Nobelium (No)
actinideSolid
Bobot Atom Standar
[259]Konfigurasi elektron
[Rn] 7s2 5f14Titik lebur
826,85 °CTitik didih
Tidak tersediaMassa jenis
9900 kg/m³Bilangan oksidasi
+2, +3Keelektronegatifan (Pauling)
1,3Energi ionisasi (ke-1)
6,62621 eVTahun penemuan
1957Jari-jari atom
Tidak tersediaDetail
Nobelium is a synthetic actinide with atomic number 102. It is produced only in particle-accelerator experiments and is studied in atom-at-a-time quantities. Its longest-lived confirmed isotopes have half-lives of only minutes, so no macroscopic sample or ordinary material application exists. Chemically, nobelium is notable because the +2 oxidation state is unusually stable for an actinide, in contrast to the more common +3 state of many neighboring elements.
Nobelium does not occur naturally in the Earth’s crust. It was first synthesized in 1966 by Russian scientists from the Joint Institute for Nuclear Research (JINR) in Dubna, Russia under Georgi Flerov. Earlier claims to have synthesized “nobelium” beginning in 1957 were shown to be erroneous. This element was originally named for Alfred Nobel (Fig. IUPAC.102.1), the inventor of dynamite and founder of the Nobel prizes. The name was later retained because of its widespread use throughout the scientific literature [636], [638]. There are no uses for isotopes of nobelium outside of scientific research.
Nobelium is named after Alfred Nobel.
In 1957, a group of scientists working at the Nobel Institute of Physics in Stockhlom, Sweden, announced the discovery of a new element. They produced this new element, which they named nobelium, by bombarding a target of curium-244 with ions of carbon-13 with a device called a cyclotron. The isotope they created had a half-life of 10 minutes. In 1958, another group of scientists, Albert Ghiorso, Glenn T. Seaborg, Torbørn Sikkeland and John R. Walton, working at the Lawrence Radiation Laboratory in Berkeley, California, attempted to confirm the Nobel Institute's discovery. They were unable to produce any isotope of nobelium with a half-life of 10 minutes, but were able to produce nobelium-254, with a half-life of three seconds, by bombarding curium-246 with carbon-12. A third group, working at the Joint Institute for Nuclear Research in Dubna, Russia, also could not duplicate the Nobel Institute's work but were able to confirm the Berkeley group's work. Credit for discovering nobelium was eventually given to the scientists working at Lawrence Radiation Laboratory, who decided to keep the name nobelium. Today, the Lawrence Radiation Laboratory is known as the Lawrence Berkeley Laboratory. Nobelium's most stable isotope, nobelium-259, has a half-life of about 58 minutes. It decays into fermium-255 through alpha decay, into mendelevium-259 through electron capture or through spontaneous fission.
Named after Alfred Nobel, inventor of dynamite. Nobelium was unambiguously discovered and identified in April 1958 at Berkeley by A. Ghiorso, T. Sikkeland, J.R. Walton, and G.T. Seaborg, who used a new double-recoil technique. A heavy-ion linear accelerator (HILAC) was used to bombard a thin target of curium (95%244Cm and 4.5% 246Cm) with 12C ions to produce 102No according to the 246Cm(12C, 4n) reaction.
In 1957 workers in the United States, Britain, and Sweden announced the discovery of an isotope of element 102 with a 10-minute half-life at 8.5 MeV, as a result of bombarding 244Cm with 13C nuclei. On the basis of this experiment, the name nobelium was assigned and accepted by the Commission on Atomic Weights of the International Union of Pure and Applied Chemistry.
The acceptance of the name was premature because both Russian and American efforts now completely rule out the possibility of any isotope of Element 102 having a half-life of 10 min in the vicinity of 8.5 MeV. Early work in 1957 on the search for this element, in Russia at the Kurchatov Institute, was marred by the assignment of 8.9 +/- 0.4 MeV alpha radiation with a half-life of 2 to 40 sec, which was too indefinite to support discovery claims.
Confirmatory experiments at Berkeley in 1966 have shown the existence of 254102 with a 55-s half-life, 252102 with a 2.3-s half-life, and 257102 with a 23-s half-life.
Following tradition giving the right to name an element to the discoverer(s), the Berkeley group in 1967, suggested that the hastily given name nobelium along with the symbol No , be retained.
The bulk appearance of nobelium is unknown, because it has never been isolated as a visible sample. Metallic nobelium is expected to be a dense, silvery actinide metal by analogy with neighboring elements, but this is a prediction rather than an observed property.
Nobelium has no practical use outside scientific research. Individual atoms are produced to study heavy-element nuclear stability, decay chains, and relativistic effects in actinide chemistry. Its isotopes have also served as links in identifying the decay products of heavier synthetic elements. These uses rely on rapid radiochemical separation and radiation detection, not on bulk nobelium metal or compounds.
Since only tiny amounts of nobelium have ever been produced, there are currently no uses for it outside of basic scientific research.
Nobelium chemistry has been examined mainly in aqueous tracer experiments. The divalent ion No²⁺ is the best-established chemically distinctive form and behaves in some separations more like alkaline earth ions than typical trivalent actinides. The trivalent ion No³⁺ is also known, but it is less favored in reducing aqueous systems. Specific bulk compounds such as nobelium(II) chloride, NoCl₂, or nobelium(III) oxide, No₂O₃, have not been isolated as macroscopic materials; their properties are inferred from trace chemistry and theory.
See more information at the Nobelium compound page.
All known nobelium isotopes are radioactive, and several decay by alpha emission or spontaneous fission. The element is made in quantities far too small to create ordinary chemical toxicity hazards outside specialized laboratories, but radiological precautions are essential during production and detection work. Safety considerations are isotope-specific because half-lives and decay modes vary widely.
Nobelium has no confirmed natural environmental reservoir. Any atoms produced on Earth are artificial and decay rapidly compared with geological or ecological timescales. Because only atom-scale amounts are generated in shielded research facilities, nobelium has no known role in biogeochemical cycles and no observed environmental transport behavior as a bulk contaminant.
Nobelium is not a traded commodity and has no commercial supply chain. It is made by bombarding heavy actinide targets, commonly curium or californium isotopes, with accelerated light ions under conditions optimized for a desired isotope. Production yields are extremely small, and separation must occur quickly because of radioactive decay. The limiting factors are accelerator access, rare target materials, radiochemical expertise, and detector time rather than market demand, recycling, or substitution.
Made by bombarding curium with carbon-13
Nobelium is not expected to have a persistent cosmic abundance. Its known isotopes are too short-lived to survive from stellar nucleosynthesis to the present, and no stable isotope is known. If formed transiently in extreme neutron-rich events or by artificial nuclear reactions, nobelium would decay rapidly into lighter nuclei.
- Nobelium was named for Alfred Nobel, the inventor and industrial chemist associated with the Nobel Prizes.
- The isotope ²⁵⁹No is among the longest-lived known nobelium isotopes, with a half-life of about an hour.
- Nobelium helped show that the +2 state can become strongly stabilized late in the actinide series.
- Most nobelium experiments detect decay events from individual atoms rather than weighing a sample.
Gambar
Sifat
Fisika
- Jari-jari van der Waals
- 246 pm Bandingkan Jari-jari van der Waals semua unsur →
- Massa jenis
- 9900 kg/m³ Bandingkan Massa jenis semua unsur →
- Fase pada STP
- Padat Bandingkan Fase pada STP semua unsur →
- Titik lebur
- 826,85 °C Bandingkan Titik lebur semua unsur →
Kimia
- Keelektronegatifan (Pauling)
- 1,3 Bandingkan Keelektronegatifan (Pauling) semua unsur →
- Afinitas elektron
- -2,36 eV (nilai negatif — atom tidak diprediksi mengikat elektron tambahan)
- Energi ionisasi (ke-1)
- 6,62621 eV Bandingkan Energi ionisasi (ke-1) semua unsur →
- Energi ionisasi (ke-2)
- 12,930045 eV Bandingkan Energi ionisasi (ke-2) semua unsur →
- Energi ionisasi (ke-3)
- 25,800089 eV Bandingkan Energi ionisasi (ke-3) semua unsur →
- Energi ionisasi (ke-4)
- 41,500143 eV Bandingkan Energi ionisasi (ke-4) semua unsur →
- Energi ionisasi (ke-5)
- 60,000207 eV Bandingkan Energi ionisasi (ke-5) semua unsur →
- Bilangan oksidasi
- +2, +3 Bandingkan Bilangan oksidasi semua unsur →
- Elektron valensi
- 3 Bandingkan Elektron valensi semua unsur →
- Konfigurasi elektron
- [Rn] 7s2 5f14
Termodinamika
- Kalor sublimasi
- 4,042079 eV
- Kalor atomisasi
- 4,042079 eV
Nuklir
- Proton
- 102 Bandingkan Proton semua unsur →
- Neutron
- 159 Bandingkan Neutron semua unsur →
- Isotop yang diketahui
- 17 Bandingkan Isotop yang diketahui semua unsur →
- Isotop stabil
- 0 Bandingkan Isotop stabil semua unsur →
- Nomor massa (paling stabil)
- 259
- Isotop paling stabil
- No-261
- Tahun penemuan
- 1957
Kelimpahan
Tidak tersedia
Struktur Kristal
Tidak tersedia
Struktur Elektronik
- Elektron per kulit
- 2, 8, 18, 32, 32, 8, 2 Bandingkan Elektron per kulit semua unsur →
Pengenal
- Nomor CAS
- 10028-14-5 Bandingkan Nomor CAS semua unsur →
- Simbol term
- 1S0
- InChI
- InChI=1S/No
- Kunci InChI
- ORQBXQOJMQIAOY-UHFFFAOYSA-N
Konfigurasi Elektron Diukur
No: 5f¹⁴ 7s²[Rn] 5f¹⁴ 7s²1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d¹⁰ 6s² 6p⁶ 5f¹⁴ 7s²Model atom
Isotop mengubah jumlah neutron, massa, dan kestabilan — bukan konfigurasi elektron atom netral.
Model atom skematis, tidak sesuai skala.
Sidik Jari Atom
Spektrum Emisi / Absorpsi
Distribusi Isotop
Tidak memiliki isotop stabil.
| Nomor massa | Massa atom (u) | Kelimpahan alami | Waktu paruh |
|---|---|---|---|
| 251 Radioaktif | 251,08894 ± 0,00012 | Tidak tersedia | 800 ms |
| 260 Radioaktif | 260,10264 ± 0,00022 | Tidak tersedia | 106 ms |
| 259 Radioaktif | 259,10103 ± 0,00011 | Tidak tersedia | 58 menit |
| 249 Radioaktif | 249,0878 ± 0,0003 | Tidak tersedia | 57 us |
| 254 Radioaktif | 254,090956 ± 0,000011 | Tidak tersedia | 51.2 detik |
Fase / Wujud
Alasan: 801,9 °C di bawah titik sublimasi (826,85 °C)
Skematis, tidak sesuai skala
Titik transisi fase
Energi transisi
Energi yang diperlukan untuk menyublimkan 1 mol pada titik sublimasi
Massa jenis
Pada kondisi standar
Pada kondisi standar
Spektrum Atom
Menampilkan 10 dari 102. Diurutkan berdasarkan muatan ion (menaik).
Data Tingkat Energi ?
| Ion | Muatan | Tingkat energi |
|---|---|---|
| No I | 0 | 2 |
| No II | +1 | 2 |
| No III | +2 | 2 |
| No IV | +3 | 2 |
| No V | +4 | 2 |
| No VI | +5 | 2 |
| No VII | +6 | 2 |
| No VIII | +7 | 2 |
| No IX | +8 | 2 |
| No X | +9 | 2 |
Data struktur kristal tidak tersedia
Jari-jari Ion
| Muatan | Koordinasi | Spin | Jari-jari |
|---|---|---|---|
| +2 | 6 | Tidak tersedia | 110.00000000000001 pm |
| +3 | 9 | Tidak tersedia | 108.5 pm |
Senyawa
Isotop (5)
Ten isotopes are now recognized, one of which 255102 has a half-life of 3 minutes.
| Nomor massa | Massa atom (u) | Kelimpahan alami | Waktu paruh | Mode peluruhan | |
|---|---|---|---|---|---|
| 251 Radioaktif | 251,08894 ± 0,00012 | Tidak tersedia | 800 ms | α =83±1.6%β+ ?SF<0.3% | |
| 260 Radioaktif | 260,10264 ± 0,00022 | Tidak tersedia | 106 ms | SF =100% | |
| 259 Radioaktif | 259,10103 ± 0,00011 | Tidak tersedia | 58 menit | α =75±0.4%ε =25±0.4%SF<10% | |
| 249 Radioaktif | 249,0878 ± 0,0003 | Tidak tersedia | 57 us | β+ ?α ? | |
| 254 Radioaktif | 254,090956 ± 0,000011 | Tidak tersedia | 51.2 detik | α =90±0.1%β+ =10±0.1%SF =0.17±0.2% |
Sifat Lanjutan
Jari-jari Kovalen (Lanjutan)
- Jari-jari kovalen (Pyykkö)
- 176 pm
Jari-jari van der Waals
- UFF
- 324,8 pm
Skala Penomoran
- Mendeleev
- 40
- Pettifor
- 35
- Glawe
- 46
Skala Keelektronegatifan
- Ghosh
- 0
Polarizabilitas & Dispersi
- Polarizabilitas dipol
- 110 a.u.
- Polarizabilitas dipol (ketidakpastian)
- 6 a.u.
Transisi Fase & Alotrop
| Titik lebur | 1100,15 K |
Kategori Bilangan Oksidasi
Data Referensi Lanjutan
Detail Jari-jari Kristal (2)
| Muatan | CN | Spin | rcrystal (pm) | Asal |
|---|---|---|---|---|
| 2 | VI | 124 | estimated, | |
| 3 | IX | — | 122,5 |
Mode Peluruhan Isotop (39)
| Isotop | Mode | Intensitas |
|---|---|---|
| 248 | SF | — |
| 249 | B+ | — |
| 249 | A | — |
| 250 | SF | 100% |
| 250 | A | — |
| 250 | B+ | — |
| 251 | A | 83% |
| 251 | B+ | — |
| 251 | SF | 0,3% |
| 252 | A | 67,6% |
Data Tambahan
Estimated Crustal Abundance
The estimated element abundance in the earth's crust.
Not Applicable
Referensi (1)
- [5] Nobelium https://education.jlab.org/itselemental/ele102.html
Estimated Oceanic Abundance
The estimated element abundance in the earth's oceans.
Not Applicable
Referensi (1)
- [5] Nobelium https://education.jlab.org/itselemental/ele102.html
Referensi
(9)
Data deposited in or computed by PubChem
The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.
Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.
The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.
Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/
The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.
The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database
This section provides all form of data related to element Nobelium.
The element property data was retrieved from publications.
