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W 74

Tungsten (W)

transition-metal
Periode: 6 Golongan: 6 Blok: d

Solid

Bobot Atom Standar

183,84 u

Konfigurasi elektron

[Xe] 6s2 4f14 5d4

Titik lebur

3421,85 °C

Titik didih

5554,85 °C

Massa jenis

1,93e+4 kg/m³

Bilangan oksidasi

−4, −2, −1, 0, +1, +2, +3, +4, +5, +6

Keelektronegatifan (Pauling)

2,36

Energi ionisasi (ke-1)

7,86403 eV

Tahun penemuan

1781

Jari-jari atom

135 pm

Detail

Asal nama Swedish: tung sten (heavy stone): symbol from its German name wolfram.
Negara penemuan Spain
Penemu Fausto and Juan José de Elhuyar

Tungsten is a dense, refractory transition metal in group 6. It has the highest melting point of any element and retains strength at temperatures where most engineering metals soften. Chemically it is best known for stable high oxidation states, especially +6, and for forming hard carbides and complex oxoanions. Natural tungsten occurs mainly in tungstate minerals rather than as the native metal.

Pure tungsten is a steel-gray to tin-white metal. Very pure tungsten can be cut with a hacksaw, forged, spun, drawn, and extruded. The impure metal is brittle and can be worked only with difficulty. Tungsten has the highest melting point of all metals, and at temperatures over 1650°C has the highest tensile strength. The metal oxidizes in air and must be protected at elevated temperatures. It has excellent corrosion resistance and is attacked only slightly by most mineral acids. The thermal expansion is about the same as borosilicate glass, which makes the metal useful for glass-to-metal seals.

The name derives from the Swedish tungsten for "heavy stone". The symbol W derives from the German wolfram, which was found with tin and interfered with the smelting of tin. It was said to eat up tin like a wolf eats up sheep. The element was discovered by the Swedish pharmacist and chemist Carl-Wilhelm Scheele in 1781. Tungsten metal was first isolated by the Spanish chemists Fausto Elhuyar and his brother Juan José in 1783.

Tungsten was discovered by Juan José and Fausto Elhuyar, Spanish chemists and brothers, in 1783 in samples of the mineral wolframite ((Fe, Mn)WO4). Today, tungsten is primarily obtained from wolframite and scheelite (CaWO4) using the same basic method developed by José and Elhuyar. Tungsten ores are crushed, cleaned and treated with alkalis to form tungsten trioxide (WO3). Tungsten trioxide is then heated with carbon or hydrogen gas (H2), forming tungsten metal and carbon dioxide (CO2) or tungsten metal and water vapor (H2O).

From Swedish, tung sten meanig heavy stone. In 1779 Peter Woulfe examined the mineral now known as wolframite and concluded it must contain a new substance. Scheele, in 1781, found that a new acid could be made from tungsten (a name first applied about 1758 to a mineral now known as scheelite). Scheele and Berman suggested the possibility of obtaining a new metal by reducing this acid. The de Elhuyar brothers found acid in wolframite in 1783 that was identical to the acid of tungsten (tungstic acid) of Scheele, and in that year they succeeded in obtaining the element by reduction of this acid with charcoal. Tungsten occurs in wolframite, scheelite, huebnertie, and ferberite. Important deposits of tungsten occur in California, Colorado, South Korea, Bolivia, Russia, and Portugal. China is reported to have about 75% of the world's tungsten resources. Natural tungsten contains five stable isotopes. Twenty one other unstable isotopes are recognized. The metal is obtained commercially be reducing tungsten oxide with hydrogen or carbon.

Gambar

Sifat

Fisika

Jari-jari atom (empiris)
135 pm Bandingkan Jari-jari atom (empiris) semua unsur →
Jari-jari kovalen
162 pm Bandingkan Jari-jari kovalen semua unsur →
Jari-jari van der Waals
210 pm Bandingkan Jari-jari van der Waals semua unsur →
Jari-jari logam
130 pm Bandingkan Jari-jari logam semua unsur →
Massa jenis
1,93 × 104 kg/m³ Bandingkan Massa jenis semua unsur →
Volume molar
0,00953 L/mol
Fase pada STP
Padat Bandingkan Fase pada STP semua unsur →
Titik lebur
3421,85 °C Bandingkan Titik lebur semua unsur →
Titik didih
5554,85 °C Bandingkan Titik didih semua unsur →
Konduktivitas termal
173 W/(m·K) Bandingkan Konduktivitas termal semua unsur →
Kapasitas kalor spesifik
0,132 J/(g·K) Bandingkan Kapasitas kalor spesifik semua unsur →
Kapasitas kalor molar
24,27 J/(mol·K) Bandingkan Kapasitas kalor molar semua unsur →
Struktur kristal
Kubik berpusat badan Bandingkan Struktur kristal semua unsur →

Kimia

Keelektronegatifan (Pauling)
2,36 Bandingkan Keelektronegatifan (Pauling) semua unsur →
Keelektronegatifan (Allen)
1,47
Afinitas elektron
0,815 eV
Energi ionisasi (ke-1)
7,86403 eV Bandingkan Energi ionisasi (ke-1) semua unsur →
Energi ionisasi (ke-2)
16,370056 eV Bandingkan Energi ionisasi (ke-2) semua unsur →
Energi ionisasi (ke-3)
26,000089 eV Bandingkan Energi ionisasi (ke-3) semua unsur →
Energi ionisasi (ke-4)
38,200131 eV Bandingkan Energi ionisasi (ke-4) semua unsur →
Energi ionisasi (ke-5)
51,600178 eV Bandingkan Energi ionisasi (ke-5) semua unsur →
Bilangan oksidasi
−4, −2, −1, 0, +1, +2, +3, +4, +5, +6 Bandingkan Bilangan oksidasi semua unsur →
Elektron valensi
6 Bandingkan Elektron valensi semua unsur →
Konfigurasi elektron
[Xe] 6s2 4f14 5d4

Termodinamika

Kalor peleburan
0,36482355 eV Bandingkan Kalor peleburan semua unsur →
Kalor penguapan
8,360885 eV Bandingkan Kalor penguapan semua unsur →
Kalor sublimasi
8,803441 eV
Kalor atomisasi
8,803441 eV
Entalpi atomisasi
8,820024 eV

Nuklir

Proton
74 Bandingkan Proton semua unsur →
Neutron
110 Bandingkan Neutron semua unsur →
Isotop yang diketahui
41 Bandingkan Isotop yang diketahui semua unsur →
Isotop stabil
0 Bandingkan Isotop stabil semua unsur →
Isotop paling stabil
W-184
Tahun penemuan
1781

Kelimpahan

Kelimpahan (kerak Bumi)
1,25 mg/kg Bandingkan Kelimpahan (kerak Bumi) semua unsur →
Kelimpahan (samudra)
1 × 10−4 mg/L Bandingkan Kelimpahan (samudra) semua unsur →

Struktur Kristal

Konstanta kisi a
316 pm

Struktur Elektronik

Elektron per kulit
2, 8, 18, 32, 12, 2 Bandingkan Elektron per kulit semua unsur →

Pengenal

Nomor CAS
7440-33-7 Bandingkan Nomor CAS semua unsur →
Simbol term
5D0
InChI
InChI=1S/W
Kunci InChI
WFKWXMTUELFFGS-UHFFFAOYSA-N

Konfigurasi Elektron Diukur

Muatan ion
Proton 74
Elektron 74
Muatan Netral
Konfigurasi W: 4f¹⁴ 5d⁴ 6s²
Konfigurasi elektron
Diukur
[Xe] 4f¹⁴ 5d⁴ 6s²
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d⁴ 6s²
Diagram orbital
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
2/2
4d
10/10
5p
6/6
6s
2/2
4f
14/14
5d
4/10 4↑
Total elektron: 74 Tidak berpasangan: 4 ?

Model atom

Proton 74
Neutron 103
Elektron 74
Nomor massa 177
Kestabilan Radioaktif

Isotop mengubah jumlah neutron, massa, dan kestabilan — bukan konfigurasi elektron atom netral.

Model atom skematis, tidak sesuai skala.

Sidik Jari Atom

Spektrum Emisi / Absorpsi

25 / 50 (50 50 dengan intensitas)
Diukur
Emisi Tampak: 380–750 nm

Distribusi Isotop

Tidak memiliki isotop stabil.

Nomor massaMassa atom (u)Kelimpahan alamiWaktu paruh
183 Radioaktif182,95022275 ± 0,000000914,3100%670 Ey
161 Radioaktif160,9672 ± 0,00021Tidak tersedia409 ms
157 Radioaktif156,97884 ± 0,00043Tidak tersedia275 ms
177 Radioaktif176,946643 ± 0,00003Tidak tersedia132.4 menit
181 Radioaktif180,9481978 ± 0,0000051Tidak tersedia120.956 hari
Diukur

Fase / Wujud

1 atm / 101.325 kPa
Padat 25 °C (298,15 K)

Alasan: 3396,8 °C di bawah titik lebur (3421,85 °C)

Titik lebur 3421,85 °C
Titik didih 5554,85 °C
Di bawah titik lebur sebesar 3396,8 °C
0 K Suhu saat ini: 25 °C 6000 K
Linimasa fase

Skematis, tidak sesuai skala

Padat
Cair
Gas
Peleburan
Pendidihan
25°C
Padat
Cair
Gas
Saat ini

Titik transisi fase

Titik lebur Literatur
3421,85 °C
Titik didih Literatur
5554,85 °C
Fase saat ini Dihitung
Padat

Energi transisi

Kalor peleburan Literatur
0,36482355 eV

Energi yang diperlukan untuk meleburkan 1 mol pada titik lebur

Kalor penguapan Literatur
8,360885 eV

Energi yang diperlukan untuk menguapkan 1 mol pada titik didih

Kalor sublimasi Literatur
8,803441 eV

Energi yang diperlukan untuk menyublimkan 1 mol pada titik sublimasi

Massa jenis

Massa jenis referensi Literatur
1,93e+4 kg/m³

Pada kondisi standar

Massa jenis saat ini Dihitung
1,93e+4 kg/m³

Pada kondisi standar

Spektrum Atom

Menampilkan 10 dari 74. Diurutkan berdasarkan muatan ion (menaik).

Data Garis Spektrum ?

IonMuatanTotal garisProbabilitas transisiPenamaan tingkat energi
W I 070495225852
W II +128382112838
W III +22644372644
W IV +37910791
W V +41930193
W VI +517017
W VII +63970397
W VIII +7193187193
Data Garis Spektrum NIST →

Data Tingkat Energi ?

IonMuatanTingkat energi
W I 0509
W II +1264
W III +2236
W IV +3106
W V +460
W VI +515
W VII +6113
W VIII +7103
W IX +83
W X +92
Data Tingkat Energi NIST →
74 W 183.84

Tungsten — Visualisasi Orbital Atom

[Xe]6s24f145d4
Tingkat energi 2 8 18 32 12 2
Bilangan oksidasi -4, -2, -1, 0, +1, +2, +3, +4, +5, +6
HOMO 5d n=5 · l=2 · m=-2
Tungsten — Pratinjau Visualisasi Orbital Atom
Three.js hanya dimuat saat diminta
74 W 183.84

Tungsten — Visualisasi Struktur Kristal

Kubik Berpusat Badan · Pearson cI2
Eksperimental
Pearson cI2
No. Koord. 8
Pengemasan 68.000%
Tungsten — Pratinjau Visualisasi Struktur Kristal
Three.js hanya dimuat saat diminta

Jari-jari Ion

MuatanKoordinasiSpinJari-jari
+46Tidak tersedia66 pm
+56Tidak tersedia62 pm
+64Tidak tersedia42 pm
+65Tidak tersedia51 pm
+66Tidak tersedia60 pm

Senyawa

W
183,840 u
W
184,953 u
W
180,948 u
W
187,958 u
W
177,946 u
W
179,947 u
W
181,948 u
W
182,950 u
W
186,957 u
W
178,947 u
W
175,946 u
W
176,947 u
W
185,954 u
W
183,951 u
W+2
183,840 u

Isotop (5)

Nomor massaMassa atom (u)Kelimpahan alamiWaktu paruhMode peluruhan
183 Radioaktif182,95022275 ± 0,000000914,3100% ± 0,0400%670 Ey
IS =14.31±0.4%α ?
161 Radioaktif160,9672 ± 0,00021Tidak tersedia409 ms
α =73±0.3%β+ =27±0.3%
157 Radioaktif156,97884 ± 0,00043Tidak tersedia275 ms
β+ =100%α =0%
177 Radioaktif176,946643 ± 0,00003Tidak tersedia132.4 menit
β+ =100%
181 Radioaktif180,9481978 ± 0,0000051Tidak tersedia120.956 hari
ε =100%
183 Radioaktif
Massa atom (u) 182,95022275 ± 0,0000009
Kelimpahan alami 14,3100% ± 0,0400%
Waktu paruh 670 Ey
Mode peluruhan
IS =14.31±0.4%α ?
161 Radioaktif
Massa atom (u) 160,9672 ± 0,00021
Kelimpahan alami Tidak tersedia
Waktu paruh 409 ms
Mode peluruhan
α =73±0.3%β+ =27±0.3%
157 Radioaktif
Massa atom (u) 156,97884 ± 0,00043
Kelimpahan alami Tidak tersedia
Waktu paruh 275 ms
Mode peluruhan
β+ =100%α =0%
177 Radioaktif
Massa atom (u) 176,946643 ± 0,00003
Kelimpahan alami Tidak tersedia
Waktu paruh 132.4 menit
Mode peluruhan
β+ =100%
181 Radioaktif
Massa atom (u) 180,9481978 ± 0,0000051
Kelimpahan alami Tidak tersedia
Waktu paruh 120.956 hari
Mode peluruhan
ε =100%

Garis Spektrum

Menampilkan 50 dari 2460. Secara bawaan, hanya garis spektrum dengan intensitas terukur yang ditampilkan.

Panjang gelombang (nm)IntensitasTahap ionisasiJenisTransisiAkurasiSumber
400.8749 nm1000W Iemission5d5.(6S).6s 7S → 5d5.(6S).6p 7P*DiukurNIST
429.4605 nm800W Iemission5d5.(6S).6s 7S → 5d5.(6S).6p 7P*DiukurNIST
386.7982 nm600W Iemission5d5.(6S).6s 7S → 5d4.6s.(6D).6p 7D*DiukurNIST
407.4357 nm600W Iemission5d5.(6S).6s 7S → 5d5.(6S).6p 7P*DiukurNIST
381.7484 nm400W Iemission5d5.(6S).6s 7S → 5d4.6s.(6D).6p 5F*DiukurNIST
484.381 nm400W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 7D*DiukurNIST
505.328 nm400W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 7D*DiukurNIST
384.6213 nm300W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 5F*DiukurNIST
525.9338 nm300W Iemission5d5.(6S).6p 7P* → 5d4.6s.(6D).7s 7DDiukurNIST
551.4684 nm300W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 7D*DiukurNIST
383.5052 nm250W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 5P*DiukurNIST
388.1394 nm250W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 5P*DiukurNIST
522.4661 nm250W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 7D*DiukurNIST
524.2973 nm250W Iemission5d4.6s2 3G → *DiukurNIST
424.4367 nm200W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 7D*DiukurNIST
426.9384 nm200W Iemission5d5.(6S).6s 7S → *DiukurNIST
430.2103 nm200W Iemission5d5.(6S).6s 7S → 5d4.6s.(6D).6p 7D*DiukurNIST
488.6902 nm200W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 7F*DiukurNIST
498.2586 nm200W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 7F*DiukurNIST
380.9234 nm150W Iemission5d5.(6S).6s 7S → 5d4.6s.(6D).6p 5D*DiukurNIST
384.749 nm150W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 5F*DiukurNIST
505.4594 nm150W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 7F*DiukurNIST
507.1736 nm150W Iemission5d4.6s.(6D).6p 7F* → 5d4.6s.(6D).7s 7DDiukurNIST
523.352 nm150W Iemission5d4.6s2 3P2 → *DiukurNIST
527.5538 nm150W Iemission5d5.(4G).6s 5G → *DiukurNIST
549.2315 nm150W Iemission5d4.6s.(6D).6p 7D* → 5d4.6s.(6D).7s 7DDiukurNIST
381.0796 nm120W Iemission5d4.6s2 3F2 → *DiukurNIST
506.9123 nm120W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 7F*DiukurNIST
525.5401 nm120W Iemission5d5.(4D).6s 5D → *DiukurNIST
434.811303 nm109W IIemission5d4.(5D).6s 4DDiukurNIST
381.0385 nm100W Iemission5d5.(4G).6s 5G → *DiukurNIST
401.5216 nm100W Iemission5d5.(4G).6s 5G → *DiukurNIST
404.56 nm100W Iemission5d5.(6S).6s 7S → 5d4.6s.(6D).6p 5F*DiukurNIST
410.2701 nm100W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 5P*DiukurNIST
424.1444 nm100W Iemission5d4.6s2 3D → *DiukurNIST
427.4553 nm100W Iemission5d4.6s.(6D).6p 7F* → 5d4.6s.(6D).7s 7DDiukurNIST
525.4544 nm100W Iemission5d4.6s2 3D → *DiukurNIST
526.3195 nm100W Iemission5d5.(4D).6s 5D → *DiukurNIST
526.9315 nm100W Iemission5d4.6s2 3F2 → *DiukurNIST
543.5042 nm100W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 7F*DiukurNIST
395.105951 nm91W IIemission5d4.(5D).6s 4D → 5d3.(4F).6s.(5F).6p 6G*DiukurNIST
406.9948 nm80W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 5P*DiukurNIST
413.7464 nm80W Iemission5d4.6s2 5D → 5d5.(6S).6p 7P*DiukurNIST
421.9375 nm80W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 5D*DiukurNIST
425.9363 nm80W Iemission5d4.6s.(6D).6p 7F* → 5d4.6s.(6D).7s 7DDiukurNIST
468.0513 nm80W Iemission5d4.6s2 5D → 5d4.6s.(6D).6p 7D*DiukurNIST
498.6924 nm80W Iemission5d4.6s2 3H → *DiukurNIST
526.8545 nm80W Iemission5d4.6s2 3F2 → *DiukurNIST
547.7798 nm80W Iemission5d4.6s2 3P2 → 5d4.6s.(6D).6p 5D*DiukurNIST
667.838 nm80W Iemission5d5.(4G).6s 5G → *DiukurNIST

Sifat Lanjutan

Jari-jari Kovalen (Lanjutan)

Jari-jari kovalen (Pyykkö)
137 pm
Jari-jari kovalen (Pyykkö, ikatan rangkap dua)
120 pm
Jari-jari kovalen (Pyykkö, ikatan rangkap tiga)
115 pm

Jari-jari van der Waals

Batsanov
210 pm
Alvarez
257 pm
UFF
309,6 pm
MM3
239 pm

Jari-jari Atom & Logam

Jari-jari atom (Rahm)
253 pm
Jari-jari logam (C12)
139 pm

Skala Penomoran

Mendeleev
53
Pettifor
56
Glawe
57

Skala Keelektronegatifan

Ghosh
0
Miedema
5
Gunnarsson–Lundqvist
6
Robles–Bartolotti
5

Polarizabilitas & Dispersi

Polarizabilitas dipol
68 a.u.
Polarizabilitas dipol (ketidakpastian)
15 a.u.
C₆ (Gould–Bučko)
757 Ha·Bohr6

Parameter Miedema

Volume molar Miedema
9,55 cm3/mol
Kerapatan elektron Miedema
6

Risiko Pasokan & Ekonomi

Konsentrasi produksi
84
Risiko pasokan relatif
10
Distribusi cadangan
61
Stabilitas politik (produsen terbesar)
24
Stabilitas politik (pemilik cadangan terbesar)
24

Transisi Fase & Alotrop

Titik lebur3687,15 K
Titik didih5828,15 K

Kategori Bilangan Oksidasi

+2 extended
+4 main
−4 extended
+5 extended
0 extended
+6 main
+3 extended
−1 extended
−2 extended
+1 extended

Data Referensi Lanjutan

Konstanta Pemerisaian (14)
nOrbitalσ
1s1,4343
2p4,4258
2s19,3302
3d13,5476
3p21,3824
3s22,13
4d36,8268
4f39,2892
4p34,4516
4s33,4412
Detail Jari-jari Kristal (5)
MuatanCNSpinrcrystal (pm)Asal
4VI80from r^3 vs V plots, from metallic oxides,
5VI76from r^3 vs V plots,
6IV56
6V65
6VI74
Mode Peluruhan Isotop (54)
IsotopModeIntensitas
157B+100%
157A0%
158A100%
159A100%
159B+—
160A87%
160B+—
161A73%
161B+27%
162B+—
Faktor Hamburan Sinar-X (541)
Energi (eV)f₁f₂
10—1,92551
10,1617—2,00949
10,3261—2,09714
10,4931—2,18428
10,6628—2,26758
10,8353—2,35405
11,0105—2,44381
11,1886—2,537
11,3696—2,63375
11,5535—2,73418

Data Tambahan

Referensi

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
W

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Tungsten

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

Catatan lisensi: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Tungsten

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

Catatan lisensi: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Tungsten

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Tungsten

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Tungsten

This section provides all form of data related to element Tungsten.

9 PubChem Elements
Tungsten

The element property data was retrieved from publications.

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