← Kembali ke Tabel Periodik
Rh 45

Rhodium (Rh)

transition-metal
Periode: 5 Golongan: 9 Blok: d

Solid

Bobot Atom Standar

102,9055 u

Konfigurasi elektron

[Kr] 5s1 4d8

Titik lebur

1963,85 °C

Titik didih

3694,85 °C

Massa jenis

1,24e+4 kg/m³

Bilangan oksidasi

−3, −1, +1, +2, +3, +4, +5, +6, +7

Keelektronegatifan (Pauling)

2,28

Energi ionisasi (ke-1)

7,4589 eV

Tahun penemuan

1803

Jari-jari atom

135 pm

Detail

Asal nama Greek: rhodon (rose). Its salts give a rosy solution.
Negara penemuan England
Penemu William Wollaston

Rhodium is a very rare platinum-group transition metal. It is chemically noble, hard, highly reflective, and most often encountered in nature alloyed with platinum, palladium, and other platinum-group elements. Its industrial importance is dominated by catalysis, especially control of nitrogen oxides in automotive exhaust. Rhodium also forms stable coordination compounds, commonly with Rh(I) and Rh(III), that are important in homogeneous catalysis and organometallic chemistry.

The metal is silvery white and at red heat slowly changes in air to the resquioxide. At higher temperatures it converts back to the element. Rhodium has a higher melting point and lower density than platinum. It is highly reflective, hard, and durable.

The name derives from the Greek rhodon for rose because of the rose color of dilute solutions of its salts. It was discovered by the English chemist and physicist William Hyde Wollaston in 1803 in a crude platinum ore.

Rhodium was discovered by William Hyde Wollaston, an English chemist, in 1803 shortly after his discovery of the element palladium. He obtained rhodium from a sample of platinum ore that was obtained from South America. After removing the platinum and palladium from the sample, he was left with a dark red powder. The powder turned out to be sodium rhodium chloride (Na3RhCl6·12H2O). Wollaston obtained rhodium from the powder by treating it with hydrogen gas (H2). Rhodium tends to occur along with deposits of platinum and is primarily obtained as a byproduct of mining and refining platinum. Rhodium is also obtained as a byproduct of the nickel mining operation in the Sudbury region of Ontario, Canada.

From the Greek word rhodon, rose. Wollaston discovered rhodium between 1803 and 1804 in crude platinum ore he presumably obtained from South America.

Gambar

Sifat

Fisika

Jari-jari atom (empiris)
135 pm Bandingkan Jari-jari atom (empiris) semua unsur →
Jari-jari kovalen
142 pm Bandingkan Jari-jari kovalen semua unsur →
Jari-jari van der Waals
195 pm Bandingkan Jari-jari van der Waals semua unsur →
Jari-jari logam
125 pm Bandingkan Jari-jari logam semua unsur →
Massa jenis
1,24 × 104 kg/m³ Bandingkan Massa jenis semua unsur →
Volume molar
0,0083 L/mol
Fase pada STP
Padat Bandingkan Fase pada STP semua unsur →
Titik lebur
1963,85 °C Bandingkan Titik lebur semua unsur →
Titik didih
3694,85 °C Bandingkan Titik didih semua unsur →
Konduktivitas termal
150 W/(m·K) Bandingkan Konduktivitas termal semua unsur →
Kapasitas kalor spesifik
0,243 J/(g·K) Bandingkan Kapasitas kalor spesifik semua unsur →
Kapasitas kalor molar
24,98 J/(mol·K) Bandingkan Kapasitas kalor molar semua unsur →
Struktur kristal
Kubik berpusat muka Bandingkan Struktur kristal semua unsur →

Kimia

Keelektronegatifan (Pauling)
2,28 Bandingkan Keelektronegatifan (Pauling) semua unsur →
Keelektronegatifan (Allen)
1,56
Afinitas elektron
1,137 eV
Energi ionisasi (ke-1)
7,4589 eV Bandingkan Energi ionisasi (ke-1) semua unsur →
Energi ionisasi (ke-2)
18,080062 eV Bandingkan Energi ionisasi (ke-2) semua unsur →
Energi ionisasi (ke-3)
31,060107 eV Bandingkan Energi ionisasi (ke-3) semua unsur →
Energi ionisasi (ke-4)
42,000145 eV Bandingkan Energi ionisasi (ke-4) semua unsur →
Energi ionisasi (ke-5)
63,000217 eV Bandingkan Energi ionisasi (ke-5) semua unsur →
Bilangan oksidasi
−3, −1, +1, +2, +3, +4, +5, +6, +7 Bandingkan Bilangan oksidasi semua unsur →
Elektron valensi
9 Bandingkan Elektron valensi semua unsur →
Konfigurasi elektron
[Kr] 5s1 4d8

Termodinamika

Kalor peleburan
0,22490543 eV Bandingkan Kalor peleburan semua unsur →
Kalor penguapan
5,119967 eV Bandingkan Kalor penguapan semua unsur →
Kalor sublimasi
5,762554 eV
Kalor atomisasi
5,762554 eV
Entalpi atomisasi
5,762554 eV

Nuklir

Proton
45 Bandingkan Proton semua unsur →
Neutron
58 Bandingkan Neutron semua unsur →
Isotop yang diketahui
41 Bandingkan Isotop yang diketahui semua unsur →
Isotop stabil
1 Bandingkan Isotop stabil semua unsur →
Isotop paling stabil
Rh-103
Tahun penemuan
1803

Kelimpahan

Kelimpahan (kerak Bumi)
0,001 mg/kg Bandingkan Kelimpahan (kerak Bumi) semua unsur →

Struktur Kristal

Konstanta kisi a
380 pm

Struktur Elektronik

Elektron per kulit
2, 8, 18, 16, 1 Bandingkan Elektron per kulit semua unsur →

Pengenal

Nomor CAS
7440-16-6 Bandingkan Nomor CAS semua unsur →
Simbol term
4F9/2
InChI
InChI=1S/Rh
Kunci InChI
MHOVAHRLVXNVSD-UHFFFAOYSA-N

Konfigurasi Elektron Diukur

Muatan ion
Proton 45
Elektron 45
Muatan Netral
Konfigurasi Rh: 4d⁸ 5s¹
Konfigurasi elektron
Diukur
[Kr] 4d⁸ 5s¹
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d⁸ 5s¹
Diagram orbital
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
1/2 1↑
4d
8/10 2↑
Total elektron: 45 Tidak berpasangan: 3 ?

Model atom

Proton 45
Neutron 58
Elektron 45
Nomor massa 103
Kestabilan Stabil

Isotop mengubah jumlah neutron, massa, dan kestabilan — bukan konfigurasi elektron atom netral.

Model atom skematis, tidak sesuai skala.

Sidik Jari Atom

Spektrum Emisi / Absorpsi

25 / 50 (50 50 dengan intensitas)
Diukur
Emisi Tampak: 380–750 nm

Distribusi Isotop

Unsur monoisotopik
Satu-satunya isotop yang terdapat di alam: 103 — 100,0000%
103100,0000%Nomor massaKelimpahan alami (%)
Nomor massaMassa atom (u)Kelimpahan alamiWaktu paruh
103 Stabil102,905498 ± 0,0000026100,0000%Stabil
Diukur

Fase / Wujud

1 atm / 101.325 kPa
Padat 25 °C (298,15 K)

Alasan: 1938,8 °C di bawah titik lebur (1963,85 °C)

Titik lebur 1963,85 °C
Titik didih 3694,85 °C
Di bawah titik lebur sebesar 1938,8 °C
0 K Suhu saat ini: 25 °C 6000 K
Linimasa fase

Skematis, tidak sesuai skala

Padat
Cair
Gas
Peleburan
Pendidihan
25°C
Padat
Cair
Gas
Saat ini

Titik transisi fase

Titik lebur Literatur
1963,85 °C
Titik didih Literatur
3694,85 °C
Fase saat ini Dihitung
Padat

Energi transisi

Kalor peleburan Literatur
0,22490543 eV

Energi yang diperlukan untuk meleburkan 1 mol pada titik lebur

Kalor penguapan Literatur
5,119967 eV

Energi yang diperlukan untuk menguapkan 1 mol pada titik didih

Kalor sublimasi Literatur
5,762554 eV

Energi yang diperlukan untuk menyublimkan 1 mol pada titik sublimasi

Massa jenis

Massa jenis referensi Literatur
1,24e+4 kg/m³

Pada kondisi standar

Massa jenis saat ini Dihitung
1,24e+4 kg/m³

Pada kondisi standar

Spektrum Atom

Menampilkan 10 dari 45. Diurutkan berdasarkan muatan ion (menaik).

Data Garis Spektrum ?

IonMuatanTotal garisProbabilitas transisiPenamaan tingkat energi
Rh I 0468111443
Rh II +134031
Rh III +27300
Data Garis Spektrum NIST →

Data Tingkat Energi ?

IonMuatanTingkat energi
Rh I 0138
Rh II +1126
Rh III +2196
Rh IV +32
Rh V +42
Rh VI +52
Rh VII +62
Rh VIII +72
Rh IX +82
Rh X +92
Data Tingkat Energi NIST →
45 Rh 102.9055

Rhodium — Visualisasi Orbital Atom

[Kr]5s14d8
Tingkat energi 2 8 18 16 1
Bilangan oksidasi -3, -1, +1, +2, +3, +4, +5, +6, +7
HOMO 5s n=5 · l=0 · m=0
Rhodium — Pratinjau Visualisasi Orbital Atom
Three.js hanya dimuat saat diminta
45 Rh 102.9055

Rhodium — Visualisasi Struktur Kristal

Face-Centered Cubic · Pearson cF4
Eksperimental
Pearson cF4
No. Koord. 12
Pengemasan 74.000%
Rhodium — Pratinjau Visualisasi Struktur Kristal
Three.js hanya dimuat saat diminta

Jari-jari Ion

MuatanKoordinasiSpinJari-jari
+36Tidak tersedia66.5 pm
+46Tidak tersedia60 pm
+56Tidak tersedia55.00000000000001 pm

Senyawa

Rh
102,906 u
Rh+3
102,906 u
Rh+2
102,906 u
Rh
105,907 u
Rh
104,906 u
Rh
101,907 u
Rh
98,908 u
Rh
99,908 u
Rh
100,906 u
Rh
106,907 u
Rh
102,905 u
Rh
103,907 u

Isotop (1)

Nomor massaMassa atom (u)Kelimpahan alamiWaktu paruhMode peluruhan
103 Stabil102,905498 ± 0,0000026100,0000%Stabil
stable
103 Stabil
Massa atom (u) 102,905498 ± 0,0000026
Kelimpahan alami 100,0000%
Waktu paruh Stabil
Mode peluruhan
stable

Garis Spektrum

Menampilkan 50 dari 186. Secara bawaan, hanya garis spektrum dengan intensitas terukur yang ditampilkan.

Panjang gelombang (nm)IntensitasTahap ionisasiJenisTransisiAkurasiSumber
385.6513 nm5900Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 2G*DiukurNIST
437.4809 nm4200Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 4G*DiukurNIST
382.226 nm3800Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 2F*DiukurNIST
395.8856 nm3800Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 2G*DiukurNIST
421.1133 nm3300Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 4F*DiukurNIST
382.8478 nm2300Rh Iemission4d8.(3P).5s a 4P → 4d8.(3P).5p z 4P*DiukurNIST
413.5275 nm2100Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 4F*DiukurNIST
383.3884 nm2000Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 2D*DiukurNIST
393.4224 nm2000Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 4G*DiukurNIST
412.8886 nm1500Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 2F*DiukurNIST
380.6759 nm1300Rh Iemission4d8.(3F).5s a 4F → 4d8.(3F).5p z 4D*DiukurNIST
381.8186 nm1300Rh Iemission4d8.(3P).5s a 4P → 4d8.(3P).5p z 4P*DiukurNIST
412.1683 nm1100Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 2D*DiukurNIST
428.8702 nm820Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 4G*DiukurNIST
380.592 nm760Rh Iemission4d8.(1D).5s b 2D → 8*DiukurNIST
381.6474 nm760Rh Iemission4d8.(1D).5s b 2D → 4d8.(1D).5p y 2F*DiukurNIST
394.271 nm590Rh Iemission4d8.(3P).5s a 4P → 4d8.(3P).5p z 4P*DiukurNIST
408.278 nm560Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 4F*DiukurNIST
387.0018 nm490Rh Iemission4d8.(1G).5s a 2G → 12*DiukurNIST
381.5021 nm470Rh Iemission4d8.(1G).5s a 2G → 13*DiukurNIST
387.7346 nm380Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 4F*DiukurNIST
397.5313 nm380Rh Iemission4d8.(1D).5s b 2D → 4*DiukurNIST
399.6149 nm380Rh Iemission4d8.(3P).5s a 2P → 4d8.(3P).5p y 4D*DiukurNIST
419.6496 nm330Rh Iemission4d8.(3P).5s a 4P → 4d8.(3F).5p z 2G*DiukurNIST
392.2195 nm240Rh Iemission4d9 a 2D → 4d8.(3F).5p z 4D*DiukurNIST
398.4393 nm240Rh Iemission4d8.(3P).5s a 4P → 4d8.(3P).5p z 4P*DiukurNIST
399.5602 nm240Rh Iemission4d8.(3P).5s a 4P → 4d8.(3P).5p z 4P*DiukurNIST
415.4343 nm240Rh Iemission4d7.5s2 b 4F → 4d8.(3P).5p y 4D*DiukurNIST
559.9419 nm160Rh Iemission4d8.(3P).5s a 4P → 4d8.(3F).5p z 4D*DiukurNIST
467.5022 nm150Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 4D*DiukurNIST
409.7508 nm140Rh Iemission4d8.(3P).5s a 4P → 4d8.(3P).5p z 4P*DiukurNIST
456.8993 nm130Rh Iemission4d8.(3P).5s a 4P → 4d8.(3F).5p z 4G*DiukurNIST
535.4428 nm130Rh Iemission4d8.(3F).5p z 2G* → 16DiukurNIST
598.3575 nm130Rh Iemission4d7.5s2 b 4F → 4d8.(3F).5p z 4F*DiukurNIST
391.3508 nm120Rh Iemission4d8.(3F).5s a 4F → 4d8.(3F).5p z 4D*DiukurNIST
402.3139 nm120Rh Iemission4d8.(1D).5s b 2D → 4d8.(1D).5p y 2P*DiukurNIST
411.9679 nm120Rh Iemission4d8.(1G).5s a 2G → 4d8.(1D).5p y 2F*DiukurNIST
381.2462 nm95Rh Iemission4d8.(1D).5s b 2D → 4d8.(3P).5p z 2S*DiukurNIST
395.8233 nm95Rh Iemission4d8.(3P).5s a 2P → 4d8.(1D).5p y 2P*DiukurNIST
437.9911 nm95Rh Iemission4d8.(3P).5s a 4P → 4d8.(3F).5p z 2D*DiukurNIST
519.313 nm95Rh Iemission4d8.(3F).5p z 4G* → 2DiukurNIST
539.0433 nm95Rh Iemission4d8.(3P).5s a 4P → 4d8.(3F).5p z 4D*DiukurNIST
387.239 nm70Rh Iemission4d9 a 2D → 4d8.(3F).5p z 4F*DiukurNIST
388.8331 nm70Rh Iemission4d8.(1D).5s b 2D → 4d8.(1D).5p y 2P*DiukurNIST
407.758 nm70Rh Iemission4d8.(1D).5s b 2D → 4d8.(3P).5p y 4D*DiukurNIST
411.6329 nm70Rh Iemission4d8.(1D).5s b 2D → 4*DiukurNIST
420.6613 nm70Rh Iemission4d9 a 2D → 4d8.(3F).5p z 4D*DiukurNIST
429.6763 nm70Rh Iemission4d8.(1D).5s b 2D → 4d8.(3P).5p y 4D*DiukurNIST
474.5116 nm70Rh Iemission4d8.(3F).5s a 2F → 4d8.(3F).5p z 4D*DiukurNIST
509.064 nm70Rh Iemission4d8.(3P).5s a 4P → 4d8.(3F).5p z 4D*DiukurNIST

Sifat Lanjutan

Jari-jari Kovalen (Lanjutan)

Jari-jari kovalen (Pyykkö)
125 pm
Jari-jari kovalen (Pyykkö, ikatan rangkap dua)
110 pm
Jari-jari kovalen (Pyykkö, ikatan rangkap tiga)
106 pm

Jari-jari van der Waals

Batsanov
200 pm
Alvarez
244 pm
UFF
292,9 pm
MM3
234 pm

Jari-jari Atom & Logam

Jari-jari atom (Rahm)
233 pm
Jari-jari logam (C12)
134 pm

Skala Penomoran

Mendeleev
64
Pettifor
66
Glawe
63

Skala Keelektronegatifan

Ghosh
0
Miedema
5
Gunnarsson–Lundqvist
4
Robles–Bartolotti
3

Polarizabilitas & Dispersi

Polarizabilitas dipol
66 a.u.
Polarizabilitas dipol (ketidakpastian)
10 a.u.
C₆ (Gould–Bučko)
708 Ha·Bohr6

Afinitas Kimia

Afinitas proton
768 kJ/mol
Kebasaan fase gas
745,4 kJ/mol

Parameter Miedema

Volume molar Miedema
8,3 cm3/mol
Kerapatan elektron Miedema
5

Risiko Pasokan & Ekonomi

Konsentrasi produksi
60
Risiko pasokan relatif
8
Distribusi cadangan
95
Stabilitas politik (produsen terbesar)
44
Stabilitas politik (pemilik cadangan terbesar)
44

Transisi Fase & Alotrop

Titik lebur2236,15 K
Titik didih3968,15 K

Kategori Bilangan Oksidasi

−1 extended
+2 extended
+6 extended
−3 extended
+4 extended
+3 main
+1 extended
+5 extended
+7 extended

Data Referensi Lanjutan

Konstanta Pemerisaian (10)
nOrbitalσ
1s0,9244
2p4,0596
2s11,8454
3d14,595
3p16,8456
3s16,5615
4d31,5576
4p27,8604
4s26,4184
5s38,3605
Detail Jari-jari Kristal (3)
MuatanCNSpinrcrystal (pm)Asal
3VI80,5from r^3 vs V plots,
4VI74from r^3 vs V plots, from metallic oxides,
5VI69
Mode Peluruhan Isotop (72)
IsotopModeIntensitas
88B+—
89B+—
89B+p—
89p—
90B+100%
90B+p0,7%
91B+100%
91B+p1,3%
92B+100%
92B+p2%
Faktor Hamburan Sinar-X (508)
Energi (eV)f₁f₂
10—1,17537
10,1617—1,24044
10,3261—1,30912
10,4931—1,3816
10,6628—1,4581
10,8353—1,53883
11,0106—1,62403
11,1886—1,71394
11,3696—1,80884
11,5535—1,90899

Data Tambahan

Sources

Sources of this element.

Rhodium occurs natively with other platinum metals in river sands of the Urals and in North and South America. It is also found with other platinum metals in the copper-nickel sulfide area of the Sudbury, Ontario region. Although the quantity occurring there is very small, the large tonnages of nickel processed make the recovery commercially feasible. The annual world production of rhodium is only 7 or 8 tons.

Referensi (1)

Referensi

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
Rh

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Rhodium

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

Catatan lisensi: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Rhodium

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

Catatan lisensi: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Rhodium

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Rhodium

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Rhodium

This section provides all form of data related to element Rhodium.

9 PubChem Elements
Rhodium

The element property data was retrieved from publications.

Terakhir diperbarui:

Data terverifikasi:

Konten ditinjau berdasarkan data ilmiah terbaru.