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Ir 77

Iridium (Ir)

transition-metal
Periode: 6 Golongan: 9 Blok: d

Solid

Bobot Atom Standar

192,217 u

Konfigurasi elektron

[Xe] 6s2 4f14 5d7

Titik lebur

2445,85 °C

Titik didih

4427,85 °C

Massa jenis

2,25622e+4 kg/m³

Bilangan oksidasi

−3, −2, −1, +1, +2, +3, +4, +5, +6, +7, +8, +9

Keelektronegatifan (Pauling)

2,2

Energi ionisasi (ke-1)

8,96702 eV

Tahun penemuan

1803

Jari-jari atom

135 pm

Detail

Asal nama Latin: iris (rainbow).
Negara penemuan England/France
Penemu S.Tenant, A.F.Fourcory, L.N.Vauquelin, H.V.Collet-Descoltils

Iridium is a very dense platinum-group transition metal with exceptional resistance to corrosion and high-temperature attack. It occurs naturally mainly with platinum-group minerals and in nickel-copper sulfide ores. Chemically it forms robust complexes, especially in oxidation states +3 and +4, and it is notable for the global iridium anomaly associated with the Cretaceous-Paleogene boundary impact layer.

Iridium, a metal of the platinum family, is white (similar to platinum) but with a slight yellowish cast. Because iridium is very hard and brittle, it is hard to machine, form, or work.

It is the most corrosion-resistant metal known, and was used in making the standard meter bar of Paris, which is a 90 percent platinum and 10 percent iridium alloy. This meter bar was replaced in 1960 as a fundamental unit of length (see Krypton).

Iridium is not attacked by any of the acids nor by aqua regia, but is attacked by molten salts, such as NaCl and NaCN. The specific gravity of iridium is to osmium's specific gravity. Calculations of the densities of iridium and osmium from the space lattices give values of 22.65 and 22.61 g/cm^3, respectively. These values may be more reliable than actual physical measurements for determining which element is heavier.

The name derives from the Latin Iris, the Greek goddess of rainbows, because of the variety of colours in the element's salt solutions. Iridium and osmium were both discovered in a crude platinum ore in 1803 by the English chemist Smithson Tennant. Iridium was discovered independently by the French chemist H. V. Collet-Descotils, who actually published his paper one month before Tennant, but Tennant is given credit for the discovery, perhaps because he alone also found osmium in the ore.

Iridium and osmium were discovered at the same time by the British chemist Smithson Tennant in 1803. Iridium and osmium were identified in the black residue remaining after dissolving platinum ore with aqua regia, a mixture of 25% nitric acid (HNO3) and 75% hydrochloric acid (HCl). Today, iridium is still obtained from platinum ores and as a by-product of mining nickel.

From the Latin word iris meaning rainbow. Tennant discovered iridium in 1803 in the residue left when crude platinum is dissolved by aqua regia. The name iridium is appropriate because its salts are highly colored.

Gambar

Sifat

Fisika

Jari-jari atom (empiris)
135 pm Bandingkan Jari-jari atom (empiris) semua unsur →
Jari-jari kovalen
141 pm Bandingkan Jari-jari kovalen semua unsur →
Jari-jari van der Waals
202 pm Bandingkan Jari-jari van der Waals semua unsur →
Jari-jari logam
127 pm Bandingkan Jari-jari logam semua unsur →
Massa jenis
2,25622 × 104 kg/m³ Bandingkan Massa jenis semua unsur →
Volume molar
0,00854 L/mol
Fase pada STP
Padat Bandingkan Fase pada STP semua unsur →
Titik lebur
2445,85 °C Bandingkan Titik lebur semua unsur →
Titik didih
4427,85 °C Bandingkan Titik didih semua unsur →
Konduktivitas termal
147 W/(m·K) Bandingkan Konduktivitas termal semua unsur →
Kapasitas kalor spesifik
0,131 J/(g·K) Bandingkan Kapasitas kalor spesifik semua unsur →
Kapasitas kalor molar
25,1 J/(mol·K) Bandingkan Kapasitas kalor molar semua unsur →
Struktur kristal
Kubik berpusat muka Bandingkan Struktur kristal semua unsur →

Kimia

Keelektronegatifan (Pauling)
2,2 Bandingkan Keelektronegatifan (Pauling) semua unsur →
Keelektronegatifan (Allen)
1,68
Afinitas elektron
1,565 eV
Energi ionisasi (ke-1)
8,96702 eV Bandingkan Energi ionisasi (ke-1) semua unsur →
Energi ionisasi (ke-2)
17,000059 eV Bandingkan Energi ionisasi (ke-2) semua unsur →
Energi ionisasi (ke-3)
28,000096 eV Bandingkan Energi ionisasi (ke-3) semua unsur →
Energi ionisasi (ke-4)
40,000138 eV Bandingkan Energi ionisasi (ke-4) semua unsur →
Energi ionisasi (ke-5)
57,000196 eV Bandingkan Energi ionisasi (ke-5) semua unsur →
Bilangan oksidasi
−3, −2, −1, +1, +2, +3, +4, +5, +6, +7, +8, +9 Bandingkan Bilangan oksidasi semua unsur →
Elektron valensi
9 Bandingkan Elektron valensi semua unsur →
Konfigurasi elektron
[Xe] 6s2 4f14 5d7

Termodinamika

Kalor peleburan
0,27050837 eV Bandingkan Kalor peleburan semua unsur →
Kalor penguapan
6,26004 eV Bandingkan Kalor penguapan semua unsur →
Kalor sublimasi
6,944085 eV
Kalor atomisasi
6,944085 eV
Entalpi atomisasi
6,93372 eV

Nuklir

Proton
77 Bandingkan Proton semua unsur →
Neutron
116 Bandingkan Neutron semua unsur →
Isotop yang diketahui
43 Bandingkan Isotop yang diketahui semua unsur →
Isotop stabil
2 Bandingkan Isotop stabil semua unsur →
Isotop paling stabil
Ir-193
Tahun penemuan
1803

Kelimpahan

Kelimpahan (kerak Bumi)
0,001 mg/kg Bandingkan Kelimpahan (kerak Bumi) semua unsur →

Struktur Kristal

Konstanta kisi a
384 pm

Struktur Elektronik

Elektron per kulit
2, 8, 18, 32, 15, 2 Bandingkan Elektron per kulit semua unsur →

Pengenal

Nomor CAS
7439-88-5 Bandingkan Nomor CAS semua unsur →
Simbol term
4F9/2
InChI
InChI=1S/Ir
Kunci InChI
GKOZUEZYRPOHIO-UHFFFAOYSA-N

Konfigurasi Elektron Diukur

Muatan ion
Proton 77
Elektron 77
Muatan Netral
Konfigurasi Ir: 4f¹⁴ 5d⁷ 6s²
Konfigurasi elektron
Diukur
[Xe] 4f¹⁴ 5d⁷ 6s²
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d⁷ 6s²
Diagram orbital
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
2/2
4d
10/10
5p
6/6
6s
2/2
4f
14/14
5d
7/10 3↑
Total elektron: 77 Tidak berpasangan: 3 ?

Model atom

Proton 77
Neutron 116
Elektron 77
Nomor massa 193
Kestabilan Stabil

Isotop mengubah jumlah neutron, massa, dan kestabilan — bukan konfigurasi elektron atom netral.

Model atom skematis, tidak sesuai skala.

Sidik Jari Atom

Spektrum Emisi / Absorpsi

24 / 24 (17 17 dengan intensitas)
Diukur
Emisi Tampak: 380–750 nm

Distribusi Isotop

19362,7000%19137,3000%Nomor massaKelimpahan alami (%)
Nomor massaMassa atom (u)Kelimpahan alamiWaktu paruh
191 Stabil190,9605893 ± 0,000002137,3000%Stabil
193 Stabil192,9629216 ± 0,000002162,7000%Stabil
Diukur

Fase / Wujud

1 atm / 101.325 kPa
Padat 25 °C (298,15 K)

Alasan: 2420,8 °C di bawah titik lebur (2445,85 °C)

Titik lebur 2445,85 °C
Titik didih 4427,85 °C
Di bawah titik lebur sebesar 2420,8 °C
0 K Suhu saat ini: 25 °C 6000 K
Linimasa fase

Skematis, tidak sesuai skala

Padat
Cair
Gas
Peleburan
Pendidihan
25°C
Padat
Cair
Gas
Saat ini

Titik transisi fase

Titik lebur Literatur
2445,85 °C
Titik didih Literatur
4427,85 °C
Fase saat ini Dihitung
Padat

Energi transisi

Kalor peleburan Literatur
0,27050837 eV

Energi yang diperlukan untuk meleburkan 1 mol pada titik lebur

Kalor penguapan Literatur
6,26004 eV

Energi yang diperlukan untuk menguapkan 1 mol pada titik didih

Kalor sublimasi Literatur
6,944085 eV

Energi yang diperlukan untuk menyublimkan 1 mol pada titik sublimasi

Massa jenis

Massa jenis referensi Literatur
2,25622e+4 kg/m³

Pada kondisi standar

Massa jenis saat ini Dihitung
2,25622e+4 kg/m³

Pada kondisi standar

Spektrum Atom

Menampilkan 10 dari 77. Diurutkan berdasarkan muatan ion (menaik).

Data Garis Spektrum ?

IonMuatanTotal garisProbabilitas transisiPenamaan tingkat energi
Ir I 040270398
Ir II +1473129473
Ir IV +3137413741374
Data Garis Spektrum NIST →

Data Tingkat Energi ?

IonMuatanTingkat energi
Ir I 0231
Ir II +176
Ir III +22
Ir IV +3224
Ir V +42
Ir VI +52
Ir VII +62
Ir VIII +72
Ir IX +82
Ir X +92
Data Tingkat Energi NIST →
77 Ir 192.217

Iridium — Visualisasi Orbital Atom

[Xe]6s24f145d7
Tingkat energi 2 8 18 32 15 2
Bilangan oksidasi -3, -2, -1, +1, +2, +3, +4, +5, +6, +7, +8, +9
HOMO 5d n=5 · l=2 · m=-2
Iridium — Pratinjau Visualisasi Orbital Atom
Three.js hanya dimuat saat diminta
77 Ir 192.217

Iridium — Visualisasi Struktur Kristal

Face-Centered Cubic · Pearson cF4
Eksperimental
Pearson cF4
No. Koord. 12
Pengemasan 74.000%
Iridium — Pratinjau Visualisasi Struktur Kristal
Three.js hanya dimuat saat diminta

Jari-jari Ion

MuatanKoordinasiSpinJari-jari
+36Tidak tersedia68 pm
+46Tidak tersedia62.5 pm
+56Tidak tersedia56.99999999999999 pm

Senyawa

Ir
192,220 u
Ir
191,963 u
Ir+3
192,220 u
Ir
193,965 u
Ir
183,958 u
Ir
190,961 u
Ir
187,959 u
Ir
186,958 u
Ir
194,966 u
Ir
188,959 u
Ir
185,958 u
Ir
181,958 u
Ir
192,963 u
Ir
189,961 u
Ir
184,957 u

Isotop (2)

Nomor massaMassa atom (u)Kelimpahan alamiWaktu paruhMode peluruhan
191 Stabil190,9605893 ± 0,000002137,3000% ± 0,2000%Stabil
stable
193 Stabil192,9629216 ± 0,000002162,7000% ± 0,2000%Stabil
stable
191 Stabil
Massa atom (u) 190,9605893 ± 0,0000021
Kelimpahan alami 37,3000% ± 0,2000%
Waktu paruh Stabil
Mode peluruhan
stable
193 Stabil
Massa atom (u) 192,9629216 ± 0,0000021
Kelimpahan alami 62,7000% ± 0,2000%
Waktu paruh Stabil
Mode peluruhan
stable

Garis Spektrum

Panjang gelombang (nm)IntensitasTahap ionisasiJenisTransisiAkurasiSumber
382.7577 nm58Ir IIemission5d7.(2D2).6s 3D → 5d7.(4F<5/2>).6p (5/2,1/2)*DiukurNIST
384.593 nmTidak tersediaIr IIemission5d7.(2G).6s 1G → 5d7.(4F<9/2>).6p (9/2,3/2)*DiukurNIST
387.3624 nm9Ir IIemission5d6.6s2 5D → 5d7.(4P<5/2>).6p (5/2,1/2)*DiukurNIST
389.558 nmTidak tersediaIr IIemission5d6.6s2 5D → 5d7.(4F<7/2>).6p (7/2,1/2)*DiukurNIST
395.1973 nmTidak tersediaIr IIemission5d6.6s2 5D → 5d7.(4F<9/2>).6p (9/2,1/2)*DiukurNIST
395.2882 nm8Ir IIemission5d7.(2H).6s 3H → 5d6.6s.(6D<9/2>).6p (9/2,1/2)*DiukurNIST
397.882 nm6Ir IIemission5d7.(2F).6s 3F → 5664*DiukurNIST
398.6377 nm5Ir IIemission5d6.6s2 5D → 5d7.(4F<3/2>).6p (3/2,1/2)*DiukurNIST
399.0389 nm6Ir IIemission5d6.6s2 3H → 6197*DiukurNIST
400.1961 nm12Ir IIemission5d7.(2D2).6s 3D → 5d7.(4P<5/2>).6p (5/2,1/2)*DiukurNIST
402.5321 nm4Ir IIemission5d7.(2F).6s 3F → 5d6.6s.(6D<5/2>).6p (5/2,1/2)*DiukurNIST
402.5399 nm29Ir IIemission5d7.(2D2).6s 3D → 5d7.(4F<7/2>).6p (7/2,1/2)*DiukurNIST
404.1381 nm45Ir IIemission5d7.(2H).6s 3H → 5d7.(4F<9/2>).6p (9/2,1/2)*DiukurNIST
404.4911 nm7Ir IIemission5d7.(2F).6s 3F → 5d7.(4F<9/2>).6p (9/2,3/2)*DiukurNIST
410.8315 nm48Ir IIemission5d7.(2F).6s 3F → 5d7.(4F<5/2>).6p (5/2,1/2)*DiukurNIST
411.7209 nm3Ir IIemission5d7.(2G).6s 3G → 5d7.(4F<9/2>).6p (9/2,1/2)*DiukurNIST
412.8911 nm17Ir IIemission5d7.(2P).6s 3P → 5d7.(4P<1/2>).6p (1/2,1/2)*DiukurNIST
413.91 nm21Ir IIemission5d7.(2P).6s 3P → 5d7.(4F<9/2>).6p (9/2,3/2)*DiukurNIST
439.0196 nm4Ir IIemission5d6.6s2 5D → 5d7.(4P<5/2>).6p (5/2,1/2)*DiukurNIST
443.3888 nmTidak tersediaIr IIemission5d7.(2F).6s 3F → 5d6.6s.(6D<7/2>).6p (7/2,1/2)*DiukurNIST
454.5672 nmTidak tersediaIr IIemission5d7.(2H).6s 3H → 5d7.(4F<9/2>).6p (9/2,1/2)*DiukurNIST
461.1752 nmTidak tersediaIr IIemission5d7.(2F).6s 3F → 5d7.(4P<5/2>).6p (5/2,1/2)*DiukurNIST
467.5844 nm5Ir IIemission5d7.(2G).6s 3G → 5d7.(4F<9/2>).6p (9/2,1/2)*DiukurNIST
479.5262 nmTidak tersediaIr IIemission5d6.6s2 5D → 5d7.(4F<9/2>).6p (9/2,1/2)*DiukurNIST

Sifat Lanjutan

Jari-jari Kovalen (Lanjutan)

Jari-jari kovalen (Pyykkö)
122 pm
Jari-jari kovalen (Pyykkö, ikatan rangkap dua)
115 pm
Jari-jari kovalen (Pyykkö, ikatan rangkap tiga)
107 pm

Jari-jari van der Waals

Batsanov
200 pm
Alvarez
241 pm
UFF
284 pm
MM3
236 pm

Jari-jari Atom & Logam

Jari-jari atom (Rahm)
240 pm
Jari-jari logam (C12)
136 pm

Skala Penomoran

Mendeleev
65
Pettifor
65
Glawe
62

Skala Keelektronegatifan

Ghosh
0
Miedema
6
Gunnarsson–Lundqvist
6
Robles–Bartolotti
6

Polarizabilitas & Dispersi

Polarizabilitas dipol
54 a.u.
Polarizabilitas dipol (ketidakpastian)
7 a.u.
C₆ (Gould–Bučko)
522 Ha·Bohr6

Parameter Miedema

Volume molar Miedema
8,52 cm3/mol
Kerapatan elektron Miedema
6

Risiko Pasokan & Ekonomi

Konsentrasi produksi
60
Risiko pasokan relatif
8
Distribusi cadangan
95
Stabilitas politik (produsen terbesar)
44
Stabilitas politik (pemilik cadangan terbesar)
44

Transisi Fase & Alotrop

Titik lebur2719,15 K
Titik didih4701,15 K

Kategori Bilangan Oksidasi

+5 extended
−2 extended
−1 extended
+7 extended
+6 extended
+4 main
−3 extended
+9 extended
+3 main
+8 extended
+2 extended
+1 extended

Data Referensi Lanjutan

Konstanta Pemerisaian (14)
nOrbitalσ
1s1,4881
2p4,4624
2s20,1102
3d13,514
3p21,9311
3s22,7942
4d37,2628
4f38,6552
4p35,086
4s34,152
Detail Jari-jari Kristal (3)
MuatanCNSpinrcrystal (pm)Asal
3VI82estimated,
4VI76,5from r^3 vs V plots,
5VI71estimated, from metallic oxides,
Mode Peluruhan Isotop (64)
IsotopModeIntensitas
163p—
164p—
164A—
164B+—
165p—
165A—
166A93%
166p7%
167A43,5%
167p38,6%
Faktor Hamburan Sinar-X (515)
Energi (eV)f₁f₂
10—2,22753
10,1617—2,30683
10,3261—2,38895
10,4931—2,474
10,6628—2,56207
10,8353—2,65417
11,0106—2,75003
11,1886—2,84935
11,3696—2,94781
11,5535—3,0118

Data Tambahan

Sources

Sources of this element.

Iridium occurs uncombined in nature with platinum and other metals of this family in alluvial deposits. It is recovered as a by-product from the nickel mining industry.

Referensi (1)

Referensi

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
Ir

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Iridium

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

Catatan lisensi: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Iridium

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

Catatan lisensi: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Iridium

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Iridium

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Iridium

This section provides all form of data related to element Iridium.

9 PubChem Elements
Iridium

The element property data was retrieved from publications.

Terakhir diperbarui:

Data terverifikasi:

Konten ditinjau berdasarkan data ilmiah terbaru.