)より801.9 °C低い
模式図、実際の縮尺とは異なります
相転移点
相転移エネルギー
昇華点で1 molを昇華させるのに必要なエネルギー
密度
標準条件下
標準条件下
原子スペクトル
全102件中10件を表示しています。 イオンの電荷の昇順で並べています。
準位データの収録状況 ?
| イオン | 電荷 | 準位 |
|---|---|---|
| No I | 0 | 2 |
| No II | +1 | 2 |
| No III | +2 | 2 |
| No IV | +3 | 2 |
| No V | +4 | 2 |
| No VI | +5 | 2 |
| No VII | +6 | 2 |
| No VIII | +7 | 2 |
| No IX | +8 | 2 |
| No X | +9 | 2 |
結晶構造のデータはありません
イオン半径
| 電荷 | 配位 | スピン | 半径 |
|---|---|---|---|
| +2 | 6 | データなし | 110.00000000000001 pm |
| +3 | 9 | データなし | 108.5 pm |
化合物
同位体 (5)
Ten isotopes are now recognized, one of which 255102 has a half-life of 3 minutes.
| 質量数 | 原子質量(u) | 天然存在比 | 半減期 | 崩壊形式 | |
|---|---|---|---|---|---|
| 251 放射性 | 251.08894 ± 0.00012 | データなし | 800 ms | α =83±1.6%β+ ?SF<0.3% | |
| 260 放射性 | 260.10264 ± 0.00022 | データなし | 106 ms | SF =100% | |
| 259 放射性 | 259.10103 ± 0.00011 | データなし | 58 分 | α =75±0.4%ε =25±0.4%SF<10% | |
| 249 放射性 | 249.0878 ± 0.0003 | データなし | 57 us | β+ ?α ? | |
| 254 放射性 | 254.090956 ± 0.000011 | データなし | 51.2 秒 | α =90±0.1%β+ =10±0.1%SF =0.17±0.2% |
詳細な性質
共有結合半径(詳細)
- 共有結合半径(Pyykkö)
- 176 pm
ファンデルワールス半径
- UFF
- 324.8 pm
番号付けの尺度
- Mendeleev
- 40
- Pettifor
- 35
- Glawe
- 46
電気陰性度の尺度
- Ghosh
- 0
分極率と分散
- 双極子分極率
- 110 a.u.
- 双極子分極率(不確かさ)
- 6 a.u.
相転移と同素体
| 融点 | 1100.15 K |
酸化数の分類
専門参考データ
結晶半径の詳細 (2)
| 電荷 | CN | スピン | rcrystal (pm) | 由来 |
|---|---|---|---|---|
| 2 | VI | 124 | estimated, | |
| 3 | IX | — | 122.5 |
同位体の崩壊形式 (39)
| 同位体 | モード | 強度 |
|---|---|---|
| 248 | SF | — |
| 249 | B+ | — |
| 249 | A | — |
| 250 | SF | 100% |
| 250 | A | — |
| 250 | B+ | — |
| 251 | A | 83% |
| 251 | B+ | — |
| 251 | SF | 0.3% |
| 252 | A | 67.6% |
追加データ
Estimated Crustal Abundance
The estimated element abundance in the earth's crust.
Not Applicable
参考文献 (1)
- [5] Nobelium https://education.jlab.org/itselemental/ele102.html
Estimated Oceanic Abundance
The estimated element abundance in the earth's oceans.
Not Applicable
参考文献 (1)
- [5] Nobelium https://education.jlab.org/itselemental/ele102.html
参考文献
(9)
Data deposited in or computed by PubChem
The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.
Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.
The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.
Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/
The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.
The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database
This section provides all form of data related to element Nobelium.
The element property data was retrieved from publications.
